{"id":"https://openalex.org/W4243551497","doi":"https://doi.org/10.1002/ange.202100655","title":"A Self\u2010Assembled Homochiral Radical Cage with Paramagnetic Behaviors","display_name":"A Self\u2010Assembled Homochiral Radical Cage with Paramagnetic Behaviors","publication_year":2021,"publication_date":"2021-03-02","ids":{"openalex":"https://openalex.org/W4243551497","doi":"https://doi.org/10.1002/ange.202100655"},"language":"en","primary_location":{"id":"doi:10.1002/ange.202100655","doi":"https://doi.org/10.1002/ange.202100655","is_oa":false,"landing_page_url":"https://doi.org/10.1002/ange.202100655","pdf_url":null,"source":{"id":"https://openalex.org/S4210200754","display_name":"Angewandte Chemie","issn_l":"0044-8249","issn":["0044-8249","0932-2140","1521-3757"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5090970359","display_name":"Tianyu Jiao","orcid":"https://orcid.org/0000-0002-5423-1061","observed_orcids":["https://orcid.org/0000-0002-5423-1061"]},"institutions":[{"id":"https://openalex.org/I76130692","display_name":"Zhejiang University","ror":"https://ror.org/00a2xv884","country_code":"CN","type":"education","lineage":["https://openalex.org/I76130692"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Tianyu Jiao","raw_affiliation_strings":["Department of Chemistry, Zhejiang University, Hangzhou, 310027 P. R. China"],"raw_orcid":"https://orcid.org/0000-0002-5423-1061","affiliations":[{"raw_affiliation_string":"Department of Chemistry, Zhejiang University, Hangzhou, 310027 P. R. China","institution_ids":["https://openalex.org/I76130692"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5008104043","display_name":"Hang Qu","orcid":"https://orcid.org/0000-0003-4263-0505","observed_orcids":["https://orcid.org/0000-0003-4263-0505"]},"institutions":[{"id":"https://openalex.org/I191208505","display_name":"Xiamen University","ror":"https://ror.org/00mcjh785","country_code":"CN","type":"education","lineage":["https://openalex.org/I191208505"]},{"id":"https://openalex.org/I4210156571","display_name":"Collaborative Innovation Center of Chemistry for Energy Materials","ror":"https://ror.org/05fdv7d34","country_code":"CN","type":"facility","lineage":["https://openalex.org/I4210156571"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Hang Qu","raw_affiliation_strings":["State Key Laboratory of Physical Chemistry of Solid Surfaces, iChEM and College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"State Key Laboratory of Physical Chemistry of Solid Surfaces, iChEM and College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 China","institution_ids":["https://openalex.org/I191208505","https://openalex.org/I4210156571"]}]},{"author_position":"middle","author":{"id":null,"display_name":"Lu Tong","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I76130692","display_name":"Zhejiang University","ror":"https://ror.org/00a2xv884","country_code":"CN","type":"education","lineage":["https://openalex.org/I76130692"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Lu Tong","raw_affiliation_strings":["Department of Chemistry, Zhejiang University, Hangzhou, 310027 P. R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Zhejiang University, Hangzhou, 310027 P. R. China","institution_ids":["https://openalex.org/I76130692"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5089234935","display_name":"Xiaoyu Cao","orcid":"https://orcid.org/0000-0003-0219-1798","observed_orcids":["https://orcid.org/0000-0003-0219-1798"]},"institutions":[{"id":"https://openalex.org/I191208505","display_name":"Xiamen University","ror":"https://ror.org/00mcjh785","country_code":"CN","type":"education","lineage":["https://openalex.org/I191208505"]},{"id":"https://openalex.org/I4210156571","display_name":"Collaborative Innovation Center of Chemistry for Energy Materials","ror":"https://ror.org/05fdv7d34","country_code":"CN","type":"facility","lineage":["https://openalex.org/I4210156571"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Xiaoyu