{"id":"https://openalex.org/W4236850656","doi":"https://doi.org/10.26434/chemrxiv.10316819.v4","title":"The Thermodynamic Way of Assessing Reversible Metal Hydride Volume Expansion: Getting a Grip on Metal Hydride Formation Overpotential","display_name":"The Thermodynamic Way of Assessing Reversible Metal Hydride Volume Expansion: Getting a Grip on Metal Hydride Formation Overpotential","publication_year":2021,"publication_date":"2021-02-08","ids":{"openalex":"https://openalex.org/W4236850656","doi":"https://doi.org/10.26434/chemrxiv.10316819.v4"},"language":"en","primary_location":{"id":"doi:10.26434/chemrxiv.10316819.v4","doi":"https://doi.org/10.26434/chemrxiv.10316819.v4","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.10316819.v4","pdf_url":"https://chemrxiv.org/engage/api-gateway/chemrxiv/assets/orp/resource/item/60c75586702a9bbf5518c710/original/the-thermodynamic-way-of-assessing-reversible-metal-hydride-volume-expansion-getting-a-grip-on-metal-hydride-formation-overpotential.pdf","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},"volume":null,"type":"preprint","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://chemrxiv.org/engage/api-gateway/chemrxiv/assets/orp/resource/item/60c75586702a9bbf5518c710/original/the-thermodynamic-way-of-assessing-reversible-metal-hydride-volume-expansion-getting-a-grip-on-metal-hydride-formation-overpotential.pdf","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5079282866","display_name":"Roland Hermann Pawelke","orcid":"https://orcid.org/0000-0002-6944-2240","observed_orcids":["https://orcid.org/0000-0002-6944-2240"]},"institutions":[{"id":"https://openalex.org/I4210151520","display_name":"Forschungs- und Technologietransfer (Austria)","ror":"https://ror.org/04tbtbw37","country_code":"AT","type":"company","lineage":["https://openalex.org/I4210151520"]}],"countries":["AT"],"is_corresponding":true,"raw_author_name":"Roland Hermann Pawelke","raw_affiliation_strings":["FOTEC Forschungs- und Technologietransfer GmbH"],"raw_orcid":"https://orcid.org/0000-0002-6944-2240","affiliations":[{"raw_affiliation_string":"FOTEC Forschungs- und Technologietransfer GmbH","institution_ids":["https://openalex.org/I4210151520"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5079282866"],"corresponding_institution_ids":["https://openalex.org/I4210151520"],"apc_list":null,"apc_paid":null,"fwci":null,"has_fulltext":true,"cited_by_count":2,"citation_normalized_percentile":null,"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10811","display_name":"Hydrogen Storage and Materials","score":0.9984999895095825,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10811","display_name":"Hydrogen Storage and Materials","score":0.9984999895095825,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11100","display_name":"Intermetallics and Advanced Alloy Properties","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/2210","display_name":"Mechanical Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10736","display_name":"Hydrogen embrittlement and corrosion behaviors in metals","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/2506","display_name":"Metals and Alloys"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/metal-hydrides","display_name":"metal hydrides","score":0.9179999828338623},{"id":"https://openalex.org/keywords/thermodynamic-analysis","display_name":"thermodynamic analysis","score":0.7590000033378601}],"concepts":[{"id":"https://openalex.org/C2777961443","wikidata":"https://www.wikidata.org/wiki/Q106520","display_name":"Hydride","level":3,"score":0.8967572450637817},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.6447705030441284},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.6289114356040955},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.4993464946746826},{"id":"https://openalex.org/C20556612","wikidata":"https://www.wikidata.org/wiki/Q4469374","display_name":"Volume (thermodynamics)","level":2,"score":0.46728190779685974},{"id":"https://openalex.org/C186460083","wikidata":"https://www.wikidata.org/wiki/Q333853","display_name":"Overpotential","level":4,"score":0.4587029218673706},{"id":"https://openalex.org/C30342001","wikidata":"https://www.wikidata.org/wiki/Q172280","display_name":"Ideal