{"id":"https://openalex.org/W4311580222","doi":"https://doi.org/10.1021/acs.jpca.2c07500","title":"Why Should the Reaction Order of a Bimolecular Reaction be 2.33 Instead of 2?","display_name":"Why Should the Reaction Order of a Bimolecular Reaction be 2.33 Instead of 2?","publication_year":2022,"publication_date":"2022-12-15","ids":{"openalex":"https://openalex.org/W4311580222","doi":"https://doi.org/10.1021/acs.jpca.2c07500","pmid":"https://pubmed.ncbi.nlm.nih.gov/36520427","pmcid":"https://www.ncbi.nlm.nih.gov/pmc/articles/9805503"},"language":"en","primary_location":{"id":"doi:10.1021/acs.jpca.2c07500","doi":"https://doi.org/10.1021/acs.jpca.2c07500","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.jpca.2c07500","pdf_url":null,"source":{"id":"https://openalex.org/S146709414","display_name":"The Journal of Physical Chemistry A","issn_l":"1089-5639","issn":["1089-5639","1520-5215"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry A","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://chemrxiv.org/engage/api-gateway/chemrxiv/assets/orp/resource/item/6388146fc5675301a89d1839/original/why-the-reaction-order-of-a-bimolecular-reaction-should-be-2-33-instead-of-2.pdf","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5088937367","display_name":"Jixin Chen","orcid":"https://orcid.org/0000-0001-7381-0918","observed_orcids":["https://orcid.org/0000-0001-7381-0918","https://orcid.org/0000-0003-1763-8644"]},"institutions":[{"id":"https://openalex.org/I4210106879","display_name":"Ohio University","ror":"https://ror.org/01jr3y717","country_code":"US","type":"education","lineage":["https://openalex.org/I4210106879"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Jixin Chen","raw_affiliation_strings":["Department of Chemistry and Biochemistry, Nanoscale and Quantum Phenomena Institute, Ohio University, Athens, Ohio45701, United States"],"raw_orcid":"https://orcid.org/0000-0001-7381-0918","affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, Nanoscale and Quantum Phenomena Institute, Ohio University, Athens, Ohio45701, United States","institution_ids":["https://openalex.org/I4210106879"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5088937367"],"corresponding_institution_ids":["https://openalex.org/I4210106879"],"apc_list":null,"apc_paid":null,"fwci":0.7571,"has_fulltext":false,"cited_by_count":6,"citation_normalized_percentile":{"value":0.63940581,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":97},"biblio":{"volume":"126","issue":"51","first_page":"9719","last_page":"9725"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12044","display_name":"Advanced Physical and Chemical Molecular Interactions","score":0.7534000277519226,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12044","display_name":"Advanced Physical and Chemical Molecular Interactions","score":0.7534000277519226,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13187","display_name":"Diffusion and Search Dynamics","score":0.20829999446868896,"subfield":{"id":"https://openalex.org/subfields/1312","display_name":"Molecular Biology"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}},{"id":"https://openalex.org/T10288","display_name":"Fractional Differential Equations Solutions","score":0.004000000189989805,"subfield":{"id":"https://openalex.org/subfields/2611","display_name":"Modeling and Simulation"},"field":{"id":"https://openalex.org/fields/26","display_name":"Mathematics"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/bimolecular-reactions","display_name":"bimolecular reactions","score":0.8960000276565552},{"id":"https://openalex.org/keywords/reaction-order","display_name":"reaction order","score":0.9440000057220459},{"id":"https://openalex.org/keywords/collision-theory","display_name":"collision theory","score":0.593999981880188},{"id":"https://openalex.org/keywords/diffusion-limited-reactions","display_name":"diffusion-controlled reaction","score":0.6449999809265137},{"id":"https://openalex.org/keywords/collision-frequency","display_name":"collision frequency","score":0.7710000276565552}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6881080865859985},{"id":"https://openalex.org/C36663273","wikidata":"https://www.wikidata.org/wiki/Q209082","display_name":"Chemical