{"id":"https://openalex.org/W4297802154","doi":"https://doi.org/10.1039/b603014a","title":"An approach to chiral magnets using \u03b1-hydroxycarboxylates","display_name":"An approach to chiral magnets using \u03b1-hydroxycarboxylates","publication_year":2006,"publication_date":"2006-01-01","ids":{"openalex":"https://openalex.org/W4297802154","doi":"https://doi.org/10.1039/b603014a"},"language":"en","primary_location":{"id":"doi:10.1039/b603014a","doi":"https://doi.org/10.1039/b603014a","is_oa":false,"landing_page_url":"https://doi.org/10.1039/b603014a","pdf_url":null,"source":{"id":"https://openalex.org/S45305740","display_name":"Journal of Materials Chemistry","issn_l":"0959-9428","issn":["0959-9428","1364-5501"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"J. Mater. Chem.","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5015305876","display_name":"Adel Beghidja","orcid":"https://orcid.org/0000-0002-9740-8787","observed_orcids":["https://orcid.org/0000-0002-9740-8787"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210123402","display_name":"Institut de Physique et Chimie des Mat\u00e9riaux de Strasbourg","ror":"https://ror.org/02za18p66","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I4210098836","https://openalex.org/I4210123402","https://openalex.org/I68947357"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Adel Beghidja","raw_affiliation_strings":["Institut de Physique et Chimie des Mat\u00e9riaux de Strasbourg, UMR 7504 CNRS-ULP, 23 rue du Loess, BP 43, 67034 Strasbourg cedex 2, France","Laboratoire DECOMET, LC003 7177 CNRS-ULP, ILB, Universit\u00e9 Louis Pasteur, 4, rue Blaise Pascal, 67000 Strasbourg, France","Institut de Physique et Chimie des Mat\u00e9riaux de Strasbourg"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institut de Physique et Chimie des Mat\u00e9riaux de Strasbourg, UMR 7504 CNRS-ULP, 23 rue du Loess, BP 43, 67034 Strasbourg cedex 2, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210123402"]},{"raw_affiliation_string":"Laboratoire DECOMET, LC003 7177 CNRS-ULP, ILB, Universit\u00e9 Louis Pasteur, 4, rue Blaise Pascal, 67000 Strasbourg, France","institution_ids":["https://openalex.org/I1294671590"]},{"raw_affiliation_string":"Institut de Physique et Chimie des Mat\u00e9riaux de Strasbourg","institution_ids":["https://openalex.org/I4210123402"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5071290461","display_name":"Guillaume Rogez","orcid":"https://orcid.org/0000-0001-9006-7273","observed_orcids":["https://orcid.org/0000-0001-9006-7273"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210123402","display_name":"Institut de Physique et Chimie des Mat\u00e9riaux de Strasbourg","ror":"https://ror.org/02za18p66","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I4210098836","https://openalex.org/I4210123402","https://openalex.org/I68947357"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Guillaume Rogez","raw_affiliation_strings":["Institut de Physique et Chimie des Mat\u00e9riaux de Strasbourg, UMR 7504 CNRS-ULP, 23 rue du Loess, BP 43, 67034 Strasbourg cedex 2, France","Institut de Physique et Chimie des Mat\u00e9riaux de Strasbourg"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institut de Physique et Chimie des Mat\u00e9riaux de Strasbourg, UMR 7504 CNRS-ULP, 23 rue du Loess, BP 43, 67034 Strasbourg cedex 2, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210123402"]},{"raw_affiliation_string":"Institut de Physique et Chimie des Mat\u00e9riaux de Strasbourg","institution_ids":["https://openalex.org/I4210123402"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5068448098","display_name":"Pierre Rabu","orcid":"https://orcid.org/0000-0002-6779-1527","observed_orcids":["https://orcid.org/0000-0002-6779-1527"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210123402","display_name":"Institut de Physique et Chimie des Mat\u00e9riaux de