{"id":"https://openalex.org/W4229367206","doi":"https://doi.org/10.3389/fchem.2022.900482","title":"Highly Efficient One-Step Conversion of Fructose to Biofuel 5-Ethoxymethylfurfural Using a UIO-66-SO3H Catalyst","display_name":"Highly Efficient One-Step Conversion of Fructose to Biofuel 5-Ethoxymethylfurfural Using a UIO-66-SO3H Catalyst","publication_year":2022,"publication_date":"2022-05-09","ids":{"openalex":"https://openalex.org/W4229367206","doi":"https://doi.org/10.3389/fchem.2022.900482","pmid":"https://pubmed.ncbi.nlm.nih.gov/35615317","pmcid":"https://www.ncbi.nlm.nih.gov/pmc/articles/9125248"},"language":"en","primary_location":{"id":"doi:10.3389/fchem.2022.900482","doi":"https://doi.org/10.3389/fchem.2022.900482","is_oa":true,"landing_page_url":"https://doi.org/10.3389/fchem.2022.900482","pdf_url":"https://www.frontiersin.org/articles/10.3389/fchem.2022.900482/pdf","source":{"id":"https://openalex.org/S2764970645","display_name":"Frontiers in Chemistry","issn_l":"2296-2646","issn":["2296-2646"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320527","host_organization_name":"Frontiers Media","host_organization_lineage":["https://openalex.org/P4310320527"],"host_organization_lineage_names":["Frontiers Media"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Frontiers in Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","doaj","pubmed"],"open_access":{"is_oa":true,"oa_status":"gold","oa_url":"https://www.frontiersin.org/articles/10.3389/fchem.2022.900482/pdf","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5058686976","display_name":"Kangyu Zhao","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I173759888","display_name":"Hunan Normal University","ror":"https://ror.org/053w1zy07","country_code":"CN","type":"education","lineage":["https://openalex.org/I173759888"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Kangyu Zhao","raw_affiliation_strings":["National and Local Joint Engineering Laboratory for New Petro-chemical Materials and Fine Utilization of Resources, Key Laboratory of the Assembly and Application of Organic Functional Molecules of Hunan Province, Hunan Normal University, Changsha, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"National and Local Joint Engineering Laboratory for New Petro-chemical Materials and Fine Utilization of Resources, Key Laboratory of the Assembly and Application of Organic Functional Molecules of Hunan Province, Hunan Normal University, Changsha, China","institution_ids":["https://openalex.org/I173759888"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5034954450","display_name":"Yanping Xiang","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I173759888","display_name":"Hunan Normal University","ror":"https://ror.org/053w1zy07","country_code":"CN","type":"education","lineage":["https://openalex.org/I173759888"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yanping Xiang","raw_affiliation_strings":["National and Local Joint Engineering Laboratory for New Petro-chemical Materials and Fine Utilization of Resources, Key Laboratory of the Assembly and Application of Organic Functional Molecules of Hunan Province, Hunan Normal University, Changsha, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"National and Local Joint Engineering Laboratory for New Petro-chemical Materials and Fine Utilization of Resources, Key Laboratory of the Assembly and Application of Organic Functional Molecules of Hunan Province, Hunan Normal University, Changsha, China","institution_ids":["https://openalex.org/I173759888"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5062829810","display_name":"Xiaoao Sun","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I173759888","display_name":"Hunan Normal University","ror":"https://ror.org/053w1zy07","country_code":"CN","type":"education","lineage":["https://openalex.org/I173759888"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Xiaoao Sun","raw_affiliation_strings":["National and Local Joint Engineering Laboratory for New Petro-chemical Materials and Fine Utilization of Resources, Key Laboratory of the Assembly and Application of Organic Functional Molecules of Hunan Province, Hunan Normal University, Changsha, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"National and Local Joint Engineering Laboratory for New Petro-chemical Materials and Fine Utilization of Resources, Key Laboratory of the Assembly and Application of Organic Functional Molecules of Hunan Province, Hunan Normal University, Changsha, China","institution_ids":["https://openalex.org/I173759888"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5023388216","display_name":"Linjiao