{"id":"https://openalex.org/W4291313402","doi":"https://doi.org/10.36807/1998-9849-2022-61-87-51-56","title":"KINETICS AND MECHANISM OF THE CURTIUS REARRANGEMENT OF m-NITROBENZOYL AZIDE IN AQUEOUS SOLUTIONS OF SULFURIC ACID","display_name":"KINETICS AND MECHANISM OF THE CURTIUS REARRANGEMENT OF m-NITROBENZOYL AZIDE IN AQUEOUS SOLUTIONS OF SULFURIC ACID","publication_year":2022,"publication_date":"2022-01-01","ids":{"openalex":"https://openalex.org/W4291313402","doi":"https://doi.org/10.36807/1998-9849-2022-61-87-51-56"},"language":"en","primary_location":{"id":"doi:10.36807/1998-9849-2022-61-87-51-56","doi":"https://doi.org/10.36807/1998-9849-2022-61-87-51-56","is_oa":true,"landing_page_url":"http://doi.org/10.36807/1998-9849-2022-61-87-51-56","pdf_url":null,"source":{"id":"https://openalex.org/S4210187031","display_name":"Bulletin of the Saint Petersburg State Institute of Technology (Technical University)","issn_l":"1998-9849","issn":["1998-9849"],"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Bulletin of the Saint Petersburg State Institute of Technology (Technical University)","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"diamond","oa_url":"http://doi.org/10.36807/1998-9849-2022-61-87-51-56","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5017224702","display_name":"Yu. N. Pavlyukova","orcid":"https://orcid.org/0000-0002-6262-1879","observed_orcids":["https://orcid.org/0000-0002-6262-1879"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Yuliya N. Pavlyukova","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5096360420","display_name":"Natalija V. Kudryavtseva","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Natalija V. Kudryavtseva","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5010677702","display_name":"Vladimir A. Ostrovskii","orcid":"https://orcid.org/0000-0002-6628-8540","observed_orcids":["https://orcid.org/0000-0002-6628-8540"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Vladimir \u0410. Ostrovskii","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":"51","last_page":"56"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12191","display_name":"Physical Organic Chemistry and Reaction Kinetics","score":0.9585000276565552,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12191","display_name":"Physical Organic Chemistry and Reaction Kinetics","score":0.9585000276565552,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13253","display_name":"Photolysis and Reactive Intermediates","score":0.02280000038444996,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T14068","display_name":"Organic and Inorganic Chemical Reactions","score":0.010599999688565731,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/curtius-rearrangement","display_name":"Curtius rearrangement","score":0.996999979019165},{"id":"https://openalex.org/keywords/reaction-kinetics","display_name":"reaction kinetics","score":0.8370000123977661},{"id":"https://openalex.org/keywords/reaction-mechanism","display_name":"reaction mechanism","score":0.9990000128746033},{"id":"https://openalex.org/keywords/sulfuric-acid","display_name":"sulfuric acid","score":0.7919999957084656},{"id":"https://openalex.org/keywords/acidic-aqueous-solutions","display_name":"acidic aqueous solutions","score":0.6439999938011169},{"id":"https://openalex.org/keywords/acidity-effects","display_name":"acidity effects","score":0.6010000109672546},{"id":"https://openalex.org/keywords/rate-limiting-step","display_name":"rate-determining step","score":0.9139999747276306},{"id":"https://openalex.org/keywords/isocyanate-formation","display_name":"isocyanate formation","score":0.9089999794960022}],"concepts":[{"id":"https://openalex.org/C91417817","wikidata":"https://www.wikidata.org/wiki/Q254370","display_name":"Curtius rearrangement","level":2,"score":0.9256749749183655},{"id":"https://openalex.org/C2778199549","wikidata":"https://www.wikidata.org/wiki/Q4118","display_name":"Sulfuric