{"id":"https://openalex.org/W4297505070","doi":"https://doi.org/10.1021/acs.inorgchem.2c02447","title":"Ruthenium-Locked Helical Chirality: A Barrier of Inversion and Formation of an Asymmetric Macrocycle","display_name":"Ruthenium-Locked Helical Chirality: A Barrier of Inversion and Formation of an Asymmetric Macrocycle","publication_year":2022,"publication_date":"2022-09-29","ids":{"openalex":"https://openalex.org/W4297505070","doi":"https://doi.org/10.1021/acs.inorgchem.2c02447","pmid":"https://pubmed.ncbi.nlm.nih.gov/36171738","pmcid":"https://www.ncbi.nlm.nih.gov/pmc/articles/9554910"},"language":"en","primary_location":{"id":"doi:10.1021/acs.inorgchem.2c02447","doi":"https://doi.org/10.1021/acs.inorgchem.2c02447","is_oa":true,"landing_page_url":"https://doi.org/10.1021/acs.inorgchem.2c02447","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"hybrid","oa_url":"https://doi.org/10.1021/acs.inorgchem.2c02447","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5104306187","display_name":"Corjan van de Griend","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I121797337","display_name":"Leiden University","ror":"https://ror.org/027bh9e22","country_code":"NL","type":"education","lineage":["https://openalex.org/I121797337"]}],"countries":["NL"],"is_corresponding":false,"raw_author_name":"Corjan van de Griend","raw_affiliation_strings":["Leiden Institute of Chemistry, Leiden University, Einsteinweg 55, Leiden 2333CC, The Netherlands"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Leiden Institute of Chemistry, Leiden University, Einsteinweg 55, Leiden 2333CC, The Netherlands","institution_ids":["https://openalex.org/I121797337"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5054242316","display_name":"Johannes J. van de Vijver","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I121797337","display_name":"Leiden University","ror":"https://ror.org/027bh9e22","country_code":"NL","type":"education","lineage":["https://openalex.org/I121797337"]}],"countries":["NL"],"is_corresponding":false,"raw_author_name":"Johannes J. van de Vijver","raw_affiliation_strings":["Leiden Institute of Chemistry, Leiden University, Einsteinweg 55, Leiden 2333CC, The Netherlands"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Leiden Institute of Chemistry, Leiden University, Einsteinweg 55, Leiden 2333CC, The Netherlands","institution_ids":["https://openalex.org/I121797337"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5005123295","display_name":"Maxime A. Siegler","orcid":"https://orcid.org/0000-0003-4165-7810","observed_orcids":["https://orcid.org/0000-0003-4165-7810"]},"institutions":[{"id":"https://openalex.org/I145311948","display_name":"Johns Hopkins University","ror":"https://ror.org/00za53h95","country_code":"US","type":"education","lineage":["https://openalex.org/I145311948"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Maxime A. Siegler","raw_affiliation_strings":["Small molecule X-ray facility, Department of Chemistry, John Hopkins University, Baltimore, Maryland 21218, United States"],"raw_orcid":"https://orcid.org/0000-0003-4165-7810","affiliations":[{"raw_affiliation_string":"Small molecule X-ray facility, Department of Chemistry, John Hopkins University, Baltimore, Maryland 21218, United States","institution_ids":["https://openalex.org/I145311948"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5069317982","display_name":"Remus Thei Dame","orcid":"https://orcid.org/0000-0001-9863-1692","observed_orcids":["https://orcid.org/0000-0001-9863-1692"]},"institutions":[{"id":"https://openalex.org/I121797337","display_name":"Leiden University","ror":"https://ror.org/027bh9e22","country_code":"NL","type":"education","lineage":["https://openalex.org/I121797337"]}],"countries":["NL"],"is_corresponding":false,"raw_author_name":"Remus T. Dame","raw_affiliation_strings":["Leiden Institute of Chemistry, Leiden University, Einsteinweg 55, Leiden 2333CC, The Netherlands"],"raw_orcid":"https://orcid.org/0000-0001-9863-1692","affiliations":[{"raw_affiliation_string":"Leiden Institute of Chemistry, Leiden University, Einsteinweg 55, Leiden 2333CC, The Netherlands","institution_ids":["https://openalex.org/I121797337"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5058318761","display_name":"Sylvestre Bonnet","orcid":"https://orcid.org/0000-0002-5810-3657","observed_orcids":["https://orcid.org/0000-0002-5810-3657"]},"institutions":[{"id":"https://openalex.org/I121797337","display_name":"Leiden