{"id":"https://openalex.org/W4212947735","doi":"https://doi.org/10.3390/ma15041465","title":"Determination of Band Structure of Naturally Occurring Goethite with Al Substitution: A Case Study of Zhushan Iron Zone","display_name":"Determination of Band Structure of Naturally Occurring Goethite with Al Substitution: A Case Study of Zhushan Iron Zone","publication_year":2022,"publication_date":"2022-02-16","ids":{"openalex":"https://openalex.org/W4212947735","doi":"https://doi.org/10.3390/ma15041465","pmid":"https://pubmed.ncbi.nlm.nih.gov/35208010","pmcid":"https://www.ncbi.nlm.nih.gov/pmc/articles/8875212"},"language":"en","primary_location":{"id":"doi:10.3390/ma15041465","doi":"https://doi.org/10.3390/ma15041465","is_oa":true,"landing_page_url":"https://doi.org/10.3390/ma15041465","pdf_url":"https://www.mdpi.com/1996-1944/15/4/1465/pdf?version=1645006030","source":{"id":"https://openalex.org/S18714766","display_name":"Materials","issn_l":"1996-1944","issn":["1996-1944"],"is_oa":true,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310310987","host_organization_name":"Multidisciplinary Digital Publishing Institute","host_organization_lineage":["https://openalex.org/P4310310987"],"host_organization_lineage_names":["Multidisciplinary Digital Publishing Institute"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Materials","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","doaj","pubmed"],"open_access":{"is_oa":true,"oa_status":"gold","oa_url":"https://www.mdpi.com/1996-1944/15/4/1465/pdf?version=1645006030","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5101835479","display_name":"Yan Shao","orcid":"https://orcid.org/0000-0001-9779-3411","observed_orcids":["https://orcid.org/0000-0001-9779-3411"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Yan Shao","raw_affiliation_strings":["Wuhan City Environment Protection Engineering Limited Company, Wuhan 430205, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Wuhan City Environment Protection Engineering Limited Company, Wuhan 430205, China","institution_ids":[]}]},{"author_position":"middle","author":{"id":null,"display_name":"Guofeng Hu","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Guofeng Hu","raw_affiliation_strings":["Wuhan City Environment Protection Engineering Limited Company, Wuhan 430205, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Wuhan City Environment Protection Engineering Limited Company, Wuhan 430205, China","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100323074","display_name":"Zihao Liu","orcid":"https://orcid.org/0000-0003-0394-5184","observed_orcids":["https://orcid.org/0000-0003-0394-5184","https://orcid.org/0009-0007-0915-1859","https://orcid.org/0009-0007-1716-4086"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Zihao Liu","raw_affiliation_strings":["Wuhan City Environment Protection Engineering Limited Company, Wuhan 430205, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Wuhan City Environment Protection Engineering Limited Company, Wuhan 430205, China","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5041685436","display_name":"Xiaoming Xu","orcid":"https://orcid.org/0000-0001-5590-3336","observed_orcids":["https://orcid.org/0000-0001-5590-3336"]},"institutions":[{"id":"https://openalex.org/I20231570","display_name":"Peking University","ror":"https://ror.org/02v51f717","country_code":"CN","type":"education","lineage":["https://openalex.org/I20231570"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Xiaoming Xu","raw_affiliation_strings":["School of Earth and Space Sciences, Peking University, Beijing 100871, China","Wuhan City Environment Protection Engineering Limited Company, Wuhan 430205, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Earth and Space Sciences, Peking University, Beijing 100871, China","institution_ids":["https://openalex.org/I20231570"]},{"raw_affiliation_string":"Wuhan City Environment Protection Engineering Limited Company, Wuhan 430205, China","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100751728","display_name":"Mengqi Zhang","orcid":"https://orcid.org/0000-0003-3167-2363","observed_orcids":["https://orcid.org/0000-0003-3167-2363"]},"institutions":[{"id":"https://openalex.org/I20231570","display_name":"Peking University","ror":"https://ror.org/02v51f717","country_code":"CN","type":"education","lineage":["https://openalex.org/I20231570"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Mengqi