{"id":"https://openalex.org/W4291789984","doi":"https://doi.org/10.1021/acs.jpcb.2c04092","title":"Emergent Sequence Biasing in Step-Growth Copolymerization: Influence of Non-Bonded Interactions and Comonomer Reactivities","display_name":"Emergent Sequence Biasing in Step-Growth Copolymerization: Influence of Non-Bonded Interactions and Comonomer Reactivities","publication_year":2022,"publication_date":"2022-08-15","ids":{"openalex":"https://openalex.org/W4291789984","doi":"https://doi.org/10.1021/acs.jpcb.2c04092","pmid":"https://pubmed.ncbi.nlm.nih.gov/35969198"},"language":"en","primary_location":{"id":"doi:10.1021/acs.jpcb.2c04092","doi":"https://doi.org/10.1021/acs.jpcb.2c04092","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.jpcb.2c04092","pdf_url":null,"source":{"id":"https://openalex.org/S185621672","display_name":"The Journal of Physical Chemistry B","issn_l":"1520-5207","issn":["1520-5207","1520-6106"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","ki-jl-1","medline","norway-1","poland-140","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry B","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://chemrxiv.org/engage/api-gateway/chemrxiv/assets/orp/resource/item/62a183cf8f92d994c74abc96/original/emergent-sequence-biasing-in-step-growth-copolymerization-influence-of-non-bonded-interactions-and-comonomer-reactivities.pdf","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5101419195","display_name":"Nhu Q. Nguyen","orcid":"https://orcid.org/0000-0001-8171-7940","observed_orcids":["https://orcid.org/0000-0001-8171-7940"]},"institutions":[{"id":"https://openalex.org/I51556381","display_name":"University of Virginia","ror":"https://ror.org/0153tk833","country_code":"US","type":"education","lineage":["https://openalex.org/I51556381"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Nhu Q. Nguyen","raw_affiliation_strings":["Department of Chemistry, University of Virginia, Charlottesville, Virginia 22904, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Virginia, Charlottesville, Virginia 22904, United States","institution_ids":["https://openalex.org/I51556381"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5071525461","display_name":"Ryan L. Hamblin","orcid":"https://orcid.org/0000-0003-2802-4314","observed_orcids":["https://orcid.org/0000-0003-2802-4314"]},"institutions":[{"id":"https://openalex.org/I51556381","display_name":"University of Virginia","ror":"https://ror.org/0153tk833","country_code":"US","type":"education","lineage":["https://openalex.org/I51556381"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Ryan L. Hamblin","raw_affiliation_strings":["Department of Chemistry, University of Virginia, Charlottesville, Virginia 22904, United States"],"raw_orcid":"https://orcid.org/0000-0003-2802-4314","affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Virginia, Charlottesville, Virginia 22904, United States","institution_ids":["https://openalex.org/I51556381"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5019934984","display_name":"Kateri H. DuBay","orcid":"https://orcid.org/0000-0003-3388-1521","observed_orcids":["https://orcid.org/0000-0003-3388-1521"]},"institutions":[{"id":"https://openalex.org/I51556381","display_name":"University of Virginia","ror":"https://ror.org/0153tk833","country_code":"US","type":"education","lineage":["https://openalex.org/I51556381"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Kateri H. DuBay","raw_affiliation_strings":["Department of Chemistry, University of Virginia, Charlottesville, Virginia 22904, United States"],"raw_orcid":"https://orcid.org/0000-0003-3388-1521","affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Virginia, Charlottesville, Virginia 22904, United States","institution_ids":["https://openalex.org/I51556381"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5019934984"],"corresponding_institution_ids":["https://openalex.org/I51556381"],"apc_list":null,"apc_paid":null,"fwci":0.462,"has_fulltext":false,"cited_by_count":5,"citation_normalized_percentile":{"value":0.44045962,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":97},"biblio":{"volume":"126","issue":"34","first_page":"6585","last_page":"6597"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.9800000190734863,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.9800000190734863,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11471","display_name":"Block Copolymer Self-Assembly","score":0.007000000216066837,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10389","display_name":"Polymer crystallization and properties","score":0.006800000090152025,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/copolymerization-kinetics","display_name":"copolymerization kinetics","score":0.796999990940094},{"id":"https://openalex.org/keywords/microphase-separation","display_name":"microphase separation","score":0.8960000276565552},{"id":"https://openalex.org/keywords/monomer-sequence-distribution","display_name":"monomer sequence