University","ror":"https://ror.org/027bh9e22","country_code":"NL","type":"education","lineage":["https://openalex.org/I121797337"]}],"countries":["NL"],"is_corresponding":true,"raw_author_name":"Sylvestre Bonnet","raw_affiliation_strings":["Leiden Institute of Chemistry, Leiden University, Einsteinweg 55, Leiden 2333CC, The Netherlands"],"raw_orcid":"https://orcid.org/0000-0002-5810-3657","affiliations":[{"raw_affiliation_string":"Leiden Institute of Chemistry, Leiden University, Einsteinweg 55, Leiden 2333CC, The Netherlands","institution_ids":["https://openalex.org/I121797337"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5058318761"],"corresponding_institution_ids":["https://openalex.org/I121797337"],"apc_list":{"value":5000,"currency":"USD","value_usd":5000},"apc_paid":{"value":5000,"currency":"USD","value_usd":5000},"fwci":0.375,"has_fulltext":true,"cited_by_count":4,"citation_normalized_percentile":{"value":0.4267597,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":95},"biblio":{"volume":"61","issue":"40","first_page":"16045","last_page":"16054"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10578","display_name":"Supramolecular Chemistry and Complexes","score":0.4708999991416931,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10578","display_name":"Supramolecular Chemistry and Complexes","score":0.4708999991416931,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12748","display_name":"Molecular spectroscopy and chirality","score":0.22059999406337738,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.08510000258684158,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/helical-chirality","display_name":"helical chirality","score":0.9100000262260437},{"id":"https://openalex.org/keywords/ruthenium-ii-complexes","display_name":"ruthenium(II) complexes","score":0.9670000076293945},{"id":"https://openalex.org/keywords/inversion-barrier","display_name":"inversion barrier","score":0.5460000038146973},{"id":"https://openalex.org/keywords/macrocyclization","display_name":"macrocyclization","score":0.7049999833106995},{"id":"https://openalex.org/keywords/sulfoxide-ligands","display_name":"sulfoxide ligands","score":0.703000009059906},{"id":"https://openalex.org/keywords/diastereotopic-protons","display_name":"diastereotopic protons","score":0.7269999980926514},{"id":"https://openalex.org/keywords/steric-strain","display_name":"steric strain","score":0.621999979019165},{"id":"https://openalex.org/keywords/methoxy-group","display_name":"methoxy substituents","score":0.5479999780654907},{"id":"https://openalex.org/keywords/chiral-ligands","display_name":"chiral ligands","score":0.36500000953674316},{"id":"https://openalex.org/keywords/axial-chirality","display_name":"axial chirality","score":0.367000013589859}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9397525787353516},{"id":"https://openalex.org/C201194858","wikidata":"https://www.wikidata.org/wiki/Q898238","display_name":"Steric effects","level":2,"score":0.7693150639533997},{"id":"https://openalex.org/C124668440","wikidata":"https://www.wikidata.org/wiki/Q2305173","display_name":"Chirality (physics)","level":5,"score":0.6985439658164978},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.5826269388198853},{"id":"https://openalex.org/C555196967","wikidata":"https://www.wikidata.org/wiki/Q1086","display_name":"Ruthenium","level":3,"score":0.5715914368629456},{"id":"https://openalex.org/C2779336533","wikidata":"https://www.wikidata.org/wiki/Q413658","display_name":"Bipyridine","level":3,"score":0.5387557148933411},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.5336571335792542},{"id":"https://openalex.org/C198819137","wikidata":"https://www.wikidata.org/wiki/Q188884","display_name":"Octahedron","level":3,"score":0.4313631057739258},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.4246480166912079},{"id":"https://openalex.org/C103319777","wikidata":"https://www.wikidata.org/wiki/Q1979695","display_name":"Proton NMR","level":2,"score":0.4190911054611206},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.18062520027160645},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.10764414072036743},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C52703039","wikidata":"https://www.wikidata.org/wiki/Q5101837","display_name":"Chiral symmetry