{"id":"https://openalex.org/W4242729263","doi":"https://doi.org/10.26434/chemrxiv.13489608","title":"Superphanes: Old Yet New Binding\u2013Agents for Highly Selective Recognition of Fluoride by Size\u2013Sieving Effect","display_name":"Superphanes: Old Yet New Binding\u2013Agents for Highly Selective Recognition of Fluoride by Size\u2013Sieving Effect","publication_year":2020,"publication_date":"2020-12-28","ids":{"openalex":"https://openalex.org/W4242729263","doi":"https://doi.org/10.26434/chemrxiv.13489608"},"language":"en","primary_location":{"id":"doi:10.26434/chemrxiv.13489608","doi":"https://doi.org/10.26434/chemrxiv.13489608","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.13489608","pdf_url":null,"source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},"volume":null,"type":"preprint","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://doi.org/10.26434/chemrxiv.13489608","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5090090558","display_name":"Qing Guo He","orcid":"https://orcid.org/0000-0003-3117-9587","observed_orcids":["https://orcid.org/0000-0003-3117-9587","https://orcid.org/0009-0009-2675-3661","https://orcid.org/0000-0001-7402-1865"]},"institutions":[{"id":"https://openalex.org/I16609230","display_name":"Hunan University","ror":"https://ror.org/05htk5m33","country_code":"CN","type":"education","lineage":["https://openalex.org/I16609230"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Qing He","raw_affiliation_strings":["Hunan University"],"raw_orcid":"https://orcid.org/0000-0003-3117-9587","affiliations":[{"raw_affiliation_string":"Hunan University","institution_ids":["https://openalex.org/I16609230"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100382830","display_name":"Ai\u2010Min Li","orcid":"https://orcid.org/0000-0001-7233-362X","observed_orcids":["https://orcid.org/0000-0001-7233-362X"]},"institutions":[{"id":"https://openalex.org/I16609230","display_name":"Hunan University","ror":"https://ror.org/05htk5m33","country_code":"CN","type":"education","lineage":["https://openalex.org/I16609230"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Aimin Li","raw_affiliation_strings":["State Key Laboratory of Chemo/Biosensing and Chemometrics, Advanced Catalytic Engineer Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, P. R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"State Key Laboratory of Chemo/Biosensing and Chemometrics, Advanced Catalytic Engineer Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, P. R. China","institution_ids":["https://openalex.org/I16609230"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5103253021","display_name":"Shenglun Xiong","orcid":"https://orcid.org/0000-0002-6016-4352","observed_orcids":["https://orcid.org/0000-0002-6016-4352"]},"institutions":[{"id":"https://openalex.org/I16609230","display_name":"Hunan University","ror":"https://ror.org/05htk5m33","country_code":"CN","type":"education","lineage":["https://openalex.org/I16609230"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Shenglun Xiong","raw_affiliation_strings":["State Key Laboratory of Chemo/Biosensing and Chemometrics, Advanced Catalytic Engineer Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, P. R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"State Key Laboratory of Chemo/Biosensing and Chemometrics, Advanced Catalytic Engineer Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, P. R. China","institution_ids":["https://openalex.org/I16609230"]}]},{"author_position":"middle","author":{"id":null,"display_name":"Wei Zhou","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I16609230","display_name":"Hunan University","ror":"https://ror.org/05htk5m33","country_code":"CN","type":"education","lineage":["https://openalex.org/I16609230"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Wei Zhou","raw_affiliation_strings":["State Key Laboratory of Chemo/Biosensing and Chemometrics, Advanced Catalytic Engineer Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, P. R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"State Key Laboratory of Chemo/Biosensing and Chemometrics, Advanced Catalytic Engineer Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, P. R. China","institution_ids":["https://openalex.org/I16609230"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5110222176","display_name":"Huijuan Zhai","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I16609230","display_name":"Hunan University","ror":"https://ror.org/05htk5m33","country_code":"CN","type":"education","lineage":["https://openalex.org/I16609230"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Huijuan Zhai","raw_affiliation_strings":["State Key Laboratory of Chemo/Biosensing and Chemometrics, Advanced Catalytic Engineer Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, P. R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"State Key Laboratory of Chemo/Biosensing and Chemometrics, Advanced Catalytic Engineer Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, P. R. China","institution_ids":["https://openalex.org/I16609230"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5085510375","display_name":"Yuanchu Liu","orcid":"https://orcid.org/0009-0004-0183-0652","observed_orcids":["https://orcid.org/0009-0004-0183-0652"]},"institutions":[{"id":"https://openalex.org/I16609230","display_name":"Hunan University","ror":"https://ror.org/05htk5m33","country_code":"CN","type":"education","lineage":["https://openalex.org/I16609230"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yuanchu Liu","raw_affiliation_strings":["State Key Laboratory of Chemo/Biosensing and Chemometrics, Advanced Catalytic Engineer Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, P. R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"State Key Laboratory of