{"id":"https://openalex.org/W4304589510","doi":"https://doi.org/10.1021/acscatal.2c04014","title":"Catalytic Desaturation and \u03b2-Fluorination of Aliphatic Amides Enabled by an Oxidative-Promoted Bond Destabilization","display_name":"Catalytic Desaturation and \u03b2-Fluorination of Aliphatic Amides Enabled by an Oxidative-Promoted Bond Destabilization","publication_year":2022,"publication_date":"2022-10-11","ids":{"openalex":"https://openalex.org/W4304589510","doi":"https://doi.org/10.1021/acscatal.2c04014"},"language":"en","primary_location":{"id":"doi:10.1021/acscatal.2c04014","doi":"https://doi.org/10.1021/acscatal.2c04014","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acscatal.2c04014","pdf_url":null,"source":{"id":"https://openalex.org/S37391459","display_name":"ACS Catalysis","issn_l":"2155-5435","issn":["2155-5435"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Catalysis","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5049533517","display_name":"Xiao\u2010Feng Xia","orcid":"https://orcid.org/0000-0002-1837-0638","observed_orcids":["https://orcid.org/0000-0002-1837-0638"]},"institutions":[{"id":"https://openalex.org/I111599522","display_name":"Jiangnan University","ror":"https://ror.org/04mkzax54","country_code":"CN","type":"education","lineage":["https://openalex.org/I111599522"]},{"id":"https://openalex.org/I4405271899","display_name":"Key Laboratory of Synthetic and Biological Colloids, Ministry of Education","ror":"https://ror.org/0380e2m71","country_code":"CN","type":"facility","lineage":["https://openalex.org/I4405271899"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Xiao-Feng Xia","raw_affiliation_strings":["Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu214122, China"],"raw_orcid":"https://orcid.org/0000-0002-1837-0638","affiliations":[{"raw_affiliation_string":"Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu214122, China","institution_ids":["https://openalex.org/I111599522","https://openalex.org/I4405271899"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5101804919","display_name":"Quan Huang","orcid":"https://orcid.org/0000-0001-9399-5614","observed_orcids":["https://orcid.org/0000-0001-9399-5614"]},"institutions":[{"id":"https://openalex.org/I111599522","display_name":"Jiangnan University","ror":"https://ror.org/04mkzax54","country_code":"CN","type":"education","lineage":["https://openalex.org/I111599522"]},{"id":"https://openalex.org/I4405271899","display_name":"Key Laboratory of Synthetic and Biological Colloids, Ministry of Education","ror":"https://ror.org/0380e2m71","country_code":"CN","type":"facility","lineage":["https://openalex.org/I4405271899"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Quan Huang","raw_affiliation_strings":["Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu214122, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu214122, China","institution_ids":["https://openalex.org/I111599522","https://openalex.org/I4405271899"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5011841066","display_name":"Tian\u2010Yu Sun","orcid":"https://orcid.org/0000-0002-7746-479X","observed_orcids":["https://orcid.org/0000-0002-7746-479X"]},"institutions":[{"id":"https://openalex.org/I4210102541","display_name":"Shenzhen Bay Laboratory","ror":"https://ror.org/00sdcjz77","country_code":"CN","type":"facility","lineage":["https://openalex.org/I4210102541"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Tian-Yu Sun","raw_affiliation_strings":["Institute of Chemical Biology, Shenzhen Bay Laboratory, Shenzhen518132, China"],"raw_orcid":"https://orcid.org/0000-0002-7746-479X","affiliations":[{"raw_affiliation_string":"Institute of Chemical Biology, Shenzhen Bay Laboratory, Shenzhen518132, China","institution_ids":["https://openalex.org/I4210102541"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5101420512","display_name":"Yuqin Jiang","orcid":"https://orcid.org/0009-0000-9607-0051","observed_orcids":["https://orcid.org/0009-0000-9607-0051"]},"institutions":[{"id":"https://openalex.org/I75955062","display_name":"Henan Normal University","ror":"https://ror.org/00s13br28","country_code":"CN","type":"education","lineage":["https://openalex.org/I75955062"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yuqin Jiang","raw_affiliation_strings":["Henan Engineering Research Centre of Chiral Hydroxyl Pharmaceutical, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang453007, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Henan Engineering Research Centre of Chiral Hydroxyl Pharmaceutical, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang453007, China","institution_ids":["https://openalex.org/I75955062"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5019589835","display_name":"Guoxia