{"id":"https://openalex.org/W4237757252","doi":"https://doi.org/10.1002/ange.201809889","title":"Nickel as a Lewis Base in a T\u2010Shaped Nickel(0) Germylene Complex Incorporating a Flexible Bis(NHC) Ligand","display_name":"Nickel as a Lewis Base in a T\u2010Shaped Nickel(0) Germylene Complex Incorporating a Flexible Bis(NHC) Ligand","publication_year":2018,"publication_date":"2018-11-08","ids":{"openalex":"https://openalex.org/W4237757252","doi":"https://doi.org/10.1002/ange.201809889"},"language":"en","primary_location":{"id":"doi:10.1002/ange.201809889","doi":"https://doi.org/10.1002/ange.201809889","is_oa":false,"landing_page_url":"https://doi.org/10.1002/ange.201809889","pdf_url":null,"source":{"id":"https://openalex.org/S4210200754","display_name":"Angewandte Chemie","issn_l":"0044-8249","issn":["0044-8249","0932-2140","1521-3757"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5000991757","display_name":"Chris Gendy","orcid":"https://orcid.org/0000-0002-3448-0941","observed_orcids":["https://orcid.org/0000-0002-3448-0941"]},"institutions":[{"id":"https://openalex.org/I168635309","display_name":"University of Calgary","ror":"https://ror.org/03yjb2x39","country_code":"CA","type":"education","lineage":["https://openalex.org/I168635309"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"Chris Gendy","raw_affiliation_strings":["Department of Chemistry, University of Calgary, 2500 University Drive NW, Calgary, AB, T2N 1N4 Canada"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Calgary, 2500 University Drive NW, Calgary, AB, T2N 1N4 Canada","institution_ids":["https://openalex.org/I168635309"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5077138082","display_name":"Akseli Mansikkam\u00e4ki","orcid":"https://orcid.org/0000-0003-0401-4373","observed_orcids":["https://orcid.org/0000-0003-0401-4373"]},"institutions":[{"id":"https://openalex.org/I94722563","display_name":"University of Jyv\u00e4skyl\u00e4","ror":"https://ror.org/05n3dz165","country_code":"FI","type":"education","lineage":["https://openalex.org/I94722563"]}],"countries":["FI"],"is_corresponding":false,"raw_author_name":"Akseli Mansikkam\u00e4ki","raw_affiliation_strings":["Department of Chemistry Nanoscience Centre University of Jyv\u00e4skyl\u00e4  40014 University of Jyv\u00e4skyl\u00e4 Finland"],"raw_orcid":"https://orcid.org/0000-0003-0401-4373","affiliations":[{"raw_affiliation_string":"Department of Chemistry Nanoscience Centre University of Jyv\u00e4skyl\u00e4  40014 University of Jyv\u00e4skyl\u00e4 Finland","institution_ids":["https://openalex.org/I94722563"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5012395980","display_name":"Juuso Valjus","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I94722563","display_name":"University of Jyv\u00e4skyl\u00e4","ror":"https://ror.org/05n3dz165","country_code":"FI","type":"education","lineage":["https://openalex.org/I94722563"]}],"countries":["FI"],"is_corresponding":false,"raw_author_name":"Juuso Valjus","raw_affiliation_strings":["Department of Chemistry Nanoscience Centre University of Jyv\u00e4skyl\u00e4  40014 University of Jyv\u00e4skyl\u00e4 Finland"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry Nanoscience Centre University of Jyv\u00e4skyl\u00e4  40014 University of Jyv\u00e4skyl\u00e4 Finland","institution_ids":["https://openalex.org/I94722563"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5044543170","display_name":"Joshua Heidebrecht","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I168635309","display_name":"University of Calgary","ror":"https://ror.org/03yjb2x39","country_code":"CA","type":"education","lineage":["https://openalex.org/I168635309"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"Joshua Heidebrecht","raw_affiliation_strings":["Department of Chemistry, University of Calgary, 2500 University Drive NW, Calgary, AB, T2N 1N4 