Chemo/Biosensing and Chemometrics, Advanced Catalytic Engineer Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, P. R. China","institution_ids":["https://openalex.org/I16609230"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I16609230"],"apc_list":null,"apc_paid":null,"fwci":null,"has_fulltext":false,"cited_by_count":1,"citation_normalized_percentile":null,"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10578","display_name":"Supramolecular Chemistry and Complexes","score":0.9442999958992004,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10578","display_name":"Supramolecular Chemistry and Complexes","score":0.9442999958992004,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10532","display_name":"Molecular Sensors and Ion Detection","score":0.04769999906420708,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10798","display_name":"Crystallography and molecular interactions","score":0.0010000000474974513,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/host-guest-chemistry","display_name":"host-guest chemistry","score":0.9660000205039978},{"id":"https://openalex.org/keywords/fluoride-recognition","display_name":"fluoride recognition","score":0.8450000286102295},{"id":"https://openalex.org/keywords/anion-recognition","display_name":"anion recognition","score":0.7070000171661377},{"id":"https://openalex.org/keywords/supramolecular-hosts","display_name":"supramolecular hosts","score":0.7379999756813049},{"id":"https://openalex.org/keywords/anion-selectivity","display_name":"anion selectivity","score":0.7200000286102295},{"id":"https://openalex.org/keywords/hydrogen-bond-donors","display_name":"hydrogen bond donors","score":0.7099999785423279},{"id":"https://openalex.org/keywords/inner-cavity","display_name":"inner cavity","score":0.460999995470047}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6049396395683289},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.4277057647705078},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.3339809775352478}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.26434/chemrxiv.13489608","doi":"https://doi.org/10.26434/chemrxiv.13489608","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.13489608","pdf_url":null,"source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"}],"best_oa_location":{"id":"doi:10.26434/chemrxiv.13489608","doi":"https://doi.org/10.26434/chemrxiv.13489608","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.13489608","pdf_url":null,"source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G1449795024","display_name":"\u975e\u7ecf\u5178\u8d85\u5206\u5b50\u4f53\u7cfb\uff1a\u65b0\u578b\u5206\u5b50\u76d1\u72f1\u53ca\u5176\u79bb\u5b50\u5305\u5408\u7269\u7684\u5408\u6210\u3001\u6027\u80fd\u53ca\u5e94\u7528\u7814\u7a76","funder_award_id":"22071050","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"},{"id":"https://openalex.org/G7008900109","display_name":null,"funder_award_id":"21901069","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"}],"funders":[{"id":"https://openalex.org/F4320321001","display_name":"National Natural Science Foundation of China","ror":"https://ror.org/01h0zpd94"},{"id":"https://openalex.org/F4320335787","display_name":"Fundamental Research Funds for the Central Universities","ror":null}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":3,"referenced_works":["https://openalex.org/W2612623348","https://openalex.org/W3043267271","https://openalex.org/W4249814346"],"related_works":["https://openalex.org/W4226400149","https://openalex.org/W3037618287","https://openalex.org/W7203478223","https://openalex.org/W2337821452","https://openalex.org/W2103892722","https://openalex.org/W1992445909","https://openalex.org/W3011399725","https://openalex.org/W2043761886","https://openalex.org/W2988692155","https://openalex.org/W1989446224"],"abstract_inverted_index":{"Superphanes,":[0],"namely":[1],"percyclophanes,":[2],"have":[3],"been":[4],"widely":[5],"investigated":[6],"for":[7,120,128],"the":[8,27,41,82,111],"sake":[9],"of":[10,30,48,124,130],"their":[11],"aesthetically":[12],"pleasing":[13],"structures":[14],"with":[15,132],"high":[16,133],"symmetry,":[17],"intriguing":[18],"physical":[19],"and":[20,23,45,63,107,122],"chemical":[21],"properties":[22],"synthetic":[24],"challenges.":[25],"Nonetheless,":[26],"host\u2013guest":[28,46],"chemistry":[29,47],"superphanes":[31],"remains":[32],"to":[33,75,92,110],"be":[34],"an":[35,49],"unmet":[36],"challenge.":[37],"Herein,":[38],"we":[39],"delineate":[40],"design,":[42],"preparation,":[43],"characterization,":[44],"unprecedented":[50],"superphane":[51],"15,":[52],"which":[53],"was":[54],"evidenced":[55],"by":[56],"mass":[57],"spectroscopy,":[58,60],"NMR":[59],"X\u2013ray":[61],"crystallography,":[62],"DFT":[64],"calculations.":[65],"15":[66,91],"features":[67],"six":[68],"bridges":[69],"between":[70],"two":[71],"benzene":[72],"planes,":[73],"up":[74,117],"18":[76],"Csp\u2013H":[77],"hydrogen\u2013bonding":[78],"donors":[79],"well\u2013distributed":[80],"around":[81],"near\u2013closed":[83],"inner":[84],"cavity":[85],"in":[86],"three":[87],"dimensions.":[88],"These":[89],"allow":[90],"exhibit":[93],"exclusive":[94],"selectivity":[95],"towards":[96],"F\u2013":[97],"against":[98],"Cl\u2013,":[99],"Br\u2013,":[100],"I\u2013,":[101],"N3\u2013,":[102],"SCN\u2013,":[103],"NO3\u2013,":[104],"ClO4\u2013,":[105],"SO42\u2013":[106],"HP2O73\u2013":[108],"due":[109],"size\u2013sieving":[112],"effect.":[113],"This":[114],"contribution":[115],"opens":[116],"new":[118,125],"opportunities":[119],"design":[121],"synthesis":[123],"supramolecular":[126],"hosts":[127],"anions":[129],"interest":[131],"selectivity.":[134]},"counts_by_year":[{"year":2022,"cited_by_count":1}],"updated_date":"2026-11-09T13:22:03.289127","created_date":"2022-05-12T00:00:00"}
