{"id":"https://openalex.org/W4313488483","doi":"https://doi.org/10.1039/d2cp05400k","title":"Investigation of a bacteriochlorin-containing pentad array for panchromatic light-harvesting and charge separation","display_name":"Investigation of a bacteriochlorin-containing pentad array for panchromatic light-harvesting and charge separation","publication_year":2023,"publication_date":"2023-01-01","ids":{"openalex":"https://openalex.org/W4313488483","doi":"https://doi.org/10.1039/d2cp05400k","pmid":"https://pubmed.ncbi.nlm.nih.gov/36597966"},"language":"en","primary_location":{"id":"doi:10.1039/d2cp05400k","doi":"https://doi.org/10.1039/d2cp05400k","is_oa":false,"landing_page_url":"https://doi.org/10.1039/d2cp05400k","pdf_url":null,"source":{"id":"https://openalex.org/S181332294","display_name":"Physical Chemistry Chemical Physics","issn_l":"1463-9076","issn":["1463-9076","1463-9084"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","jufo-3","ki-jl-1","medline","norway-2","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Physical Chemistry Chemical Physics","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5089453573","display_name":"Haoyu Jing","orcid":"https://orcid.org/0000-0001-7839-9582","observed_orcids":["https://orcid.org/0000-0001-7839-9582"]},"institutions":[{"id":"https://openalex.org/I137902535","display_name":"North Carolina State University","ror":"https://ror.org/04tj63d06","country_code":"US","type":"education","lineage":["https://openalex.org/I137902535"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Haoyu Jing","raw_affiliation_strings":["Department of Chemistry, North Carolina State University, Raleigh, North Carolina 27695-8204, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, North Carolina State University, Raleigh, North Carolina 27695-8204, USA","institution_ids":["https://openalex.org/I137902535"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5076914099","display_name":"Nikki Cecil M. Magdaong","orcid":"https://orcid.org/0000-0003-3550-8288","observed_orcids":["https://orcid.org/0000-0003-3550-8288"]},"institutions":[{"id":"https://openalex.org/I204465549","display_name":"Washington University in St. Louis","ror":"https://ror.org/01yc7t268","country_code":"US","type":"education","lineage":["https://openalex.org/I204465549"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Nikki Cecil M. Magdaong","raw_affiliation_strings":["Department of Chemistry, Washington University, St. Louis, Missouri 63130-4889, USA"],"raw_orcid":"https://orcid.org/0000-0003-3550-8288","affiliations":[{"raw_affiliation_string":"Department of Chemistry, Washington University, St. Louis, Missouri 63130-4889, USA","institution_ids":["https://openalex.org/I204465549"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5069007068","display_name":"James R. Diers","orcid":"https://orcid.org/0000-0002-7357-2048","observed_orcids":["https://orcid.org/0000-0002-7357-2048"]},"institutions":[{"id":"https://openalex.org/I103635307","display_name":"University of California, Riverside","ror":"https://ror.org/03nawhv43","country_code":"US","type":"education","lineage":["https://openalex.org/I103635307"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"James R. Diers","raw_affiliation_strings":["Department of Chemistry, University of California, Riverside, California 92521-0403, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of California, Riverside, California 92521-0403, USA","institution_ids":["https://openalex.org/I103635307"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5012555254","display_name":"Christine Kirmaier","orcid":"https://orcid.org/0000-0003-1825-4546","observed_orcids":["https://orcid.org/0000-0003-1825-4546"]},"institutions":[{"id":"https://openalex.org/I204465549","display_name":"Washington University in St. Louis","ror":"https://ror.org/01yc7t268","country_code":"US","type":"education","lineage":["https://openalex.org/I204465549"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Christine Kirmaier","raw_affiliation_strings":["Department of Chemistry, Washington University, St. Louis, Missouri 63130-4889, USA"],"raw_orcid":"https://orcid.org/0000-0003-1825-4546","affiliations":[{"raw_affiliation_string":"Department of Chemistry, Washington University, St. Louis, Missouri 63130-4889, USA","institution_ids":["https://openalex.org/I204465549"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5029454398","display_name":"David