{"id":"https://openalex.org/W4243195031","doi":"https://doi.org/10.26434/chemrxiv.9874454","title":"Arene Dearomatization via Radical Hydroarylation","display_name":"Arene Dearomatization via Radical Hydroarylation","publication_year":2019,"publication_date":"2019-09-23","ids":{"openalex":"https://openalex.org/W4243195031","doi":"https://doi.org/10.26434/chemrxiv.9874454"},"language":"en","primary_location":{"id":"doi:10.26434/chemrxiv.9874454","doi":"https://doi.org/10.26434/chemrxiv.9874454","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.9874454","pdf_url":null,"source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},"volume":null,"type":"preprint","indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://doi.org/10.26434/chemrxiv.9874454","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5041989549","display_name":"Autumn R. Flynn","orcid":"https://orcid.org/0000-0003-2504-2365","observed_orcids":["https://orcid.org/0000-0003-2504-2365"]},"institutions":[{"id":"https://openalex.org/I150468666","display_name":"Emory University","ror":"https://ror.org/03czfpz43","country_code":"US","type":"education","lineage":["https://openalex.org/I150468666"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Autumn Flynn","raw_affiliation_strings":["Emory University"],"raw_orcid":"https://orcid.org/0000-0003-2504-2365","affiliations":[{"raw_affiliation_string":"Emory University","institution_ids":["https://openalex.org/I150468666"]}]},{"author_position":"middle","author":{"id":null,"display_name":"Kelly McDaniel","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Kelly McDaniel","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5110209411","display_name":"Meredith Hughes","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Meredith Hughes","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5027313768","display_name":"David B. Vogt","orcid":"https://orcid.org/0000-0002-2694-809X","observed_orcids":["https://orcid.org/0000-0002-2694-809X"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"David Vogt","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5037444457","display_name":"Nathan T. Jui","orcid":"https://orcid.org/0000-0001-5315-0270","observed_orcids":["https://orcid.org/0000-0001-5315-0270"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Nathan Jui","raw_affiliation_strings":[],"raw_orcid":"https://orcid.org/0000-0001-5315-0270","affiliations":[]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":null,"has_fulltext":false,"cited_by_count":2,"citation_normalized_percentile":null,"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10701","display_name":"Radical Photochemical Reactions","score":1.0,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10701","display_name":"Radical Photochemical Reactions","score":1.0,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10548","display_name":"Catalytic Cross-Coupling Reactions","score":0.0,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10078","display_name":"Advanced Photocatalysis Techniques","score":0.0,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/photocatalysis","display_name":"photocatalysis","score":0.9259999990463257},{"id":"https://openalex.org/keywords/benzene-derivatives","display_name":"benzene derivatives","score":0.8999999761581421},{"id":"https://openalex.org/keywords/aryl-halide-reduction","display_name":"aryl halide reduction","score":0.8640000224113464},{"id":"https://openalex.org/keywords/regioselective-cyclization","display_name":"regioselective cyclization","score":0.8339999914169312},{"id":"https://openalex.org/keywords/photoredox-catalysis","display_name":"photoredox catalysis","score":0.8109999895095825},{"id":"https://openalex.org/keywords/metal-free-catalysis","display_name":"metal-free catalysis","score":0.6110000014305115},{"id":"https://openalex.org/keywords/green-solvents","display_name":"green solvents","score":0.597000002861023}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7333811521530151},{"id":"https://openalex.org/C40875361","wikidata":"https://www.wikidata.org/wiki/Q2356542","display_name":"Reagent","level":2,"score":0.7049248218536377},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.6877496242523193},{"id":"https://openalex.org/C2777691172","wikidata":"https://www.wikidata.org/wiki/Q2270","display_name":"Benzene","level":2,"score":0.5775290727615356},{"id":"https://openalex.org/C65165184","wikidata":"https://www.wikidata.org/wiki/Q218831","display_name":"Photocatalysis","level":3,"score":0.5762380957603455},{"id":"https://openalex.org/C2781076698","wikidata":"https://www.wikidata.org/wiki/Q718074","display_name":"Aryl","level":3,"score":0.5391232371330261},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.5339818000793457},{"id":"https://openalex.org/C171560689","wikidata":"https://www.wikidata.org/wiki/Q193086","display_name":"Halide","level":2,"score":0.5290642976760864},{"id":"https://openalex.org/C144082473","wikidata":"https://www.wikidata.org/wiki/Q213185","display_name":"Stoichiometry","level":2,"score":0.5135514736175537},{"id":"https://openalex.org/C59759590","wikidata":"https://www.wikidata.org/wiki/Q2275927","display_name":"Regioselectivity","level":3,"score":0.49060121178627014},{"id":"https://openalex.org/C131779359","wikidata":"https://www.wikidata.org/wiki/Q471875","display_name":"Amine gas treating","level":2,"score":0.48150214552879333},{"id":"https://openalex.org/C2780471494","wikidata":"https://www.wikidata.org/wiki/Q146505","display_name":"Solvent","level":2,"score":0.44859635829925537},{"id":"https://openalex.org/C45849291","wikidata":"https://www.wikidata.org/wiki/Q17166058","display_name":"Photoredox catalysis","level":4,"score":0.4351489245891571},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.3923134207725525},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.3623650074005127},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.1478651463985443}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.26434/chemrxiv.9874454","doi":"https://doi.org/10.26434/chemrxiv.9874454","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.9874454","pdf_url":null,"source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"}],"best_oa_location":{"id":"doi:10.26434/chemrxiv.9874454","doi":"https://doi.org/10.26434/chemrxiv.9874454","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.9874454","pdf_url":null,"source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W3022725963","https://openalex.org/W3168356744","https://openalex.org/W3178971503","https://openalex.org/W4403500170","https://openalex.org/W3129292244","https://openalex.org/W3151302678","https://openalex.org/W4396901581","https://openalex.org/W4406134178","https://openalex.org/W3123058883","https://openalex.org/W3028500395"],"abstract_inverted_index":{"A":[0],"photocatalytic":[1],"system":[2,63],"for":[3,69],"the":[4,67,76],"dearomative":[5],"hydroarylation":[6],"of":[7,16,48,78],"benzene":[8],"derivatives":[9],"has":[10],"been":[11],"developed.":[12],"Using":[13],"a":[14,29,39,46,60],"combination":[15],"an":[17,22],"organic":[18],"photoredox":[19],"catalyst":[20],"and":[21],"amine":[23],"reductant,":[24],"this":[25],"process":[26],"operates":[27],"through":[28],"reductive":[30],"radical-polar":[31],"crossover":[32],"mechanism":[33],"where":[34],"aryl":[35],"halide":[36],"reduction":[37],"triggers":[38],"regioselective":[40],"cyclization":[41],"event,":[42],"giving":[43],"rise":[44],"to":[45],"range":[47],"complex":[49],"spirocyclic":[50],"cyclohexadienes.":[51],"This":[52],"light-driven":[53],"protocol":[54],"functions":[55],"at":[56],"room":[57],"temperature":[58],"in":[59],"green":[61],"solvent":[62],"(aq.":[64],"MeCN),":[65],"without":[66],"need":[68],"precious":[70],"metal-based":[71],"catalysts":[72],"or":[73,75],"reagents,":[74],"generation":[77],"stoichiometric":[79],"metal":[80],"byproducts.":[81]},"counts_by_year":[{"year":2020,"cited_by_count":2}],"updated_date":"2026-09-29T14:09:16.559479","created_date":"2022-05-12T00:00:00"}