{"id":"https://openalex.org/W4281746960","doi":"https://doi.org/10.1021/acs.jpca.2c00521","title":"Strong Bases Design: Predicted Limits of Basicity","display_name":"Strong Bases Design: Predicted Limits of Basicity","publication_year":2022,"publication_date":"2022-06-03","ids":{"openalex":"https://openalex.org/W4281746960","doi":"https://doi.org/10.1021/acs.jpca.2c00521","pmid":"https://pubmed.ncbi.nlm.nih.gov/35657384"},"language":"en","primary_location":{"id":"doi:10.1021/acs.jpca.2c00521","doi":"https://doi.org/10.1021/acs.jpca.2c00521","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.jpca.2c00521","pdf_url":null,"source":{"id":"https://openalex.org/S146709414","display_name":"The Journal of Physical Chemistry A","issn_l":"1089-5639","issn":["1089-5639","1520-5215"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry A","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5087935978","display_name":"Andrey V. Kulsha","orcid":"https://orcid.org/0000-0001-5068-7101","observed_orcids":["https://orcid.org/0000-0001-5068-7101"]},"institutions":[{"id":"https://openalex.org/I291386647","display_name":"Belarusian State University","ror":"https://ror.org/021036w13","country_code":"BY","type":"education","lineage":["https://openalex.org/I291386647"]}],"countries":["BY"],"is_corresponding":true,"raw_author_name":"Andrey V. Kulsha","raw_affiliation_strings":["Chemical Department, Belarusian State University, 4 Nezavisimosti Avenue, 220030 Minsk, Republic of Belarus"],"raw_orcid":"https://orcid.org/0000-0001-5068-7101","affiliations":[{"raw_affiliation_string":"Chemical Department, Belarusian State University, 4 Nezavisimosti Avenue, 220030 Minsk, Republic of Belarus","institution_ids":["https://openalex.org/I291386647"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5075829626","display_name":"Ekaterina G. Ragoyja","orcid":"https://orcid.org/0000-0002-8344-8438","observed_orcids":["https://orcid.org/0000-0002-8344-8438"]},"institutions":[{"id":"https://openalex.org/I291386647","display_name":"Belarusian State University","ror":"https://ror.org/021036w13","country_code":"BY","type":"education","lineage":["https://openalex.org/I291386647"]}],"countries":["BY"],"is_corresponding":false,"raw_author_name":"Ekaterina G. Ragoyja","raw_affiliation_strings":["Chemical Department, Belarusian State University, 4 Nezavisimosti Avenue, 220030 Minsk, Republic of Belarus"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Chemical Department, Belarusian State University, 4 Nezavisimosti Avenue, 220030 Minsk, Republic of Belarus","institution_ids":["https://openalex.org/I291386647"]}]},{"author_position":"last","author":{"id":null,"display_name":"Oleg A. Ivashkevich","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I291386647","display_name":"Belarusian State University","ror":"https://ror.org/021036w13","country_code":"BY","type":"education","lineage":["https://openalex.org/I291386647"]}],"countries":["BY"],"is_corresponding":false,"raw_author_name":"Oleg A. Ivashkevich","raw_affiliation_strings":["Laboratory for Chemistry of Condensed Systems, Research Institute for Physical Chemical Problems of the Belarusian State University, 14 Leningradskaya Street, 220006 Minsk, Republic of Belarus"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratory for Chemistry of Condensed Systems, Research Institute for Physical Chemical Problems of the Belarusian State University, 14 Leningradskaya Street, 220006 Minsk, Republic of Belarus","institution_ids":["https://openalex.org/I291386647"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5087935978"],"corresponding_institution_ids":["https://openalex.org/I291386647"],"apc_list":null,"apc_paid":null,"fwci":0.924,"has_fulltext":false,"cited_by_count":10,"citation_normalized_percentile":{"value":0.65571102,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":93,"max":97},"biblio":{"volume":"126","issue":"23","first_page":"3642","last_page":"3652"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12191","display_name":"Physical Organic Chemistry and Reaction Kinetics","score":0.8554999828338623,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12191","display_name":"Physical Organic Chemistry