breaking","level":3,"score":0.0},{"id":"https://openalex.org/C20621625","wikidata":"https://www.wikidata.org/wiki/Q6961432","display_name":"Nambu\u2013Jona-Lasinio model","level":4,"score":0.0},{"id":"https://openalex.org/C7602139","wikidata":"https://www.wikidata.org/wiki/Q6718","display_name":"Quark","level":2,"score":0.0},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0}],"mesh":[],"locations_count":6,"locations":[{"id":"doi:10.1021/acs.inorgchem.2c02447","doi":"https://doi.org/10.1021/acs.inorgchem.2c02447","is_oa":true,"landing_page_url":"https://doi.org/10.1021/acs.inorgchem.2c02447","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},{"id":"pmh:oai:pubmedcentral.nih.gov:9554910","doi":null,"is_oa":true,"landing_page_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/9554910","pdf_url":null,"source":{"id":"https://openalex.org/S2764455111","display_name":"PubMed Central","issn_l":null,"issn":null,"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorg Chem","raw_type":"Text"},{"id":"pmid:36171738","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/36171738","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic chemistry","raw_type":"Journal Article"},{"id":"pmh:oai:alma.31UKB_LEU:9940748598302711","doi":null,"is_oa":true,"landing_page_url":"https://scholarlypublications.universiteitleiden.nl/handle/1887/3480131","pdf_url":"https://scholarlypublications.universiteitleiden.nl/download/1887/3480131/1?col=81522199430002711","source":{"id":"https://openalex.org/S4306400850","display_name":"Leiden Repository (Leiden University)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I121797337","host_organization_name":"Leiden University","host_organization_lineage":["https://openalex.org/I121797337"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Inorganic Chemistry, Vol. 61, no. 40, p. 16045\u201316054","raw_type":"http://purl.org/coar/resource_type/c_6501"},{"id":"pmh:oai:scholarlypublications.universiteitleiden.nl:item_3480131","doi":null,"is_oa":true,"landing_page_url":"https://hdl.handle.net/1887/3480131","pdf_url":null,"source":{"id":"https://openalex.org/S4306400850","display_name":"Leiden Repository (Leiden University)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I121797337","host_organization_name":"Leiden University","host_organization_lineage":["https://openalex.org/I121797337"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Inorganic Chemistry","raw_type":"Article / Letter to editor"},{"id":"pmh:ul:oai:scholarlypublications.universiteitleiden.nl:item_3480131","doi":null,"is_oa":true,"landing_page_url":"http://hdl.handle.net/1887/3480131","pdf_url":null,"source":{"id":"https://openalex.org/S4306401843","display_name":"Data Archiving and Networked Services (DANS)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1322597698","host_organization_name":"Royal Netherlands Academy of Arts and Sciences","host_organization_lineage":["https://openalex.org/I1322597698"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Inorganic Chemistry, 61(40), 16045\u201316054. AMER CHEMICAL SOC","raw_type":"info:eu-repo/semantics/article"}],"best_oa_location":{"id":"doi:10.1021/acs.inorgchem.2c02447","doi":"https://doi.org/10.1021/acs.inorgchem.2c02447","is_oa":true,"landing_page_url":"https://doi.org/10.1021/acs.inorgchem.2c02447","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320320929","display_name":"Universiteit Leiden","ror":"https://ror.org/027bh9e22"}],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W4297505070.pdf","grobid_xml":"https://content.openalex.org/works/W4297505070.grobid-xml"},"referenced_works_count":42,"referenced_works":["https://openalex.org/W74691089","https://openalex.org/W153075741","https://openalex.org/W1741860215","https://openalex.org/W1980411311","https://openalex.org/W1998849540","https://openalex.org/W2016565254","https://openalex.org/W2018308587","https://openalex.org/W2019626206","https://openalex.org/W2028991168","https://openalex.org/W2031193300","https://openalex.org/W2034890160","https://openalex.org/W2056591085","https://openalex.org/W2066257950","https://openalex.org/W2078071000","https://openalex.org/W2100269707","https://openalex.org/W2105249240","https://openalex.org/W2130177169","https://openalex.org/W2148642364","https://openalex.org/W2236820649","https://openalex.org/W2311097780","https://openalex.org/W2343194531","https://openalex.org/W2496618181","