acid","level":2,"score":0.8724865913391113},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7643923163414001},{"id":"https://openalex.org/C2780997848","wikidata":"https://www.wikidata.org/wiki/Q407627","display_name":"Azide","level":2,"score":0.7472748160362244},{"id":"https://openalex.org/C184651966","wikidata":"https://www.wikidata.org/wiki/Q906356","display_name":"Aqueous solution","level":2,"score":0.7119897603988647},{"id":"https://openalex.org/C2780534471","wikidata":"https://www.wikidata.org/wiki/Q408365","display_name":"Isocyanate","level":3,"score":0.6764875650405884},{"id":"https://openalex.org/C30095370","wikidata":"https://www.wikidata.org/wiki/Q899488","display_name":"Protonation","level":3,"score":0.57295823097229},{"id":"https://openalex.org/C148898269","wikidata":"https://www.wikidata.org/wiki/Q1108792","display_name":"Kinetics","level":2,"score":0.5667663812637329},{"id":"https://openalex.org/C65024703","wikidata":"https://www.wikidata.org/wiki/Q373406","display_name":"Reaction mechanism","level":3,"score":0.4297883212566376},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.371384859085083},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.3586145043373108},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.3241499662399292},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.19341668486595154},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.12393784523010254},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C2779578285","wikidata":"https://www.wikidata.org/wiki/Q146322","display_name":"Polyurethane","level":2,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.36807/1998-9849-2022-61-87-51-56","doi":"https://doi.org/10.36807/1998-9849-2022-61-87-51-56","is_oa":true,"landing_page_url":"http://doi.org/10.36807/1998-9849-2022-61-87-51-56","pdf_url":null,"source":{"id":"https://openalex.org/S4210187031","display_name":"Bulletin of the Saint Petersburg State Institute of Technology (Technical University)","issn_l":"1998-9849","issn":["1998-9849"],"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Bulletin of the Saint Petersburg State Institute of Technology (Technical University)","raw_type":"journal-article"}],"best_oa_location":{"id":"doi:10.36807/1998-9849-2022-61-87-51-56","doi":"https://doi.org/10.36807/1998-9849-2022-61-87-51-56","is_oa":true,"landing_page_url":"http://doi.org/10.36807/1998-9849-2022-61-87-51-56","pdf_url":null,"source":{"id":"https://openalex.org/S4210187031","display_name":"Bulletin of the Saint Petersburg State Institute of Technology (Technical University)","issn_l":"1998-9849","issn":["1998-9849"],"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Bulletin of the Saint Petersburg State Institute of Technology (Technical University)","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W753587283","https://openalex.org/W2060064377","https://openalex.org/W2313245377","https://openalex.org/W2314257869","https://openalex.org/W2329247140","https://openalex.org/W1537660283","https://openalex.org/W2047649894","https://openalex.org/W1506006972","https://openalex.org/W1988182922","https://openalex.org/W7153133340"],"abstract_inverted_index":{"The":[0,48],"kinetics":[1],"and":[2],"mechanism":[3],"of":[4,8,14,17,25,28,37,45,51,57,61],"the":[5,26,29,35,38,46,52,55,58,65],"Curtius":[6],"rearrangement":[7,56],"m-nitrobenzoyl":[9,62],"azide":[10,63],"in":[11,34],"aqueous":[12],"solutions":[13],"sulfuric":[15],"acid":[16],"various":[18],"concentrations":[19],"has":[20],"been":[21],"studied.":[22],"An":[23],"increase":[24,33],"acidity":[27,36],"reaction":[30,39,53],"solution":[31,40],"an":[32,43],"leads":[41],"to":[42,64],"acceleration":[44],"rearrangement.":[47],"rate-limiting":[49],"step":[50],"is":[54],"protonated":[59],"form":[60],"corresponding":[66],"isocyanate":[67]},"counts_by_year":[],"updated_date":"2026-09-26T08:19:03.415552","created_date":"2022-08-14T00:00:00"}