{"id":"https://openalex.org/W4283369152","doi":"https://doi.org/10.1021/acs.jpcc.2c01511","title":"Molecular Structural Insight into the Cold Crystallization Process of Ionic Liquid Crystals","display_name":"Molecular Structural Insight into the Cold Crystallization Process of Ionic Liquid Crystals","publication_year":2022,"publication_date":"2022-06-23","ids":{"openalex":"https://openalex.org/W4283369152","doi":"https://doi.org/10.1021/acs.jpcc.2c01511"},"language":"en","primary_location":{"id":"doi:10.1021/acs.jpcc.2c01511","doi":"https://doi.org/10.1021/acs.jpcc.2c01511","is_oa":true,"landing_page_url":"https://doi.org/10.1021/acs.jpcc.2c01511","pdf_url":null,"source":{"id":"https://openalex.org/S95739953","display_name":"The Journal of Physical Chemistry C","issn_l":"1932-7447","issn":["1932-7447","1932-7455"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-2","ki-jl-1","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry C","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"hybrid","oa_url":"https://doi.org/10.1021/acs.jpcc.2c01511","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5035489537","display_name":"Katsunori Iwase","orcid":"https://orcid.org/0000-0001-7944-4971","observed_orcids":["https://orcid.org/0000-0001-7944-4971"]},"institutions":[{"id":"https://openalex.org/I4405286711","display_name":"Institute of Materials and Systems for Sustainability, Nagoya University","ror":"https://ror.org/02wb1d827","country_code":"JP","type":"facility","lineage":["https://openalex.org/I4405286711","https://openalex.org/I60134161"]},{"id":"https://openalex.org/I60134161","display_name":"Nagoya University","ror":"https://ror.org/04chrp450","country_code":"JP","type":"education","lineage":["https://openalex.org/I60134161"]}],"countries":["JP"],"is_corresponding":true,"raw_author_name":"Katsunori Iwase","raw_affiliation_strings":["DENSO CORPORATION, 500-1 minamiyama, Komenoki-cho, Nisshin, Aichi 470-0111, Japan","Institute of Materials and Systems for Sustainability, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Aichi 464-8601, Japan"],"raw_orcid":"https://orcid.org/0000-0001-7944-4971","affiliations":[{"raw_affiliation_string":"DENSO CORPORATION, 500-1 minamiyama, Komenoki-cho, Nisshin, Aichi 470-0111, Japan","institution_ids":[]},{"raw_affiliation_string":"Institute of Materials and Systems for Sustainability, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Aichi 464-8601, Japan","institution_ids":["https://openalex.org/I4405286711","https://openalex.org/I60134161"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5058216974","display_name":"Yasuyuki Hikita","orcid":"https://orcid.org/0000-0002-7748-8329","observed_orcids":["https://orcid.org/0000-0002-7748-8329"]},"institutions":[],"countries":[],"is_corresponding":true,"raw_author_name":"Yasuyuki Hikita","raw_affiliation_strings":["DENSO CORPORATION, 500-1 minamiyama, Komenoki-cho, Nisshin, Aichi 470-0111, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"DENSO CORPORATION, 500-1 minamiyama, Komenoki-cho, Nisshin, Aichi 470-0111, Japan","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5043451960","display_name":"Isao Yoshikawa","orcid":"https://orcid.org/0000-0002-9183-7636","observed_orcids":["https://orcid.org/0000-0002-9183-7636"]},"institutions":[{"id":"https://openalex.org/I4405287318","display_name":"Institute of Industrial Science, The University of Tokyo","ror":"https://ror.org/04t6zpd80","country_code":"JP","type":"facility","lineage":["https://openalex.org/I4405287318","https://openalex.org/I74801974"]},{"id":"https://openalex.org/I74801974","display_name":"The University of Tokyo","ror":"https://ror.org/057zh3y96","country_code":"JP","type":"education","lineage":["https://openalex.org/I74801974"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Isao Yoshikawa","raw_affiliation_strings":["Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8505, Japan"],"raw_orcid":"https://orcid.org/0000-0002-9183-7636","affiliations":[{"raw_affiliation_string":"Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8505, Japan","institution_ids":["https://openalex.org/I4405287318","https://openalex.org/I74801974"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5046900544","display_name":"Hirohiko