{"id":"https://openalex.org/W4237933642","doi":"https://doi.org/10.1021/bk-1995-0612.ch003","title":"Sulfur Transformations in Early Diagenetic Sediments from the Bay of Conception, Off Chile","display_name":"Sulfur Transformations in Early Diagenetic Sediments from the Bay of Conception, Off Chile","publication_year":1995,"publication_date":"1995-05-05","ids":{"openalex":"https://openalex.org/W4237933642","doi":"https://doi.org/10.1021/bk-1995-0612.ch003"},"language":"en","primary_location":{"id":"doi:10.1021/bk-1995-0612.ch003","doi":"https://doi.org/10.1021/bk-1995-0612.ch003","is_oa":false,"landing_page_url":"https://doi.org/10.1021/bk-1995-0612.ch003","pdf_url":null,"source":{"id":"https://openalex.org/S205053445","display_name":"ACS symposium series","issn_l":"0097-6156","issn":["0097-6156","1947-5918"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-1","norway-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"book series"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Symposium Series","raw_type":"book-chapter"},"volume":{"id":"https://openalex.org/W2196488394","display_name":"Geochemical Transformations of Sedimentary Sulfur"},"type":"conference-paper","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5044413592","display_name":"Murthy A. Vairavamurthy","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I200870766","display_name":"Brookhaven National Laboratory","ror":"https://ror.org/02ex6cf31","country_code":"US","type":"facility","lineage":["https://openalex.org/I1330989302","https://openalex.org/I200870766","https://openalex.org/I39565521","https://openalex.org/I4210142672"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Murthy A. Vairavamurthy","raw_affiliation_strings":["Department of Applied Science, Geochemistry Program, Applied Physical Sciences Division, Brookhaven National Laboratory, Upton, NY 11973"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Applied Science, Geochemistry Program, Applied Physical Sciences Division, Brookhaven National Laboratory, Upton, NY 11973","institution_ids":["https://openalex.org/I200870766"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5017601344","display_name":"Shengke Wang","orcid":"https://orcid.org/0000-0002-4906-8773","observed_orcids":["https://orcid.org/0000-0002-4906-8773"]},"institutions":[{"id":"https://openalex.org/I200870766","display_name":"Brookhaven National Laboratory","ror":"https://ror.org/02ex6cf31","country_code":"US","type":"facility","lineage":["https://openalex.org/I1330989302","https://openalex.org/I200870766","https://openalex.org/I39565521","https://openalex.org/I4210142672"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Shengke Wang","raw_affiliation_strings":["Department of Applied Science, Geochemistry Program, Applied Physical Sciences Division, Brookhaven National Laboratory, Upton, NY 11973"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Applied Science, Geochemistry Program, Applied Physical Sciences Division, Brookhaven National Laboratory, Upton, NY 11973","institution_ids":["https://openalex.org/I200870766"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5084606822","display_name":"Bandana Khandelwal","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I200870766","display_name":"Brookhaven National Laboratory","ror":"https://ror.org/02ex6cf31","country_code":"US","type":"facility","lineage":["https://openalex.org/I1330989302","https://openalex.org/I200870766","https://openalex.org/I39565521","https://openalex.org/I4210142672"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Bandana Khandelwal","raw_affiliation_strings":["Department of Applied Science, Geochemistry Program, Applied Physical Sciences Division, Brookhaven National Laboratory, Upton, NY 11973"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Applied Science, Geochemistry Program, Applied Physical Sciences Division, Brookhaven National Laboratory, Upton, NY 11973","institution_ids":["https://openalex.org/I200870766"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5083416812","display_name":"B. Manowitz","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I200870766","display_name":"Brookhaven National