{"id":"https://openalex.org/W4233077445","doi":"https://doi.org/10.1002/ange.201703279","title":"Total Synthesis of Dictyodendrins by the Gold\u2010Catalyzed Cascade Cyclization of Conjugated Diynes with Pyrroles","display_name":"Total Synthesis of Dictyodendrins by the Gold\u2010Catalyzed Cascade Cyclization of Conjugated Diynes with Pyrroles","publication_year":2017,"publication_date":"2017-05-31","ids":{"openalex":"https://openalex.org/W4233077445","doi":"https://doi.org/10.1002/ange.201703279"},"language":"en","primary_location":{"id":"doi:10.1002/ange.201703279","doi":"https://doi.org/10.1002/ange.201703279","is_oa":false,"landing_page_url":"https://doi.org/10.1002/ange.201703279","pdf_url":null,"source":{"id":"https://openalex.org/S4210200754","display_name":"Angewandte Chemie","issn_l":"0044-8249","issn":["0044-8249","0932-2140","1521-3757"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5067263046","display_name":"Junpei Matsuoka","orcid":"https://orcid.org/0000-0002-2648-0853","observed_orcids":["https://orcid.org/0000-0002-2648-0853"]},"institutions":[{"id":"https://openalex.org/I22299242","display_name":"Kyoto University","ror":"https://ror.org/02kpeqv85","country_code":"JP","type":"education","lineage":["https://openalex.org/I22299242"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Junpei Matsuoka","raw_affiliation_strings":["Graduate School of Pharmaceutical Sciences, Kyoto University, Sakyo-ku, Kyoto, 606-8501 Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Graduate School of Pharmaceutical Sciences, Kyoto University, Sakyo-ku, Kyoto, 606-8501 Japan","institution_ids":["https://openalex.org/I22299242"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5109719633","display_name":"Yuka Matsuda","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I22299242","display_name":"Kyoto University","ror":"https://ror.org/02kpeqv85","country_code":"JP","type":"education","lineage":["https://openalex.org/I22299242"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Yuka Matsuda","raw_affiliation_strings":["Graduate School of Pharmaceutical Sciences, Kyoto University, Sakyo-ku, Kyoto, 606-8501 Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Graduate School of Pharmaceutical Sciences, Kyoto University, Sakyo-ku, Kyoto, 606-8501 Japan","institution_ids":["https://openalex.org/I22299242"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5061799802","display_name":"Yuiki Kawada","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I22299242","display_name":"Kyoto University","ror":"https://ror.org/02kpeqv85","country_code":"JP","type":"education","lineage":["https://openalex.org/I22299242"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Yuiki Kawada","raw_affiliation_strings":["Graduate School of Pharmaceutical Sciences, Kyoto University, Sakyo-ku, Kyoto, 606-8501 Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Graduate School of Pharmaceutical Sciences, Kyoto University, Sakyo-ku, Kyoto, 606-8501 Japan","institution_ids":["https://openalex.org/I22299242"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5033128839","display_name":"Shinya Oishi","orcid":"https://orcid.org/0000-0002-2833-2539","observed_orcids":["https://orcid.org/0000-0002-2833-2539"]},"institutions":[{"id":"https://openalex.org/I22299242","display_name":"Kyoto University","ror":"https://ror.org/02kpeqv85","country_code":"JP","type":"education","lineage":["https://openalex.org/I22299242"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Shinya Oishi","raw_affiliation_strings":["Graduate School of Pharmaceutical Sciences, Kyoto University, Sakyo-ku, Kyoto, 606-8501 Japan"],"raw_orcid":"https://orcid.org/0000-0002-2833-2539","affiliations":[{"raw_affiliation_string":"Graduate School of Pharmaceutical Sciences, Kyoto University, Sakyo-ku, Kyoto, 606-8501 Japan","institution_ids":["https://openalex.org/I22299242"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5013135912","display_name":"Hiroaki Ohno","orcid":"https://orcid.org/0000-0002-3246-4809","observed_orcids":["https://orcid.org/0000-0002-3246-4809"]},"institutions":[{"id":"https://openalex.org/I22299242","display_name":"Kyoto University","ror":"https://ror.org/02kpeqv85","country_code":"JP","type":"education","lineage":["https://openalex.org/I22299242"]}],"countries":["JP"],"is_corresponding":true,"raw_author_name":"Hiroaki