{"id":"https://openalex.org/W4250036375","doi":"https://doi.org/10.1002/ange.202112683","title":"Rapid Iron(III)\u2212Fluoride\u2010Mediated Hydrogen Atom Transfer","display_name":"Rapid Iron(III)\u2212Fluoride\u2010Mediated Hydrogen Atom Transfer","publication_year":2021,"publication_date":"2021-09-28","ids":{"openalex":"https://openalex.org/W4250036375","doi":"https://doi.org/10.1002/ange.202112683"},"language":"en","primary_location":{"id":"doi:10.1002/ange.202112683","doi":"https://doi.org/10.1002/ange.202112683","is_oa":true,"landing_page_url":"https://doi.org/10.1002/ange.202112683","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/ange.202112683","source":{"id":"https://openalex.org/S4210200754","display_name":"Angewandte Chemie","issn_l":"0044-8249","issn":["0044-8249","0932-2140","1521-3757"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"hybrid","oa_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/ange.202112683","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5028753641","display_name":"Chakadola Panda","orcid":"https://orcid.org/0000-0003-3073-8025","observed_orcids":["https://orcid.org/0000-0003-3073-8025"]},"institutions":[{"id":"https://openalex.org/I205274468","display_name":"Trinity College Dublin","ror":"https://ror.org/02tyrky19","country_code":"IE","type":"education","lineage":["https://openalex.org/I205274468"]}],"countries":["IE"],"is_corresponding":false,"raw_author_name":"Chakadola Panda","raw_affiliation_strings":["School of Chemistry, Trinity College Dublin, The University of Dublin, College Green, Dublin 2, Ireland"],"raw_orcid":"https://orcid.org/0000-0003-3073-8025","affiliations":[{"raw_affiliation_string":"School of Chemistry, Trinity College Dublin, The University of Dublin, College Green, Dublin 2, Ireland","institution_ids":["https://openalex.org/I205274468"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5077099956","display_name":"Lorna M. Doyle","orcid":"https://orcid.org/0000-0002-0065-8801","observed_orcids":["https://orcid.org/0000-0002-0065-8801"]},"institutions":[{"id":"https://openalex.org/I205274468","display_name":"Trinity College Dublin","ror":"https://ror.org/02tyrky19","country_code":"IE","type":"education","lineage":["https://openalex.org/I205274468"]}],"countries":["IE"],"is_corresponding":false,"raw_author_name":"Lorna M. Doyle","raw_affiliation_strings":["School of Chemistry, Trinity College Dublin, The University of Dublin, College Green, Dublin 2, Ireland"],"raw_orcid":"https://orcid.org/0000-0002-0065-8801","affiliations":[{"raw_affiliation_string":"School of Chemistry, Trinity College Dublin, The University of Dublin, College Green, Dublin 2, Ireland","institution_ids":["https://openalex.org/I205274468"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5081153980","display_name":"Robert Gericke","orcid":"https://orcid.org/0000-0003-4669-0206","observed_orcids":["https://orcid.org/0000-0003-4669-0206"]},"institutions":[{"id":"https://openalex.org/I205274468","display_name":"Trinity College Dublin","ror":"https://ror.org/02tyrky19","country_code":"IE","type":"education","lineage":["https://openalex.org/I205274468"]},{"id":"https://openalex.org/I2801798921","display_name":"Helmholtz-Zentrum Dresden-Rossendorf","ror":"https://ror.org/01zy2cs03","country_code":"DE","type":"facility","lineage":["https://openalex.org/I1305996414","https://openalex.org/I2801798921"]}],"countries":["DE","IE"],"is_corresponding":false,"raw_author_name":"Robert Gericke","raw_affiliation_strings":["Current address: Helmholtz-Zentrum Dresden-Rossendorf e. V., Institute of Resource Ecology, Bautzner Landstrasse 400, 01328 Dresden, Germany","School of Chemistry, Trinity College Dublin, The University of Dublin, College Green, Dublin 2, Ireland"],"raw_orcid":"https://orcid.org/0000-0003-4669-0206","affiliations":[{"raw_affiliation_string":"Current address: Helmholtz-Zentrum Dresden-Rossendorf e. V., Institute of Resource Ecology, Bautzner Landstrasse 400, 01328 Dresden, Germany","institution_ids":["https://openalex.org/I2801798921"]},{"raw_affiliation_string":"School