{"id":"https://openalex.org/W4375853183","doi":"https://doi.org/10.1002/ange.202304960","title":"Pnictogen Interactions with Nitrogen Acceptors","display_name":"Pnictogen Interactions with Nitrogen Acceptors","publication_year":2023,"publication_date":"2023-05-08","ids":{"openalex":"https://openalex.org/W4375853183","doi":"https://doi.org/10.1002/ange.202304960"},"language":"en","primary_location":{"id":"doi:10.1002/ange.202304960","doi":"https://doi.org/10.1002/ange.202304960","is_oa":true,"landing_page_url":"https://doi.org/10.1002/ange.202304960","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/ange.202304960","source":{"id":"https://openalex.org/S4210200754","display_name":"Angewandte Chemie","issn_l":"0044-8249","issn":["0044-8249","0932-2140","1521-3757"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":"cc-by-nc","license_id":"https://openalex.org/licenses/cc-by-nc","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"hybrid","oa_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/ange.202304960","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5085556206","display_name":"Binzhou Lin","orcid":"https://orcid.org/0009-0002-0907-5888","observed_orcids":["https://orcid.org/0009-0002-0907-5888"]},"institutions":[{"id":"https://openalex.org/I155781252","display_name":"University of South Carolina","ror":"https://ror.org/02b6qw903","country_code":"US","type":"education","lineage":["https://openalex.org/I155781252"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Binzhou Lin","raw_affiliation_strings":["Department of Chemistry and Biochemistry University of South Carolina Columbia SC 29208 USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry University of South Carolina Columbia SC 29208 USA","institution_ids":["https://openalex.org/I155781252"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100458907","display_name":"Hao Liu","orcid":"https://orcid.org/0009-0003-2313-1425","observed_orcids":["https://orcid.org/0009-0003-2313-1425"]},"institutions":[{"id":"https://openalex.org/I155781252","display_name":"University of South Carolina","ror":"https://ror.org/02b6qw903","country_code":"US","type":"education","lineage":["https://openalex.org/I155781252"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Hao Liu","raw_affiliation_strings":["Department of Chemistry and Biochemistry University of South Carolina Columbia SC 29208 USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry University of South Carolina Columbia SC 29208 USA","institution_ids":["https://openalex.org/I155781252"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5043486985","display_name":"Ishwor Karki","orcid":"https://orcid.org/0000-0001-7187-0968","observed_orcids":["https://orcid.org/0000-0001-7187-0968"]},"institutions":[{"id":"https://openalex.org/I155781252","display_name":"University of South Carolina","ror":"https://ror.org/02b6qw903","country_code":"US","type":"education","lineage":["https://openalex.org/I155781252"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Ishwor Karki","raw_affiliation_strings":["Department of Chemistry and Biochemistry University of South Carolina Columbia SC 29208 USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry University of South Carolina Columbia SC 29208 USA","institution_ids":["https://openalex.org/I155781252"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5033663033","display_name":"Erik C. Vik","orcid":"https://orcid.org/0000-0003-1334-0293","observed_orcids":["https://orcid.org/0000-0003-1334-0293"]},"institutions":[{"id":"https://openalex.org/I155781252","display_name":"University of South Carolina","ror":"https://ror.org/02b6qw903","country_code":"US","type":"education","lineage":["https://openalex.org/I155781252"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Erik C. Vik","raw_affiliation_strings":["Department of Chemistry and Biochemistry University of South Carolina Columbia SC 29208 USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry University of South Carolina Columbia SC 29208 USA","institution_ids":["https://openalex.org/I155781252"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5034938361","display_name":"Mark