{"id":"https://openalex.org/W4297722213","doi":null,"title":"Quantitative confirmation of diffusion-limited oxidation theories","display_name":"Quantitative confirmation of diffusion-limited oxidation theories","publication_year":2021,"publication_date":"2021-06-30","ids":{"openalex":"https://openalex.org/W4297722213"},"language":"en","primary_location":{"id":"pmh:oai:osti.gov:6816855","doi":null,"is_oa":true,"landing_page_url":"https://www.osti.gov/biblio/6816855","pdf_url":null,"source":{"id":"https://openalex.org/S4306402487","display_name":"OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I139351228","host_organization_name":"Office of Scientific and Technical Information","host_organization_lineage":["https://openalex.org/I139351228"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null},"volume":null,"type":"article","is_traditional":true,"indexed_in":[],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://www.osti.gov/biblio/6816855","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5011935059","display_name":"K. T. Gillen","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":true,"raw_author_name":"Gillen, K.T.; Clough, R.L.","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":["https://openalex.org/A5011935059"],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":0.071,"has_fulltext":false,"cited_by_count":7,"citation_normalized_percentile":{"value":0.20279443,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":97},"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12358","display_name":"Thermal and Kinetic Analysis","score":0.33739998936653137,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12358","display_name":"Thermal and Kinetic Analysis","score":0.33739998936653137,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13171","display_name":"Polymer Science and PVC","score":0.11940000206232071,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13013","display_name":"Free Radicals and Antioxidants","score":0.09809999912977219,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/diffusion-limited-oxidation","display_name":"diffusion-controlled oxidation","score":0.9959999918937683},{"id":"https://openalex.org/keywords/heterogeneous-oxidation","display_name":"heterogeneous oxidation","score":0.9269999861717224},{"id":"https://openalex.org/keywords/polymer-degradation","display_name":"polymer degradation","score":0.9480000138282776},{"id":"https://openalex.org/keywords/ionizing-radiation","display_name":"ionizing radiation","score":0.656000018119812},{"id":"https://openalex.org/keywords/gamma-irradiation","display_name":"gamma irradiation","score":0.6510000228881836},{"id":"https://openalex.org/keywords/epdm-rubber","display_name":"EPDM rubber","score":0.8980000019073486},{"id":"https://openalex.org/keywords/oxygen-permeation","display_name":"oxygen permeation","score":0.7820000052452087},{"id":"https://openalex.org/keywords/oxygen-consumption","display_name":"oxygen consumption","score":0.8009999990463257},{"id":"https://openalex.org/keywords/accelerated-aging","display_name":"accelerated aging","score":0.875}],"concepts":[{"id":"https://openalex.org/C69357855","wikidata":"https://www.wikidata.org/wiki/Q163214","display_name":"Diffusion","level":2,"score":0.6545277833938599},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.513118326663971},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.14916899800300598},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.1467559039592743}],"mesh":[],"locations_count":1,"locations":[{"id":"pmh:oai:osti.gov:6816855","doi":null,"is_oa":true,"landing_page_url":"https://www.osti.gov/biblio/6816855","pdf_url":null,"source":{"id":"https://openalex.org/S4306402487","display_name":"OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I139351228","host_organization_name":"Office of Scientific and Technical Information","host_organization_lineage":["https://openalex.org/I139351228"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null}],"best_oa_location":{"id":"pmh:oai:osti.gov:6816855","doi":null,"is_oa":true,"landing_page_url":"https://www.osti.gov/biblio/6816855","pdf_url":null,"source":{"id":"https://openalex.org/S4306402487","display_name":"OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I139351228","host_organization_name":"Office of Scientific and Technical Information","host_organization_lineage":["https://openalex.org/I139351228"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2058492302","https://openalex.org/W2489850654","https://openalex.org/W1998555159","https://openalex.org/W2071548564","https://openalex.org/W2052468415","https://openalex.org/W1970027950","https://openalex.org/W2042792150","https://openalex.org/W2008625274","https://openalex.org/W4407261063","https://openalex.org/W2092921542"],"abstract_inverted_index":{"Diffusion-limited":[0],"(heterogeneous)":[1],"oxidation":[2,32,117,148],"effects":[3,13],"are":[4,14,141],"often":[5],"important":[6],"for":[7,72,183],"studies":[8],"of":[9,40,76,118,121,159,169],"polymer":[10],"degradation.":[11],"Such":[12],"common":[15],"in":[16,37],"polymers":[17],"subjected":[18],"to":[19,35,48,51,92,132,143,180],"ionizing":[20],"radiation":[21],"at":[22],"relatively":[23],"high":[24],"dose":[25],"rate.":[26],"To":[27,112],"better":[28],"understand":[29,55],"the":[30,38,98,114,138,155,160,175,184,187],"underlying":[31],"processes":[33],"and":[34,53,101,110,163,171],"aid":[36],"planning":[39],"accelerated":[41],"aging":[42],"studies,":[43],"it":[44],"would":[45],"be":[46,49],"desirable":[47],"able":[50],"monitor":[52],"quantitatively":[54,181],"these":[56],"effects.":[57],"In":[58,150],"this":[59],"paper,":[60],"we":[61],"briefly":[62],"review":[63],"a":[64,93,119],"theoretical":[65,139,189],"diffusion":[66],"approach":[67],"which":[68,130],"derives":[69],"model":[70,107],"profiles":[71],"oxygen":[73,80,86,99,161],"surrounded":[74],"sheets":[75],"material":[77,158],"by":[78],"combining":[79],"permeation":[81,102,164],"rates":[82,103],"with":[83,105,167],"kinetically":[84],"based":[85],"consumption":[87,100,162],"expressions.":[88],"The":[89],"theory":[90],"leads":[91],"simple":[94],"governing":[95,188],"expression":[96],"involving":[97],"together":[104,166],"two":[106],"parameters":[108],"{alpha}":[109,170],"{beta}.":[111],"test":[113],"theory,":[115],"gamma-initiated":[116],"sheet":[120],"commercially":[122],"formulated":[123],"EPDM":[124,157],"rubber":[125],"was":[126],"performed":[127],"under":[128],"conditions":[129],"led":[131],"diffusion-limited":[133],"oxidation.":[134],"Profile":[135],"shapes":[136],"from":[137,174],"treatments":[140],"shown":[142],"accurately":[144],"fit":[145],"experimentally":[146],"derived":[147,173],"profiles.":[149],"addition,":[151],"direct":[152],"measurements":[153],"on":[154],"same":[156],"rates,":[165],"values":[168],"{beta}":[172],"fitting":[176],"procedure,":[177],"allow":[178],"us":[179],"confirm":[182],"first":[185],"time":[186],"relationship.":[190],"17":[191],"refs.,":[192],"3":[193],"figs.":[194]},"counts_by_year":[{"year":2022,"cited_by_count":1},{"year":2019,"cited_by_count":3}],"updated_date":"2026-09-25T08:18:29.962427","created_date":"2022-09-30T00:00:00"}