Chen","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I173759888","display_name":"Hunan Normal University","ror":"https://ror.org/053w1zy07","country_code":"CN","type":"education","lineage":["https://openalex.org/I173759888"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Linjiao Chen","raw_affiliation_strings":["National and Local Joint Engineering Laboratory for New Petro-chemical Materials and Fine Utilization of Resources, Key Laboratory of the Assembly and Application of Organic Functional Molecules of Hunan Province, Hunan Normal University, Changsha, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"National and Local Joint Engineering Laboratory for New Petro-chemical Materials and Fine Utilization of Resources, Key Laboratory of the Assembly and Application of Organic Functional Molecules of Hunan Province, Hunan Normal University, Changsha, China","institution_ids":["https://openalex.org/I173759888"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5103167947","display_name":"Jiafu Xiao","orcid":"https://orcid.org/0000-0002-8704-8693","observed_orcids":["https://orcid.org/0000-0002-8704-8693"]},"institutions":[{"id":"https://openalex.org/I4405281344","display_name":"Hunan University of Medicine","ror":"https://ror.org/047sgsy47","country_code":"CN","type":"education","lineage":["https://openalex.org/I4405281344"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Jiafu Xiao","raw_affiliation_strings":["Hunan Provincial Key Laboratory for Synthetic Biology of Traditional Chinese Medicine, School of Pharmaceutical Sciences, Hunan University of Medicine, Huaihua, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Hunan Provincial Key Laboratory for Synthetic Biology of Traditional Chinese Medicine, School of Pharmaceutical Sciences, Hunan University of Medicine, Huaihua, China","institution_ids":["https://openalex.org/I4405281344"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5043259359","display_name":"Xianxiang Liu","orcid":"https://orcid.org/0000-0001-5549-6339","observed_orcids":["https://orcid.org/0000-0001-5549-6339","https://orcid.org/0009-0009-8960-5957"]},"institutions":[{"id":"https://openalex.org/I173759888","display_name":"Hunan Normal University","ror":"https://ror.org/053w1zy07","country_code":"CN","type":"education","lineage":["https://openalex.org/I173759888"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Xianxiang Liu","raw_affiliation_strings":["National and Local Joint Engineering Laboratory for New Petro-chemical Materials and Fine Utilization of Resources, Key Laboratory of the Assembly and Application of Organic Functional Molecules of Hunan Province, Hunan Normal University, Changsha, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"National and Local Joint Engineering Laboratory for New Petro-chemical Materials and Fine Utilization of Resources, Key Laboratory of the Assembly and Application of Organic Functional Molecules of Hunan Province, Hunan Normal University, Changsha, China","institution_ids":["https://openalex.org/I173759888"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5043259359","https://openalex.org/A5103167947"],"corresponding_institution_ids":["https://openalex.org/I173759888","https://openalex.org/I4405281344"],"apc_list":{"value":2950,"currency":"USD","value_usd":2950},"apc_paid":{"value":2950,"currency":"USD","value_usd":2950},"fwci":0.9183,"has_fulltext":true,"cited_by_count":22,"citation_normalized_percentile":{"value":0.67565781,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":99},"biblio":{"volume":"10","issue":null,"first_page":"900482","last_page":"900482"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11009","display_name":"Catalysis for Biomass Conversion","score":1.0,"subfield":{"id":"https://openalex.org/subfields/1503","display_name":"Catalysis"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11009","display_name":"Catalysis for Biomass Conversion","score":1.0,"subfield":{"id":"https://openalex.org/subfields/1503","display_name":"Catalysis"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10096","display_name":"Metal-Organic Frameworks: Synthesis and Applications","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11351","display_name":"Catalysis and Hydrodesulfurization Studies","score":0.0,"subfield":{"id":"https://openalex.org/subfields/1503","display_name":"Catalysis"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/5-ethoxymethylfurfural","display_name":"5-ethoxymethylfurfural","score":0.953000009059906},{"id":"https://openalex.org/keywords/fructose-conversion","display_name":"fructose conversion","score":0.9599999785423279},{"id":"https://openalex.org/keywords/heterogeneous-catalysis","display_name":"heterogeneous