Canada"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Calgary, 2500 University Drive NW, Calgary, AB, T2N 1N4 Canada","institution_ids":["https://openalex.org/I168635309"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5060498444","display_name":"Paul Chuk\u2010Yan Hui","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I168635309","display_name":"University of Calgary","ror":"https://ror.org/03yjb2x39","country_code":"CA","type":"education","lineage":["https://openalex.org/I168635309"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"Paul Chuk\u2010Yan Hui","raw_affiliation_strings":["Department of Chemistry, University of Calgary, 2500 University Drive NW, Calgary, AB, T2N 1N4 Canada"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Calgary, 2500 University Drive NW, Calgary, AB, T2N 1N4 Canada","institution_ids":["https://openalex.org/I168635309"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5071172724","display_name":"Guy M. Bernard","orcid":"https://orcid.org/0000-0003-1507-6705","observed_orcids":["https://orcid.org/0000-0003-1507-6705"]},"institutions":[{"id":"https://openalex.org/I154425047","display_name":"University of Alberta","ror":"https://ror.org/0160cpw27","country_code":"CA","type":"education","lineage":["https://openalex.org/I154425047"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"Guy M. Bernard","raw_affiliation_strings":["Gunning-Lemieux Chemistry Centre, University of Alberta, 11227 Saskatchewan Drive NW, Edmonton, AB, T6G 2G2 Canada"],"raw_orcid":"https://orcid.org/0000-0003-1507-6705","affiliations":[{"raw_affiliation_string":"Gunning-Lemieux Chemistry Centre, University of Alberta, 11227 Saskatchewan Drive NW, Edmonton, AB, T6G 2G2 Canada","institution_ids":["https://openalex.org/I154425047"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5064601612","display_name":"Heikki M. Tuononen","orcid":"https://orcid.org/0000-0002-4820-979X","observed_orcids":["https://orcid.org/0000-0002-4820-979X"]},"institutions":[{"id":"https://openalex.org/I94722563","display_name":"University of Jyv\u00e4skyl\u00e4","ror":"https://ror.org/05n3dz165","country_code":"FI","type":"education","lineage":["https://openalex.org/I94722563"]}],"countries":["FI"],"is_corresponding":false,"raw_author_name":"Heikki M. Tuononen","raw_affiliation_strings":["Department of Chemistry Nanoscience Centre University of Jyv\u00e4skyl\u00e4  40014 University of Jyv\u00e4skyl\u00e4 Finland"],"raw_orcid":"https://orcid.org/0000-0002-4820-979X","affiliations":[{"raw_affiliation_string":"Department of Chemistry Nanoscience Centre University of Jyv\u00e4skyl\u00e4  40014 University of Jyv\u00e4skyl\u00e4 Finland","institution_ids":["https://openalex.org/I94722563"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5058851361","display_name":"Roderick E. Wasylishen","orcid":"https://orcid.org/0000-0003-4150-3651","observed_orcids":["https://orcid.org/0000-0003-4150-3651"]},"institutions":[{"id":"https://openalex.org/I154425047","display_name":"University of Alberta","ror":"https://ror.org/0160cpw27","country_code":"CA","type":"education","lineage":["https://openalex.org/I154425047"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"Roderick E. Wasylishen","raw_affiliation_strings":["Gunning-Lemieux Chemistry Centre, University of Alberta, 11227 Saskatchewan Drive NW, Edmonton, AB, T6G 2G2 Canada"],"raw_orcid":"https://orcid.org/0000-0003-4150-3651","affiliations":[{"raw_affiliation_string":"Gunning-Lemieux Chemistry Centre, University of Alberta, 11227 Saskatchewan Drive NW, Edmonton, AB, T6G 2G2 Canada","institution_ids":["https://openalex.org/I154425047"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5018432146","display_name":"Vladimir K. Michaelis","orcid":"https://orcid.org/0000-0002-6708-7660","observed_orcids":["https://orcid.org/0000-0002-6708-7660"]},"institutions":[{"id":"https://openalex.org/I154425047","display_name":"University