F. Bocian","orcid":"https://orcid.org/0000-0002-1411-7846","observed_orcids":["https://orcid.org/0000-0002-1411-7846"]},"institutions":[{"id":"https://openalex.org/I103635307","display_name":"University of California, Riverside","ror":"https://ror.org/03nawhv43","country_code":"US","type":"education","lineage":["https://openalex.org/I103635307"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"David F. Bocian","raw_affiliation_strings":["Department of Chemistry, University of California, Riverside, California 92521-0403, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of California, Riverside, California 92521-0403, USA","institution_ids":["https://openalex.org/I103635307"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5076604331","display_name":"Dewey Holten","orcid":"https://orcid.org/0000-0003-3639-6345","observed_orcids":["https://orcid.org/0000-0003-3639-6345"]},"institutions":[{"id":"https://openalex.org/I204465549","display_name":"Washington University in St. Louis","ror":"https://ror.org/01yc7t268","country_code":"US","type":"education","lineage":["https://openalex.org/I204465549"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Dewey Holten","raw_affiliation_strings":["Department of Chemistry, Washington University, St. Louis, Missouri 63130-4889, USA"],"raw_orcid":"https://orcid.org/0000-0003-3639-6345","affiliations":[{"raw_affiliation_string":"Department of Chemistry, Washington University, St. Louis, Missouri 63130-4889, USA","institution_ids":["https://openalex.org/I204465549"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5083917347","display_name":"Jonathan S. Lindsey","orcid":"https://orcid.org/0000-0002-4872-2040","observed_orcids":["https://orcid.org/0000-0002-4872-2040"]},"institutions":[{"id":"https://openalex.org/I137902535","display_name":"North Carolina State University","ror":"https://ror.org/04tj63d06","country_code":"US","type":"education","lineage":["https://openalex.org/I137902535"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Jonathan S. Lindsey","raw_affiliation_strings":["Department of Chemistry, North Carolina State University, Raleigh, North Carolina 27695-8204, USA"],"raw_orcid":"https://orcid.org/0000-0002-4872-2040","affiliations":[{"raw_affiliation_string":"Department of Chemistry, North Carolina State University, Raleigh, North Carolina 27695-8204, USA","institution_ids":["https://openalex.org/I137902535"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":3,"corresponding_author_ids":["https://openalex.org/A5029454398","https://openalex.org/A5076604331","https://openalex.org/A5083917347"],"corresponding_institution_ids":["https://openalex.org/I103635307","https://openalex.org/I137902535","https://openalex.org/I204465549"],"apc_list":null,"apc_paid":null,"fwci":0.432,"has_fulltext":false,"cited_by_count":6,"citation_normalized_percentile":{"value":0.4506999,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":90,"max":98},"biblio":{"volume":"25","issue":"3","first_page":"1781","last_page":"1798"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10903","display_name":"Porphyrin and Phthalocyanine Chemistry","score":0.9970999956130981,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10903","display_name":"Porphyrin and Phthalocyanine Chemistry","score":0.9970999956130981,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11129","display_name":"Photochemistry and Electron Transfer Studies","score":0.0017000000225380063,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10957","display_name":"Photodynamic Therapy Research Studies","score":0.0005000000237487257,"subfield":{"id":"https://openalex.org/subfields/2740","display_name":"Pulmonary and Respiratory Medicine"},"field":{"id":"https://openalex.org/fields/27","display_name":"Medicine"},"domain":{"id":"https://openalex.org/domains/4","display_name":"Health Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/bacteriochlorins","display_name":"bacteriochlorins","score":0.984000027179718},{"id":"https://openalex.org/keywords/porphyrins","display_name":"porphyrins","score":0.7630000114440918},{"id":"https://openalex.org/keywords/charge-separation","display_name":"charge separation","score":0.7770000100135803},{"id":"https://openalex.org/keywords/charge-recombination","display_name":"charge