Ran","orcid":"https://orcid.org/0000-0002-4968-8083","observed_orcids":["https://orcid.org/0000-0002-4968-8083"]},"institutions":[{"id":"https://openalex.org/I111599522","display_name":"Jiangnan University","ror":"https://ror.org/04mkzax54","country_code":"CN","type":"education","lineage":["https://openalex.org/I111599522"]},{"id":"https://openalex.org/I4405271899","display_name":"Key Laboratory of Synthetic and Biological Colloids, Ministry of Education","ror":"https://ror.org/0380e2m71","country_code":"CN","type":"facility","lineage":["https://openalex.org/I4405271899"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Guoxia Ran","raw_affiliation_strings":["Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu214122, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu214122, China","institution_ids":["https://openalex.org/I111599522","https://openalex.org/I4405271899"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":4,"corresponding_author_ids":["https://openalex.org/A5011841066","https://openalex.org/A5049533517"],"corresponding_institution_ids":["https://openalex.org/I111599522","https://openalex.org/I4210102541","https://openalex.org/I4405271899"],"apc_list":{"value":5000,"currency":"USD","value_usd":5000},"apc_paid":null,"fwci":1.4784,"has_fulltext":false,"cited_by_count":19,"citation_normalized_percentile":{"value":0.79225161,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":96,"max":98},"biblio":{"volume":"12","issue":"20","first_page":"12964","last_page":"12972"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10947","display_name":"Fluorine in Organic Chemistry","score":0.86080002784729,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10947","display_name":"Fluorine in Organic Chemistry","score":0.86080002784729,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11989","display_name":"Oxidative Organic Chemistry Reactions","score":0.0471000000834465,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10701","display_name":"Radical Photochemical Reactions","score":0.04340000078082085,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/aliphatic-amides","display_name":"aliphatic amides","score":0.8690000176429749},{"id":"https://openalex.org/keywords/lactams","display_name":"lactams","score":0.8960000276565552},{"id":"https://openalex.org/keywords/c-n-bond-cleavage","display_name":"C\u2013N bond cleavage","score":0.7910000085830688},{"id":"https://openalex.org/keywords/hydrogen-atom-transfer","display_name":"hydrogen atom transfer","score":0.7300000190734863},{"id":"https://openalex.org/keywords/isomerization","display_name":"isomerization","score":0.8050000071525574},{"id":"https://openalex.org/keywords/electrophilic-fluorination","display_name":"electrophilic fluorination","score":0.921999990940094},{"id":"https://openalex.org/keywords/selectfluor","display_name":"Selectfluor","score":0.9850000143051147},{"id":"https://openalex.org/keywords/reaction-mechanism","display_name":"reaction mechanism","score":0.6610000133514404}],"concepts":[{"id":"https://openalex.org/C2778656812","wikidata":"https://www.wikidata.org/wiki/Q2649515","display_name":"Selectfluor","level":3,"score":0.8464512228965759},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8096809983253479},{"id":"https://openalex.org/C126661725","wikidata":"https://www.wikidata.org/wiki/Q903420","display_name":"Isomerization","level":3,"score":0.8054406642913818},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.7620704770088196},{"id":"https://openalex.org/C119889771","wikidata":"https://www.wikidata.org/wiki/Q898262","display_name":"Dehydrogenation","level":3,"score":0.7548987865447998},{"id":"https://openalex.org/C50027330","wikidata":"https://www.wikidata.org/wiki/Q908086","display_name":"Electrophile","level":3,"score":0.640626847743988},{"id":"https://openalex.org/C3044715","wikidata":"https://www.wikidata.org/wiki/Q3952437","display_name":"Bond cleavage","level":3,"score":0.6229560375213623},{"id":"https://openalex.org/C57600042","wikidata":"https://www.wikidata.org/wiki/Q227564","display_name":"Oxidative phosphorylation","level":2,"score":0.5126053690910339},{"id":"https://openalex.org/C94882840","wikidata":"https://www.wikidata.org/wiki/Q2123471","display_name":"Oxidative addition","level":3,"score":0.4984889030456543},{"id":"https://openalex.org/C2778824931","wikidata":"https://www.wikidata.org/wiki/Q5358518","display_name":"Electrophilic fluorination","level":4,"score":0.49442148208618164},{"id":"https://openalex.org/C2781076698","wikidata":"https://www.wikidata.org/wiki/Q718074","display_name":"Aryl","level":3,"score":0.4806296229362488},{"id":"https://openalex.org/C2991908781","wikidata":"https://www.wikidata.org/wiki/Q2161141","display_name":"Oxidative