gas","level":2,"score":0.4518654942512512},{"id":"https://openalex.org/C106301342","wikidata":"https://www.wikidata.org/wiki/Q4117933","display_name":"Entropy (arrow of time)","level":2,"score":0.4474334120750427},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.36402082443237305},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.3379175066947937},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.334320068359375},{"id":"https://openalex.org/C191897082","wikidata":"https://www.wikidata.org/wiki/Q11467","display_name":"Metallurgy","level":1,"score":0.21061721444129944},{"id":"https://openalex.org/C17525397","wikidata":"https://www.wikidata.org/wiki/Q176140","display_name":"Electrode","level":2,"score":0.062339961528778076},{"id":"https://openalex.org/C52859227","wikidata":"https://www.wikidata.org/wiki/Q7877","display_name":"Electrochemistry","level":3,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.26434/chemrxiv.10316819.v4","doi":"https://doi.org/10.26434/chemrxiv.10316819.v4","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.10316819.v4","pdf_url":"https://chemrxiv.org/engage/api-gateway/chemrxiv/assets/orp/resource/item/60c75586702a9bbf5518c710/original/the-thermodynamic-way-of-assessing-reversible-metal-hydride-volume-expansion-getting-a-grip-on-metal-hydride-formation-overpotential.pdf","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},{"id":"pmh:oai:figshare.com:article/10316819","doi":null,"is_oa":true,"landing_page_url":"https://figshare.com/articles/preprint/How_to_Assess_the_Relative_Volume_Change_of_Reversible_Metal_Hydrides_Easily_Speedily_and_Concisely_Enough_with_a_Surprising_Relevance_for_Clarifying_Thermodynamic_Tailoring_Effects/10316819","pdf_url":null,"source":{"id":"https://openalex.org/S7407051385","display_name":"Royal College of Surgeons in Ireland","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I142762351","host_organization_name":"Royal College of Surgeons in Ireland","host_organization_lineage":["https://openalex.org/I142762351"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"Text"}],"best_oa_location":{"id":"doi:10.26434/chemrxiv.10316819.v4","doi":"https://doi.org/10.26434/chemrxiv.10316819.v4","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.10316819.v4","pdf_url":"https://chemrxiv.org/engage/api-gateway/chemrxiv/assets/orp/resource/item/60c75586702a9bbf5518c710/original/the-thermodynamic-way-of-assessing-reversible-metal-hydride-volume-expansion-getting-a-grip-on-metal-hydride-formation-overpotential.pdf","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":true,"pdf":true},"content_urls":{"pdf":"https://content.openalex.org/works/W4236850656.pdf","grobid_xml":"https://content.openalex.org/works/W4236850656.grobid-xml"},"referenced_works_count":3,"referenced_works":["https://openalex.org/W2330014076","https://openalex.org/W4234666268","https://openalex.org/W4237455901"],"related_works":["https://openalex.org/W3199730568","https://openalex.org/W4249315929","https://openalex.org/W1981331292","https://openalex.org/W1994727991","https://openalex.org/W1631740167","https://openalex.org/W2054708017","https://openalex.org/W7096709464","https://openalex.org/W1997226154","https://openalex.org/W3205500634","https://openalex.org/W2169556745"],"abstract_inverted_index":{"The":[0],"relative":[1],"volume":[2],"expansion":[3],"of":[4,15,28,57],"reversible":[5],"metal":[6,38],"hydride":[7,39,50],"crystals":[8],"upon":[9],"formation":[10],"is":[11],"determined":[12],"by":[13,54],"means":[14],"the":[16,26,46,55],"van\u2019t":[17],"Hoff":[18],"reaction":[19],"entropy":[20],"and":[21],"STP":[22],"ideal":[23],"gas":[24],"parameters,":[25],"development":[27],"this":[29],"approach":[30],"leads":[31],"to":[32,49],"a":[33],"general":[34],"method":[35],"for":[36],"calculating":[37],"single-crystal":[40],"density.":[41],"These":[42],"results":[43],"allow":[44],"highlighting":[45],"pressure":[47],"requirement":[48],"phase":[51],"formation,":[52],"shown":[53],"example":[56],"Ti-NaAlH":[58],"4":[59],".":[60]},"counts_by_year":[{"year":2021,"cited_by_count":2}],"updated_date":"2026-11-09T13:22:03.289127","created_date":"2022-05-12T00:00:00"}