distribution","score":0.5619999766349792}],"concepts":[{"id":"https://openalex.org/C2780672802","wikidata":"https://www.wikidata.org/wiki/Q55999569","display_name":"Comonomer","level":4,"score":0.9736534357070923},{"id":"https://openalex.org/C15920480","wikidata":"https://www.wikidata.org/wiki/Q421281","display_name":"Copolymer","level":3,"score":0.88115394115448},{"id":"https://openalex.org/C166940927","wikidata":"https://www.wikidata.org/wiki/Q178827","display_name":"Monomer","level":3,"score":0.7635166645050049},{"id":"https://openalex.org/C148898269","wikidata":"https://www.wikidata.org/wiki/Q1108792","display_name":"Kinetics","level":2,"score":0.6375287771224976},{"id":"https://openalex.org/C2778112365","wikidata":"https://www.wikidata.org/wiki/Q3511065","display_name":"Sequence (biology)","level":2,"score":0.6156778931617737},{"id":"https://openalex.org/C44228677","wikidata":"https://www.wikidata.org/wiki/Q181898","display_name":"Polymerization","level":3,"score":0.5398285984992981},{"id":"https://openalex.org/C2776910235","wikidata":"https://www.wikidata.org/wiki/Q18574","display_name":"Reactivity (psychology)","level":3,"score":0.5103949904441833},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5094819664955139},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.470016747713089},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.4044300317764282},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.3796512484550476},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.35852235555648804},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.12883791327476501},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.07856661081314087},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C204787440","wikidata":"https://www.wikidata.org/wiki/Q188504","display_name":"Alternative medicine","level":2,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C142724271","wikidata":"https://www.wikidata.org/wiki/Q7208","display_name":"Pathology","level":1,"score":0.0}],"mesh":[{"descriptor_ui":"D007700","descriptor_name":"Kinetics","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D011108","descriptor_name":"Polymers","qualifier_ui":null,"qualifier_name":null,"is_major_topic":true},{"descriptor_ui":"D058105","descriptor_name":"Polymerization","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false}],"locations_count":3,"locations":[{"id":"doi:10.1021/acs.jpcb.2c04092","doi":"https://doi.org/10.1021/acs.jpcb.2c04092","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.jpcb.2c04092","pdf_url":null,"source":{"id":"https://openalex.org/S185621672","display_name":"The Journal of Physical Chemistry B","issn_l":"1520-5207","issn":["1520-5207","1520-6106"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","ki-jl-1","medline","norway-1","poland-140","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry B","raw_type":"journal-article"},{"id":"doi:10.26434/chemrxiv-2022-vj3cx","doi":"https://doi.org/10.26434/chemrxiv-2022-vj3cx","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv-2022-vj3cx","pdf_url":"https://chemrxiv.org/engage/api-gateway/chemrxiv/assets/orp/resource/item/62a183cf8f92d994c74abc96/original/emergent-sequence-biasing-in-step-growth-copolymerization-influence-of-non-bonded-interactions-and-comonomer-reactivities.pdf","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},{"id":"pmid:35969198","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/35969198","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The journal of physical chemistry. B","raw_type":"Journal Article"}],"best_oa_location":{"id":"doi:10.26434/chemrxiv-2022-vj3cx","doi":"https://doi.org/10.26434/chemrxiv-2022-vj3cx","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv-2022-vj3cx","pdf_url":"https://chemrxiv.org/engage/api-gateway/chemrxiv/assets/orp/resource/item/62a183cf8f92d994c74abc96/original/emergent-sequence-biasing-in-step-growth-copolymerization-influence-of-non-bonded-interactions-and-comonomer-reactivities.pdf","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G2083274571","display_name":null,"funder_award_id":"1848009","funder_id":"https://openalex.org/F4320337393","funder_display_name":"Division of Chemistry"},{"id":"https://openalex.org/G6135615301","display_name":"CAREER: Using numerical simulation to investigate the influence of collective behaviors on the sequences of step-grown copolymers","funder_award_id":"1848009","funder_id":"https://openalex.org/F4320306076","funder_display_name":"National Science Foundation"},{"id":"https://openalex.org/G8785681038","display_name":null,"funder_award_id":"26863","funder_id":"https://openalex.org/F4320306487","funder_display_name":"Research Corporation for Science Advancement"}],"funders":[{"id":"https://openalex.org/F4320306076","display_name":"National Science Foundation","ror":"https://ror.org/021nxhr62"},{"id":"https://openalex.org/F4320306487","display_name":"Research Corporation for Science Advancement","ror":"https://ror.org/00jp8d455"},{"id":"https://openalex.org/F4320310536","display_name":"University of Virginia","ror":"https://ror.org/0153tk833"},{"id":"https://openalex.org/F4320337393","display_name":"Division of