recombination","score":0.7379999756813049},{"id":"https://openalex.org/keywords/excited-state-quenching","display_name":"excited-state quenching","score":0.8939999938011169},{"id":"https://openalex.org/keywords/near-infrared-absorption","display_name":"near-infrared absorption","score":0.8679999709129333},{"id":"https://openalex.org/keywords/solar-energy-conversion","display_name":"solar energy conversion","score":0.7360000014305115}],"concepts":[{"id":"https://openalex.org/C176038584","wikidata":"https://www.wikidata.org/wiki/Q626432","display_name":"Triad (sociology)","level":2,"score":0.959120512008667},{"id":"https://openalex.org/C107445234","wikidata":"https://www.wikidata.org/wiki/Q280995","display_name":"Panchromatic film","level":3,"score":0.9433097243309021},{"id":"https://openalex.org/C188082385","wikidata":"https://www.wikidata.org/wiki/Q73792","display_name":"Charge (physics)","level":2,"score":0.5914649367332458},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.43907877802848816},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.415707528591156},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.3609970808029175},{"id":"https://openalex.org/C120665830","wikidata":"https://www.wikidata.org/wiki/Q14620","display_name":"Optics","level":1,"score":0.22649675607681274},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.20610535144805908},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C15744967","wikidata":"https://www.wikidata.org/wiki/Q9418","display_name":"Psychology","level":0,"score":0.0},{"id":"https://openalex.org/C11171543","wikidata":"https://www.wikidata.org/wiki/Q41630","display_name":"Psychoanalysis","level":1,"score":0.0},{"id":"https://openalex.org/C205372480","wikidata":"https://www.wikidata.org/wiki/Q210521","display_name":"Image resolution","level":2,"score":0.0}],"mesh":[{"descriptor_ui":"D004735","descriptor_name":"Energy Transfer","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D010569","descriptor_name":"Perylene","qualifier_ui":null,"qualifier_name":null,"is_major_topic":true},{"descriptor_ui":"D011166","descriptor_name":"Porphyrins","qualifier_ui":null,"qualifier_name":null,"is_major_topic":true}],"locations_count":4,"locations":[{"id":"doi:10.1039/d2cp05400k","doi":"https://doi.org/10.1039/d2cp05400k","is_oa":false,"landing_page_url":"https://doi.org/10.1039/d2cp05400k","pdf_url":null,"source":{"id":"https://openalex.org/S181332294","display_name":"Physical Chemistry Chemical Physics","issn_l":"1463-9076","issn":["1463-9076","1463-9084"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","jufo-3","ki-jl-1","medline","norway-2","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Physical Chemistry Chemical Physics","raw_type":"journal-article"},{"id":"pmid:36597966","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/36597966","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Physical chemistry chemical physics : PCCP","raw_type":"Journal Article"},{"id":"pmh:oai:osti.gov:1907913","doi":null,"is_oa":false,"landing_page_url":"https://www.osti.gov/biblio/1907913","pdf_url":null,"source":{"id":"https://openalex.org/S4306402487","display_name":"OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I139351228","host_organization_name":"Office of Scientific and Technical Information","host_organization_lineage":["https://openalex.org/I139351228"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null},{"id":"pmh:oai:osti.gov:2263524","doi":null,"is_oa":false,"landing_page_url":"https://www.osti.gov/biblio/2263524","pdf_url":null,"source":{"id":"https://openalex.org/S4306402487","display_name":"OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I139351228","host_organization_name":"Office of Scientific and Technical Information","host_organization_lineage":["https://openalex.org/I139351228"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G8722356438","display_name":"FUNDAMENTAL STUDIES OF HYDROPORPHYRIN ARCHITECTURES FOR SOLAR ENERGY APPLICATIONS","funder_award_id":"DEFG0205ER15661","funder_id":"https://openalex.org/F4320306084","funder_display_name":"U.S. Department of Energy"}],"funders":[{"id":"https://openalex.org/F4320306084","display_name":"U.S. Department of