and Reaction Kinetics","score":0.8554999828338623,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.0843999981880188,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10002","display_name":"Advanced Chemical Physics Studies","score":0.010200000368058681,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/hexamethylphosphoramide","display_name":"hexamethylphosphoramide","score":0.8460000157356262},{"id":"https://openalex.org/keywords/c-h-activation","display_name":"C\u2013H activation","score":0.7149999737739563},{"id":"https://openalex.org/keywords/gas-phase-basicity","display_name":"gas-phase basicity","score":0.7450000047683716}],"concepts":[{"id":"https://openalex.org/C2778044633","wikidata":"https://www.wikidata.org/wiki/Q901690","display_name":"Superbase","level":3,"score":0.9041352868080139},{"id":"https://openalex.org/C2778006127","wikidata":"https://www.wikidata.org/wiki/Q416086","display_name":"Hexamethylphosphoramide","level":2,"score":0.8378540873527527},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6838822960853577},{"id":"https://openalex.org/C2991951333","wikidata":"https://www.wikidata.org/wiki/Q188403","display_name":"Quantum chemical","level":3,"score":0.6005999445915222},{"id":"https://openalex.org/C147597530","wikidata":"https://www.wikidata.org/wiki/Q369472","display_name":"Computational chemistry","level":1,"score":0.5215097069740295},{"id":"https://openalex.org/C2780471494","wikidata":"https://www.wikidata.org/wiki/Q146505","display_name":"Solvent","level":2,"score":0.4719986915588379},{"id":"https://openalex.org/C154283680","wikidata":"https://www.wikidata.org/wiki/Q1328823","display_name":"Organic base","level":2,"score":0.4466516971588135},{"id":"https://openalex.org/C3020013744","wikidata":"https://www.wikidata.org/wiki/Q104837","display_name":"Gas phase","level":2,"score":0.4242638349533081},{"id":"https://openalex.org/C22994065","wikidata":"https://www.wikidata.org/wiki/Q188403","display_name":"Quantum chemistry","level":4,"score":0.4137609601020813},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.3049076795578003},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.2112974226474762},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.1441211998462677},{"id":"https://openalex.org/C65024703","wikidata":"https://www.wikidata.org/wiki/Q373406","display_name":"Reaction mechanism","level":3,"score":0.1406499147415161}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1021/acs.jpca.2c00521","doi":"https://doi.org/10.1021/acs.jpca.2c00521","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.jpca.2c00521","pdf_url":null,"source":{"id":"https://openalex.org/S146709414","display_name":"The Journal of Physical Chemistry A","issn_l":"1089-5639","issn":["1089-5639","1520-5215"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry A","raw_type":"journal-article"},{"id":"pmid:35657384","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/35657384","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The journal of physical chemistry. A","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":97,"referenced_works":["https://openalex.org/W1467189040","https://openalex.org/W1966235871","https://openalex.org/W1966296851","https://openalex.org/W1971275758","https://openalex.org/W1975708211","https://openalex.org/W1976530061","https://openalex.org/W1976774792","https://openalex.org/W1984430187","https://openalex.org/W1985975908","https://openalex.org/W1992640856","https://openalex.org/W1993077801","https://openalex.org/W1994042184","https://openalex.org/W2007541314","https://openalex.org/W2008423326","https://openalex.org/W2010376000","https://openalex.org/W2018585677","https://openalex.org/W2018674598","https://openalex.org/W2018731963","https://openalex.org/W2018770868","https://openalex.org/W2030037377","https://openalex.org/W2038499688","https://openalex.org/W2043964666","https://openalex.org/W2044039308","https://openalex.org/W2044268702","https://openalex.org/W2045162110","https://openalex.org/W2049205367","https://openalex.org/W2057654474","https://openalex.org/W2058848030","https://openalex.org/W2064798852","https://openalex.org/W2066127431","https://openalex.org/W2069006374","https