Houjou","orcid":"https://orcid.org/0000-0003-3761-9221","observed_orcids":["https://orcid.org/0000-0003-3761-9221"]},"institutions":[{"id":"https://openalex.org/I4405286337","display_name":"Environmental Science Center, The University of Tokyo","ror":"https://ror.org/01ve7d417","country_code":"JP","type":"facility","lineage":["https://openalex.org/I4405286337","https://openalex.org/I74801974"]},{"id":"https://openalex.org/I4405287318","display_name":"Institute of Industrial Science, The University of Tokyo","ror":"https://ror.org/04t6zpd80","country_code":"JP","type":"facility","lineage":["https://openalex.org/I4405287318","https://openalex.org/I74801974"]},{"id":"https://openalex.org/I74801974","display_name":"The University of Tokyo","ror":"https://ror.org/057zh3y96","country_code":"JP","type":"education","lineage":["https://openalex.org/I74801974"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Hirohiko Houjou","raw_affiliation_strings":["Environmental Science Center, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan","Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8505, Japan"],"raw_orcid":"https://orcid.org/0000-0003-3761-9221","affiliations":[{"raw_affiliation_string":"Environmental Science Center, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan","institution_ids":["https://openalex.org/I4405286337","https://openalex.org/I74801974"]},{"raw_affiliation_string":"Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8505, Japan","institution_ids":["https://openalex.org/I4405287318","https://openalex.org/I74801974"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5088169176","display_name":"Katsuma Ishino","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Katsuma Ishino","raw_affiliation_strings":["DENSO CORPORATION, 500-1 minamiyama, Komenoki-cho, Nisshin, Aichi 470-0111, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"DENSO CORPORATION, 500-1 minamiyama, Komenoki-cho, Nisshin, Aichi 470-0111, Japan","institution_ids":[]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":5,"corresponding_author_ids":["https://openalex.org/A5035489537","https://openalex.org/A5058216974"],"corresponding_institution_ids":["https://openalex.org/I4405286711","https://openalex.org/I60134161"],"apc_list":{"value":5000,"currency":"USD","value_usd":5000},"apc_paid":{"value":5000,"currency":"USD","value_usd":5000},"fwci":0.7109,"has_fulltext":false,"cited_by_count":9,"citation_normalized_percentile":{"value":0.55417021,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":96},"biblio":{"volume":"126","issue":"26","first_page":"10668","last_page":"10676"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10480","display_name":"Ionic liquids properties and applications","score":0.8779000043869019,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10480","display_name":"Ionic liquids properties and applications","score":0.8779000043869019,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10306","display_name":"Liquid Crystal Research Advancements","score":0.06449999660253525,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10938","display_name":"Phase Change Materials Research","score":0.03319999948143959,"subfield":{"id":"https://openalex.org/subfields/2210","display_name":"Mechanical Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/ionic-liquid-crystals","display_name":"ionic liquid crystals","score":0.9679999947547913},{"id":"https://openalex.org/keywords/cold-crystallization","display_name":"cold crystallization","score":0.9980000257492065},{"id":"https://openalex.org/keywords/carbon-nanotubes","display_name":"carbon nanotubes","score":0.9139999747276306},{"id":"https://openalex.org/keywords/crystal-nucleation","display_name":"crystal nucleation","score":0.7760000228881836},{"id":"https://openalex.org/keywords/pi-pi-stacking","display_name":"\u03c0-\u03c0 stacking","score":0.9869999885559082},{"id":"https://openalex.org/keywords/imidazolium-tetrafluoroborate","display_name":"imidazolium