Ohno","raw_affiliation_strings":["Graduate School of Pharmaceutical Sciences, Kyoto University, Sakyo-ku, Kyoto, 606-8501 Japan"],"raw_orcid":"https://orcid.org/0000-0002-3246-4809","affiliations":[{"raw_affiliation_string":"Graduate School of Pharmaceutical Sciences, Kyoto University, Sakyo-ku, Kyoto, 606-8501 Japan","institution_ids":["https://openalex.org/I22299242"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5013135912"],"corresponding_institution_ids":["https://openalex.org/I22299242"],"apc_list":{"value":5790,"currency":"USD","value_usd":5790},"apc_paid":null,"fwci":1.801,"has_fulltext":false,"cited_by_count":28,"citation_normalized_percentile":{"value":0.82968603,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":98},"biblio":{"volume":"129","issue":"26","first_page":"7552","last_page":"7556"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10871","display_name":"Catalytic Alkyne Reactions","score":0.961899995803833,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10871","display_name":"Catalytic Alkyne Reactions","score":0.961899995803833,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13859","display_name":"Organic Chemistry Synthesis Methods","score":0.012799999676644802,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12653","display_name":"Cyclization and Aryne Chemistry","score":0.008700000122189522,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/total-synthesis","display_name":"total synthesis","score":0.9279999732971191},{"id":"https://openalex.org/keywords/gold-catalysis","display_name":"gold catalysis","score":0.847000002861023},{"id":"https://openalex.org/keywords/cascade-cyclization","display_name":"tandem cyclization","score":0.9860000014305115},{"id":"https://openalex.org/keywords/conjugated-diynes","display_name":"conjugated diynes","score":0.9789999723434448},{"id":"https://openalex.org/keywords/pyrrole","display_name":"pyrrole","score":0.9670000076293945},{"id":"https://openalex.org/keywords/suzuki-miyaura-coupling","display_name":"Suzuki coupling","score":0.7260000109672546},{"id":"https://openalex.org/keywords/ullmann-coupling","display_name":"Ullmann coupling","score":0.9290000200271606},{"id":"https://openalex.org/keywords/natural-product-synthesis","display_name":"natural product synthesis","score":0.39800000190734863}],"concepts":[{"id":"https://openalex.org/C112613896","wikidata":"https://www.wikidata.org/wiki/Q898370","display_name":"Conjugated system","level":3,"score":0.8386549949645996},{"id":"https://openalex.org/C7512685","wikidata":"https://www.wikidata.org/wiki/Q529093","display_name":"Annulation","level":3,"score":0.7403762340545654},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7264629602432251},{"id":"https://openalex.org/C2779400197","wikidata":"https://www.wikidata.org/wiki/Q242627","display_name":"Pyrrole","level":2,"score":0.6920024752616882},{"id":"https://openalex.org/C2779825165","wikidata":"https://www.wikidata.org/wiki/Q101497","display_name":"Aldehyde","level":3,"score":0.628115177154541},{"id":"https://openalex.org/C164361826","wikidata":"https://www.wikidata.org/wiki/Q177604","display_name":"Alkylation","level":3,"score":0.616820216178894},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.6132826805114746},{"id":"https://openalex.org/C2776127813","wikidata":"https://www.wikidata.org/wiki/Q424003","display_name":"Carbazole","level":2,"score":0.5174113512039185},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.4936710298061371},{"id":"https://openalex.org/C34146451","wikidata":"https://www.wikidata.org/wiki/Q5048094","display_name":"Cascade","level":2,"score":0.48691070079803467},{"id":"https://openalex.org/C35753019","wikidata":"https://www.wikidata.org/wiki/Q644785","display_name":"Total synthesis","level":2,"score":0.41352295875549316},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.40185925364494324},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.25115272402763367},{"id":"https://openalex.org/C43617362","wikidata":"https://www.wikidata.org/wiki/Q170050","display_name":"Chromatography","level":1,"score":0.0},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/ange.201703279","doi":"https://doi.org/10.1002/ange.201703279","is_oa":false,"landing_page_url":"https://doi.org/10.1002/ange.201703279","pdf_url":null,"source":{"id":"https://openalex.org/S4210200754","display_name":"Angewandte