Laboratory","ror":"https://ror.org/02ex6cf31","country_code":"US","type":"facility","lineage":["https://openalex.org/I1330989302","https://openalex.org/I200870766","https://openalex.org/I39565521","https://openalex.org/I4210142672"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Bernard Manowitz","raw_affiliation_strings":["Department of Applied Science, Geochemistry Program, Applied Physical Sciences Division, Brookhaven National Laboratory, Upton, NY 11973"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Applied Science, Geochemistry Program, Applied Physical Sciences Division, Brookhaven National Laboratory, Upton, NY 11973","institution_ids":["https://openalex.org/I200870766"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5077445912","display_name":"Timothy G. Ferdelman","orcid":"https://orcid.org/0000-0002-9701-3793","observed_orcids":["https://orcid.org/0000-0002-9701-3793"]},"institutions":[{"id":"https://openalex.org/I4210103014","display_name":"Max Planck Institute for Marine Microbiology","ror":"https://ror.org/02385fa51","country_code":"DE","type":"facility","lineage":["https://openalex.org/I149899117","https://openalex.org/I4210103014"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Timothy Ferdelman","raw_affiliation_strings":["Department of Biogeochemistry, Max Planck Institute for Marine Microbiology, Fahrenheitstrasse 1, W-28359 Bremen, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Biogeochemistry, Max Planck Institute for Marine Microbiology, Fahrenheitstrasse 1, W-28359 Bremen, Germany","institution_ids":["https://openalex.org/I4210103014"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5032699853","display_name":"Henrik Fossing","orcid":"https://orcid.org/0000-0001-5193-176X","observed_orcids":["https://orcid.org/0000-0001-5193-176X"]},"institutions":[{"id":"https://openalex.org/I4210103014","display_name":"Max Planck Institute for Marine Microbiology","ror":"https://ror.org/02385fa51","country_code":"DE","type":"facility","lineage":["https://openalex.org/I149899117","https://openalex.org/I4210103014"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Henrik Fossing","raw_affiliation_strings":["Department of Biogeochemistry, Max Planck Institute for Marine Microbiology, Fahrenheitstrasse 1, W-28359 Bremen, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Biogeochemistry, Max Planck Institute for Marine Microbiology, Fahrenheitstrasse 1, W-28359 Bremen, Germany","institution_ids":["https://openalex.org/I4210103014"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":2,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":5.9302,"has_fulltext":false,"cited_by_count":21,"citation_normalized_percentile":{"value":0.97619048,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":87,"max":97},"biblio":{"volume":null,"issue":null,"first_page":"38","last_page":"58"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10109","display_name":"Paleontology and Stratigraphy of Fossils","score":0.9101999998092651,"subfield":{"id":"https://openalex.org/subfields/1911","display_name":"Paleontology"},"field":{"id":"https://openalex.org/fields/19","display_name":"Earth and Planetary Sciences"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10109","display_name":"Paleontology and Stratigraphy of Fossils","score":0.9101999998092651,"subfield":{"id":"https://openalex.org/subfields/1911","display_name":"Paleontology"},"field":{"id":"https://openalex.org/fields/19","display_name":"Earth and Planetary Sciences"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11740","display_name":"Geochemistry and Elemental Analysis","score":0.053199999034404755,"subfield":{"id":"https://openalex.org/subfields/1906","display_name":"Geochemistry and Petrology"},"field":{"id":"https://openalex.org/fields/19","display_name":"Earth and Planetary Sciences"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10995","display_name":"Methane Hydrates and Related Phenomena","score":0.022099999710917473,"subfield":{"id":"https://openalex.org/subfields/2304","display_name":"Environmental Chemistry"},"field":{"id":"https://openalex.org/fields/23","display_name":"Environmental Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/early-diagenesis","display_name":"early diagenesis","score":0.9010000228881836},{"id":"https://openalex.org/keywords/organosulfur-compounds","display_name":"organosulfur