{"id":"https://openalex.org/W4252632915","doi":"https://doi.org/10.1021/bk-1992-0486.ch013","title":"Reaction of 2-Amino-4-Substituted Phenols with Aryl Phosphorodichloridates","display_name":"Reaction of 2-Amino-4-Substituted Phenols with Aryl Phosphorodichloridates","publication_year":1992,"publication_date":"1992-04-07","ids":{"openalex":"https://openalex.org/W4252632915","doi":"https://doi.org/10.1021/bk-1992-0486.ch013"},"language":"en","primary_location":{"id":"doi:10.1021/bk-1992-0486.ch013","doi":"https://doi.org/10.1021/bk-1992-0486.ch013","is_oa":false,"landing_page_url":"https://doi.org/10.1021/bk-1992-0486.ch013","pdf_url":null,"source":{"id":"https://openalex.org/S205053445","display_name":"ACS symposium series","issn_l":"0097-6156","issn":["0097-6156","1947-5918"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-1","norway-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"book series"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Symposium Series","raw_type":"book-chapter"},"volume":{"id":"https://openalex.org/W1577852288","display_name":"Phosphorus Chemistry"},"type":"conference-paper","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5103852540","display_name":"Chichili Devendranath Reddy","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I170558118","display_name":"Sri Venkateswara University","ror":"https://ror.org/05weahn72","country_code":"IN","type":"education","lineage":["https://openalex.org/I170558118"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"C. D. Reddy","raw_affiliation_strings":["Department of Chemistry, Engineering College, Sri Venkateswara University, Tirupati 517 502, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Engineering College, Sri Venkateswara University, Tirupati 517 502, India","institution_ids":["https://openalex.org/I170558118"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5111928527","display_name":"Kenneth Darrell Berlin","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I115475287","display_name":"Oklahoma State University","ror":"https://ror.org/01g9vbr38","country_code":"US","type":"education","lineage":["https://openalex.org/I115475287"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"K. D. Berlin","raw_affiliation_strings":["Department of Chemistry, Oklahoma State University, Stillwater, OK 74078"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Oklahoma State University, Stillwater, OK 74078","institution_ids":["https://openalex.org/I115475287"]}]},{"author_position":"middle","author":{"id":null,"display_name":"M. ElMasri","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I115475287","display_name":"Oklahoma State University","ror":"https://ror.org/01g9vbr38","country_code":"US","type":"education","lineage":["https://openalex.org/I115475287"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"M. ElMasri","raw_affiliation_strings":["Department of Chemistry, Oklahoma State University, Stillwater, OK 74078"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Oklahoma State University, Stillwater, OK 74078","institution_ids":["https://openalex.org/I115475287"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5079999850","display_name":"S. Subramanian","orcid":"https://orcid.org/0000-0001-7971-6842","observed_orcids":["https://orcid.org/0000-0001-7971-6842"]},"institutions":[{"id":"https://openalex.org/I115475287","display_name":"Oklahoma State University","ror":"https://ror.org/01g9vbr38","country_code":"US","type":"education","lineage":["https://openalex.org/I115475287"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"S. Subramanian","raw_affiliation_strings":["Department of Chemistry, Oklahoma State University, Stillwater, OK 74078"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Oklahoma State University, Stillwater, OK 74078","institution_ids":["https://openalex.org/I115475287"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5010847371","display_name":"Satish V. Mulekar","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I115475287","display_name":"Oklahoma State University","ror":"https://ror.org/01g9vbr38","country_code":"US","type":"education","lineage":["https://openalex.org/I115475287"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"S. V. Mulekar","raw_affiliation_strings":["Department of Chemistry, Oklahoma State University, Stillwater, OK 74078"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Oklahoma State University, Stillwater, OK 74078","institution_ids":["https://openalex.org/I115475287"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5091330886","display_name":"R. Suryanarayana