D. Smith","orcid":"https://orcid.org/0000-0001-6977-7131","observed_orcids":["https://orcid.org/0000-0001-6977-7131"]},"institutions":[{"id":"https://openalex.org/I155781252","display_name":"University of South Carolina","ror":"https://ror.org/02b6qw903","country_code":"US","type":"education","lineage":["https://openalex.org/I155781252"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Mark D. Smith","raw_affiliation_strings":["Department of Chemistry and Biochemistry University of South Carolina Columbia SC 29208 USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry University of South Carolina Columbia SC 29208 USA","institution_ids":["https://openalex.org/I155781252"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5049387891","display_name":"Perry J. Pellechia","orcid":"https://orcid.org/0000-0002-2377-7790","observed_orcids":["https://orcid.org/0000-0002-2377-7790"]},"institutions":[{"id":"https://openalex.org/I155781252","display_name":"University of South Carolina","ror":"https://ror.org/02b6qw903","country_code":"US","type":"education","lineage":["https://openalex.org/I155781252"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Perry J. Pellechia","raw_affiliation_strings":["Department of Chemistry and Biochemistry University of South Carolina Columbia SC 29208 USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry University of South Carolina Columbia SC 29208 USA","institution_ids":["https://openalex.org/I155781252"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5037332577","display_name":"Ken D. Shimizu","orcid":"https://orcid.org/0000-0002-0229-6541","observed_orcids":["https://orcid.org/0000-0002-0229-6541"]},"institutions":[{"id":"https://openalex.org/I155781252","display_name":"University of South Carolina","ror":"https://ror.org/02b6qw903","country_code":"US","type":"education","lineage":["https://openalex.org/I155781252"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Ken D. Shimizu","raw_affiliation_strings":["Department of Chemistry and Biochemistry University of South Carolina  Columbia SC 29208 USA","University of South Carolina, Department of Chemistry & Biochemistry, -, 29208 Columbia, UNITED STATES"],"raw_orcid":"https://orcid.org/0000-0002-0229-6541","affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry University of South Carolina  Columbia SC 29208 USA","institution_ids":["https://openalex.org/I155781252"]},{"raw_affiliation_string":"University of South Carolina, Department of Chemistry & Biochemistry, -, 29208 Columbia, UNITED STATES","institution_ids":["https://openalex.org/I155781252"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5037332577"],"corresponding_institution_ids":["https://openalex.org/I155781252"],"apc_list":{"value":5250,"currency":"USD","value_usd":5250},"apc_paid":{"value":5250,"currency":"USD","value_usd":5250},"fwci":0.5922,"has_fulltext":true,"cited_by_count":6,"citation_normalized_percentile":{"value":0.51537563,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":97},"biblio":{"volume":"135","issue":"28","first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10798","display_name":"Crystallography and molecular interactions","score":0.7973999977111816,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10798","display_name":"Crystallography and molecular interactions","score":0.7973999977111816,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.1581999957561493,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11441","display_name":"Organoboron and organosilicon chemistry","score":0.005200000014156103,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/nitrogen-acceptors","display_name":"nitrogen acceptors","score":0.7829999923706055},{"id":"https://openalex.org/keywords/molecular-rotors","display_name":"molecular rotors","score":0.8220000267028809},{"id":"https://openalex.org/keywords/intramolecular-hydrogen-bonding","display_name":"intramolecular hydrogen bonding","score":0.6919999718666077},{"id":"https://openalex.org/keywords/rotational-barriers","display_name":"rotational barriers","score":0.6370000243186951},{"id":"https://openalex.org/keywords/exsy-nmr","display_name":"EXSY NMR","score":0.8100000023841858},{"id":"https://openalex.org/keywords/electrostatic-potential","display_name":"electrostatic potential","score":0.8410000205039978},{"id":"https://openalex.org/keywords/nbo-analysis","display_name":"natural