catalysis","score":0.6600000262260437},{"id":"https://openalex.org/keywords/one-pot-conversion","display_name":"one-pot conversion","score":0.6690000295639038},{"id":"https://openalex.org/keywords/chlorosulfonation","display_name":"chlorosulfonation","score":0.9150000214576721},{"id":"https://openalex.org/keywords/biomass-derived-liquid-fuels","display_name":"biomass-derived liquid fuels","score":0.7289999723434448},{"id":"https://openalex.org/keywords/furfural-derivatives","display_name":"furfural derivatives","score":0.43299999833106995}],"concepts":[{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.8438078761100769},{"id":"https://openalex.org/C2778502040","wikidata":"https://www.wikidata.org/wiki/Q250437","display_name":"Sulfonic acid","level":2,"score":0.8422461748123169},{"id":"https://openalex.org/C2776424955","wikidata":"https://www.wikidata.org/wiki/Q2246598","display_name":"Phosphotungstic acid","level":3,"score":0.6746110916137695},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6460472941398621},{"id":"https://openalex.org/C2776970464","wikidata":"https://www.wikidata.org/wiki/Q122043","display_name":"Fructose","level":2,"score":0.6218387484550476},{"id":"https://openalex.org/C160892712","wikidata":"https://www.wikidata.org/wiki/Q901559","display_name":"Fourier transform infrared spectroscopy","level":2,"score":0.6063687205314636},{"id":"https://openalex.org/C134121241","wikidata":"https://www.wikidata.org/wiki/Q899301","display_name":"Yield (engineering)","level":2,"score":0.5999562740325928},{"id":"https://openalex.org/C40875361","wikidata":"https://www.wikidata.org/wiki/Q2356542","display_name":"Reagent","level":2,"score":0.5683687925338745},{"id":"https://openalex.org/C13965031","wikidata":"https://www.wikidata.org/wiki/Q243545","display_name":"Nuclear chemistry","level":1,"score":0.4885788857936859},{"id":"https://openalex.org/C153642686","wikidata":"https://www.wikidata.org/wiki/Q70906","display_name":"Infrared spectroscopy","level":2,"score":0.4384195804595947},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.36458003520965576},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.32682347297668457},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.2903618812561035},{"id":"https://openalex.org/C191897082","wikidata":"https://www.wikidata.org/wiki/Q11467","display_name":"Metallurgy","level":1,"score":0.0},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0}],"mesh":[],"locations_count":4,"locations":[{"id":"doi:10.3389/fchem.2022.900482","doi":"https://doi.org/10.3389/fchem.2022.900482","is_oa":true,"landing_page_url":"https://doi.org/10.3389/fchem.2022.900482","pdf_url":"https://www.frontiersin.org/articles/10.3389/fchem.2022.900482/pdf","source":{"id":"https://openalex.org/S2764970645","display_name":"Frontiers in Chemistry","issn_l":"2296-2646","issn":["2296-2646"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320527","host_organization_name":"Frontiers Media","host_organization_lineage":["https://openalex.org/P4310320527"],"host_organization_lineage_names":["Frontiers Media"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Frontiers in Chemistry","raw_type":"journal-article"},{"id":"pmid:35615317","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/35615317","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Frontiers in chemistry","raw_type":"Journal Article"},{"id":"pmh:oai:pubmedcentral.nih.gov:9125248","doi":null,"is_oa":true,"landing_page_url":"https://pmc.ncbi.nlm.nih.gov/articles/PMC9125248/","pdf_url":null,"source":{"id":"https://openalex.org/S2764455111","display_name":"PubMed Central","issn_l":null,"issn":null,"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Front Chem","raw_type":"Text"},{"id":"pmh:oai:doaj.org/article:5364414bf508401fb871f4696eb264d9","doi":null,"is_oa":true,"landing_page_url":"https://doaj.org/article/5364414bf508401fb871f4696eb264d9","pdf_url":null,"source":{"id":"https://openalex.org/S4306401280","display_name":"DOAJ (DOAJ: Directory of Open Access Journals)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-sa","license_id":"https://openalex.org/licenses/cc-by-sa","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Frontiers in Chemistry, Vol 10 (2022)","raw_type":"article"}],"best_oa_location":{"id":"doi:10.3389/fchem.2022.900482","doi":"https://doi.org/10.3389/fchem.2022.900482","is_oa":true,"landing_page_url":"https://doi.org/10.3389/fchem.2022.900482","pdf_url":"https://www.frontiersin.org/articles/10.3389/fchem.2022.900482/pdf","source":{"id":"https://openalex.org/S2764970645","display_name":"Frontiers in