of Chemistry, Trinity College Dublin, The University of Dublin, College Green, Dublin 2, Ireland","institution_ids":["https://openalex.org/I205274468"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5054670336","display_name":"Aidan R. McDonald","orcid":"https://orcid.org/0000-0002-8930-3256","observed_orcids":["https://orcid.org/0000-0002-8930-3256"]},"institutions":[{"id":"https://openalex.org/I205274468","display_name":"Trinity College Dublin","ror":"https://ror.org/02tyrky19","country_code":"IE","type":"education","lineage":["https://openalex.org/I205274468"]}],"countries":["IE"],"is_corresponding":true,"raw_author_name":"Aidan R. McDonald","raw_affiliation_strings":["School of Chemistry, Trinity College Dublin, The University of Dublin, College Green, Dublin 2, Ireland"],"raw_orcid":"https://orcid.org/0000-0002-8930-3256","affiliations":[{"raw_affiliation_string":"School of Chemistry, Trinity College Dublin, The University of Dublin, College Green, Dublin 2, Ireland","institution_ids":["https://openalex.org/I205274468"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5054670336"],"corresponding_institution_ids":["https://openalex.org/I205274468"],"apc_list":{"value":5000,"currency":"USD","value_usd":5000},"apc_paid":{"value":5000,"currency":"USD","value_usd":5000},"fwci":0.2364,"has_fulltext":true,"cited_by_count":5,"citation_normalized_percentile":{"value":0.42722193,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":95},"biblio":{"volume":"133","issue":"50","first_page":"26485","last_page":"26490"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11747","display_name":"Metal-Catalyzed Oxygenation Mechanisms","score":0.49950000643730164,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11747","display_name":"Metal-Catalyzed Oxygenation Mechanisms","score":0.49950000643730164,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11989","display_name":"Oxidative Organic Chemistry Reactions","score":0.36160001158714294,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.04309999942779541,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/hydrogen-atom-transfer","display_name":"hydrogen atom transfer","score":0.8080000281333923},{"id":"https://openalex.org/keywords/oxidative-c-h-activation","display_name":"oxidative C\u2013H activation","score":0.8050000071525574},{"id":"https://openalex.org/keywords/lewis-acid-activation","display_name":"Lewis acid activation","score":0.6880000233650208},{"id":"https://openalex.org/keywords/brnsted-acid-activation","display_name":"Br\u00f8nsted acid activation","score":0.9670000076293945}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.888613224029541},{"id":"https://openalex.org/C40875361","wikidata":"https://www.wikidata.org/wiki/Q2356542","display_name":"Reagent","level":2,"score":0.5605016946792603},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.5438980460166931},{"id":"https://openalex.org/C134121241","wikidata":"https://www.wikidata.org/wiki/Q899301","display_name":"Yield (engineering)","level":2,"score":0.5246660709381104},{"id":"https://openalex.org/C187961010","wikidata":"https://www.wikidata.org/wiki/Q260463","display_name":"Electron paramagnetic resonance","level":2,"score":0.5212581753730774},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.5160486102104187},{"id":"https://openalex.org/C131779359","wikidata":"https://www.wikidata.org/wiki/Q471875","display_name":"Amine gas treating","level":2,"score":0.49770334362983704},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.46043509244918823},{"id":"https://openalex.org/C2780828025","wikidata":"https://www.wikidata.org/wiki/Q44793182","display_name":"Fluoride","level":2,"score":0.4593719244003296},{"id":"https://openalex.org/C166940927","wikidata":"https://www.wikidata.org/wiki/Q178827","display_name":"Monomer","level":3,"score":0.43744397163391113},{"id":"https://openalex.org/C2779546866","wikidata":"https://www.wikidata.org/wiki/Q531306","display_name":"Dimer","level":2,"score":0.4337235689163208},{"id":"https://openalex.org/C2776640939","wikidata":"https://www.wikidata.org/wiki/Q6643508","display_name":"Hydrogen