bond orbital analysis","score":0.6499999761581421},{"id":"https://openalex.org/keywords/pyramidalization","display_name":"pyramidalization","score":0.9539999961853027},{"id":"https://openalex.org/keywords/transition-state-stabilization","display_name":"transition state stabilization","score":0.6290000081062317},{"id":"https://openalex.org/keywords/catalysis","display_name":"catalysis","score":0.5889999866485596}],"concepts":[{"id":"https://openalex.org/C192095803","wikidata":"https://www.wikidata.org/wiki/Q106675","display_name":"Pnictogen","level":3,"score":0.9672690629959106},{"id":"https://openalex.org/C75079739","wikidata":"https://www.wikidata.org/wiki/Q1571801","display_name":"Intramolecular force","level":2,"score":0.7320124506950378},{"id":"https://openalex.org/C130188946","wikidata":"https://www.wikidata.org/wiki/Q4391470","display_name":"Natural bond orbital","level":3,"score":0.7182154655456543},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6771113276481628},{"id":"https://openalex.org/C46000676","wikidata":"https://www.wikidata.org/wiki/Q804644","display_name":"Lone pair","level":3,"score":0.5503152012825012},{"id":"https://openalex.org/C537208039","wikidata":"https://www.wikidata.org/wiki/Q627","display_name":"Nitrogen","level":2,"score":0.4791373908519745},{"id":"https://openalex.org/C147597530","wikidata":"https://www.wikidata.org/wiki/Q369472","display_name":"Computational chemistry","level":1,"score":0.4311727285385132},{"id":"https://openalex.org/C159467904","wikidata":"https://www.wikidata.org/wiki/Q2001702","display_name":"Chemical physics","level":1,"score":0.39746761322021484},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.35705989599227905},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.251997172832489},{"id":"https://openalex.org/C54101563","wikidata":"https://www.wikidata.org/wiki/Q124131","display_name":"Superconductivity","level":2,"score":0.16687089204788208},{"id":"https://openalex.org/C152365726","wikidata":"https://www.wikidata.org/wiki/Q1048589","display_name":"Density functional theory","level":2,"score":0.16352424025535583},{"id":"https://openalex.org/C26873012","wikidata":"https://www.wikidata.org/wiki/Q214781","display_name":"Condensed matter physics","level":1,"score":0.1462288796901703},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.14125365018844604},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.12752965092658997},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.11701714992523193}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/ange.202304960","doi":"https://doi.org/10.1002/ange.202304960","is_oa":true,"landing_page_url":"https://doi.org/10.1002/ange.202304960","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/ange.202304960","source":{"id":"https://openalex.org/S4210200754","display_name":"Angewandte Chemie","issn_l":"0044-8249","issn":["0044-8249","0932-2140","1521-3757"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":"cc-by-nc","license_id":"https://openalex.org/licenses/cc-by-nc","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie","raw_type":"journal-article"}],"best_oa_location":{"id":"doi:10.1002/ange.202304960","doi":"https://doi.org/10.1002/ange.202304960","is_oa":true,"landing_page_url":"https://doi.org/10.1002/ange.202304960","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/ange.202304960","source":{"id":"https://openalex.org/S4210200754","display_name":"Angewandte Chemie","issn_l":"0044-8249","issn":["0044-8249","0932-2140","1521-3757"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":"cc-by-nc","license_id":"https://openalex.org/licenses/cc-by-nc","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G1269981608","display_name":null,"funder_award_id":"CHE 2003889","funder_id":"https://openalex.org/F4320337393","funder_display_name":"Division of Chemistry"},{"id":"https://openalex.org/G3117315144","display_name":null,"funder_award_id":"2003889","funder_id":"https://openalex.org/F4320337393","funder_display_name":"Division of Chemistry"},{"id":"https://openalex.org/G545044990","display_name":"Molecular rotors for studying transition state stabilization by non-covalent