{"id":"https://openalex.org/W4317212752","doi":"https://doi.org/10.1021/acs.macromol.2c02025","title":"Macrocyclic Allylic Sulfone as a Universal Comonomer in Organocatalyzed Photocontrolled Radical Copolymerization with Vinyl Monomers","display_name":"Macrocyclic Allylic Sulfone as a Universal Comonomer in Organocatalyzed Photocontrolled Radical Copolymerization with Vinyl Monomers","publication_year":2023,"publication_date":"2023-01-18","ids":{"openalex":"https://openalex.org/W4317212752","doi":"https://doi.org/10.1021/acs.macromol.2c02025"},"language":"en","primary_location":{"id":"doi:10.1021/acs.macromol.2c02025","doi":"https://doi.org/10.1021/acs.macromol.2c02025","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.macromol.2c02025","pdf_url":null,"source":{"id":"https://openalex.org/S177196338","display_name":"Macromolecules","issn_l":"0024-9297","issn":["0024-9297","1520-5835"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-3","ki-jl-1","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Macromolecules","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5100759561","display_name":"Wenqi Wang","orcid":"https://orcid.org/0000-0001-8244-3865","observed_orcids":["https://orcid.org/0000-0001-8244-3865"]},"institutions":[{"id":"https://openalex.org/I103531236","display_name":"Boston College","ror":"https://ror.org/02n2fzt79","country_code":"US","type":"education","lineage":["https://openalex.org/I103531236"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Wenqi Wang","raw_affiliation_strings":["Department of Chemistry, Boston College, Chestnut Hill, Massachusetts02467, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Boston College, Chestnut Hill, Massachusetts02467, United States","institution_ids":["https://openalex.org/I103531236"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5010012459","display_name":"Brayan Rondon","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I103531236","display_name":"Boston College","ror":"https://ror.org/02n2fzt79","country_code":"US","type":"education","lineage":["https://openalex.org/I103531236"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Brayan Rondon","raw_affiliation_strings":["Department of Chemistry, Boston College, Chestnut Hill, Massachusetts02467, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Boston College, Chestnut Hill, Massachusetts02467, United States","institution_ids":["https://openalex.org/I103531236"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5029409733","display_name":"Zeyu Wang","orcid":"https://orcid.org/0000-0002-6343-0548","observed_orcids":["https://orcid.org/0000-0002-6343-0548"]},"institutions":[{"id":"https://openalex.org/I110152177","display_name":"University of Akron","ror":"https://ror.org/02kyckx55","country_code":"US","type":"education","lineage":["https://openalex.org/I110152177"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Zeyu Wang","raw_affiliation_strings":["School of Polymer Science and Polymer Engineering, The University of Akron, Akron, Ohio44325, United States"],"raw_orcid":"https://orcid.org/0000-0002-6343-0548","affiliations":[{"raw_affiliation_string":"School of Polymer Science and Polymer Engineering, The University of Akron, Akron, Ohio44325, United States","institution_ids":["https://openalex.org/I110152177"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5002963148","display_name":"Junpeng Wang","orcid":"https://orcid.org/0000-0002-4503-5026","observed_orcids":["https://orcid.org/0000-0002-4503-5026","https://orcid.org/0000-0003-0180-7116","https://orcid.org/0000-0002-2833-5932"]},"institutions":[{"id":"https://openalex.org/I110152177","display_name":"University of Akron","ror":"https://ror.org/02kyckx55","country_code":"US","type":"education","lineage":["https://openalex.org/I110152177"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Junpeng Wang","raw_affiliation_strings":["School