Cao","raw_affiliation_strings":["State Key Laboratory of Physical Chemistry of Solid Surfaces, iChEM and College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 China"],"raw_orcid":"https://orcid.org/0000-0003-0219-1798","affiliations":[{"raw_affiliation_string":"State Key Laboratory of Physical Chemistry of Solid Surfaces, iChEM and College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 China","institution_ids":["https://openalex.org/I191208505","https://openalex.org/I4210156571"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5100348625","display_name":"Hao Li","orcid":"https://orcid.org/0000-0002-6959-3233","observed_orcids":["https://orcid.org/0000-0002-6959-3233"]},"institutions":[{"id":"https://openalex.org/I76130692","display_name":"Zhejiang University","ror":"https://ror.org/00a2xv884","country_code":"CN","type":"education","lineage":["https://openalex.org/I76130692"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Hao Li","raw_affiliation_strings":["Department of Chemistry, Zhejiang University, Hangzhou, 310027 P. R. China"],"raw_orcid":"https://orcid.org/0000-0002-6959-3233","affiliations":[{"raw_affiliation_string":"Department of Chemistry, Zhejiang University, Hangzhou, 310027 P. R. China","institution_ids":["https://openalex.org/I76130692"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":3,"corresponding_author_ids":["https://openalex.org/A5089234935","https://openalex.org/A5090970359","https://openalex.org/A5100348625"],"corresponding_institution_ids":["https://openalex.org/I191208505","https://openalex.org/I4210156571","https://openalex.org/I76130692"],"apc_list":{"value":5000,"currency":"USD","value_usd":5000},"apc_paid":null,"fwci":0.479,"has_fulltext":false,"cited_by_count":5,"citation_normalized_percentile":{"value":0.46358459,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":93,"max":96},"biblio":{"volume":"133","issue":"18","first_page":"9940","last_page":"9946"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10578","display_name":"Supramolecular Chemistry and Complexes","score":0.8163999915122986,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10578","display_name":"Supramolecular Chemistry and Complexes","score":0.8163999915122986,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11298","display_name":"Synthesis and Properties of Aromatic Compounds","score":0.11010000109672546,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10612","display_name":"Magnetism in coordination complexes","score":0.012299999594688416,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/tren","display_name":"TREN","score":0.6570000052452087},{"id":"https://openalex.org/keywords/c3-symmetry","display_name":"C3 symmetry","score":0.7649999856948853},{"id":"https://openalex.org/keywords/hydrogen-bonding","display_name":"hydrogen bonding","score":0.9620000123977661},{"id":"https://openalex.org/keywords/through-space-coupling","display_name":"through-space coupling","score":0.8510000109672546},{"id":"https://openalex.org/keywords/paramagnetism","display_name":"paramagnetism","score":0.8500000238418579},{"id":"https://openalex.org/keywords/spin-density","display_name":"spin density","score":0.3799999952316284},{"id":"https://openalex.org/keywords/enantiomers","display_name":"enantiomers","score":0.5690000057220459},{"id":"https://openalex.org/keywords/self-assembly","display_name":"self-assembly","score":0.7990000247955322}],"concepts":[{"id":"https://openalex.org/C146888428","wikidata":"https://www.wikidata.org/wiki/Q903478","display_name":"Homochirality","level":3,"score":0.8580591082572937},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8133477568626404},{"id":"https://openalex.org/C160272327","wikidata":"https://www.wikidata.org/wiki/Q841007","display_name":"Cage","level":2,"score":0.8085830211639404},{"id":"https://openalex.org/C75079739","wikidata":"https://www.wikidata.org/wiki/Q1571801","display_name":"Intramolecular