atom","level":3,"score":0.42404812574386597},{"id":"https://openalex.org/C94882840","wikidata":"https://www.wikidata.org/wiki/Q2123471","display_name":"Oxidative addition","level":3,"score":0.4109218120574951},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.38874268531799316},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.23223161697387695},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.1921248435974121},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.0},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.0},{"id":"https://openalex.org/C46141821","wikidata":"https://www.wikidata.org/wiki/Q209402","display_name":"Nuclear magnetic resonance","level":1,"score":0.0},{"id":"https://openalex.org/C191897082","wikidata":"https://www.wikidata.org/wiki/Q11467","display_name":"Metallurgy","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/ange.202112683","doi":"https://doi.org/10.1002/ange.202112683","is_oa":true,"landing_page_url":"https://doi.org/10.1002/ange.202112683","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/ange.202112683","source":{"id":"https://openalex.org/S4210200754","display_name":"Angewandte Chemie","issn_l":"0044-8249","issn":["0044-8249","0932-2140","1521-3757"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie","raw_type":"journal-article"}],"best_oa_location":{"id":"doi:10.1002/ange.202112683","doi":"https://doi.org/10.1002/ange.202112683","is_oa":true,"landing_page_url":"https://doi.org/10.1002/ange.202112683","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/ange.202112683","source":{"id":"https://openalex.org/S4210200754","display_name":"Angewandte Chemie","issn_l":"0044-8249","issn":["0044-8249","0932-2140","1521-3757"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G137528073","display_name":null,"funder_award_id":"SFI/15/RS-URF/3307","funder_id":"https://openalex.org/F4320320847","funder_display_name":"Science Foundation Ireland"},{"id":"https://openalex.org/G433666920","display_name":null,"funder_award_id":"ERC-2015-STG-678202","funder_id":"https://openalex.org/F4320338335","funder_display_name":"H2020 European Research Council"}],"funders":[{"id":"https://openalex.org/F4320318630","display_name":"Irish Research eLibrary","ror":"https://ror.org/05c347015"},{"id":"https://openalex.org/F4320320847","display_name":"Science Foundation Ireland","ror":"https://ror.org/0271asj38"},{"id":"https://openalex.org/F4320338335","display_name":"H2020 European Research Council","ror":"https://ror.org/0472cxd90"}],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W4250036375.pdf","grobid_xml":"https://content.openalex.org/works/W4250036375.grobid-xml"},"referenced_works_count":90,"referenced_works":["https://openalex.org/W579107163","https://openalex.org/W1965285273","https://openalex.org/W1965969235","https://openalex.org/W1967700647","https://openalex.org/W1972846946","https://openalex.org/W1974892037","https://openalex.org/W1976205221","https://openalex.org/W1977417266","https://openalex.org/W1978754214","https://openalex.org/W1981077946","https://openalex.org/W1981763423","https://openalex.org/W1986260849","https://openalex.org/W1987979669","https://openalex.org/W1989269725","https://openalex.org/W1990611195","https://openalex.org/W1991692692","https://openalex.org/W1995891356","https://openalex.org/W1998714557","https://openalex.org/W1999582957","https://openalex.org/W2003300576","https://openalex.org/W2005661768","https://openalex.org/W2008186722","https://openalex.org/W2008851567","https://openalex.org/W2012776986","https://openalex.org/W2013686593","https://openalex.org/W2024122173","https://openalex.org/W2033035711","https://openalex.org/W2041930594","https://openalex.org/W2060738076","https://openalex.org/W2062273343","https://openalex.org/W2062416450","https://openalex.org/W2078575717","https://openalex.org/W2085831526","https://openalex.org/W2087373022","https://openalex.org/W2090027364","https://openalex.org/W2090688899","https://openalex.org/W2091255628","https://openalex.org/W2094204173","https://openalex.org/W2098057202","https://openalex.org/W2100449328","https://openalex.org/W2102503864","https://openalex.org/W2104238415","https://openalex.org/W2109781946","https://openalex.org/W2121061700","https://openalex.org/W2122261874","https://openalex.org/W2123813684","https://openalex.org/W2144025618","https://openalex.org/W2151975138","https://openalex.org/W2170020637","https://openalex.org/W2316012065","https://openalex.org/W2325148188","https://openalex.org/W2325573195","https://openalex.org/W2333153781","https://openalex.org/W2333164660","https://openalex.org/W2421346213","https://openalex.org/W2482298036","https://openalex.org/W2485422416","https://openalex.org/W2518909640","https://openalex.org/W2521754066","https://openalex.org/W2530107767","https://openalex.org/W2565539480","https://openalex.org/W2580609831","https://openalex.org/W2592485594","https://openalex.org/W2601224882","https://openalex.org/W2777651827","https://openalex.org/W2781936076","https://openalex.org/W2782752877","https://openalex.org/W2787805923","https://openalex.org/W2795631484","https://openalex.org/W2896437944","https://openalex.org/W2897531901","https://openalex.org/W2911739709","https://openalex.org/W2914549714","https://openalex.org/W2921880109","https://openalex.org/W2954285621","https://openalex.org/W2979130254","https://openalex.org/W2985629046","https://openalex.org/W2992353457","https://openalex.org/W2998875157","https://openalex.org/W3018224301","https://openalex.org/W3087416550","https://openalex.org/W3121395803","https://openalex.org/W3137030814","https://openalex.org/W3156962377","https://openalex.org/W4210956767","https://openalex.org/W4241392921","https://openalex.org/W4242867995","https://openalex.org/W4246015811","https://openalex.org/W4246108227","https://openalex.org/W4249100237"],"related_works":["https://openalex.org/W4323047934","https://openalex.org/W2755366472","https://openalex.org/W2592485594","https://openalex.org/W2324394961","https://openalex.org/W2088175316","https://openalex.org/W2408830764","https://openalex.org/W2013686593","https://openalex.org/W4405838702","https://openalex.org/W2141722172","https://openalex.org/W4415878651"],"abstract_inverted_index":{"Abstract":[0],"We":[1,30],"anticipate":[2],"high\u2010valent":[3],"metal\u2013fluoride":[4],"species":[5],"will":[6],"be":[7],"highly":[8],"effective":[9],"hydrogen":[10],"atom":[11],"transfer":[12],"(HAT)":[13],"oxidants":[14],"because":[15],"of":[16,19],"the":[17,20,24,104],"magnitude":[18],"H\u2212F":[21],"bond":[22],"(in":[23],"product)":[25],"that":[26],"drives":[27],"HAT":[28,101],"oxidation.":[29],"prepared":[31],"a":[32,46,63,87],"dimeric":[33],"FeIII(F)\u2212F\u2212FeIII(F)":[34],"complex":[35,66],"(1)":[36],"by":[37,54],"reacting":[38],"[FeII(NCCH3)2(TPA)](ClO4)2":[39],"(TPA=tris(2\u2010pyridylmethyl)amine)":[40],"with":[41,56],"difluoro(phenyl)\u2010\u03bb3\u2010iodane":[42],"(difluoroiodobenzene).":[43],"1":[44,70],"was":[45,51,86],"sluggish":[47],"oxidant,":[48],"however,":[49],"it":[50],"readily":[52],"activated":[53],"reaction":[55,97],"Lewis":[57],"or":[58],"Br\u00f8nsted":[59],"acids":[60],"to":[61,103],"yield":[62],"monomeric":[64],"[FeIII(TPA)(F)(X)]+":[65],"(2)":[67],"where":[68],"X=F/OTf.":[69],"and":[71,79,82,108],"2":[72,85],"were":[73],"characterized":[74],"using":[75],"NMR,":[76],"EPR,":[77],"UV/Vis,":[78],"FT\u2010IR":[80],"spectroscopies":[81],"mass":[83],"spectrometry.":[84],"remarkably":[88],"reactive":[89,106],"FeIII":[90,107],"reagent":[91],"for":[92,99],"oxidative":[93],"C\u2212H":[94],"activation,":[95],"demonstrating":[96],"rates":[98],"hydrocarbon":[100],"comparable":[102],"most":[105],"FeIV":[109],"oxidants.":[110]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2025,"cited_by_count":1},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":2}],"updated_date":"2026-11-03T10:50:19.383937","created_date":"2022-05-12T00:00:00"}