Energy","ror":"https://ror.org/01bj3aw27"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":66,"referenced_works":["https://openalex.org/W575404724","https://openalex.org/W1725817609","https://openalex.org/W1895139516","https://openalex.org/W1963631775","https://openalex.org/W1964062707","https://openalex.org/W1971350904","https://openalex.org/W1978104862","https://openalex.org/W1989854295","https://openalex.org/W1991032561","https://openalex.org/W1994453332","https://openalex.org/W1995075275","https://openalex.org/W2015548573","https://openalex.org/W2023544689","https://openalex.org/W2024736322","https://openalex.org/W2027570307","https://openalex.org/W2032854058","https://openalex.org/W2033501696","https://openalex.org/W2038392478","https://openalex.org/W2038421329","https://openalex.org/W2045749273","https://openalex.org/W2049745418","https://openalex.org/W2056352715","https://openalex.org/W2059246555","https://openalex.org/W2067896577","https://openalex.org/W2068531496","https://openalex.org/W2069506896","https://openalex.org/W2072369418","https://openalex.org/W2079052647","https://openalex.org/W2082678930","https://openalex.org/W2085890982","https://openalex.org/W2086915866","https://openalex.org/W2090323486","https://openalex.org/W2091780943","https://openalex.org/W2095637504","https://openalex.org/W2105546576","https://openalex.org/W2107157324","https://openalex.org/W2116691173","https://openalex.org/W2117192948","https://openalex.org/W2121575516","https://openalex.org/W2168578425","https://openalex.org/W2169301580","https://openalex.org/W2175728538","https://openalex.org/W2316149515","https://openalex.org/W2320090962","https://openalex.org/W2323662546","https://openalex.org/W2328401517","https://openalex.org/W2491312585","https://openalex.org/W2491766328","https://openalex.org/W2497092011","https://openalex.org/W2809790946","https://openalex.org/W2949312157","https://openalex.org/W2949552448","https://openalex.org/W2950168003","https://openalex.org/W2950170555","https://openalex.org/W3127385664","https://openalex.org/W3196500858","https://openalex.org/W3198400822","https://openalex.org/W4210426898","https://openalex.org/W4226083711","https://openalex.org/W4237391075","https://openalex.org/W4239116693","https://openalex.org/W4241282025","https://openalex.org/W4248708102","https://openalex.org/W4250869419","https://openalex.org/W4293825650","https://openalex.org/W4312113282"],"related_works":["https://openalex.org/W4312113282","https://openalex.org/W2237300923","https://openalex.org/W3166723161","https://openalex.org/W2085890982","https://openalex.org/W3170402648","https://openalex.org/W3196500858","https://openalex.org/W1841467575","https://openalex.org/W2518667717","https://openalex.org/W2314122079","https://openalex.org/W2030064387"],"abstract_inverted_index":{")":[0],"band":[1],"of":[2,30],"the":[3,9,24,27,31,36,41,55,64,83,87,102],"bacteriochlorin":[4,25,104],"also":[5],"enhances":[6],"absorption":[7,123],"in":[8,57,128],"near-infrared":[10],"spectral":[11],"region.":[12],"Due":[13],"to":[14,22,26,63,101],"synthetic":[15],"constraints,":[16],"a":[17,74],"phenylethyne":[18],"linker":[19,38,107],"was":[20,69,79],"used":[21],"join":[23],"core":[28],"porphyrin":[29,106],"panchromatic":[32,122],"triad":[33],"rather":[34],"than":[35],"diphenylethyne":[37],"employed":[39],"for":[40,54,86,112,120,131],"prior":[42,65],"chlorin-containing":[43,66],"pentads.":[44],"Static":[45],"and":[46,59,124],"time-resolved":[47],"photophysical":[48],"studies":[49,116],"reveal":[50],"enhanced":[51],"excited-state":[52],"quenching":[53],"pentad":[56],"benzonitrile":[58],"dimethyl":[60],"sulfoxide":[61],"compared":[62],"analogues.":[67],"Success":[68],"only":[70],"partial,":[71],"however,":[72],"as":[73],"long-lived":[75,125],"charge":[76,126],"separated":[77],"state":[78],"not":[80],"observed":[81],"despite":[82],"improved":[84],"energetics":[85],"final":[88],"ground-state":[89],"hole/electron-shift":[90],"reaction.":[91],"The":[92,115],"apparent":[93],"reason":[94],"is":[95],"more":[96],"facile":[97],"competing":[98],"charge-recombination":[99],"due":[100],"shorter":[103],"-":[105],"that":[108],"increases":[109],"electronic":[110],"coupling":[111],"this":[113],"process.":[114],"highlight":[117],"design":[118],"criteria":[119],"balancing":[121],"separation":[127],"molecular":[129],"architectures":[130],"solar-energy":[132],"conversion.":[133]},"counts_by_year":[{"year":2025,"cited_by_count":1},{"year":2023,"cited_by_count":5}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2023-01-06T00:00:00"}