cleavage","level":3,"score":0.438442587852478},{"id":"https://openalex.org/C65973085","wikidata":"https://www.wikidata.org/wiki/Q888529","display_name":"Halogenation","level":2,"score":0.425071656703949},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.3713951110839844},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.3709229826927185},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.340376615524292},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.3276464641094208},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/acscatal.2c04014","doi":"https://doi.org/10.1021/acscatal.2c04014","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acscatal.2c04014","pdf_url":null,"source":{"id":"https://openalex.org/S37391459","display_name":"ACS Catalysis","issn_l":"2155-5435","issn":["2155-5435"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Catalysis","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G42322103","display_name":"\u5316\u5b66\u952e\u80fd\u7684\u6d4b\u5b9a\u3001\u9884\u6d4b\u4e0e\u76f8\u5173\u673a\u7406\u7814\u7a76","funder_award_id":"21933004","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"},{"id":"https://openalex.org/G7804533014","display_name":null,"funder_award_id":"22171108","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"}],"funders":[{"id":"https://openalex.org/F4320311345","display_name":"Henan Normal University","ror":"https://ror.org/00s13br28"},{"id":"https://openalex.org/F4320321001","display_name":"National Natural Science Foundation of China","ror":"https://ror.org/01h0zpd94"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":35,"referenced_works":["https://openalex.org/W1972340781","https://openalex.org/W1990442032","https://openalex.org/W2113099474","https://openalex.org/W2125454637","https://openalex.org/W2132525235","https://openalex.org/W2264719596","https://openalex.org/W2334572606","https://openalex.org/W2407040666","https://openalex.org/W2613210016","https://openalex.org/W2780444177","https://openalex.org/W2786272128","https://openalex.org/W2852755113","https://openalex.org/W2883959769","https://openalex.org/W2888357341","https://openalex.org/W2889304413","https://openalex.org/W2908595662","https://openalex.org/W2911470664","https://openalex.org/W2948962284","https://openalex.org/W2971247064","https://openalex.org/W2971588593","https://openalex.org/W2973796961","https://openalex.org/W3017263771","https://openalex.org/W3037161445","https://openalex.org/W3044807851","https://openalex.org/W3091983478","https://openalex.org/W3112354201","https://openalex.org/W3127224102","https://openalex.org/W3131036488","https://openalex.org/W3161273225","https://openalex.org/W3179266548","https://openalex.org/W3198429545","https://openalex.org/W4206957761","https://openalex.org/W4285006078","https://openalex.org/W4285193754","https://openalex.org/W4290660646"],"related_works":["https://openalex.org/W4229035811","https://openalex.org/W2950250890","https://openalex.org/W2510462186","https://openalex.org/W2549504266","https://openalex.org/W4413753142","https://openalex.org/W2799538543","https://openalex.org/W3012132787","https://openalex.org/W3089143297","https://openalex.org/W2936568018","https://openalex.org/W4387692502"],"abstract_inverted_index":{"Described":[0],"herein":[1],"is":[2,15],"the":[3,26,48,56,64],"development":[4],"of":[5,11,28,40,60,69],"a":[6],"desaturation":[7],"and":[8,33,38,78],"\u03b2-fluorination":[9],"reaction":[10,71],"cyclic":[12],"amides,":[13],"which":[14],"achieved":[16],"by":[17],"an":[18,29],"oxidative-promoted":[19],"selective":[20,50],"hydrogen":[21],"atom-transfer/isomerization/electrophilic":[22],"fluorination":[23],"process.":[24],"Moreover,":[25],"combination":[27],"N":[30,41],"-hydroxy":[31],"catalyst":[32],"Selectfluor":[34],"allows":[35],"\u03b1,":[36],"\u03b2-dehydrogenation":[37],"\u03b3-di-fluorination":[39],"-aryl":[42],"lactams":[43],"to":[44],"be":[45],"established.":[46],"Furthermore,":[47],"present":[49],"catalysis":[51],"also":[52],"works":[53],"well":[54],"for":[55],"C\u2013N":[57],"bond":[58],"cleavage":[59],"acyclic":[61],"amides":[62],"at":[63],"less-crowded":[65],"site.":[66],"The":[67],"mechanism":[68],"this":[70],"has":[72],"been":[73],"carefully":[74],"illustrated":[75],"with":[76],"experimental":[77],"computational":[79],"studies.":[80]},"counts_by_year":[{"year":2026,"cited_by_count":3},{"year":2025,"cited_by_count":5},{"year":2024,"cited_by_count":6},{"year":2023,"cited_by_count":5}],"updated_date":"2026-10-13T10:08:12.033832","created_date":"2022-10-12T00:00:00"}