of Alberta","ror":"https://ror.org/0160cpw27","country_code":"CA","type":"education","lineage":["https://openalex.org/I154425047"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"Vladimir K. Michaelis","raw_affiliation_strings":["Gunning-Lemieux Chemistry Centre, University of Alberta, 11227 Saskatchewan Drive NW, Edmonton, AB, T6G 2G2 Canada"],"raw_orcid":"https://orcid.org/0000-0002-6708-7660","affiliations":[{"raw_affiliation_string":"Gunning-Lemieux Chemistry Centre, University of Alberta, 11227 Saskatchewan Drive NW, Edmonton, AB, T6G 2G2 Canada","institution_ids":["https://openalex.org/I154425047"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5064926015","display_name":"Roland Roesler","orcid":"https://orcid.org/0000-0002-1235-3976","observed_orcids":["https://orcid.org/0000-0002-1235-3976"]},"institutions":[{"id":"https://openalex.org/I168635309","display_name":"University of Calgary","ror":"https://ror.org/03yjb2x39","country_code":"CA","type":"education","lineage":["https://openalex.org/I168635309"]}],"countries":["CA"],"is_corresponding":true,"raw_author_name":"Roland Roesler","raw_affiliation_strings":["Department of Chemistry, University of Calgary, 2500 University Drive NW, Calgary, AB, T2N 1N4 Canada"],"raw_orcid":"https://orcid.org/0000-0002-1235-3976","affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Calgary, 2500 University Drive NW, Calgary, AB, T2N 1N4 Canada","institution_ids":["https://openalex.org/I168635309"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":3,"corresponding_author_ids":["https://openalex.org/A5064926015"],"corresponding_institution_ids":["https://openalex.org/I168635309"],"apc_list":{"value":5790,"currency":"USD","value_usd":5790},"apc_paid":null,"fwci":0.7092,"has_fulltext":false,"cited_by_count":20,"citation_normalized_percentile":{"value":0.62390272,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":87,"max":99},"biblio":{"volume":"131","issue":"1","first_page":"160","last_page":"164"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.8330000042915344,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.8330000042915344,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11790","display_name":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","score":0.09269999712705612,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.05979999899864197,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/bis-nhc-ligands","display_name":"bis-NHC ligands","score":0.8949999809265137},{"id":"https://openalex.org/keywords/sigma-donation","display_name":"sigma donation","score":0.42899999022483826},{"id":"https://openalex.org/keywords/ni-cod-2","display_name":"Ni(COD)2","score":0.5370000004768372},{"id":"https://openalex.org/keywords/computational-analysis","display_name":"computational analysis","score":0.4350000023841858}],"concepts":[{"id":"https://openalex.org/C142653250","wikidata":"https://www.wikidata.org/wiki/Q900742","display_name":"Transmetalation","level":3,"score":0.8930301666259766},{"id":"https://openalex.org/C504270822","wikidata":"https://www.wikidata.org/wiki/Q744","display_name":"Nickel","level":2,"score":0.7965434193611145},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.7483834028244019},{"id":"https://openalex.org/C2776568683","wikidata":"https://www.wikidata.org/wiki/Q23005640","display_name":"Moiety","level":2,"score":0.7092885971069336},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6871411800384521},{"id":"https://openalex.org/C163638829","wikidata":"https://www.wikidata.org/wiki/Q900337","display_name":"Lewis acids and bases","level":3,"score":0.6435150504112244},{"id":"https://openalex.org/C197404232","wikidata":"https://www.wikidata.org/wiki/Q319827","display_name":"Chelation","level":2,"score":0.5601405501365662},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.5134637951850891},{"id":"https://openalex.org/C111771559","wikidata":"https://www.wikidata.org/wiki/Q66295","display_name":"Derivative (finance)","level":2,"score":0.4429696798324585},{"id":"https://openalex.org/C68913812","wikidata":"https://www.wikidata.org/wiki/Q238156","display_name":"Coordination complex","level":3,"score":0.4425976872444153},{"id":"https://openalex.org/C514695523","wikidata":"https://www.wikidata.org/wiki/Q237200","display_name":"Organometallic chemistry","level":3,"score":0.44252756237983704},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.3939395546913147},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.37397316098213196},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.3339862823486328},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.2789815664291382},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.2376018464565277},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.15060055255889893},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.14735063910484314},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.14728102087974548},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C106159729","wikidata":"https://www.wikidata.org/wiki/Q2294553","display_name":"Financial economics","level":1,"score":0.0},{"id":"https://openalex.org/C162324750","wikidata":"https://www.wikidata.org/wiki/Q8134","display_name":"Economics","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/ange.201809889","doi":"https://doi.org/10.1002/ange.201809889","is_oa":false,"landing_page_url":"https://doi.org/10.1002/ange.201809889","pdf_url":null,"source":{"id":"https://openalex.org/S4210200754","display_name":"Angewandte Chemie","issn_l":"0044-8249","issn":["0044-8249","0932-2140","1521-3757"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G5468277992","display_name":null,"funder_award_id":"262037","funder_id":"https://openalex.org/F4320334593","funder_display_name":"Natural Sciences and Engineering Research Council of Canada"},{"id":"https://openalex.org/G6492271423","display_name":null,"funder_award_id":"05447","funder_id":"https://openalex.org/F4320334593","funder_display_name":"Natural Sciences and Engineering Research Council of Canada"}],"funders":[{"id":"https://openalex.org/F4320326644","display_name":"Canada First Research Excellence Fund","ror":"https://ror.org/01ktx4s83"},{"id":"https://openalex.org/F4320334593","display_name":"Natural Sciences and Engineering Research Council of Canada","ror":"https://ror.org/01h531d29"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":80,"referenced_works":["https://openalex.org/W1891586698","https://openalex.org/W1968710845","https://openalex.org/W1970813681","https://openalex.org/W1972279940","https://openalex.org/W1982825189","https://openalex.org/W1983134925","https://openalex.org/W1985138031","https://openalex.org/W1986295512","https://openalex.org/W1991366794","https://openalex.org/W1992602645","https://openalex.org/W1998453547","https://openalex.org/W1998537076","https://openalex.org/W2008544171","https://openalex.org/W2017859818","https://openalex.org/W2021273164","https://openalex.org/W2024323724","https://openalex.org/W2031862295","https://openalex.org/W2034836312","https://openalex.org/W2034941446","https://openalex.org/W2041488759","https://openalex.org/W2041695876","https://openalex.org/W2048110897","https://openalex.org/W2050134971","https://openalex.org/W2052073080","https://openalex.org/W2054578125","https://openalex.org/W2058484679","https://openalex.org/W2060847489","https://openalex.org/W2063815525","https://openalex.org/W2069288102","https://openalex.org/W2086581193","https://openalex.org/W2092409183","https://openalex.org/W2095561677","https://openalex.org/W2097242301","https://openalex.org/W2097787317","https://openalex.org/W2098166525","https://openalex.org/W2112938239","https://openalex.org/W2116795644","https://openalex.org/W2127507065","https://openalex.org/W2129821016","https://openalex.org/W2138