Strasbourg","ror":"https://ror.org/02za18p66","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I4210098836","https://openalex.org/I4210123402","https://openalex.org/I68947357"]}],"countries":["FR"],"is_corresponding":true,"raw_author_name":"Pierre Rabu","raw_affiliation_strings":["Institut de Physique et Chimie des Mat\u00e9riaux de Strasbourg, UMR 7504 CNRS-ULP, 23 rue du Loess, BP 43, 67034 Strasbourg cedex 2, France","Institut de Physique et Chimie des Mat\u00e9riaux de Strasbourg"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institut de Physique et Chimie des Mat\u00e9riaux de Strasbourg, UMR 7504 CNRS-ULP, 23 rue du Loess, BP 43, 67034 Strasbourg cedex 2, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210123402"]},{"raw_affiliation_string":"Institut de Physique et Chimie des Mat\u00e9riaux de Strasbourg","institution_ids":["https://openalex.org/I4210123402"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5058483083","display_name":"Richard Welter","orcid":"https://orcid.org/0009-0005-3630-019X","observed_orcids":["https://orcid.org/0009-0005-3630-019X"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]}],"countries":["FR"],"is_corresponding":true,"raw_author_name":"Richard Welter","raw_affiliation_strings":["Laboratoire DECOMET, LC003 7177 CNRS-ULP, ILB, Universit\u00e9 Louis Pasteur, 4, rue Blaise Pascal, 67000 Strasbourg, France"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratoire DECOMET, LC003 7177 CNRS-ULP, ILB, Universit\u00e9 Louis Pasteur, 4, rue Blaise Pascal, 67000 Strasbourg, France","institution_ids":["https://openalex.org/I1294671590"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5107391586","display_name":"Marc Drillon","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210123402","display_name":"Institut de Physique et Chimie des Mat\u00e9riaux de Strasbourg","ror":"https://ror.org/02za18p66","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I4210098836","https://openalex.org/I4210123402","https://openalex.org/I68947357"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Marc Drillon","raw_affiliation_strings":["Institut de Physique et Chimie des Mat\u00e9riaux de Strasbourg, UMR 7504 CNRS-ULP, 23 rue du Loess, BP 43, 67034 Strasbourg cedex 2, France","Institut de Physique et Chimie des Mat\u00e9riaux de Strasbourg"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institut de Physique et Chimie des Mat\u00e9riaux de Strasbourg, UMR 7504 CNRS-ULP, 23 rue du Loess, BP 43, 67034 Strasbourg cedex 2, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210123402"]},{"raw_affiliation_string":"Institut de Physique et Chimie des Mat\u00e9riaux de Strasbourg","institution_ids":["https://openalex.org/I4210123402"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5058483083","https://openalex.org/A5068448098"],"corresponding_institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210123402"],"apc_list":null,"apc_paid":null,"fwci":2.3625,"has_fulltext":false,"cited_by_count":53,"citation_normalized_percentile":{"value":0.89381926,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":98},"biblio":{"volume":"16","issue":"26","first_page":"2715","last_page":"2728"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10612","display_name":"Magnetism in coordination complexes","score":0.9897000193595886,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10612","display_name":"Magnetism in coordination complexes","score":0.9897000193595886,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11682","display_name":"Advanced Condensed Matter Physics","score":0.002199999988079071,"subfield":{"id":"https://openalex.org/subfields/3104","display_name":"Condensed Matter Physics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10096","display_name":"Metal-Organic Frameworks: Synthesis and Applications","score":0.0015999999595806003,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/chiral-magnets","display_name":"chiral