of Polymer Science and Polymer Engineering, The University of Akron, Akron, Ohio44325, United States"],"raw_orcid":"https://orcid.org/0000-0002-4503-5026","affiliations":[{"raw_affiliation_string":"School of Polymer Science and Polymer Engineering, The University of Akron, Akron, Ohio44325, United States","institution_ids":["https://openalex.org/I110152177"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5030202415","display_name":"Jia Niu","orcid":"https://orcid.org/0000-0002-5622-6362","observed_orcids":["https://orcid.org/0000-0002-5622-6362"]},"institutions":[{"id":"https://openalex.org/I103531236","display_name":"Boston College","ror":"https://ror.org/02n2fzt79","country_code":"US","type":"education","lineage":["https://openalex.org/I103531236"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Jia Niu","raw_affiliation_strings":["Department of Chemistry, Boston College, Chestnut Hill, Massachusetts02467, United States"],"raw_orcid":"https://orcid.org/0000-0002-5622-6362","affiliations":[{"raw_affiliation_string":"Department of Chemistry, Boston College, Chestnut Hill, Massachusetts02467, United States","institution_ids":["https://openalex.org/I103531236"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5030202415"],"corresponding_institution_ids":["https://openalex.org/I103531236"],"apc_list":{"value":5000,"currency":"USD","value_usd":5000},"apc_paid":null,"fwci":2.8692,"has_fulltext":false,"cited_by_count":28,"citation_normalized_percentile":{"value":0.919869,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":98,"max":99},"biblio":{"volume":"56","issue":"5","first_page":"2052","last_page":"2061"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.8467000126838684,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.8467000126838684,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12570","display_name":"Photopolymerization techniques and applications","score":0.12960000336170197,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10661","display_name":"biodegradable polymer synthesis and properties","score":0.018200000748038292,"subfield":{"id":"https://openalex.org/subfields/2502","display_name":"Biomaterials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/organocatalysis","display_name":"organocatalysis","score":0.7319999933242798},{"id":"https://openalex.org/keywords/eosin-y","display_name":"eosin Y","score":0.7940000295639038},{"id":"https://openalex.org/keywords/visible-light-photocatalysis","display_name":"visible light photocatalysis","score":0.6779999732971191},{"id":"https://openalex.org/keywords/vinyl-monomers","display_name":"vinyl monomers","score":0.7689999938011169},{"id":"https://openalex.org/keywords/acrylates","display_name":"acrylates","score":0.8080000281333923},{"id":"https://openalex.org/keywords/acrylamide","display_name":"acrylamide","score":0.9769999980926514},{"id":"https://openalex.org/keywords/styrene","display_name":"styrene","score":0.9879999756813049},{"id":"https://openalex.org/keywords/methyl-methacrylate","display_name":"methyl methacrylate","score":0.9959999918937683},{"id":"https://openalex.org/keywords/polystyrene","display_name":"polystyrene","score":0.7409999966621399},{"id":"https://openalex.org/keywords/poly-methyl-methacrylate","display_name":"poly(methyl methacrylate)","score":0.9990000128746033},{"id":"https://openalex.org/keywords/comonomer-reactivity-ratios","display_name":"comonomer reactivity ratios","score":0.8799999952316284},{"id":"https://openalex.org/keywords/thermal-properties","display_name":"thermal