force","level":2,"score":0.6177423596382141},{"id":"https://openalex.org/C139066938","wikidata":"https://www.wikidata.org/wiki/Q185056","display_name":"Radical","level":2,"score":0.6074332594871521},{"id":"https://openalex.org/C112887158","wikidata":"https://www.wikidata.org/wiki/Q169324","display_name":"Hydrogen bond","level":3,"score":0.6060312986373901},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.6051258444786072},{"id":"https://openalex.org/C486523","wikidata":"https://www.wikidata.org/wiki/Q494483","display_name":"Enantiomer","level":2,"score":0.6051042079925537},{"id":"https://openalex.org/C134121241","wikidata":"https://www.wikidata.org/wiki/Q899301","display_name":"Yield (engineering)","level":2,"score":0.5283183455467224},{"id":"https://openalex.org/C131779359","wikidata":"https://www.wikidata.org/wiki/Q471875","display_name":"Amine gas treating","level":2,"score":0.41453981399536133},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.3868989646434784},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.17855802178382874},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.11392369866371155},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.09802782535552979},{"id":"https://openalex.org/C114614502","wikidata":"https://www.wikidata.org/wiki/Q76592","display_name":"Combinatorics","level":1,"score":0.0},{"id":"https://openalex.org/C191897082","wikidata":"https://www.wikidata.org/wiki/Q11467","display_name":"Metallurgy","level":1,"score":0.0},{"id":"https://openalex.org/C33923547","wikidata":"https://www.wikidata.org/wiki/Q395","display_name":"Mathematics","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/ange.202100655","doi":"https://doi.org/10.1002/ange.202100655","is_oa":false,"landing_page_url":"https://doi.org/10.1002/ange.202100655","pdf_url":null,"source":{"id":"https://openalex.org/S4210200754","display_name":"Angewandte Chemie","issn_l":"0044-8249","issn":["0044-8249","0932-2140","1521-3757"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G3057925081","display_name":null,"funder_award_id":"21772173","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"},{"id":"https://openalex.org/G426908240","display_name":null,"funder_award_id":"21922108","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"},{"id":"https://openalex.org/G6441109170","display_name":null,"funder_award_id":"2019FZA3007","funder_id":"https://openalex.org/F4320335787","funder_display_name":"Fundamental Research Funds for the Central Universities"},{"id":"https://openalex.org/G7991763063","display_name":null,"funder_award_id":"21722304","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"},{"id":"https://openalex.org/G8580253982","display_name":null,"funder_award_id":"LR18B020001","funder_id":"https://openalex.org/F4320338464","funder_display_name":"Natural Science Foundation of Zhejiang Province"},{"id":"https://openalex.org/G8978862096","display_name":null,"funder_award_id":"91856116","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"}],"funders":[{"id":"https://openalex.org/F4320321001","display_name":"National Natural Science Foundation of China","ror":"https://ror.org/01h0zpd94"},{"id":"https://openalex.org/F4320335787","display_name":"Fundamental Research Funds for the Central Universities","ror":null},{"id":"https://openalex.org/F4320338464","display_name":"Natural Science Foundation of Zhejiang