kinetics","level":3,"score":0.6397764682769775},{"id":"https://openalex.org/C148898269","wikidata":"https://www.wikidata.org/wiki/Q1108792","display_name":"Kinetics","level":2,"score":0.6170608997344971},{"id":"https://openalex.org/C175113610","wikidata":"https://www.wikidata.org/wiki/Q3394849","display_name":"Reaction rate","level":3,"score":0.6157877445220947},{"id":"https://openalex.org/C96618451","wikidata":"https://www.wikidata.org/wiki/Q3028008","display_name":"Dilution","level":2,"score":0.5982677340507507},{"id":"https://openalex.org/C135502975","wikidata":"https://www.wikidata.org/wiki/Q904041","display_name":"Order of reaction","level":4,"score":0.5638440251350403},{"id":"https://openalex.org/C177801218","wikidata":"https://www.wikidata.org/wiki/Q36534","display_name":"Chemical reaction","level":2,"score":0.5496255159378052},{"id":"https://openalex.org/C69357855","wikidata":"https://www.wikidata.org/wiki/Q163214","display_name":"Diffusion","level":2,"score":0.49535834789276123},{"id":"https://openalex.org/C150394285","wikidata":"https://www.wikidata.org/wiki/Q180254","display_name":"Adsorption","level":2,"score":0.4564107060432434},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.43570151925086975},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.4314536452293396},{"id":"https://openalex.org/C121704057","wikidata":"https://www.wikidata.org/wiki/Q352070","display_name":"Collision","level":2,"score":0.426222026348114},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.32783201336860657},{"id":"https://openalex.org/C93391505","wikidata":"https://www.wikidata.org/wiki/Q658700","display_name":"Reaction rate constant","level":3,"score":0.27941280603408813},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.2337709367275238},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.1449071168899536},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.09315720200538635},{"id":"https://openalex.org/C74650414","wikidata":"https://www.wikidata.org/wiki/Q11397","display_name":"Classical mechanics","level":1,"score":0.067384272813797},{"id":"https://openalex.org/C38652104","wikidata":"https://www.wikidata.org/wiki/Q3510521","display_name":"Computer security","level":1,"score":0.0},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.0}],"mesh":[{"descriptor_ui":"D004058","descriptor_name":"Diffusion","qualifier_ui":null,"qualifier_name":null,"is_major_topic":true},{"descriptor_ui":"D007700","descriptor_name":"Kinetics","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D012996","descriptor_name":"Solutions","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false}],"locations_count":4,"locations":[{"id":"doi:10.1021/acs.jpca.2c07500","doi":"https://doi.org/10.1021/acs.jpca.2c07500","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.jpca.2c07500","pdf_url":null,"source":{"id":"https://openalex.org/S146709414","display_name":"The Journal of Physical Chemistry A","issn_l":"1089-5639","issn":["1089-5639","1520-5215"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry A","raw_type":"journal-article"},{"id":"doi:10.26434/chemrxiv-2022-fdt7c-v5","doi":"https://doi.org/10.26434/chemrxiv-2022-fdt7c-v5","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv-2022-fdt7c-v5","pdf_url":"https://chemrxiv.org/engage/api-gateway/chemrxiv/assets/orp/resource/item/6388146fc5675301a89d1839/original/why-the-reaction-order-of-a-bimolecular-reaction-should-be-2-33-instead-of-2.pdf","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},{"id":"pmid:36520427","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/36520427","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The journal of physical chemistry. A","raw_type":"Journal Article"},{"id":"pmh:oai:pubmedcentral.nih.gov:9805503","doi":null,"is_oa":true,"landing_page_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/9805503","pdf_url":null,"source":{"id":"https://openalex.org/S2764455111","display_name":"PubMed Central","issn_l":null,"issn":null,"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":"J Phys Chem A","raw_type":"Text"}],"best_oa_location":{"id":"doi:10.26434/chemrxiv-2022-fdt7c-v5","doi":"https://doi.org/10.26434/chemrxiv-2022-fdt7c-v5","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv-2022-fdt7c-v5","pdf_url":"https://chemrxiv.org/engage/api-gateway/chemrxiv/assets/orp/resource/item/6388146fc5675301a89d1839/original/why-the-reaction-order-of-a-bimolecular-reaction-should-be-2-33-instead-of-2.pdf","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G3112304589","display_name":"Super-Resolution