tetrafluoroborate","score":0.8230000138282776},{"id":"https://openalex.org/keywords/heat-of-fusion","display_name":"heat of fusion","score":0.8709999918937683},{"id":"https://openalex.org/keywords/thermal-energy-storage","display_name":"thermal energy storage","score":0.7239999771118164},{"id":"https://openalex.org/keywords/melt-crystallization","display_name":"melt crystallization","score":0.6650000214576721}],"concepts":[{"id":"https://openalex.org/C203036418","wikidata":"https://www.wikidata.org/wiki/Q284256","display_name":"Crystallization","level":2,"score":0.9242179989814758},{"id":"https://openalex.org/C61048295","wikidata":"https://www.wikidata.org/wiki/Q909022","display_name":"Nucleation","level":2,"score":0.8075793981552124},{"id":"https://openalex.org/C112964491","wikidata":"https://www.wikidata.org/wiki/Q213659","display_name":"Supercooling","level":2,"score":0.7995384931564331},{"id":"https://openalex.org/C154881586","wikidata":"https://www.wikidata.org/wiki/Q898579","display_name":"Ionic liquid","level":3,"score":0.6906790733337402},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.6176257133483887},{"id":"https://openalex.org/C2182769","wikidata":"https://www.wikidata.org/wiki/Q62500","display_name":"Ionic bonding","level":3,"score":0.5589585900306702},{"id":"https://openalex.org/C3288061","wikidata":"https://www.wikidata.org/wiki/Q161064","display_name":"Enthalpy","level":2,"score":0.5033389925956726},{"id":"https://openalex.org/C2781285689","wikidata":"https://www.wikidata.org/wiki/Q21921428","display_name":"Crystal (programming language)","level":2,"score":0.4939129948616028},{"id":"https://openalex.org/C2780872544","wikidata":"https://www.wikidata.org/wiki/Q7706343","display_name":"Tetrafluoroborate","level":4,"score":0.41225191950798035},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.40279239416122437},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.36843234300613403},{"id":"https://openalex.org/C159467904","wikidata":"https://www.wikidata.org/wiki/Q2001702","display_name":"Chemical physics","level":1,"score":0.3496958315372467},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.2645871043205261},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.24879702925682068},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.16962727904319763},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.12293568253517151},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.056587040424346924},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0},{"id":"https://openalex.org/C199360897","wikidata":"https://www.wikidata.org/wiki/Q9143","display_name":"Programming language","level":1,"score":0.0},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/acs.jpcc.2c01511","doi":"https://doi.org/10.1021/acs.jpcc.2c01511","is_oa":true,"landing_page_url":"https://doi.org/10.1021/acs.jpcc.2c01511","pdf_url":null,"source":{"id":"https://openalex.org/S95739953","display_name":"The Journal of Physical Chemistry C","issn_l":"1932-7447","issn":["1932-7447","1932-7455"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-2","ki-jl-1","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry C","raw_type":"journal-article"}],"best_oa_location":{"id":"doi:10.1021/acs.jpcc.2c01511","doi":"https://doi.org/10.1021/acs.jpcc.2c01511","is_oa":true,"landing_page_url":"https://doi.org/10.1021/acs.jpcc.2c01511","pdf_url":null,"source":{"id":"https://openalex.org/S95739953","display_name":"The Journal of Physical Chemistry C","issn_l":"1932-7447","issn":["1932-7447","1932-7455"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-2","ki-jl-1","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry C","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":53,"referenced_works":["https://openalex.org/W1968344479","https://openalex.org/W1968948623","https://openalex.org/W1972486510","https://openalex.org/W1973905161","https://openalex.org/W1980094141","https://openalex.org/W1980675538","https://openalex.org/W1997173539","https://openalex.org/W2003003371","https://openalex.org/W2007092853","https://openalex.org/W2018571316","https://openalex.org/W2018858346","https://openalex.org/W2024722845","https://openalex.org/W2028250640","https://openalex.org/W2029365841","https://openalex.org/W2034656418","https://openalex.org/W2038348935","https://openalex.org/W2043942465","https://openalex.org/W2047241264","https://openalex.org/W2053858888","https://openalex.org/W2069924395","https://openalex.org/W2087070363","https://openalex.org/W2108567026","https://openalex.org/W2142594455","https://openalex.org/W2143263741","https://openalex.org/W2162001928","https://openalex.org/W2163016819","https://openalex.org/W2190652351","https://openalex.org/W2320962443","https://openalex.org/W2324955831","https://openalex.org/W2474643630","https://openalex.org/W2528775237","https://openalex.org/W2531492665","https://openalex.org/W2594766488","https://openalex.org/W2788155855","https://openalex.org/W2794335328","https://openalex.org/W2898752612","https://openalex.org/W2941285239","https://openalex.org/W2953372082","https://openalex.org/W2972003195","https://openalex.org/W2980920066","https://openalex.org/W2994735770","https://openalex.org/W3004749979","https://openalex.org/W3015023337","https://openalex.org/W3042038034","https://openalex.org/W3116178077","https://openalex.org/W3122319685","https://openalex.org/W3129947070","https://openalex.org/W3138551969","https://openalex.org/W3178025484","https://openalex.org/W3194661389","https://openalex.org/W3199325199","https://openalex.org/W3217385514","https://openalex.org/W4210984548"],"related_works":["https://openalex.org/W3217385514","https://openalex.org/W2091408479","https://openalex.org/W7110374778","https://openalex.org/W2088427897","https://openalex.org/W2332548709","https://openalex.org/W1993360250","https://openalex.org/W7064933815","https://openalex.org/W2042282338","https://openalex.org/W2323702159","https://openalex.org/W2291215829"],"abstract_inverted_index":{"We":[0],"have":[1],"demonstrated":[2],"a":[3,63],"modified":[4],"crystallization":[5,32,41,69,123],"process":[6],"of":[7,19,39,46,48,125,138,140],"an":[8,97],"ionic":[9,126,142],"liquid":[10],"crystal,":[11],"1-{[4\u2032-(4\u2033-nitrophenylazo)phenyloxy]}hexyl-3-methyl-1":[12],"H":[13],"-imidazol-3-ium":[14],"tetrafluoroborate,":[15],"by":[16,71,96],"the":[17,25,30,36,49,55,68,104,108,111,122,136],"addition":[18],"carbon":[20],"nanotubes":[21],"(CNTs),":[22],"successfully":[23],"suppressing":[24],"supercooled":[26],"state,":[27],"and":[28,81,110],"hence":[29],"cold":[31],"during":[33],"reheating,":[34],"to":[35,103,134],"complete":[37],"conversion":[38],"melt":[40],"upon":[42],"cooling.":[43],"The":[44],"enthalpies":[45],"fusion":[47],"crystals":[50],"produced":[51],"were":[52],"similar":[53],"among":[54],"samples":[56],"(29.3\u201332.2":[57],"kJ":[58],"mol":[59],"\u20131":[60],");":[61],"however,":[62],"crystallization-promoting":[64],"pathway":[65],"that":[66,91],"increases":[67],"enthalpy":[70],"20%":[72],"was":[73],"present.":[74],"Through":[75],"comprehensive":[76],"thermal":[77,146],"analysis,":[78,80],"structural":[79],"infrared":[82],"spectroscopy":[83],"combined":[84],"with":[85],"quantum":[86],"chemical":[87],"calculations,":[88],"we":[89],"propose":[90],"this":[92],"effect":[93],"is":[94],"caused":[95],"increased":[98],"crystal":[99],"nucleation":[100],"rate":[101],"due":[102],"\u03c0\u2013\u03c0":[105],"interactions":[106],"between":[107],"molecule":[109],"rigid":[112],"CNT":[113],"surface.":[114],"These":[115],"results":[116],"not":[117],"only":[118],"give":[119],"insights":[120],"into":[121],"processes":[124],"liquids":[127],"in":[128],"general":[129],"but":[130],"also":[131],"provide":[132],"guidelines":[133],"expand":[135],"range":[137],"applications":[139],"cold-crystallizing":[141],"crystalline":[143],"materials":[144],"for":[145],"energy":[147],"storage":[148],"applications.":[149]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2025,"cited_by_count":2},{"year":2024,"cited_by_count":3},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":1}],"updated_date":"2026-11-10T11:39:43.021295","created_date":"2022-06-25T00:00:00"}