https://openalex.org/W2770352080","https://openalex.org/W2795508872","https://openalex.org/W2809083810","https://openalex.org/W2903866919","https://openalex.org/W2917695861","https://openalex.org/W2922467890","https://openalex.org/W2943752752","https://openalex.org/W2960179821","https://openalex.org/W2968796917","https://openalex.org/W2997280099","https://openalex.org/W3026365981","https://openalex.org/W3046931753","https://openalex.org/W3103600027","https://openalex.org/W3148602146","https://openalex.org/W3157057151","https://openalex.org/W3172188606","https://openalex.org/W3176190665","https://openalex.org/W3186674810","https://openalex.org/W3190904588","https://openalex.org/W3198990617"],"related_works":["https://openalex.org/W2061940521","https://openalex.org/W1976530900","https://openalex.org/W1991917830","https://openalex.org/W3186674810","https://openalex.org/W2346586739","https://openalex.org/W2023485857","https://openalex.org/W1970374111","https://openalex.org/W1969686416","https://openalex.org/W4415216456","https://openalex.org/W2081709885"],"abstract_inverted_index":{"High":[0],"Resolution":[1],"Image":[2],"Download":[3],"MS":[4],"PowerPoint":[5],"Slide":[6],"Upon":[7],"coordination":[8,243],"to":[9,25,46,125,159,179,204,232,235,248],"metal":[10,48],"centers,":[11],"tetradentate":[12],"ligands":[13,44],"based":[14],"on":[15,63],"the":[16,26,30,34,40,47,67,105,108,143,171,180,184,192,245],"6,6\u2032-bis(2\u2033-aminopyridyl)-2,2\u2032-bipyridine":[17],"(bapbpy)":[18],"structure":[19],"form":[20],"helical":[21,71,109,163],"chiral":[22,89,218],"complexes":[23],"due":[24],"steric":[27,172],"clash":[28],"between":[29],"terminal":[31,145,185],"pyridines":[32],"of":[33,70,107,111,162,183,195,244],"ligand.":[35],"For":[36],"octahedral":[37],"ruthenium(II)":[38,236],"complexes,":[39,76],"two":[41],"additional":[42],"axial":[43],"bound":[45],"center,":[49],"when":[50],"different,":[51],"generate":[52],"diastereotopic":[53],"aromatic":[54],"protons":[55],"that":[56,199],"can":[57],"be":[58,126,233],"distinguished":[59],"by":[60,96,142,174],"NMR.":[61,100],"Based":[62],"these":[64],"geometrical":[65],"features,":[66],"inversion":[68,106,165],"barrier":[69],"[Ru":[72],"II":[73],"(L)(RR\u2032SO)Cl]":[74],"+":[75,207],"where":[77,221],"L":[78],"is":[79,87,117,223],"a":[80,88,150,196,217],"sterically":[81],"hindered":[82],"bapbpy":[83,189],"derivative":[84],"and":[85,113,128],"RR\u2032SO":[86],"or":[90,250],"achiral":[91],"sulfoxide":[92],"ligand,":[93],"was":[94],"studied":[95],"variable-temperature":[97],"1":[98],"H":[99],"The":[101],"coalescence":[102,151],"energies":[103],"for":[104],"chirality":[110,164],"[Ru(bapbpy)(DMSO)(Cl)]Cl":[112],"[Ru(bapbpy)(MTSO)(Cl)]Cl":[114],"(where":[115],"MTSO":[116],"(":[118],"R":[119],")-methyl":[120],"p":[121],"-tolylsulfoxide)":[122],"were":[123],"found":[124],"43":[127],"44":[129],"kJ/mol,":[130],"respectively.":[131],"By":[132],"contrast,":[133],"in":[134,149,188,191,214],"[Ru(biqbpy)(DMSO)(Cl)]Cl":[135],"(biqbpy":[136],"=":[137,209],"6,6\u2032-bis(aminoquinolyl)-2,2\u2032-bipyridine),":[138],"increased":[139],"strain":[140,173],"caused":[141],"larger":[144],"quinoline":[146],"groups":[147,177,187],"resulted":[148,190],"temperature":[152],"higher":[153],"than":[154],"376":[155],"K,":[156],"which":[157],"pointed":[158],"an":[160,224],"absence":[161],"at":[166],"room":[167],"temperature.":[168],"Further":[169],"increasing":[170],"introducing":[175],"methoxy":[176],"ortho":[178],"nitrogen":[181],"atoms":[182],"pyridyl":[186],"serendipitous":[193],"discovery":[194],"ring-closing":[197],"reaction":[198,212],"took":[200],"place":[201],"upon":[202,242],"trying":[203],"make":[205],"[Ru(OMe-bapbpy)(DMSO)Cl]":[206],"(OMe-bapbpy":[208],"6,6\u2032-bis(6-methoxy-aminopyridyl)-2,2\u2032-bipyridine).":[210],"This":[211,228],"generated,":[213],"excellent":[215],"yields,":[216],"complex":[219],"[Ru(L\u2033)(DMSO)Cl]Cl,":[220],"L\u2033":[222],"asymmetric":[225],"tetrapyridyl":[226],"macrocycle.":[227],"unexpected":[229],"transformation":[230],"appears":[231],"specific":[234],"as":[237],"macrocyclization":[238],"did":[239],"not":[240],"occur":[241],"same":[246],"ligand":[247],"palladium(II)":[249],"rhodium(III).":[251]},"counts_by_year":[{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":1},{"year":2023,"cited_by_count":2}],"updated_date":"2026-11-06T12:05:46.655746","created_date":"2022-09-29T00:00:00"}