magnets","score":0.9959999918937683},{"id":"https://openalex.org/keywords/mandelic-acid","display_name":"mandelic acid","score":0.9419999718666077},{"id":"https://openalex.org/keywords/malic-acid","display_name":"malic acid","score":0.9369999766349792},{"id":"https://openalex.org/keywords/transition-metal-complexes","display_name":"transition metal complexes","score":0.8309999704360962},{"id":"https://openalex.org/keywords/hydrothermal-synthesis","display_name":"hydrothermal synthesis","score":0.8370000123977661},{"id":"https://openalex.org/keywords/racemization","display_name":"racemization","score":0.5929999947547913},{"id":"https://openalex.org/keywords/circular-dichroism","display_name":"circular dichroism","score":0.9710000157356262},{"id":"https://openalex.org/keywords/magnetic-coupling","display_name":"magnetic coupling","score":0.5820000171661377},{"id":"https://openalex.org/keywords/antiferromagnetism","display_name":"antiferromagnetism","score":0.7990000247955322},{"id":"https://openalex.org/keywords/ferromagnetism","display_name":"ferromagnetism","score":0.8809999823570251},{"id":"https://openalex.org/keywords/bimetallic-complexes","display_name":"bimetallic complexes","score":0.7559999823570251},{"id":"https://openalex.org/keywords/coordination-networks","display_name":"coordination networks","score":0.3440000116825104}],"concepts":[{"id":"https://openalex.org/C16389437","wikidata":"https://www.wikidata.org/wiki/Q11421","display_name":"Magnet","level":2,"score":0.7289379239082336},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.39278846979141235},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.36701124906539917},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0641951858997345}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1039/b603014a","doi":"https://doi.org/10.1039/b603014a","is_oa":false,"landing_page_url":"https://doi.org/10.1039/b603014a","pdf_url":null,"source":{"id":"https://openalex.org/S45305740","display_name":"Journal of Materials Chemistry","issn_l":"0959-9428","issn":["0959-9428","1364-5501"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"J. Mater. Chem.","raw_type":"journal-article"},{"id":"pmh:oai:HAL:hal-00205000v1","doi":null,"is_oa":false,"landing_page_url":"https://hal.science/hal-00205000","pdf_url":null,"source":{"id":"https://openalex.org/S4306402512","display_name":"HAL","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I4405252976","host_organization_name":"Centre pour la Communication Scientifique Directe","host_organization_lineage":["https://openalex.org/I4405252976"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Journal of Materials Chemistry, 2006, 16, pp.2715-2728","raw_type":"info:eu-repo/semantics/article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":60,"referenced_works":["https://openalex.org/W1483014147","https://openalex.org/W1566536395","https://openalex.org/W1659869836","https://openalex.org/W1850120019","https://openalex.org/W1968883476","https://openalex.org/W1970228396","https://openalex.org/W1971630079","https://openalex.org/W1972907354","https://openalex.org/W1983903380","https://openalex.org/W1985311268","https://openalex.org/W1992609971","https://openalex.org/W1995571998","https://openalex.org/W1998981899","https://openalex.org/W1999908724","https://openalex.org/W2000339772","https://openalex.org/W2000929824","https://openalex.org/W2005063414","https://openalex.org/W2006321001","https://openalex.org/W2006911445","https://openalex.org/W2007338127","https://openalex.org/W2007661885","https://openalex.org/W2008416598","https://openalex.org/W2008531219","https://openalex.org/W2009191711","https://openalex.org/W2009626366","https://openalex.org/W2009762784","https://openalex.org/W2011757095","https://openalex.org/W2012615244","https://openalex.org/W2021022741","https://openalex.org/W2029812407","https://openalex.org/W2030223380","https://openalex.org/W2032686478","https://openalex.org/W2036637182","https://openalex.org/W2041000952","https://openalex.org/W2042034542","https://openalex.org/W2043164916","https://openalex.org/W2046471185","https://openalex.org/W2049926447","https://openalex.org/W2054069750","https://openalex.org/W2056707510","https://openalex.org/W2065368491","https://openalex.org/W2071787451","https://openalex.org/W2083385160","https://openalex.org/W2086981229","https://openalex.org/W2089740902","https://openalex.org/W2090748133","https://openalex.org/W2097044076","https://openalex.org/W2110492955","https://openalex.org/W2126822973","https://openalex.org/W2127864138","https://openalex.org/W2130899135","https://openalex.org/W2133045527","https://openalex.org/W2149336686","https://openalex.org/W2166181554","https://openalex.org/W2168058993","https://openalex.org/W2314057309","https://openalex.org/W2315371705","https://openalex.org/W2335223626","https://openalex.org/W4248052365","https://openalex.org/W4252712467"],"related_works":["https://openalex.org/W2164426589","https://openalex.org/W594938351","https://openalex.org/W1963570514","https://openalex.org/W7043401640","https://openalex.org/W2036048113","https://openalex.org/W2091818574","https://openalex.org/W2036637182","https://openalex.org/W2126916179","https://openalex.org/W1978331751","https://openalex.org/W2033631250"],"abstract_inverted_index":{"Carboxylate-bridged":[0],"complexes":[1,84],"of":[2,16,40,120,151,168],"transition":[3],"metals,":[4],"MII":[5,17],"=":[6],"MnII,":[7],"FeII,":[8],"CoII,":[9],"NiII,":[10],"CuII,":[11],"were":[12],"synthesized":[13],"by":[14],"reaction":[15,94,102],"salts":[18],"with":[19,45,58,74,107],"(R)-mandelic":[20,97],"acid":[21,25,31,76,109],"((R)-2-hydroxyphenylacetic":[22],"acid),":[23],"methoxymandelic":[24],"(racemic)":[26],"(2-methoxyphenylacetic":[27],"acid)":[28,33],"and":[29,71,77,90,112,145,161],"(R)-malic":[30,108],"((R)-2-hydroxybutanedioic":[32],"under":[34],"hydrothermal":[35],"conditions.":[36],"A":[37],"wide":[38],"variety":[39],"structures":[41],"has":[42],"been":[43,86],"obtained,":[44],"various":[46],"dimensionalities:":[47],"3D":[48],"networks":[49,57],"when":[50],"the":[51,59,69,80,93,96,104,149,152],"malic":[52],"diacid":[53],"is":[54,146],"used,":[55],"2D":[56],"mandelic":[60],"acid,":[61],"1D":[62],"isolated":[63],"chains":[64],"organised":[65],"in":[66],"planes":[67],"for":[68,79],"Co":[70],"Cu":[72],"compounds":[73,105,122,157],"MeOmandelic":[75],"monomers":[78],"Ni":[81],"analogue.":[82],"These":[83],"have":[85],"fully":[87],"characterized":[88],"structurally":[89],"magnetically.":[91],"During":[92],"process,":[95],"ligand":[98],"undergoes":[99],"a":[100],"racemisation":[101],"but":[103],"obtained":[106],"are":[110,165],"chiral":[111,169],"exhibit":[113],"metal-centred":[114],"circular":[115],"dichroism.":[116],"Extensive":[117],"magnetic":[118],"characterization":[119],"all":[121],"indicates":[123],"rather":[124],"weak":[125,140],"coupling":[126],"interactions":[127],"between":[128],"paramagnetic":[129],"centres":[130],"linked":[131],"through":[132],"carboxylate":[133],"bridges.":[134],"Curie-like":[135],"paramagnetic,":[136],"antiferromagnetic,":[137],"ferromagnetic":[138,141],"or":[139],"behaviour":[142],"was":[143],"observed":[144],"discussed":[147],"on":[148],"basis":[150],"structural":[153],"features.":[154],"The":[155],"bimetallic":[156],"Mn0.63Co0.37(R)-malate":[158],"monohydrate":[159,163],"(12)":[160],"Mn0.79Ni0.21(R)-malate":[162],"(13)":[164],"new":[166],"examples":[167],"magnets.":[170]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2024,"cited_by_count":2},{"year":2023,"cited_by_count":3},{"year":2022,"cited_by_count":1},{"year":2021,"cited_by_count":2},{"year":2020,"cited_by_count":3},{"year":2019,"cited_by_count":3},{"year":2018,"cited_by_count":2},{"year":2014,"cited_by_count":2},{"year":2013,"cited_by_count":5},{"year":2012,"cited_by_count":4}],"updated_date":"2026-11-08T12:12:28.789561","created_date":"2025-10-10T00:00:00"}