Zhang","raw_affiliation_strings":["School of Earth and Space Sciences, Peking University, Beijing 100871, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Earth and Space Sciences, Peking University, Beijing 100871, China","institution_ids":["https://openalex.org/I20231570"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5080149086","display_name":"Cong Ding","orcid":"https://orcid.org/0000-0003-0198-4024","observed_orcids":["https://orcid.org/0000-0003-0198-4024"]},"institutions":[{"id":"https://openalex.org/I20231570","display_name":"Peking University","ror":"https://ror.org/02v51f717","country_code":"CN","type":"education","lineage":["https://openalex.org/I20231570"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Cong Ding","raw_affiliation_strings":["School of Earth and Space Sciences, Peking University, Beijing 100871, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Earth and Space Sciences, Peking University, Beijing 100871, China","institution_ids":["https://openalex.org/I20231570"]}]},{"author_position":"last","author":{"id":null,"display_name":"Yan Li","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I20231570","display_name":"Peking University","ror":"https://ror.org/02v51f717","country_code":"CN","type":"education","lineage":["https://openalex.org/I20231570"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yan Li","raw_affiliation_strings":["School of Earth and Space Sciences, Peking University, Beijing 100871, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Earth and Space Sciences, Peking University, Beijing 100871, China","institution_ids":["https://openalex.org/I20231570"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5041685436"],"corresponding_institution_ids":["https://openalex.org/I20231570"],"apc_list":{"value":2300,"currency":"CHF","value_usd":2408},"apc_paid":{"value":2300,"currency":"CHF","value_usd":2408},"fwci":1.0574,"has_fulltext":true,"cited_by_count":27,"citation_normalized_percentile":{"value":0.71578858,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":93,"max":99},"biblio":{"volume":"15","issue":"4","first_page":"1465","last_page":"1465"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11877","display_name":"Iron oxide chemistry and applications","score":0.9574999809265137,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11877","display_name":"Iron oxide chemistry and applications","score":0.9574999809265137,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10078","display_name":"Advanced Photocatalysis Techniques","score":0.03799999877810478,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10024","display_name":"TiO2 Photocatalysis and Solar Cells","score":0.001500000013038516,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/goethite","display_name":"goethite","score":0.9010000228881836},{"id":"https://openalex.org/keywords/aluminum-substitution","display_name":"aluminum substitution","score":0.8730000257492065},{"id":"https://openalex.org/keywords/band-structure","display_name":"electronic band structure","score":0.8920000195503235},{"id":"https://openalex.org/keywords/band-gap-narrowing","display_name":"band gap narrowing","score":0.9639999866485596},{"id":"https://openalex.org/keywords/photocatalysis","display_name":"photocatalysis","score":0.8840000033378601},{"id":"https://openalex.org/keywords/methyl-orange-degradation","display_name":"methyl orange degradation","score":0.996999979019165},{"id":"https://openalex.org/keywords/valence-band-position","display_name":"valence band position","score":0.8479999899864197},{"id":"https://openalex.org/keywords/iron-oxide-mineralogy","display_name":"iron oxide mineralogy","score":0.42100000381469727}],"concepts":[{"id":"https://openalex.org/C2777787761","wikidata":"https://www.wikidata.org/wiki/Q189703","display_name":"Goethite","level":3,"score":0.967792272567749},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.511130154132843},{"id":"https://openalex.org/C32891209","wikidata":"https://www.wikidata.org/wiki/Q483666","display_name":"Spectroscopy","level":2,"score":0.5085138082504272},{"id":"https://openalex.org/C181966813","wikidata":"https://www.wikidata.org/wiki/Q806352","display_name":"Band gap","level":2,"score":0.5026915073394775},{"id":"https://openalex.org/C175708663","wikidata":"https://www.wikidata.org/wiki/Q899559","display_name":"X-ray photoelectron