Province","ror":"https://ror.org/01h0zpd94"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":81,"referenced_works":["https://openalex.org/W1964408943","https://openalex.org/W1965918233","https://openalex.org/W1967906197","https://openalex.org/W1975171177","https://openalex.org/W1990080806","https://openalex.org/W1991014537","https://openalex.org/W1994081445","https://openalex.org/W1999145419","https://openalex.org/W2009103043","https://openalex.org/W2020259659","https://openalex.org/W2029294723","https://openalex.org/W2038643187","https://openalex.org/W2045611889","https://openalex.org/W2055734831","https://openalex.org/W2064410717","https://openalex.org/W2064813419","https://openalex.org/W2066334640","https://openalex.org/W2080431611","https://openalex.org/W2087024183","https://openalex.org/W2095617477","https://openalex.org/W2100080515","https://openalex.org/W2100185137","https://openalex.org/W2110996562","https://openalex.org/W2115282762","https://openalex.org/W2117724887","https://openalex.org/W2121653663","https://openalex.org/W2124082439","https://openalex.org/W2136464084","https://openalex.org/W2136840263","https://openalex.org/W2137472239","https://openalex.org/W2144777184","https://openalex.org/W2148510145","https://openalex.org/W2299481623","https://openalex.org/W2319000324","https://openalex.org/W2338156589","https://openalex.org/W2412476668","https://openalex.org/W2473432380","https://openalex.org/W2515025141","https://openalex.org/W2545778511","https://openalex.org/W2563395883","https://openalex.org/W2586444907","https://openalex.org/W2587875856","https://openalex.org/W2590220706","https://openalex.org/W2594242993","https://openalex.org/W2738071157","https://openalex.org/W2755903930","https://openalex.org/W2760882706","https://openalex.org/W2766331266","https://openalex.org/W2790388047","https://openalex.org/W2793731839","https://openalex.org/W2889870701","https://openalex.org/W2908293473","https://openalex.org/W2911312900","https://openalex.org/W2941883279","https://openalex.org/W2942941303","https://openalex.org/W2943789104","https://openalex.org/W2952504211","https://openalex.org/W2952918190","https://openalex.org/W2962441069","https://openalex.org/W2972413223","https://openalex.org/W2982222559","https://openalex.org/W2985328857","https://openalex.org/W2994146667","https://openalex.org/W3040658539","https://openalex.org/W3073534603","https://openalex.org/W3106830441","https://openalex.org/W3108069488","https://openalex.org/W3118134382","https://openalex.org/W3172303481","https://openalex.org/W4211007953","https://openalex.org/W4230380788","https://openalex.org/W4231227339","https://openalex.org/W4235486380","https://openalex.org/W4237074635","https://openalex.org/W4239887792","https://openalex.org/W4240808427","https://openalex.org/W4242368965","https://openalex.org/W4251024354","https://openalex.org/W4251352880","https://openalex.org/W4252604816","https://openalex.org/W4253342640"],"related_works":["https://openalex.org/W3172303481","https://openalex.org/W4244691985","https://openalex.org/W7140702128","https://openalex.org/W3160601414","https://openalex.org/W2087628306","https://openalex.org/W3153245444","https://openalex.org/W2005347872","https://openalex.org/W4241585139","https://openalex.org/W4399215612","https://openalex.org/W2048933938"],"abstract_inverted_index":{"Abstract":[0],"Condensation":[1],"of":[2,23,41],"an":[3],"inherently":[4],"C3\u2010symmetric":[5],"polychlorotriphenylmethyl":[6],"(PTM)":[7],"radical":[8,17],"trisaldehyde":[9],"with":[10],"tris(2\u2010aminoethyl)amine":[11],"(TREN)":[12],"yields":[13],"a":[14,20,63],"[4+4]":[15],"tetrahedral":[16],"cage":[18,43,56,64,74],"as":[19],"racemic":[21],"pair":[22],"homochiral":[24],"enantiomers":[25],"in":[26,62],"75":[27],"%":[28],"isolated":[29],"yield.":[30],"The":[31,45,58],"structure":[32],"was":[33],"characterized":[34],"by":[35],"X\u2010ray":[36],"crystallography,":[37],"confirming":[38],"the":[39,55],"homochirality":[40,46],"each":[42,73],"framework.":[44,57],"results":[47],"from":[48],"intramolecular":[49],"[CH\u22c5\u22c5\u22c5\u03c0]":[50],"and":[51],"hydrogen\u2010bonding":[52],"interactions":[53],"within":[54],"four":[59],"PTM":[60],"radicals":[61],"undergo":[65],"weak":[66],"through\u2010space":[67],"coupling.":[68],"Magnetic":[69],"measurements":[70],"demonstrated":[71],"that":[72],"bears":[75],"3.58":[76],"spins.":[77]},"counts_by_year":[{"year":2024,"cited_by_count":2},{"year":2023,"cited_by_count":3}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2022-05-12T00:00:00"}