interactions","funder_award_id":"2003889","funder_id":"https://openalex.org/F4320306076","funder_display_name":"National Science Foundation"}],"funders":[{"id":"https://openalex.org/F4320306076","display_name":"National Science Foundation","ror":"https://ror.org/021nxhr62"},{"id":"https://openalex.org/F4320337393","display_name":"Division of Chemistry","ror":"https://ror.org/01ar8dr59"}],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W4375853183.pdf","grobid_xml":"https://content.openalex.org/works/W4375853183.grobid-xml"},"referenced_works_count":46,"referenced_works":["https://openalex.org/W1979611360","https://openalex.org/W1981882904","https://openalex.org/W1982329120","https://openalex.org/W2034424854","https://openalex.org/W2057928456","https://openalex.org/W2061608849","https://openalex.org/W2098376669","https://openalex.org/W2100787790","https://openalex.org/W2101882076","https://openalex.org/W2117102279","https://openalex.org/W2151473802","https://openalex.org/W2497641583","https://openalex.org/W2540429553","https://openalex.org/W2591145738","https://openalex.org/W2615827955","https://openalex.org/W2734509685","https://openalex.org/W2739354641","https://openalex.org/W2753770342","https://openalex.org/W2754480017","https://openalex.org/W2774067949","https://openalex.org/W2792863608","https://openalex.org/W2888057875","https://openalex.org/W2896998435","https://openalex.org/W2900723203","https://openalex.org/W2908845942","https://openalex.org/W2939928361","https://openalex.org/W2980026137","https://openalex.org/W2980244148","https://openalex.org/W2980313702","https://openalex.org/W3000429525","https://openalex.org/W3037292086","https://openalex.org/W3097309472","https://openalex.org/W3115373323","https://openalex.org/W3117237796","https://openalex.org/W3132691871","https://openalex.org/W3166837876","https://openalex.org/W3182301988","https://openalex.org/W3193945445","https://openalex.org/W3206929227","https://openalex.org/W3212113936","https://openalex.org/W3215124921","https://openalex.org/W4220760259","https://openalex.org/W4224939046","https://openalex.org/W4286005427","https://openalex.org/W4296639035","https://openalex.org/W4366285844"],"related_works":["https://openalex.org/W2144826357","https://openalex.org/W3003380190","https://openalex.org/W2980244148","https://openalex.org/W2292613815","https://openalex.org/W2323688122","https://openalex.org/W2037619792","https://openalex.org/W4231910282","https://openalex.org/W7118173406","https://openalex.org/W2026468514","https://openalex.org/W3132691871"],"abstract_inverted_index":{"Abstract":[0],"Stabilizing":[1],"nitrogen":[2,108],"pnictogen":[3,39,83,109],"bond":[4,18],"interactions":[5,13,84,89,110],"were":[6,14,85,91],"measured":[7,34,97],"using":[8,98],"molecular":[9],"rotors.":[10],"Intramolecular":[11],"C=O\u22c5\u22c5\u22c5N":[12,82],"formed":[15],"in":[16,122],"the":[17,24,29,48,64,75,99,107],"rotation":[19],"transition":[20,113],"states":[21,114],"which":[22,54],"lowered":[23],"rotational":[25],"barriers":[26],"and":[27,67,90,115,124],"increased":[28],"rates":[30],"of":[31,106],"rotation,":[32],"as":[33],"by":[35],"EXSY":[36],"NMR.":[37],"The":[38,80,104],"interaction":[40],"energies":[41],"show":[42,70],"a":[43,58],"very":[44],"strong":[45,59],"correlation":[46],"with":[47,57],"positive":[49],"electrostatic":[50,60],"potential":[51,121],"on":[52],"nitrogen,":[53],"was":[55],"consistent":[56],"component.":[61],"In":[62],"contrast,":[63],"NBO":[65],"perturbation":[66],"pyramidalization":[68],"analyses":[69],"no":[71],"correlation,":[72],"suggesting":[73],"that":[74],"orbital\u2010orbital":[76],"component":[77],"is":[78],"minor.":[79],"strongest":[81],"comparable":[86],"to":[87,111],"C=O\u22c5\u22c5\u22c5C=O":[88],"stronger":[92],"than":[93],"C=O\u22c5\u22c5\u22c5Ph":[94],"interactions,":[95],"when":[96],"same":[100],"N\u2010phenylimide":[101],"rotor":[102],"system.":[103],"ability":[105],"stabilize":[112],"enhance":[116],"kinetic":[117],"processes":[118],"demonstrates":[119],"their":[120],"catalysis":[123],"reaction":[125],"design.":[126]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2025,"cited_by_count":3},{"year":2024,"cited_by_count":1},{"year":2023,"cited_by_count":1}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2023-05-10T00:00:00"}