{"id":"https://openalex.org/W4249719682","doi":"https://doi.org/10.1002/ange.201306007","title":"Cascade Palladium Catalysis: A Predictable and Selectable Regiocontrolled Synthesis of N\u2010Arylbenzimidazoles","display_name":"Cascade Palladium Catalysis: A Predictable and Selectable Regiocontrolled Synthesis of N\u2010Arylbenzimidazoles","publication_year":2013,"publication_date":"2013-09-13","ids":{"openalex":"https://openalex.org/W4249719682","doi":"https://doi.org/10.1002/ange.201306007"},"language":"en","primary_location":{"id":"doi:10.1002/ange.201306007","doi":"https://doi.org/10.1002/ange.201306007","is_oa":false,"landing_page_url":"https://doi.org/10.1002/ange.201306007","pdf_url":null,"source":{"id":"https://openalex.org/S4210200754","display_name":"Angewandte Chemie","issn_l":"0044-8249","issn":["0044-8249","0932-2140","1521-3757"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5037444457","display_name":"Nathan T. Jui","orcid":"https://orcid.org/0000-0001-5315-0270","observed_orcids":["https://orcid.org/0000-0001-5315-0270"]},"institutions":[{"id":"https://openalex.org/I63966007","display_name":"Massachusetts Institute of Technology","ror":"https://ror.org/042nb2s44","country_code":"US","type":"education","lineage":["https://openalex.org/I63966007"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Nathan T. Jui","raw_affiliation_strings":["Department of Chemistry, Room 18-490, Massachusetts Institute of Technology, Cambridge, MA 02139 (USA)"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Room 18-490, Massachusetts Institute of Technology, Cambridge, MA 02139 (USA)","institution_ids":["https://openalex.org/I63966007"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5039233288","display_name":"Stephen L. Buchwald","orcid":"https://orcid.org/0000-0003-3875-4775","observed_orcids":["https://orcid.org/0000-0003-3875-4775"]},"institutions":[{"id":"https://openalex.org/I63966007","display_name":"Massachusetts Institute of Technology","ror":"https://ror.org/042nb2s44","country_code":"US","type":"education","lineage":["https://openalex.org/I63966007"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Stephen L. Buchwald","raw_affiliation_strings":["Department of Chemistry, Room 18-490, Massachusetts Institute of Technology, Cambridge, MA 02139 (USA)"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Room 18-490, Massachusetts Institute of Technology, Cambridge, MA 02139 (USA)","institution_ids":["https://openalex.org/I63966007"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5039233288"],"corresponding_institution_ids":["https://openalex.org/I63966007"],"apc_list":{"value":5790,"currency":"USD","value_usd":5790},"apc_paid":null,"fwci":1.0629,"has_fulltext":false,"cited_by_count":12,"citation_normalized_percentile":{"value":0.74816069,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":98},"biblio":{"volume":"125","issue":"44","first_page":"11838","last_page":"11841"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10548","display_name":"Catalytic Cross-Coupling Reactions","score":0.8647000193595886,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10548","display_name":"Catalytic Cross-Coupling Reactions","score":0.8647000193595886,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10354","display_name":"Catalytic C\u2013H Functionalization Methods","score":0.10589999705553055,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12189","display_name":"Sulfur-Based Synthesis Techniques","score":0.005799999926239252,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/palladium-catalysis","display_name":"palladium catalysis","score":0.9160000085830688},{"id":"https://openalex.org/keywords/cascade-reactions","display_name":"cascade reactions","score":0.8320000171661377},{"id":"https://openalex.org/keywords/regioselective-synthesis","display_name":"regioselective synthesis","score":0.8040000200271606},{"id":"https://openalex.org/keywords/oxidative-addition","display_name":"oxidative addition","score":0.8410000205039978},{"id":"https://openalex.org/keywords/aromatic-amines","display_name":"aromatic amines","score":0.8479999899864197},{"id":"https://openalex.org/keywords/triflate","display_name":"trifluoromethanesulfonate","score":0.6930000185966492},{"id":"https://openalex.org/keywords/mesylate","display_name":"mesylate","score":0.972000002861023},{"id":"https://openalex.org/keywords/heterocycle-synthesis","display_name":"heterocyclic