Chemistry","issn_l":"2296-2646","issn":["2296-2646"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320527","host_organization_name":"Frontiers Media","host_organization_lineage":["https://openalex.org/P4310320527"],"host_organization_lineage_names":["Frontiers Media"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Frontiers in Chemistry","raw_type":"journal-article"},"sustainable_development_goals":[{"id":"https://metadata.un.org/sdg/7","score":0.878000020980835,"display_name":"Affordable and clean energy"}],"study_designs":[],"awards":[{"id":"https://openalex.org/G4758361526","display_name":null,"funder_award_id":"21606082","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"}],"funders":[{"id":"https://openalex.org/F4320321001","display_name":"National Natural Science Foundation of China","ror":"https://ror.org/01h0zpd94"}],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W4229367206.pdf","grobid_xml":"https://content.openalex.org/works/W4229367206.grobid-xml"},"referenced_works_count":36,"referenced_works":["https://openalex.org/W1812932069","https://openalex.org/W1975914784","https://openalex.org/W2082755747","https://openalex.org/W2084726128","https://openalex.org/W2088408995","https://openalex.org/W2138078544","https://openalex.org/W2282615526","https://openalex.org/W2309896310","https://openalex.org/W2314395232","https://openalex.org/W2321026588","https://openalex.org/W2335753267","https://openalex.org/W2513475441","https://openalex.org/W2793399982","https://openalex.org/W2810792935","https://openalex.org/W2883075654","https://openalex.org/W2903778999","https://openalex.org/W2904247003","https://openalex.org/W2907853357","https://openalex.org/W2916007804","https://openalex.org/W2937782454","https://openalex.org/W2942241060","https://openalex.org/W2956766987","https://openalex.org/W2967313923","https://openalex.org/W2990721944","https://openalex.org/W2994316396","https://openalex.org/W3016991592","https://openalex.org/W3017293172","https://openalex.org/W3049065955","https://openalex.org/W3111850530","https://openalex.org/W3123915556","https://openalex.org/W3135264265","https://openalex.org/W3159669306","https://openalex.org/W3165912416","https://openalex.org/W3178495014","https://openalex.org/W3194540133","https://openalex.org/W3216416197"],"related_works":["https://openalex.org/W4383033171","https://openalex.org/W3178495014","https://openalex.org/W2295578511","https://openalex.org/W3014325304","https://openalex.org/W2116458986","https://openalex.org/W7134935188","https://openalex.org/W2944533444","https://openalex.org/W3196980769","https://openalex.org/W1976578765","https://openalex.org/W2559369547"],"abstract_inverted_index":{"H)":[0],"was":[1,63,108],"synthesized":[2],"using":[3],"chlorosulfonic":[4],"acid":[5,61,86],"as":[6,13],"a":[7,28,124],"sulfonating":[8],"reagent":[9],"and":[10,50,70,79,92],"first":[11],"used":[12],"efficient":[14,135],"heterogeneous":[15],"catalysts":[16],"for":[17,133],"the":[18,59,67,82,104,116,134],"one-pot":[19],"conversion":[20,105],"of":[21,35,84,106,129,137],"fructose":[22,107],"into":[23],"biofuel":[24],"5-ethoxymethylfurfural":[25],"(EMF)":[26],"in":[27],"cosolvent":[29],"free":[30],"system.":[31],"The":[32,55,100],"physicochemical":[33],"properties":[34],"this":[36],"catalyst":[37,85,93],"were":[38,98],"characterized":[39],"by":[40,127],"Fourier":[41],"transform":[42],"infrared":[43],"spectroscopy":[44],"(FT-IR),":[45],"transmission":[46],"electron":[47],"microscopy":[48],"(TEM),":[49],"powder":[51],"X-ray":[52],"diffraction":[53],"(XRD).":[54],"characterization":[56],"demonstrated":[57],"that":[58,103],"sulfonic":[60,130],"group":[62],"successfully":[64],"grafted":[65],"onto":[66],"MOF":[68],"material":[69],"did":[71],"not":[72],"cause":[73],"significant":[74],"changes":[75],"to":[76],"its":[77],"morphology":[78],"structure.":[80],"Furthermore,":[81],"effects":[83],"amount,":[87],"reaction":[88,90,96],"temperature,":[89],"time,":[91],"dosage":[94],"on":[95],"results":[97,101],"investigated.":[99],"showed":[102],"99.7%":[109],"within":[110],"1":[111],"h":[112],"at":[113],"140\u00b0C,":[114],"while":[115],"EMF":[117,141],"yield":[118],"reached":[119],"80.4%.":[120],"This":[121],"work":[122],"provides":[123],"viable":[125],"strategy":[126],"application":[128],"acid-based":[131],"MOFs":[132],"synthesis":[136],"potential":[138],"liquid":[139],"fuel":[140],"from":[142],"renewable":[143],"biomass.":[144]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2025,"cited_by_count":7},{"year":2024,"cited_by_count":9},{"year":2023,"cited_by_count":3},{"year":2022,"cited_by_count":1}],"updated_date":"2026-11-10T11:39:43.021295","created_date":"2022-05-10T00:00:00"}