Reddy","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I170558118","display_name":"Sri Venkateswara University","ror":"https://ror.org/05weahn72","country_code":"IN","type":"education","lineage":["https://openalex.org/I170558118"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"R. S. Reddy","raw_affiliation_strings":["Department of Chemistry, Engineering College, Sri Venkateswara University, Tirupati 517 502, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Engineering College, Sri Venkateswara University, Tirupati 517 502, India","institution_ids":["https://openalex.org/I170558118"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5011020530","display_name":"Srinivasa B. Reddy","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I170558118","display_name":"Sri Venkateswara University","ror":"https://ror.org/05weahn72","country_code":"IN","type":"education","lineage":["https://openalex.org/I170558118"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"S. B. S. Reddy","raw_affiliation_strings":["Department of Chemistry, Engineering College, Sri Venkateswara University, Tirupati 517 502, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Engineering College, Sri Venkateswara University, Tirupati 517 502, India","institution_ids":["https://openalex.org/I170558118"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5062624916","display_name":"Lothar Esser","orcid":"https://orcid.org/0000-0002-8680-6851","observed_orcids":["https://orcid.org/0000-0002-8680-6851"]},"institutions":[{"id":"https://openalex.org/I8692664","display_name":"University of Oklahoma","ror":"https://ror.org/02aqsxs83","country_code":"US","type":"education","lineage":["https://openalex.org/I8692664"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"L. Esser","raw_affiliation_strings":["Department of Chemistry, University of Oklahoma, Norman, OK 73019"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Oklahoma, Norman, OK 73019","institution_ids":["https://openalex.org/I8692664"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5069231811","display_name":"Xinhua Ji","orcid":"https://orcid.org/0000-0001-6942-1514","observed_orcids":["https://orcid.org/0000-0001-6942-1514"]},"institutions":[{"id":"https://openalex.org/I8692664","display_name":"University of Oklahoma","ror":"https://ror.org/02aqsxs83","country_code":"US","type":"education","lineage":["https://openalex.org/I8692664"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"X. Ji","raw_affiliation_strings":["Department of Chemistry, University of Oklahoma, Norman, OK 73019"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Oklahoma, Norman, OK 73019","institution_ids":["https://openalex.org/I8692664"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5030359826","display_name":"D. van der Helm","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I8692664","display_name":"University of Oklahoma","ror":"https://ror.org/02aqsxs83","country_code":"US","type":"education","lineage":["https://openalex.org/I8692664"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"D. van der Helm","raw_affiliation_strings":["Department of Chemistry, University of Oklahoma, Norman, OK 73019"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Oklahoma, Norman, OK 73019","institution_ids":["https://openalex.org/I8692664"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":3,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":1.2355,"has_fulltext":false,"cited_by_count":1,"citation_normalized_percentile":{"value":0.87640449,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":"162","last_page":"172"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11748","display_name":"Organophosphorus compounds synthesis","score":0.9423999786376953,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11748","display_name":"Organophosphorus compounds synthesis","score":0.9423999786376953,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13239","display_name":"Phosphorus compounds and reactions","score":0.04349999874830246,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.00430000014603138,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/phosphorus-nitrogen-heterocycles","display_name":"phosphorus-nitrogen heterocycles","score":0.7279999852180481},{"id":"https://openalex.org/keywords/2-amino-4-chlorophenol","display_name":"2-amino-4-chlorophenol","score":0.9990000128746033},{"id":"https://openalex.org/keywords/crystal-structure","display_name":"crystal structure","score":0.41999998688697815},{"id":"https://openalex.org/keywords/condensation-reactions","display_name":"condensation