properties","score":0.7559999823570251}],"concepts":[{"id":"https://openalex.org/C2780672802","wikidata":"https://www.wikidata.org/wiki/Q55999569","display_name":"Comonomer","level":4,"score":0.927212655544281},{"id":"https://openalex.org/C15920480","wikidata":"https://www.wikidata.org/wiki/Q421281","display_name":"Copolymer","level":3,"score":0.8454651832580566},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.7281287908554077},{"id":"https://openalex.org/C166940927","wikidata":"https://www.wikidata.org/wiki/Q178827","display_name":"Monomer","level":3,"score":0.6785784959793091},{"id":"https://openalex.org/C120095180","wikidata":"https://www.wikidata.org/wiki/Q2695010","display_name":"Allylic rearrangement","level":3,"score":0.5957943797111511},{"id":"https://openalex.org/C2778806918","wikidata":"https://www.wikidata.org/wiki/Q411193","display_name":"Sulfone","level":2,"score":0.5638006329536438},{"id":"https://openalex.org/C2777935641","wikidata":"https://www.wikidata.org/wiki/Q382897","display_name":"Methyl methacrylate","level":4,"score":0.5264114737510681},{"id":"https://openalex.org/C2777566558","wikidata":"https://www.wikidata.org/wiki/Q28917","display_name":"Styrene","level":4,"score":0.5243642330169678},{"id":"https://openalex.org/C2777922577","wikidata":"https://www.wikidata.org/wiki/Q146243","display_name":"Polystyrene","level":3,"score":0.47646188735961914},{"id":"https://openalex.org/C132050475","wikidata":"https://www.wikidata.org/wiki/Q736232","display_name":"Methacrylate","level":4,"score":0.43074166774749756},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.4201597273349762},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.37407541275024414},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.28014224767684937},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.16737356781959534},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.09438741207122803}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/acs.macromol.2c02025","doi":"https://doi.org/10.1021/acs.macromol.2c02025","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.macromol.2c02025","pdf_url":null,"source":{"id":"https://openalex.org/S177196338","display_name":"Macromolecules","issn_l":"0024-9297","issn":["0024-9297","1520-5835"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-3","ki-jl-1","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Macromolecules","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G1482848736","display_name":"CryoProbe-enabled Bruker AVANCE NEO 500 MHz NMR Spectrometer","funder_award_id":"1s10od026910-01a1","funder_id":"https://openalex.org/F4320332161","funder_display_name":"National Institutes of Health"},{"id":"https://openalex.org/G3101338656","display_name":"CAREER: CAS: Radical Cascade-Driven Polymerization and Depolymerization","funder_award_id":"1944512","funder_id":"https://openalex.org/F4320306076","funder_display_name":"National Science Foundation"},{"id":"https://openalex.org/G7054237862","display_name":"MRI: Acquisition of a CryoProbe-Enabled NMR Spectrometer for Enhanced Efficiency and Sensitivity in Chemical and Biological Research","funder_award_id":"2117246","funder_id":"https://openalex.org/F4320306076","funder_display_name":"National Science Foundation"},{"id":"https://openalex.org/G8418650912","display_name":null,"funder_award_id":"60747DNI7","funder_id":"https://openalex.org/F4320332454","funder_display_name":"American Chemical Society Petroleum Research Fund"}],"funders":[{"id":"https://openalex.org/F4320306076","display_name":"National Science Foundation","ror":"https://ror.org/021nxhr62"},{"id":"https://openalex.org/F4320332161","display_name":"National Institutes of Health","ror":"https://ror.org/01cwqze88"},{"id":"https://openalex.org/F4320332454","display_name":"American Chemical Society Petroleum Research