{"id":"https://openalex.org/W4200603566","doi":"https://doi.org/10.1002/ange.202113204","title":"Chiral Phosphoric Acid Catalyzed Conversion of Epoxides into Thiiranes: Mechanism, Stereochemical Model, and New Catalyst Design","display_name":"Chiral Phosphoric Acid Catalyzed Conversion of Epoxides into Thiiranes: Mechanism, Stereochemical Model, and New Catalyst Design","publication_year":2021,"publication_date":"2021-12-09","ids":{"openalex":"https://openalex.org/W4200603566","doi":"https://doi.org/10.1002/ange.202113204"},"language":"en","primary_location":{"id":"doi:10.1002/ange.202113204","doi":"https://doi.org/10.1002/ange.202113204","is_oa":true,"landing_page_url":"https://doi.org/10.1002/ange.202113204","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/ange.202113204","source":{"id":"https://openalex.org/S4210200754","display_name":"Angewandte Chemie","issn_l":"0044-8249","issn":["0044-8249","0932-2140","1521-3757"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":"cc-by-nc","license_id":"https://openalex.org/licenses/cc-by-nc","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"hybrid","oa_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/ange.202113204","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5101974303","display_name":"Meng Duan","orcid":"https://orcid.org/0000-0002-4689-9811","observed_orcids":["https://orcid.org/0000-0002-4689-9811"]},"institutions":[{"id":"https://openalex.org/I161318765","display_name":"University of California, Los Angeles","ror":"https://ror.org/046rm7j60","country_code":"US","type":"education","lineage":["https://openalex.org/I161318765"]},{"id":"https://openalex.org/I3045169105","display_name":"Southern University of Science and Technology","ror":"https://ror.org/049tv2d57","country_code":"CN","type":"education","lineage":["https://openalex.org/I3045169105"]},{"id":"https://openalex.org/I38877650","display_name":"Zhengzhou University","ror":"https://ror.org/04ypx8c21","country_code":"CN","type":"education","lineage":["https://openalex.org/I38877650"]}],"countries":["CN","US"],"is_corresponding":false,"raw_author_name":"Meng Duan","raw_affiliation_strings":["Department of Chemistry and Biochemistry, University of California, Los Angeles, CA, 90095 USA","Department of Chemistry and Shenzhen Grubbs Institute, Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and Technology, Shenzhen, 518055 China","Green Catalysis Center, and College of Chemistry, Zhengzhou University, Zhengzhou, Henan, 450001 China","These authors contributed equally to this work"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, University of California, Los Angeles, CA, 90095 USA","institution_ids":["https://openalex.org/I161318765"]},{"raw_affiliation_string":"Department of Chemistry and Shenzhen Grubbs Institute, Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and Technology, Shenzhen, 518055 China","institution_ids":["https://openalex.org/I3045169105"]},{"raw_affiliation_string":"Green Catalysis Center, and College of Chemistry, Zhengzhou University, Zhengzhou, Henan, 450001 China","institution_ids":["https://openalex.org/I38877650"]},{"raw_affiliation_string":"These authors contributed equally to this work","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5026566869","display_name":"Christian David D\u00edaz\u2010Oviedo","orcid":"https://orcid.org/0000-0003-0499-2863","observed_orcids":["https://orcid.org/0000-0003-0499-2863"]},"institutions":[{"id":"https://openalex.org/I4210090782","display_name":"Max-Planck-Institut f\u00fcr Kohlenforschung","ror":"https://ror.org/00a7vgh58","country_code":"DE","type":"facility","lineage":["https://openalex.org/I149899117","https://openalex.org/I4210090782"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Christian David D\u00edaz\u2010Oviedo","raw_affiliation_strings":["Max-Planck-Institut f\u00fcr Kohlenforschung  45470 M\u00fclheim an der Ruhr Germany","These authors contributed equally to this work"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Max-Planck-Institut f\u00fcr Kohlenforschung  45470 M\u00fclheim an der Ruhr Germany","institution_ids":["https://openalex.org/I4210090782"]},{"raw_affiliation_string":"These authors contributed equally to this work","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5045975978","display_name":"Yang Zhou","orcid":"https://orcid.org/0000-0002-2023-0941","observed_orcids":["https://orcid.org/0000-0002-2023-0941"]},"institutions":[{"id":"https://openalex.org/I3045169105","display_name":"Southern University of Science and Technology","ror":"https://ror.org/049tv2d57","country_code":"CN","type":"education","lineage":["https://openalex.org/I3045169105"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yang Zhou","raw_affiliation_strings":["Department of Chemistry and Shenzhen Grubbs Institute, Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and Technology, Shenzhen, 518055 China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Shenzhen Grubbs Institute, Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and Technology, Shenzhen, 518055 China","institution_ids":["https://openalex.org/I3045169105"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5053412068","display_name":"Xiangyang Chen","orcid":"https://orcid.org/0000-0002-6981-7022","observed_orcids":["https://orcid.org/0000-0002-6981-7022","https://orcid.org/0009-0004-4358-6678"]},"institutions":[{"id":"https://openalex.org/I161318765","display_name":"University of California, Los Angeles","ror":"https://ror.org/046rm7j60","country_code":"US","type":"education","lineage":["https://openalex.org/I161318765"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Xiangyang