reactions","score":0.527999997138977}],"concepts":[{"id":"https://openalex.org/C2781283055","wikidata":"https://www.wikidata.org/wiki/Q139199","display_name":"Triethylamine","level":2,"score":0.8389492034912109},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7423794269561768},{"id":"https://openalex.org/C2777702071","wikidata":"https://www.wikidata.org/wiki/Q130336","display_name":"Phenol","level":2,"score":0.7238736748695374},{"id":"https://openalex.org/C2781076698","wikidata":"https://www.wikidata.org/wiki/Q718074","display_name":"Aryl","level":3,"score":0.6970314383506775},{"id":"https://openalex.org/C40875361","wikidata":"https://www.wikidata.org/wiki/Q2356542","display_name":"Reagent","level":2,"score":0.6967273950576782},{"id":"https://openalex.org/C2778142098","wikidata":"https://www.wikidata.org/wiki/Q15779","display_name":"Toluene","level":2,"score":0.6548625826835632},{"id":"https://openalex.org/C2777728882","wikidata":"https://www.wikidata.org/wiki/Q407142","display_name":"Phenols","level":2,"score":0.6484032869338989},{"id":"https://openalex.org/C134121241","wikidata":"https://www.wikidata.org/wiki/Q899301","display_name":"Yield (engineering)","level":2,"score":0.6278455853462219},{"id":"https://openalex.org/C515207424","wikidata":"https://www.wikidata.org/wiki/Q8066","display_name":"Amino acid","level":2,"score":0.4845108389854431},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.4583245515823364},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.31742215156555176},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.09928455948829651},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.06775310635566711},{"id":"https://openalex.org/C191897082","wikidata":"https://www.wikidata.org/wiki/Q11467","display_name":"Metallurgy","level":1,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/bk-1992-0486.ch013","doi":"https://doi.org/10.1021/bk-1992-0486.ch013","is_oa":false,"landing_page_url":"https://doi.org/10.1021/bk-1992-0486.ch013","pdf_url":null,"source":{"id":"https://openalex.org/S205053445","display_name":"ACS symposium series","issn_l":"0097-6156","issn":["0097-6156","1947-5918"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-1","norway-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"book series"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Symposium Series","raw_type":"book-chapter"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2075163178","https://openalex.org/W4234859152","https://openalex.org/W2952740253","https://openalex.org/W1990674536","https://openalex.org/W2047988848","https://openalex.org/W1981110281","https://openalex.org/W379337779","https://openalex.org/W2119130100","https://openalex.org/W2324898221","https://openalex.org/W4241050640"],"abstract_inverted_index":{"A":[0],"series":[1],"of":[2,11,26,48,58,104],"experiments":[3],"was":[4],"performed":[5],"in":[6,20,23,60,77],"which":[7,73],"three":[8],"systems":[9,30],"consisting":[10],"2-amino-4-substituted-phenols":[12],"were":[13,31],"allowed":[14],"to":[15,53,91],"react":[16],"with":[17,44],"aryl":[18],"phosphorodichloridates":[19],"boiling":[21],"toluene":[22],"the":[24,49,108],"presence":[25],"triethylamine.":[27],"Novel":[28],"spirobis[1,3,2-benzoxazaphosphole]":[29],"obtained.":[32],"With":[33],"2-amino-4-methylphenol,":[34],"a":[35,45],"pentavalent":[36],"phosphorus-containing":[37],"intermediate":[38],"1":[39],"probably":[40],"formed":[41],"and":[42,87,96,120,125],"reacted":[43],"third":[46],"equivalent":[47],"amino-phenol":[50],"starting":[51],"reagent":[52],"yield":[54],"2a":[55,59,106],".":[56],"Analysis":[57],"DCCl":[61],"3":[62],"via":[63],"31":[64],"P":[65],"NMR":[66],"spectroscopy":[67],"revealed":[68],"two":[69,80,121,126],"narrowly":[70],"separated":[71],"signals":[72],"suggested":[74],"an":[75],"equilibrium":[76],"solution":[78],"involving":[79],"forms.":[81],"Condensations":[82],"using":[83],"2-amino-4-":[84],"t":[85],"-butylphenol":[86],"2-amino-4-chlorophenol":[88],"proceeded":[89],"similarly":[90],"give":[92],"related":[93],"solids":[94],"4":[95],"5,":[97],"respectively.":[98],"Single":[99],"crystal":[100],"X-ray":[101],"diffraction":[102],"analysis":[103],"crystalline":[105],"confirmed":[107],"structure":[109],"as":[110],"8,8\u2033-dimethyl-2-(2-amino-4-methylphenoxy)-2\u03bb":[111],"5":[112],"-2,2\u2032(3":[113],"H,3":[114],"H":[115],"\u2032)spirobis[1,3,2-benzoxazaphosphole]":[116],"possessing":[117],"one":[118],"equatorial":[119,127],"apical":[122],"P-O":[123],"bonds":[124],"P-N":[128],"bonds.":[129]},"counts_by_year":[],"updated_date":"2026-10-10T09:11:00.788812","created_date":"2022-05-12T00:00:00"}