compounds","score":0.7940000295639038},{"id":"https://openalex.org/keywords/polysulfides","display_name":"polysulfides","score":0.7570000290870667},{"id":"https://openalex.org/keywords/sulfonates","display_name":"sulfonates","score":0.9769999980926514},{"id":"https://openalex.org/keywords/pyrite-formation","display_name":"pyrite formation","score":0.7870000004768372},{"id":"https://openalex.org/keywords/hydrogen-sulfide-oxidation","display_name":"hydrogen sulfide oxidation","score":0.8550000190734863},{"id":"https://openalex.org/keywords/bacterial-sulfate-reduction","display_name":"bacterial sulfate reduction","score":0.8489999771118164},{"id":"https://openalex.org/keywords/iron-monosulfide","display_name":"iron monosulfide","score":0.8529999852180481},{"id":"https://openalex.org/keywords/oxic-anoxic-interface","display_name":"oxic-anoxic interface","score":0.8289999961853027},{"id":"https://openalex.org/keywords/organic-rich-sediments","display_name":"organic-rich sediments","score":0.7990000247955322},{"id":"https://openalex.org/keywords/sulfur-speciation","display_name":"sulfur speciation","score":0.8949999809265137}],"concepts":[{"id":"https://openalex.org/C518881349","wikidata":"https://www.wikidata.org/wiki/Q682","display_name":"Sulfur","level":2,"score":0.8648020029067993},{"id":"https://openalex.org/C2776062231","wikidata":"https://www.wikidata.org/wiki/Q50769","display_name":"Pyrite","level":2,"score":0.8501445055007935},{"id":"https://openalex.org/C130452526","wikidata":"https://www.wikidata.org/wiki/Q180621","display_name":"Diagenesis","level":2,"score":0.8074229955673218},{"id":"https://openalex.org/C74826761","wikidata":"https://www.wikidata.org/wiki/Q1361502","display_name":"Sulfur cycle","level":3,"score":0.7110926508903503},{"id":"https://openalex.org/C48743137","wikidata":"https://www.wikidata.org/wiki/Q1783121","display_name":"Organic matter","level":2,"score":0.6897400617599487},{"id":"https://openalex.org/C2781090017","wikidata":"https://www.wikidata.org/wiki/Q410739","display_name":"Thiosulfate","level":3,"score":0.6753565669059753},{"id":"https://openalex.org/C2778343803","wikidata":"https://www.wikidata.org/wiki/Q172290","display_name":"Sulfate","level":2,"score":0.6687458753585815},{"id":"https://openalex.org/C2780596425","wikidata":"https://www.wikidata.org/wiki/Q221205","display_name":"Sulfide","level":2,"score":0.6246880292892456},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5765824913978577},{"id":"https://openalex.org/C108970007","wikidata":"https://www.wikidata.org/wiki/Q568324","display_name":"Anoxic waters","level":2,"score":0.5594228506088257},{"id":"https://openalex.org/C107872376","wikidata":"https://www.wikidata.org/wiki/Q321355","display_name":"Environmental chemistry","level":1,"score":0.5360648036003113},{"id":"https://openalex.org/C2816523","wikidata":"https://www.wikidata.org/wiki/Q180184","display_name":"Sediment","level":2,"score":0.5270348191261292},{"id":"https://openalex.org/C115880899","wikidata":"https://www.wikidata.org/wiki/Q1124247","display_name":"Bay","level":2,"score":0.49712303280830383},{"id":"https://openalex.org/C127313418","wikidata":"https://www.wikidata.org/wiki/Q1069","display_name":"Geology","level":0,"score":0.37686365842819214},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.32398784160614014},{"id":"https://openalex.org/C199289684","wikidata":"https://www.wikidata.org/wiki/Q83353","display_name":"Mineralogy","level":1,"score":0.25669604539871216},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.1773594617843628},{"id":"https://openalex.org/C111368507","wikidata":"https://www.wikidata.org/wiki/Q43518","display_name":"Oceanography","level":1,"score":0.12630954384803772},{"id":"https://openalex.org/C151730666","wikidata":"https://www.wikidata.org/wiki/Q7205","display_name":"Paleontology","level":1,"score":0.09373298287391663}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1021/bk-1995-0612.ch003","doi":"https://doi.org/10.1021/bk-1995-0612.ch003","is_oa":false,"landing_page_url":"https://doi.org/10.1021/bk-1995-0612.ch003","pdf_url":null,"source":{"id":"https://openalex.org/S205053445","display_name":"ACS symposium series","issn_l":"0097-6156","issn":["0097-6156","1947-5918"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-1","norway-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"book