306650","https://openalex.org/W2138971600","https://openalex.org/W2139160539","https://openalex.org/W2139953241","https://openalex.org/W2141669783","https://openalex.org/W2141704337","https://openalex.org/W2141858359","https://openalex.org/W2143410047","https://openalex.org/W2155939955","https://openalex.org/W2162482309","https://openalex.org/W2164409154","https://openalex.org/W2172555889","https://openalex.org/W2203103084","https://openalex.org/W2221410500","https://openalex.org/W2225827106","https://openalex.org/W2312451120","https://openalex.org/W2315495104","https://openalex.org/W2316861270","https://openalex.org/W2319627834","https://openalex.org/W2324826227","https://openalex.org/W2327415113","https://openalex.org/W2327951570","https://openalex.org/W2494280892","https://openalex.org/W2541885639","https://openalex.org/W2554568965","https://openalex.org/W2577787397","https://openalex.org/W2581594061","https://openalex.org/W2587628999","https://openalex.org/W2594380937","https://openalex.org/W2618070503","https://openalex.org/W2729344465","https://openalex.org/W2733368051","https://openalex.org/W2740445194","https://openalex.org/W2949169341","https://openalex.org/W2950135483","https://openalex.org/W2952544519","https://openalex.org/W4232586436","https://openalex.org/W4245060927","https://openalex.org/W4245906251","https://openalex.org/W4248053143","https://openalex.org/W4254168738"],"related_works":["https://openalex.org/W2969747007","https://openalex.org/W4388671661","https://openalex.org/W2971662548","https://openalex.org/W1991366794","https://openalex.org/W1983736604","https://openalex.org/W2043681213","https://openalex.org/W3134908590","https://openalex.org/W2950516189","https://openalex.org/W1807759071","https://openalex.org/W2605546208"],"abstract_inverted_index":{"Abstract":[0],"Flexible,":[1],"chelating":[2],"bis(NHC)":[3],"ligand":[4],"2,":[5],"able":[6],"to":[7,16,64,92,115,135],"accommodate":[8,109],"both":[9],"cis\u2010":[10],"and":[11,32,46,76,89,97],"trans\u2010coordination":[12],"modes,":[13],"was":[14],"used":[15],"synthesize":[17],"(2)Ni(\u03b72\u2010cod),":[18],"3.":[19],"In":[20],"reaction":[21,50],"with":[22],"GeCl2,":[23],"it":[24],"produced":[25],"(2)NiGeCl2,":[26],"4,":[27],"featuring":[28],"a":[29,33,49,110,138],"T\u2010shaped":[30],"Ni0":[31],"pyramidal":[34],"Ge":[35],"center.":[36],"Complex":[37],"4":[38,71],"could":[39],"also":[40],"be":[41],"prepared":[42],"from":[43,84],"[(2)GeCl]Cl,":[44],"5,":[45],"Ni(cod)2,":[47],"in":[48],"that":[51,70,107],"formally":[52],"involved":[53],"Ni\u2013Ge":[54,118],"transmetalation,":[55],"followed":[56],"by":[57],"coordination":[58],"of":[59,122,131],"the":[60,77,85,129,132],"extruded":[61],"GeCl2":[62],"moiety":[63],"Ni.":[65],"A":[66],"computational":[67],"analysis":[68],"showed":[69],"possesses":[72],"considerable":[73],"multiconfigurational":[74],"character":[75],"Ni\u2192Ge":[78],"bond":[79],"is":[80],"formed":[81],"through":[82],"\u03c3\u2010donation":[83],"Ni":[86],"4s,":[87],"4p,":[88],"3d":[90],"orbitals":[91],"Ge.":[93],"(NHC)2Ni(cod)":[94],"complexes":[95],"9":[96],"10,":[98],"as":[99,101,137],"well":[100],"(NHC)2GeCl2":[102],"derivative":[103],"11,":[104],"incorporating":[105],"ligands":[106],"cannot":[108],"wide":[111],"bite":[112],"angle,":[113],"failed":[114],"produce":[116],"isolable":[117],"complexes.":[119],"The":[120],"isolation":[121],"(2)Ni(\u03b72\u2010Py),":[123],"12,":[124],"provides":[125],"further":[126],"evidence":[127],"for":[128],"reluctance":[130],"(2)Ni0":[133],"fragment":[134],"act":[136],"\u03c3\u2010Lewis":[139],"acid.":[140]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2025,"cited_by_count":1},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":8},{"year":2021,"cited_by_count":2},{"year":2020,"cited_by_count":5},{"year":2019,"cited_by_count":1}],"updated_date":"2026-11-12T12:28:57.059296","created_date":"2022-05-12T00:00:00"}