synthesis","score":0.8420000076293945}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7556535601615906},{"id":"https://openalex.org/C502130503","wikidata":"https://www.wikidata.org/wiki/Q1089","display_name":"Palladium","level":3,"score":0.7238690853118896},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.6306389570236206},{"id":"https://openalex.org/C59759590","wikidata":"https://www.wikidata.org/wiki/Q2275927","display_name":"Regioselectivity","level":3,"score":0.6280579566955566},{"id":"https://openalex.org/C202235601","wikidata":"https://www.wikidata.org/wiki/Q7361732","display_name":"Structural isomer","level":2,"score":0.47562530636787415},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.4161977767944336},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.38547271490097046},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.3390103578567505},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.21512392163276672}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/ange.201306007","doi":"https://doi.org/10.1002/ange.201306007","is_oa":false,"landing_page_url":"https://doi.org/10.1002/ange.201306007","pdf_url":null,"source":{"id":"https://openalex.org/S4210200754","display_name":"Angewandte Chemie","issn_l":"0044-8249","issn":["0044-8249","0932-2140","1521-3757"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"sustainable_development_goals_aurora":[{"display_name":"Clean water and sanitation","id":"https://metadata.un.org/sdg/6","score":0.5899999737739563}],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":50,"referenced_works":["https://openalex.org/W563825137","https://openalex.org/W1485337939","https://openalex.org/W1543830028","https://openalex.org/W1567523921","https://openalex.org/W1969859378","https://openalex.org/W1973503725","https://openalex.org/W1996562668","https://openalex.org/W1998312717","https://openalex.org/W1998869379","https://openalex.org/W2004867175","https://openalex.org/W2010224630","https://openalex.org/W2013581526","https://openalex.org/W2019975683","https://openalex.org/W2029131679","https://openalex.org/W2031774809","https://openalex.org/W2040407360","https://openalex.org/W2043889031","https://openalex.org/W2046549749","https://openalex.org/W2048512643","https://openalex.org/W2048986263","https://openalex.org/W2060548501","https://openalex.org/W2060912642","https://openalex.org/W2061025899","https://openalex.org/W2063674611","https://openalex.org/W2065047384","https://openalex.org/W2083790594","https://openalex.org/W2084159338","https://openalex.org/W2096042804","https://openalex.org/W2096332023","https://openalex.org/W2099075274","https://openalex.org/W2106573870","https://openalex.org/W2107236186","https://openalex.org/W2108240183","https://openalex.org/W2132626909","https://openalex.org/W2153003477","https://openalex.org/W2153971092","https://openalex.org/W2159860925","https://openalex.org/W2166976828","https://openalex.org/W2206066738","https://openalex.org/W2312212513","https://openalex.org/W2323505461","https://openalex.org/W2334618617","https://openalex.org/W2950602720","https://openalex.org/W2951360372","https://openalex.org/W2953221427","https://openalex.org/W4214702629","https://openalex.org/W4230699419","https://openalex.org/W4236218853","https://openalex.org/W4237733705","https://openalex.org/W4252106558"],"related_works":["https://openalex.org/W2951221874","https://openalex.org/W2580719623","https://openalex.org/W2950328689","https://openalex.org/W4237733705","https://openalex.org/W2030075102","https://openalex.org/W2326007782","https://openalex.org/W2949970424","https://openalex.org/W2080023648","https://openalex.org/W1996785187","https://openalex.org/W2952867256"],"abstract_inverted_index":{"Nach":[0],"Wahl:":[1],"Eine":[2],"palladiumkatalysierte":[3],"Reaktionskaskade":[4],"baut":[5],"N-Arylbenzimidazole":[6],"direkt":[7],"aus":[8],"2-Chlorarylsulfonaten,":[9],"Arylaminen":[10],"und":[11],"Amidnucleophilen":[12],"auf.":[13],"Die":[14],"Heterocyclen":[15],"entstehen":[16],"dabei":[17],"\u00fcber":[18],"eine":[19],"chemoselektive":[20],"oxidative":[21],"Addition.":[22],"Mit":[23],"2-Chloraryltriflaten":[24],"(Tf)":[25],"wird":[26],"gezielt":[27],"ein":[28],"Regioisomer":[29],"erhalten,":[30],"mit":[31],"den":[32],"entsprechenden":[33],"2-Chlorarylmesylaten":[34],"(Ms)":[35],"das":[36],"andere.":[37]},"counts_by_year":[{"year":2020,"cited_by_count":1},{"year":2019,"cited_by_count":2},{"year":2018,"cited_by_count":2},{"year":2016,"cited_by_count":4},{"year":2015,"cited_by_count":2},{"year":2014,"cited_by_count":1}],"updated_date":"2026-10-14T16:39:01.820549","created_date":"2022-05-12T00:00:00"}