spectroscopy","level":2,"score":0.47371619939804077},{"id":"https://openalex.org/C113196181","wikidata":"https://www.wikidata.org/wiki/Q485223","display_name":"Analytical Chemistry (journal)","level":2,"score":0.38995257019996643},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.3877374529838562},{"id":"https://openalex.org/C199289684","wikidata":"https://www.wikidata.org/wiki/Q83353","display_name":"Mineralogy","level":1,"score":0.34941133856773376},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.13032397627830505},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.13018199801445007},{"id":"https://openalex.org/C46141821","wikidata":"https://www.wikidata.org/wiki/Q209402","display_name":"Nuclear magnetic resonance","level":1,"score":0.11907181143760681},{"id":"https://openalex.org/C49040817","wikidata":"https://www.wikidata.org/wiki/Q193091","display_name":"Optoelectronics","level":1,"score":0.09013974666595459},{"id":"https://openalex.org/C107872376","wikidata":"https://www.wikidata.org/wiki/Q321355","display_name":"Environmental chemistry","level":1,"score":0.08174443244934082},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C150394285","wikidata":"https://www.wikidata.org/wiki/Q180254","display_name":"Adsorption","level":2,"score":0.0}],"mesh":[],"locations_count":4,"locations":[{"id":"doi:10.3390/ma15041465","doi":"https://doi.org/10.3390/ma15041465","is_oa":true,"landing_page_url":"https://doi.org/10.3390/ma15041465","pdf_url":"https://www.mdpi.com/1996-1944/15/4/1465/pdf?version=1645006030","source":{"id":"https://openalex.org/S18714766","display_name":"Materials","issn_l":"1996-1944","issn":["1996-1944"],"is_oa":true,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310310987","host_organization_name":"Multidisciplinary Digital Publishing Institute","host_organization_lineage":["https://openalex.org/P4310310987"],"host_organization_lineage_names":["Multidisciplinary Digital Publishing Institute"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Materials","raw_type":"journal-article"},{"id":"pmh:oai:pubmedcentral.nih.gov:8875212","doi":null,"is_oa":true,"landing_page_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/8875212","pdf_url":null,"source":{"id":"https://openalex.org/S2764455111","display_name":"PubMed Central","issn_l":null,"issn":null,"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Materials (Basel)","raw_type":"Text"},{"id":"pmid:35208010","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/35208010","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Materials (Basel, Switzerland)","raw_type":"Journal Article"},{"id":"pmh:oai:doaj.org/article:ec5b69f79d974ee8920091d8fc8e3b9c","doi":null,"is_oa":true,"landing_page_url":"https://doaj.org/article/ec5b69f79d974ee8920091d8fc8e3b9c","pdf_url":null,"source":{"id":"https://openalex.org/S4306401280","display_name":"DOAJ (DOAJ: Directory of Open Access Journals)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-sa","license_id":"https://openalex.org/licenses/cc-by-sa","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Materials, Vol 15, Iss 4, p 1465 (2022)","raw_type":"article"}],"best_oa_location":{"id":"doi:10.3390/ma15041465","doi":"https://doi.org/10.3390/ma15041465","is_oa":true,"landing_page_url":"https://doi.org/10.3390/ma15041465","pdf_url":"https://www.mdpi.com/1996-1944/15/4/1465/pdf?version=1645006030","source":{"id":"https://openalex.org/S18714766","display_name":"Materials","issn_l":"1996-1944","issn":["1996-1944"],"is_oa":true,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310310987","host_organization_name":"Multidisciplinary Digital Publishing Institute","host_organization_lineage":["https://openalex.org/P4310310987"],"host_organization_lineage_names":["Multidisciplinary Digital Publishing Institute"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Materials","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G3393712367","display_name":null,"funder_award_id":"2018YFC1801700","funder_id":"https://openalex.org/F4320335777","funder_display_name":"National Key Research and Development Program of China"}],"funders":[{"id":"https://openalex.org/F4320335777","display_name":"National Key Research and Development Program of