{"id":"https://openalex.org/W4244863344","doi":"https://doi.org/10.1002/ange.201611409","title":"Selective Arene Cleavage by Direct Insertion of Iridium into the Aromatic Ring","display_name":"Selective Arene Cleavage by Direct Insertion of Iridium into the Aromatic Ring","publication_year":2017,"publication_date":"2017-02-16","ids":{"openalex":"https://openalex.org/W4244863344","doi":"https://doi.org/10.1002/ange.201611409"},"language":"en","primary_location":{"id":"doi:10.1002/ange.201611409","doi":"https://doi.org/10.1002/ange.201611409","is_oa":false,"landing_page_url":"https://doi.org/10.1002/ange.201611409","pdf_url":null,"source":{"id":"https://openalex.org/S4210200754","display_name":"Angewandte Chemie","issn_l":"0044-8249","issn":["0044-8249","0932-2140","1521-3757"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5026181857","display_name":"Martin Jakoobi","orcid":"https://orcid.org/0000-0002-6181-4839","observed_orcids":["https://orcid.org/0000-0002-6181-4839"]},"institutions":[{"id":"https://openalex.org/I146655781","display_name":"University of Liverpool","ror":"https://ror.org/04xs57h96","country_code":"GB","type":"education","lineage":["https://openalex.org/I146655781"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"Martin Jakoobi","raw_affiliation_strings":["Department of Chemistry, University of Liverpool, Crown Street, Liverpool, L69 7ZD UK"],"raw_orcid":"https://orcid.org/0000-0002-6181-4839","affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Liverpool, Crown Street, Liverpool, L69 7ZD UK","institution_ids":["https://openalex.org/I146655781"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5043535926","display_name":"Nathan R. Halcovitch","orcid":"https://orcid.org/0000-0001-6831-9681","observed_orcids":["https://orcid.org/0000-0001-6831-9681"]},"institutions":[{"id":"https://openalex.org/I67415387","display_name":"Lancaster University","ror":"https://ror.org/04f2nsd36","country_code":"GB","type":"education","lineage":["https://openalex.org/I67415387"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"Nathan Halcovitch","raw_affiliation_strings":["Department of Chemistry, Lancaster University, Lancaster, 2LA1 4YB UK"],"raw_orcid":"https://orcid.org/0000-0001-6831-9681","affiliations":[{"raw_affiliation_string":"Department of Chemistry, Lancaster University, Lancaster, 2LA1 4YB UK","institution_ids":["https://openalex.org/I67415387"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5026876058","display_name":"George F. S. Whitehead","orcid":"https://orcid.org/0000-0003-1949-4250","observed_orcids":["https://orcid.org/0000-0003-1949-4250","https://orcid.org/0000-0002-9570-1584"]},"institutions":[{"id":"https://openalex.org/I146655781","display_name":"University of Liverpool","ror":"https://ror.org/04xs57h96","country_code":"GB","type":"education","lineage":["https://openalex.org/I146655781"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"George F. S. Whitehead","raw_affiliation_strings":["Department of Chemistry, University of Liverpool, Crown Street, Liverpool, L69 7ZD UK"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Liverpool, Crown Street, Liverpool, L69 7ZD UK","institution_ids":["https://openalex.org/I146655781"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5001342570","display_name":"Alexey G. Sergeev","orcid":"https://orcid.org/0000-0003-1587-2517","observed_orcids":["https://orcid.org/0000-0003-1587-2517"]},"institutions":[{"id":"https://openalex.org/I146655781","display_name":"University of Liverpool","ror":"https://ror.org/04xs57h96","country_code":"GB","type":"education","lineage":["https://openalex.org/I146655781"]}],"countries":["GB"],"is_corresponding":true,"raw_author_name":"Alexey G. Sergeev","raw_affiliation_strings":["Department of Chemistry, University of Liverpool, Crown Street, Liverpool, L69 7ZD UK"],"raw_orcid":"https://orcid.org/0000-0003-1587-2517","affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Liverpool, Crown Street, Liverpool, L69 7ZD UK","institution_ids":["https://openalex.org/I146655781"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5001342570"],"corresponding_institution_ids":["https://openalex.org/I146655781"],"apc_list":{"value":5790,"currency":"USD","value_usd":5790},"apc_paid":null,"fwci":0.8475,"has_fulltext":false,"cited_by_count":12,"citation_normalized_percentile":{"value":0.6374283,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":97},"biblio":{"volume":"129","issue":"12","first_page":"3314","last_page":"3317"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.9491999745368958,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.9491999745368958,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10354","display_name":"Catalytic C\u2013H Functionalization Methods","score":0.03150000050663948,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.0044999998062849045,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/iridium-complexes","display_name":"iridium complexes","score":0.824999988079071},{"id":"https://openalex.org/keywords/metallacycles","display_name":"metallacycles","score":0.7200000286102295},{"id":"https://openalex.org/keywords/alkylarenes","display_name":"alkylarenes","score":0.7950000166893005},{"id":"https://openalex.org/keywords/ring-strain","display_name":"ring