://openalex.org/W2070127123","https://openalex.org/W2072711439","https://openalex.org/W2078511427","https://openalex.org/W2083108156","https://openalex.org/W2091826324","https://openalex.org/W2092925808","https://openalex.org/W2101627524","https://openalex.org/W2120836927","https://openalex.org/W2136570285","https://openalex.org/W2141400817","https://openalex.org/W2145416500","https://openalex.org/W2153017562","https://openalex.org/W2159261057","https://openalex.org/W2162618806","https://openalex.org/W2164714240","https://openalex.org/W2167814906","https://openalex.org/W2168906023","https://openalex.org/W2190096651","https://openalex.org/W2233212601","https://openalex.org/W2234552091","https://openalex.org/W2313740294","https://openalex.org/W2322038385","https://openalex.org/W2331677572","https://openalex.org/W2333008517","https://openalex.org/W2337092891","https://openalex.org/W2397496513","https://openalex.org/W2410747900","https://openalex.org/W2468149131","https://openalex.org/W2471849292","https://openalex.org/W2473318018","https://openalex.org/W2485796174","https://openalex.org/W2530670950","https://openalex.org/W2567342479","https://openalex.org/W2589471238","https://openalex.org/W2607884604","https://openalex.org/W2628292446","https://openalex.org/W2686396682","https://openalex.org/W2739439285","https://openalex.org/W2780190628","https://openalex.org/W2782113496","https://openalex.org/W2792601795","https://openalex.org/W2803909435","https://openalex.org/W2911985350","https://openalex.org/W2922411724","https://openalex.org/W2942665060","https://openalex.org/W2946274769","https://openalex.org/W2951021591","https://openalex.org/W2951912712","https://openalex.org/W2953268131","https://openalex.org/W2968364024","https://openalex.org/W2970699026","https://openalex.org/W2971917160","https://openalex.org/W2986212643","https://openalex.org/W3028338492","https://openalex.org/W3041317787","https://openalex.org/W3041922912","https://openalex.org/W3046300612","https://openalex.org/W3080287371","https://openalex.org/W3115936582","https://openalex.org/W3127021009","https://openalex.org/W3165848298","https://openalex.org/W3184460329","https://openalex.org/W3209698557","https://openalex.org/W4231131750","https://openalex.org/W4240035468","https://openalex.org/W4252691090"],"related_works":["https://openalex.org/W2168906023","https://openalex.org/W3184460329","https://openalex.org/W2144787858","https://openalex.org/W2471849292","https://openalex.org/W4205476580","https://openalex.org/W4388047582","https://openalex.org/W2089922114","https://openalex.org/W2325731725","https://openalex.org/W2160552831","https://openalex.org/W2922411724"],"abstract_inverted_index":{"Br\u00f8nsted":[0],"superbases":[1],"have":[2],"wide":[3],"applications":[4],"in":[5,26],"organic":[6],"chemistry":[7],"due":[8],"to":[9,12,20,40,85],"their":[10],"ability":[11],"activate":[13],"C-H":[14],"bonds.":[15],"The":[16],"strongest":[17],"neutral":[18,44],"bases":[19],"date":[21],"are":[22,58,69],"substituted":[23],"aminophosphazenes":[24],"developed":[25],"the":[27,49,52,77],"late":[28],"1980s":[29],"by":[30,60],"Reinhard":[31],"Schwesinger.":[32],"Since":[33],"then,":[34],"much":[35],"effort":[36],"has":[37],"been":[38],"expended":[39],"create":[41],"even":[42],"stronger":[43],"bases.":[45],"In":[46],"this":[47],"article,":[48],"reasons":[50],"for":[51,71,76,102],"instability":[53],"of":[54,62],"very":[55],"basic":[56],"compounds":[57],"investigated":[59],"means":[61],"high-level":[63],"quantum-chemical":[64],"calculations.":[65],"Theoretical":[66],"basicity":[67],"limits":[68],"suggested":[70],"solutions":[72],"as":[73,75],"well":[74],"gas":[78],"phase.":[79],"A":[80],"record-breaking":[81],"superbase":[82],"most":[83],"likely":[84],"be":[86],"synthesizable":[87],"and":[88],"stable":[89],"at":[90],"ambient":[91],"conditions":[92],"is":[93,96],"proposed.":[94],"Hexamethylphosphoramide":[95],"considered":[97],"a":[98],"reliable":[99],"ionizing":[100],"solvent":[101],"superbases.":[103]},"counts_by_year":[{"year":2025,"cited_by_count":2},{"year":2024,"cited_by_count":4},{"year":2023,"cited_by_count":4}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2022-06-13T00:00:00"}