Chemie","issn_l":"0044-8249","issn":["0044-8249","0932-2140","1521-3757"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G5797345890","display_name":null,"funder_award_id":"JP15KT0061","funder_id":"https://openalex.org/F4320334764","funder_display_name":"Japan Society for the Promotion of Science"},{"id":"https://openalex.org/G7573927872","display_name":"Innovative Molecular Transformations Based on Consecutive pai-Activation and Their Medicinal Applications","funder_award_id":"24689001","funder_id":"https://openalex.org/F4320334764","funder_display_name":"Japan Society for the Promotion of Science"}],"funders":[{"id":"https://openalex.org/F4320320912","display_name":"Ministry of Education, Culture, Sports, Science and Technology","ror":"https://ror.org/048rj2z13"},{"id":"https://openalex.org/F4320324271","display_name":"Astellas Foundation for Research on Metabolic Disorders","ror":"https://ror.org/01cjash87"},{"id":"https://openalex.org/F4320334764","display_name":"Japan Society for the Promotion of Science","ror":"https://ror.org/00hhkn466"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":41,"referenced_works":["https://openalex.org/W1859718632","https://openalex.org/W1946987759","https://openalex.org/W1967429049","https://openalex.org/W1968133563","https://openalex.org/W1968294999","https://openalex.org/W1970259159","https://openalex.org/W1972836172","https://openalex.org/W1980377192","https://openalex.org/W1985042903","https://openalex.org/W1986319965","https://openalex.org/W1986907092","https://openalex.org/W1989753419","https://openalex.org/W2003071992","https://openalex.org/W2017819783","https://openalex.org/W2025550347","https://openalex.org/W2044403013","https://openalex.org/W2048069438","https://openalex.org/W2051464474","https://openalex.org/W2053105399","https://openalex.org/W2065673772","https://openalex.org/W2065746176","https://openalex.org/W2077101653","https://openalex.org/W2083609038","https://openalex.org/W2089100356","https://openalex.org/W2103428139","https://openalex.org/W2104404935","https://openalex.org/W2115124231","https://openalex.org/W2124913553","https://openalex.org/W2133078504","https://openalex.org/W2148197391","https://openalex.org/W2317325110","https://openalex.org/W2323646210","https://openalex.org/W2326778858","https://openalex.org/W2333884794","https://openalex.org/W2427128833","https://openalex.org/W2501857248","https://openalex.org/W2949319715","https://openalex.org/W4236728544","https://openalex.org/W4238276390","https://openalex.org/W4250779107","https://openalex.org/W4252813240"],"related_works":["https://openalex.org/W3095544569","https://openalex.org/W4240807057","https://openalex.org/W3021358299","https://openalex.org/W2025550347","https://openalex.org/W2747948333","https://openalex.org/W1987676662","https://openalex.org/W1986907092","https://openalex.org/W2501857248","https://openalex.org/W4362657082","https://openalex.org/W2480480782"],"abstract_inverted_index":{"Abstract":[0],"In":[1],"total":[2],"and":[3,11,39,60],"formal":[4],"syntheses":[5],"of":[6,20,28,46],"dictyodendrins":[7],"B,":[8],"C,":[9],"E,":[10],"F,":[12],"the":[13,17,21,25,49],"key":[14],"step":[15],"involved":[16],"direct":[18],"construction":[19],"pyrrolo[2,3\u2010c]carbazole":[22],"core":[23],"by":[24],"gold\u2010catalyzed":[26],"annulation":[27],"a":[29,33],"conjugated":[30],"diyne":[31],"with":[32],"pyrrole":[34],"to":[35,55,68],"form":[36],"three":[37],"bonds":[38],"two":[40],"aromatic":[41],"rings.":[42],"The":[43],"subsequent":[44],"introduction":[45],"substituents":[47],"at":[48],"C1":[50],"(Suzuki\u2013Miyaura":[51],"coupling),":[52],"C2":[53],"(addition":[54],"an":[56],"aldehyde),":[57],"N3":[58],"(alkylation),":[59],"C5":[61],"positions":[62],"(Ullman":[63],"coupling)":[64],"provided":[65],"divergent":[66],"access":[67],"dictyodendrins.":[69]},"counts_by_year":[{"year":2024,"cited_by_count":1},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":4},{"year":2021,"cited_by_count":5},{"year":2020,"cited_by_count":6},{"year":2019,"cited_by_count":5},{"year":2018,"cited_by_count":4},{"year":2017,"cited_by_count":2}],"updated_date":"2026-11-03T10:50:19.383937","created_date":"2022-05-12T00:00:00"}