Fund","ror":"https://ror.org/059dqb057"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":41,"referenced_works":["https://openalex.org/W1975588461","https://openalex.org/W1998350146","https://openalex.org/W2052899501","https://openalex.org/W2059574550","https://openalex.org/W2067894883","https://openalex.org/W2090487791","https://openalex.org/W2144886187","https://openalex.org/W2156640963","https://openalex.org/W2209405800","https://openalex.org/W2299481623","https://openalex.org/W2315112119","https://openalex.org/W2510380476","https://openalex.org/W2572929162","https://openalex.org/W2737217596","https://openalex.org/W2754600897","https://openalex.org/W2755252571","https://openalex.org/W2759655425","https://openalex.org/W2767019436","https://openalex.org/W2902683008","https://openalex.org/W2910869068","https://openalex.org/W2922210360","https://openalex.org/W2966152810","https://openalex.org/W3000135456","https://openalex.org/W3005332201","https://openalex.org/W3007733712","https://openalex.org/W3023913531","https://openalex.org/W3025935277","https://openalex.org/W3040658539","https://openalex.org/W3093224954","https://openalex.org/W3110095379","https://openalex.org/W3173983729","https://openalex.org/W3176667207","https://openalex.org/W3177287813","https://openalex.org/W3206396973","https://openalex.org/W3214858261","https://openalex.org/W4200561393","https://openalex.org/W4205894533","https://openalex.org/W4283702232","https://openalex.org/W4285795529","https://openalex.org/W4287509905","https://openalex.org/W4293094222"],"related_works":["https://openalex.org/W4200624691","https://openalex.org/W3200431225","https://openalex.org/W7223306698","https://openalex.org/W4311936111","https://openalex.org/W2809187472","https://openalex.org/W7204195332","https://openalex.org/W2069884239","https://openalex.org/W4403172682","https://openalex.org/W4389121649","https://openalex.org/W7150944872"],"abstract_inverted_index":{"Radical":[0],"copolymerization":[1,50,77],"of":[2,21,32,52,59,78,152,179],"vinyl":[3,14,33,60,142,181],"monomers":[4,7,24,34,84],"and":[5,56,66,82,115,128,137,186],"cyclic":[6,23],"is":[8],"a":[9,19,40,172],"versatile":[10],"approach":[11,174],"to":[12,96,133,175],"degradable":[13,135,141,154,180],"plastics.":[15],"Despite":[16],"recent":[17],"advances,":[18],"class":[20],"\u201cuniversal\u201d":[22],"that":[25,161],"possess":[26],"broad":[27],"reactivities":[28,160],"with":[29,108,149,183],"various":[30,57,184],"types":[31,58],"remains":[35],"elusive.":[36],"Herein,":[37],"we":[38],"report":[39],"general":[41,173],"method":[42],"for":[43],"the":[44,76,93,97,150,153,167,176],"organocatalyzed":[45,168],"photocontrolled":[46,169],"radical":[47],"ring-opening":[48],"cascade":[49],"(rROCCP)":[51],"macrocyclic":[53,79,162],"allylic":[54,80,102,163],"sulfone":[55,81,103,164],"monomers,":[61],"including":[62],"acrylates,":[63],"acrylamides,":[64],"styrene,":[65],"methacrylate.":[67],"Catalyzed":[68],"by":[69,91],"Eosin":[70],"Y":[71],"under":[72],"visible":[73],"light":[74],"irradiation,":[75],"acrylic":[83],"displayed":[85],"near":[86],"unity":[87],"comonomer":[88],"reactivity":[89],"ratios":[90],"fitting":[92],"copolymer":[94],"composition":[95],"Beckingham\u2013Sanoya\u2013Lynd":[98],"integrated":[99],"model.":[100],"Macrocyclic":[101],"was":[104],"also":[105],"successfully":[106],"copolymerized":[107],"styrene":[109],"(":[110,123],"r":[111,116,124,129],"1":[112,125],"=":[113,118,126,131],"3.02":[114],"St":[117],"0.35)":[119],"or":[120],"methyl":[121],"methacrylate":[122],"0.18":[127],"MMA":[130],"5.81)":[132],"generate":[134],"polystyrene":[136],"poly(methyl":[138],"methacrylate).":[139],"These":[140],"copolymers":[143],"exhibited":[144],"tunable":[145],"thermal":[146],"properties":[147],"correlated":[148],"incorporation":[151],"main-chain":[155],"diester":[156],"motif.":[157],"The":[158],"unprecedented":[159],"demonstrated":[165],"in":[166],"rROCCP":[170],"provide":[171],"wide":[177],"range":[178],"plastics":[182],"structures":[185],"functions.":[187]},"counts_by_year":[{"year":2026,"cited_by_count":4},{"year":2025,"cited_by_count":8},{"year":2024,"cited_by_count":9},{"year":2023,"cited_by_count":7}],"updated_date":"2026-10-16T09:59:22.235173","created_date":"2023-01-18T00:00:00"}