series"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Symposium Series","raw_type":"book-chapter"},{"id":"pmh:oai:pure.mpg.de:item_3154403","doi":null,"is_oa":false,"landing_page_url":"http://hdl.handle.net/21.11116/0000-0004-9B4E-7","pdf_url":null,"source":{"id":"https://openalex.org/S4306400654","display_name":"MPG.PuRe (Max Planck Society)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I149899117","host_organization_name":"Max Planck Society","host_organization_lineage":["https://openalex.org/I149899117"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Geochemical transformations of sedimentary sulfur","raw_type":"info:eu-repo/semantics/conferenceObject"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320306084","display_name":"U.S. Department of Energy","ror":"https://ror.org/01bj3aw27"},{"id":"https://openalex.org/F4320323717","display_name":"Universidad de Concepci\u00f3n","ror":"https://ror.org/0460jpj73"},{"id":"https://openalex.org/F4320337480","display_name":"Basic Energy Sciences","ror":"https://ror.org/05mg91w61"},{"id":"https://openalex.org/F4320338289","display_name":"Brookhaven National Laboratory","ror":"https://ror.org/02ex6cf31"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W7043484268","https://openalex.org/W2502877913","https://openalex.org/W2061159791","https://openalex.org/W2012709420","https://openalex.org/W3034949443","https://openalex.org/W2105853832","https://openalex.org/W590011687","https://openalex.org/W7096455997","https://openalex.org/W1975466317","https://openalex.org/W2379954135"],"abstract_inverted_index":{"Despite":[0],"the":[1,11,19,34,37,50,60,80,84,92,96,104,129,141,144,182,190,228,233],"recognition":[2],"that":[3,18,161,208],"both":[4],"organic":[5,97,155,176,196,225],"sulfur":[6,54,77,174],"and":[7,17,36,99,133,157,159,185,221],"pyrite":[8,231],"form":[9],"during":[10],"very":[12],"early":[13],"stages":[14],"of":[15,21,53,86,95,131,143,230],"diagenesis,":[16],"amount":[20],"H":[22,112,164,191,218],"2":[23,113,165,192,219],"S":[24,114,166,193],"generated":[25,120],"in":[26,56,64,79,140,172,181,201,232],"bacterial":[27],"sulfate":[28],"reduction":[29],"primarily":[30],"limits":[31],"their":[32],"formation,":[33],"mechanisms":[35,62],"active":[38],"species":[39],"involved":[40,63],"still":[41],"are":[42],"not":[43],"clear.":[44],"In":[45],"this":[46],"study,":[47],"we":[48,206],"quantified":[49],"major":[51,93],"forms":[52],"distributed":[55],"sediments":[57,82],"to":[58,75,118,199],"assess":[59],"geochemical":[61,152],"these":[65,204],"transformations.":[66],"XANES":[67],"spectroscopy,":[68],"together":[69],"with":[70,217,224],"elemental":[71],"analysis,":[72],"were":[73,116],"used":[74],"measure":[76],"speciation":[78],"organic-rich":[81],"from":[83,111,163,215],"Bay":[85],"Concepcion,":[87],"Chile.":[88],"Organic":[89],"polysulfides":[90,156,197],"constituted":[91],"fraction":[94],"sulfur,":[98],"occurred":[100],"maximally":[101],"just":[102,188],"below":[103,189],"sediment":[105,234],"surface":[106],"(1-3":[107],"cm),":[108],"where":[109,195],"intermediates":[110,162],"oxidation":[115,167],"likely":[117],"be":[119,126],"most":[121],"abundantly.":[122],"Sulfonates,":[123],"which":[124],"could":[125],"formed":[127,213],"through":[128],"reactions":[130,216],"sulfite":[132],"thiosulfate,":[134],"also":[135],"showed":[136],"a":[137,151,169],"sub-surface":[138],"maximum":[139],"vicinity":[142],"\"oxic-anoxic":[145],"interface\".":[146],"These":[147],"results":[148],"strongly":[149],"suggest":[150],"origin":[153],"for":[154],"sulfonates,":[158],"illustrate":[160],"play":[168],"dominant":[170],"role":[171],"incorporating":[173],"into":[175],"matter.":[177],"Pyrite":[178],"was":[179],"absent":[180],"surficial":[183],"layer,":[184],"first":[186,214],"appeared":[187],"maximum,":[194],"began":[198],"decrease":[200],"abundance.":[202],"From":[203],"results,":[205],"argue,":[207],"an":[209],"iron":[210],"monosulfide":[211],"precursor":[212],"S,":[220],"then":[222],"reacts":[223],"polysulfides,":[226],"completing":[227],"synthesis":[229],"column.":[235]},"counts_by_year":[{"year":2024,"cited_by_count":1},{"year":2021,"cited_by_count":1},{"year":2018,"cited_by_count":1},{"year":2014,"cited_by_count":2},{"year":2013,"cited_by_count":4}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2022-05-12T00:00:00"}