Chemistry","ror":"https://ror.org/01ar8dr59"}],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W4291789984.pdf","grobid_xml":"https://content.openalex.org/works/W4291789984.grobid-xml"},"referenced_works_count":39,"referenced_works":["https://openalex.org/W1507573241","https://openalex.org/W1970571815","https://openalex.org/W1992258152","https://openalex.org/W1995024825","https://openalex.org/W2025383314","https://openalex.org/W2035972208","https://openalex.org/W2041278780","https://openalex.org/W2052349761","https://openalex.org/W2057953526","https://openalex.org/W2062987995","https://openalex.org/W2092837266","https://openalex.org/W2104018884","https://openalex.org/W2125065227","https://openalex.org/W2141298141","https://openalex.org/W2150184000","https://openalex.org/W2166295771","https://openalex.org/W2314659927","https://openalex.org/W2315929257","https://openalex.org/W2320556745","https://openalex.org/W2324818055","https://openalex.org/W2566858994","https://openalex.org/W2619183858","https://openalex.org/W2758667808","https://openalex.org/W2783300534","https://openalex.org/W2794179757","https://openalex.org/W2893803688","https://openalex.org/W2900761099","https://openalex.org/W2904335390","https://openalex.org/W2950705664","https://openalex.org/W2958825947","https://openalex.org/W2964103090","https://openalex.org/W2965497785","https://openalex.org/W3122664836","https://openalex.org/W3148722499","https://openalex.org/W3173312870","https://openalex.org/W3196846102","https://openalex.org/W3206396973","https://openalex.org/W3217535724","https://openalex.org/W4239115759"],"related_works":["https://openalex.org/W6888043540","https://openalex.org/W6944497035","https://openalex.org/W2958825947","https://openalex.org/W6962690282","https://openalex.org/W2020177295","https://openalex.org/W3148722499","https://openalex.org/W4403423451","https://openalex.org/W2359873998","https://openalex.org/W2083672735","https://openalex.org/W1981459713"],"abstract_inverted_index":{"The":[0],"phase":[1,262,270],"behavior":[2],"and":[3,38,65,67,169,174,195,229,238,259],"material":[4],"properties":[5,40,271],"of":[6,41,50,72,163,241,276],"copolymers":[7],"are":[8,58,68,233],"intrinsically":[9],"dependent":[10],"on":[11,70,160,203],"their":[12],"primary":[13],"comonomer":[14],"sequences.":[15,127],"Achieving":[16],"precise":[17],"control":[18],"over":[19],"monomer":[20,94,149],"sequence":[21,28,66,231,258],"in":[22,82,114,123,133,165,197,213,216,272],"synthetic":[23],"copolymerizations":[24],"is":[25,30],"challenging,":[26],"as":[27,245],"determination":[29],"influenced":[31],"not":[32],"only":[33],"by":[34,46],"the":[35,39,42,47,51,111,124,136,157,176,193,204,223,239,246,254,265,273],"reaction":[36,143,247],"conditions":[37],"reactants":[43],"but":[44],"also":[45,119,201],"statistical":[48],"nature":[49],"copolymerization":[52,161,183],"process":[53],"itself.":[54],"Mayo-Lewis":[55],"reactivity":[56,74],"ratios":[57,71],"often":[59],"used":[60],"to":[61,104,110,218,221],"predict":[62],"copolymer":[63,126],"composition":[64],"based":[69],"static":[73],"constants.":[75],"However,":[76],"prior":[77],"results":[78,186],"have":[79],"demonstrated":[80],"that":[81,145,188,200,208],"a":[83,198],"generic,":[84],"solution-based":[85],"step-growth":[86,182],"A,B-copolymerization,":[87],"relatively":[88],"weak":[89],"non-bonded":[90,170,205],"attractions":[91,171],"between":[92,147,172,257],"certain":[93,236],"pairs":[95],"induce":[96],"emergent":[97,112,269],"microphase":[98],"separations.":[99],"Such":[100],"polymerization-driven":[101],"separations":[102],"lead":[103],"deviations":[105],"from":[106],"standard":[107],"kinetics":[108,162,194],"due":[109],"heterogeneities":[113],"reactant":[115],"concentrations,":[116],"which":[117],"can":[118],"cause":[120],"significant":[121],"shifts":[122,244],"resulting":[125],"Previously,":[128],"these":[129,209],"effects":[130,159,210],"were":[131,139],"observed":[132,234],"systems":[134],"where":[135],"activation":[137,167,190],"energies":[138,168,191],"equal":[140],"for":[141,267],"all":[142,148],"pathways,":[144],"is,":[146],"pair":[150],"combinations.":[151],"In":[152],"this":[153,180],"work,":[154],"we":[155],"explore":[156],"combined":[158],"differences":[164],"both":[166],"monomers":[173],"examine":[175],"sequences":[177,196,224],"produced":[178],"within":[179],"same":[181],"model.":[184],"Our":[185],"indicate":[187],"altering":[189],"influences":[192],"manner":[199],"depends":[202],"attractions,":[206],"showing":[207],"may":[211],"work":[212],"concert":[214],"or":[215],"opposition":[217],"one":[219],"another":[220],"bias":[222],"formed.":[225],"Non-standard":[226],"kinetic":[227],"behaviors":[228],"long-range":[230],"biasing":[232],"under":[235],"conditions,":[237],"extent":[240],"each":[242],"clearly":[243],"proceeds.":[248],"These":[249],"findings":[250],"provide":[251],"insight":[252],"into":[253],"complex":[255],"interplay":[256],"nascent":[260],"oligomer":[261],"behavior,":[263],"highlighting":[264],"potential":[266],"exploiting":[268],"informed":[274],"design":[275],"advanced":[277],"sequence-biased":[278],"materials.":[279]},"counts_by_year":[{"year":2025,"cited_by_count":4},{"year":2024,"cited_by_count":1}],"updated_date":"2026-11-09T13:22:03.289127","created_date":"2022-08-16T00:00:00"}