China","ror":null}],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W4212947735.pdf","grobid_xml":"https://content.openalex.org/works/W4212947735.grobid-xml"},"referenced_works_count":33,"referenced_works":["https://openalex.org/W156468121","https://openalex.org/W1487107260","https://openalex.org/W1634912898","https://openalex.org/W1906682345","https://openalex.org/W1967344963","https://openalex.org/W1970034195","https://openalex.org/W1973767821","https://openalex.org/W1981368803","https://openalex.org/W1985654479","https://openalex.org/W1986052302","https://openalex.org/W1991878788","https://openalex.org/W1995072795","https://openalex.org/W2002785471","https://openalex.org/W2005781904","https://openalex.org/W2009814844","https://openalex.org/W2015864659","https://openalex.org/W2043396593","https://openalex.org/W2043916827","https://openalex.org/W2062036496","https://openalex.org/W2070716407","https://openalex.org/W2071059454","https://openalex.org/W2098012383","https://openalex.org/W2122758691","https://openalex.org/W2161825099","https://openalex.org/W2266872834","https://openalex.org/W2313310609","https://openalex.org/W2584355916","https://openalex.org/W2614191866","https://openalex.org/W2626983743","https://openalex.org/W2945570555","https://openalex.org/W3041520248","https://openalex.org/W3183336675","https://openalex.org/W4255412919"],"related_works":["https://openalex.org/W4410124561","https://openalex.org/W4283023084","https://openalex.org/W4283378038","https://openalex.org/W3036922432","https://openalex.org/W7010675923","https://openalex.org/W1985654479","https://openalex.org/W2390605879","https://openalex.org/W2041886754","https://openalex.org/W2979626983","https://openalex.org/W2945783728"],"abstract_inverted_index":{"The":[0,97,157,193],"photocatalytic":[1,232],"property":[2],"of":[3,26,32,36,49,100,109,120,131,170,176,213,234],"Fe":[4],"oxide":[5],"minerals":[6],"has":[7,39],"long":[8],"been":[9,41],"considered":[10],"to":[11,23,129,154],"play":[12,239],"an":[13,240],"important":[14,241],"role":[15,242],"in":[16,138,243],"shaping":[17],"modern":[18],"terrestrial":[19],"environments.":[20],"However,":[21],"due":[22],"the":[24,33,46,75,116,145,149,161,168,174,177,205,214,222,226,231],"complexity":[25],"natural":[27,37,50,80,101,121,139,197,235],"settings,":[28],"a":[29,190],"precise":[30],"determination":[31],"band":[34,76,98,118,163,227],"structure":[35,77,228],"goethite":[38,51,83,102,122,133,140,198,216],"not":[40],"achieved.":[42],"In":[43],"this":[44,155],"work,":[45],"mineralogical":[47,146],"characteristics":[48],"samples":[52,84],"obtained":[53],"from":[54],"Zhushan,":[55],"China,":[56],"were":[57],"systematically":[58],"studied":[59],"through":[60],"X-ray":[61,66,71,89],"diffraction,":[62],"transmission":[63],"electron":[64],"microscopy,":[65],"energy":[67],"dispersive":[68],"spectroscopy,":[69],"and":[70,81,91,94,115,204,229,247],"fluorescence":[72],"spectroscopy.":[73,96],"Afterward,":[74],"for":[78,221],"both":[79],"synthetic":[82,111,132,215],"was":[85,105,123,148,165,208],"determined":[86],"by":[87,144,167],"synchrotron-based":[88],"absorption":[90],"emission":[92],"spectra":[93],"photoelectron":[95],"gap":[99,164],"(2.25":[103],"eV)":[104,127],"narrower":[106],"than":[107,211],"that":[108,130,152,196,212],"its":[110],"counterpart":[112],"(2.55":[113],"eV),":[114],"valence":[117,178],"position":[119],"slightly":[124],"lifted":[125],"(-5.06":[126],"compared":[128],"(-5.38":[134],"eV).":[135],"Al":[136],"doping":[137],"crystal,":[141],"as":[142],"revealed":[143,225],"tests,":[147],"main":[150],"reason":[151],"contributed":[153],"difference.":[156],"theoretical":[158],"calculation":[159],"showed":[160,195],"narrowed":[162],"caused":[166],"contribution":[169],"Al-2p":[171],"orbits":[172],"at":[173],"top":[175],"band.":[179],"Therefore,":[180],"free":[181],"electrons":[182],"can":[183,199],"be":[184],"created":[185],"under":[186],"light":[187],"irradiation":[188],"with":[189],"shorter":[191],"wavelength.":[192],"experiments":[194],"photo-catalytically":[200],"degrade":[201],"methyl":[202],"orange,":[203],"degradation":[206],"efficiency":[207],"better":[209],"(47.5%)":[210],"group":[217],"(31.5%).":[218],"This":[219],"study,":[220],"first":[223],"time,":[224],"confirmed":[230],"properties":[233],"goethite,":[236],"which":[237],"should":[238],"surface":[244],"substance":[245],"evolution":[246],"elemental":[248],"cycling.":[249]},"counts_by_year":[{"year":2026,"cited_by_count":11},{"year":2025,"cited_by_count":6},{"year":2024,"cited_by_count":5},{"year":2023,"cited_by_count":3},{"year":2022,"cited_by_count":2}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2022-02-24T00:00:00"}