strain","score":0.8579999804496765}],"concepts":[{"id":"https://openalex.org/C528581852","wikidata":"https://www.wikidata.org/wiki/Q877","display_name":"Iridium","level":3,"score":0.8546459674835205},{"id":"https://openalex.org/C2780378348","wikidata":"https://www.wikidata.org/wiki/Q25351438","display_name":"Ring (chemistry)","level":2,"score":0.7495294809341431},{"id":"https://openalex.org/C175156509","wikidata":"https://www.wikidata.org/wiki/Q1990218","display_name":"Cleavage (geology)","level":3,"score":0.7255386710166931},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7204297184944153},{"id":"https://openalex.org/C107111320","wikidata":"https://www.wikidata.org/wiki/Q905231","display_name":"Ring strain","level":3,"score":0.5741574168205261},{"id":"https://openalex.org/C3044715","wikidata":"https://www.wikidata.org/wiki/Q3952437","display_name":"Bond cleavage","level":3,"score":0.5301409959793091},{"id":"https://openalex.org/C2779909098","wikidata":"https://www.wikidata.org/wiki/Q287991","display_name":"Insertion reaction","level":3,"score":0.4965570569038391},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.4907878339290619},{"id":"https://openalex.org/C154256306","wikidata":"https://www.wikidata.org/wiki/Q41795528","display_name":"Inert","level":2,"score":0.4393073320388794},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.4234706163406372},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.36004483699798584},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.16194245219230652},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.14633700251579285},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.10281825065612793},{"id":"https://openalex.org/C43369102","wikidata":"https://www.wikidata.org/wiki/Q2307625","display_name":"Fracture (geology)","level":2,"score":0.0},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/ange.201611409","doi":"https://doi.org/10.1002/ange.201611409","is_oa":false,"landing_page_url":"https://doi.org/10.1002/ange.201611409","pdf_url":null,"source":{"id":"https://openalex.org/S4210200754","display_name":"Angewandte Chemie","issn_l":"0044-8249","issn":["0044-8249","0932-2140","1521-3757"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320320006","display_name":"Royal Society","ror":"https://ror.org/03wnrjx87"},{"id":"https://openalex.org/F4320320323","display_name":"University of Liverpool","ror":"https://ror.org/04xs57h96"},{"id":"https://openalex.org/F4320320667","display_name":"Swansea University","ror":"https://ror.org/053fq8t95"},{"id":"https://openalex.org/F4320334627","display_name":"Engineering and Physical Sciences Research Council","ror":"https://ror.org/0439y7842"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":28,"referenced_works":["https://openalex.org/W110454106","https://openalex.org/W565854973","https://openalex.org/W1484707803","https://openalex.org/W1750457094","https://openalex.org/W1966633160","https://openalex.org/W1977930210","https://openalex.org/W1990827413","https://openalex.org/W2006653270","https://openalex.org/W2009636281","https://openalex.org/W2011865693","https://openalex.org/W2021581294","https://openalex.org/W2044385474","https://openalex.org/W2072642557","https://openalex.org/W2086586029","https://openalex.org/W2087013611","https://openalex.org/W2092398327","https://openalex.org/W2095213125","https://openalex.org/W2100256773","https://openalex.org/W2105195481","https://openalex.org/W2108719033","https://openalex.org/W2123720939","https://openalex.org/W2136807818","https://openalex.org/W2165071949","https://openalex.org/W2316990227","https://openalex.org/W2479475740","https://openalex.org/W4206552432","https://openalex.org/W4243207892","https://openalex.org/W4245238438"],"related_works":["https://openalex.org/W2920948904","https://openalex.org/W3120685272","https://openalex.org/W2979398594","https://openalex.org/W2793825657","https://openalex.org/W4283258321","https://openalex.org/W2798036745","https://openalex.org/W4412835437","https://openalex.org/W4324128903","https://openalex.org/W4238475385","https://openalex.org/W2130391588"],"abstract_inverted_index":{"Abstract":[0],"We":[1],"report":[2],"an":[3],"unprecedented":[4],"selective":[5,70],"cleavage":[6],"of":[7,14,22,34,51,57,72],"aromatic":[8,20],"C\u2212C":[9,38,81],"bonds":[10,39],"through":[11],"the":[12,19,32,49,58,73,76],"insertion":[13,26,71],"well\u2010defined":[15],"iridium":[16],"complexes":[17],"into":[18,75],"ring":[21,64,80],"simple":[23],"alkylarenes.":[24],"The":[25],"occurs":[27],"at":[28],"50\u2013100":[29],"\u00b0C":[30],"without":[31],"activation":[33],"weaker":[35],"C\u2212H":[36],"and":[37,40,66,69],"gives":[41],"unique":[42],"metallacycles":[43],"in":[44],"high":[45],"yields.":[46],"Key":[47],"to":[48],"success":[50],"this":[52],"approach":[53],"is":[54],"metal\u2010induced":[55],"deformation":[56],"arene":[59,79],"ring,":[60],"which":[61],"creates":[62],"temporary":[63],"strain":[65],"promotes":[67],"direct":[68],"metal":[74],"otherwise":[77],"inert":[78],"bonds.":[82]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2022,"cited_by_count":1},{"year":2021,"cited_by_count":2},{"year":2020,"cited_by_count":4},{"year":2019,"cited_by_count":2},{"year":2017,"cited_by_count":2}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2022-05-12T00:00:00"}