Optical Mapping for DNA Analysis Using Triplex-Forming Oligonucleotides as Stochastic Molecular Probes","funder_award_id":"R15HG009972","funder_id":"https://openalex.org/F4320337348","funder_display_name":"National Human Genome Research Institute"}],"funders":[{"id":"https://openalex.org/F4320332161","display_name":"National Institutes of Health","ror":"https://ror.org/01cwqze88"},{"id":"https://openalex.org/F4320337348","display_name":"National Human Genome Research Institute","ror":"https://ror.org/00baak391"}],"has_content":{"grobid_xml":true,"pdf":true},"content_urls":{"pdf":"https://content.openalex.org/works/W4311580222.pdf","grobid_xml":"https://content.openalex.org/works/W4311580222.grobid-xml"},"referenced_works_count":31,"referenced_works":["https://openalex.org/W8456792","https://openalex.org/W46860574","https://openalex.org/W561716561","https://openalex.org/W1576320143","https://openalex.org/W1621033879","https://openalex.org/W1944776925","https://openalex.org/W1970805130","https://openalex.org/W2004790462","https://openalex.org/W2025396755","https://openalex.org/W2034665579","https://openalex.org/W2035141480","https://openalex.org/W2045050273","https://openalex.org/W2050574242","https://openalex.org/W2057788561","https://openalex.org/W2057980421","https://openalex.org/W2075871360","https://openalex.org/W2084405546","https://openalex.org/W2097081551","https://openalex.org/W2098793851","https://openalex.org/W2099926307","https://openalex.org/W2118343782","https://openalex.org/W2172250191","https://openalex.org/W2314955286","https://openalex.org/W2469417314","https://openalex.org/W2532738368","https://openalex.org/W2580793072","https://openalex.org/W2610323627","https://openalex.org/W4205898344","https://openalex.org/W4230060386","https://openalex.org/W4240384253","https://openalex.org/W4253789658"],"related_works":["https://openalex.org/W4307251694","https://openalex.org/W4294324903","https://openalex.org/W2031106408","https://openalex.org/W1976411678","https://openalex.org/W2013412468","https://openalex.org/W2075871360","https://openalex.org/W1995766000","https://openalex.org/W1997529194","https://openalex.org/W7117412474","https://openalex.org/W2029177223"],"abstract_inverted_index":{"Predicting":[0],"the":[1,54,80,95,107,127,142],"reaction":[2,9,55,65,143,159],"kinetics,":[3],"that":[4,141],"is,":[5],"how":[6],"fast":[7],"a":[8,13,64,67,73,92,102,114,120,132,157],"can":[10],"happen":[11],"in":[12,35,41,66,90,113],"solution,":[14,76],"is":[15,85,99,124,138],"essential":[16],"information":[17],"for":[18,145],"many":[19],"processes,":[20],"such":[21,91],"as":[22,101],"industrial":[23],"chemical":[24],"manufacturing,":[25],"refining,":[26],"synthesis":[27],"and":[28,37,44,151],"separation":[29],"of":[30,57,110,129,154],"petroleum":[31],"products,":[32],"environmental":[33],"processes":[34],"air":[36],"water,":[38],"biological":[39],"reactions":[40,59,147],"cells,":[42],"biosensing,":[43],"drug":[45],"delivery.":[46],"Collision":[47],"theory":[48],"was":[49],"originally":[50],"developed":[51],"to":[52,87,105],"explain":[53],"kinetics":[56],"gas":[58,70],"with":[60],"no":[61],"dilution.":[62],"For":[63],"diluted":[68,74,115],"inert":[69],"solution":[71],"or":[72],"liquid":[75],"diffusion":[77,89],"often":[78],"dominates":[79],"collision":[81,108,122],"process.":[82],"Thus,":[83],"it":[84],"necessary":[86],"include":[88],"calculation.":[93],"Traditionally,":[94],"classical":[96],"Smoluchowski":[97],"rate":[98],"used":[100],"starting":[103],"point":[104],"predict":[106],"frequency":[109],"two":[111],"molecules":[112,130],"solution.":[116],"In":[117],"this":[118],"report,":[119],"different":[121],"model":[123],"derived":[125],"from":[126],"adsorption":[128],"on":[131],"flat":[133],"surface.":[134],"A":[135],"surprising":[136],"result":[137],"obtained,":[139],"showing":[140],"order":[144],"bimolecular":[146],"should":[148],"be":[149],"2":[150],"1/3":[152],"instead":[153],"2,":[155],"following":[156],"fractal":[158],"kinetics.":[160]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":3},{"year":2023,"cited_by_count":1}],"updated_date":"2026-10-31T12:09:11.096373","created_date":"2022-12-27T00:00:00"}