Chen","raw_affiliation_strings":["Department of Chemistry and Biochemistry, University of California, Los Angeles, CA, 90095 USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, University of California, Los Angeles, CA, 90095 USA","institution_ids":["https://openalex.org/I161318765"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5025860351","display_name":"Peiyuan Yu","orcid":"https://orcid.org/0000-0002-4367-6866","observed_orcids":["https://orcid.org/0000-0002-4367-6866"]},"institutions":[{"id":"https://openalex.org/I3045169105","display_name":"Southern University of Science and Technology","ror":"https://ror.org/049tv2d57","country_code":"CN","type":"education","lineage":["https://openalex.org/I3045169105"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Peiyuan Yu","raw_affiliation_strings":["Department of Chemistry and Shenzhen Grubbs Institute, Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and Technology, Shenzhen, 518055 China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Shenzhen Grubbs Institute, Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and Technology, Shenzhen, 518055 China","institution_ids":["https://openalex.org/I3045169105"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5040055598","display_name":"Benjamin List","orcid":"https://orcid.org/0000-0002-9804-599X","observed_orcids":["https://orcid.org/0000-0002-9804-599X"]},"institutions":[{"id":"https://openalex.org/I4210090782","display_name":"Max-Planck-Institut f\u00fcr Kohlenforschung","ror":"https://ror.org/00a7vgh58","country_code":"DE","type":"facility","lineage":["https://openalex.org/I149899117","https://openalex.org/I4210090782"]}],"countries":["DE"],"is_corresponding":true,"raw_author_name":"Benjamin List","raw_affiliation_strings":["Max-Planck-Institut f\u00fcr Kohlenforschung  45470 M\u00fclheim an der Ruhr Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Max-Planck-Institut f\u00fcr Kohlenforschung  45470 M\u00fclheim an der Ruhr Germany","institution_ids":["https://openalex.org/I4210090782"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5042178740","display_name":"Kendall N. Houk","orcid":"https://orcid.org/0000-0002-8387-5261","observed_orcids":["https://orcid.org/0000-0002-8387-5261"]},"institutions":[{"id":"https://openalex.org/I161318765","display_name":"University of California, Los Angeles","ror":"https://ror.org/046rm7j60","country_code":"US","type":"education","lineage":["https://openalex.org/I161318765"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Kendall N. Houk","raw_affiliation_strings":["Department of Chemistry and Biochemistry, University of California, Los Angeles, CA, 90095 USA"],"raw_orcid":"https://orcid.org/0000-0002-8387-5261","affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, University of California, Los Angeles, CA, 90095 USA","institution_ids":["https://openalex.org/I161318765"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5061000219","display_name":"Yu Lan","orcid":"https://orcid.org/0000-0002-2328-0020","observed_orcids":["https://orcid.org/0000-0002-2328-0020"]},"institutions":[{"id":"https://openalex.org/I38877650","display_name":"Zhengzhou University","ror":"https://ror.org/04ypx8c21","country_code":"CN","type":"education","lineage":["https://openalex.org/I38877650"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Yu Lan","raw_affiliation_strings":["Green Catalysis Center, and College of Chemistry, Zhengzhou University, Zhengzhou, Henan, 450001 China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Green Catalysis Center, and College of Chemistry, Zhengzhou University, Zhengzhou, Henan, 450001 China","institution_ids":["https://openalex.org/I38877650"]}]}],"institutions":[],"countries_distinct_count":3,"institutions_distinct_count":4,"corresponding_author_ids":["https://openalex.org/A5040055598","https://openalex.org/A5042178740","https://openalex.org/A5061000219"],"corresponding_institution_ids":["https://openalex.org/I161318765","https://openalex.org/I38877650","https://openalex.org/I4210090782"],"apc_list":{"value":5000,"currency":"USD","value_usd":5000},"apc_paid":{"value":5000,"currency":"USD","value_usd":5000},"fwci":0.6931,"has_fulltext":true,"cited_by_count":7,"citation_normalized_percentile":{"value":0.60888789,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":98},"biblio":{"volume":"134","issue":"9","first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10013","display_name":"Asymmetric Synthesis and Catalysis","score":0.9940999746322632,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10013","display_name":"Asymmetric Synthesis and Catalysis","score":0.9940999746322632,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12191","display_name":"Chemical Reaction Mechanisms","score":0.0015999999595806003,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11831","display_name":"Chemical Synthesis and Reactions","score":0.0008999999845400453,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/chiral-phosphoric-acid","display_name":"chiral phosphoric acid","score":0.9419999718666077},{"id":"https://openalex.org/keywords/epoxides","display_name":"epoxides","score":0.7179999947547913},{"id":"https://openalex.org/keywords/thiiranes","display_name":"thiiranes","score":0.9800000190734863},{"id":"https://openalex.org/keywords/asymmetric-catalysis","display_name":"asymmetric catalysis","score":0.8849999904632568},{"id":"https://openalex.org/keywords/reaction-mechanism","display_name":"reaction mechanism","score":0.9259999990463257},{"id":"https://openalex.org/keywords/stereochemical-model","display_name":"stereochemical model","score":0.7900000214576721},{"id":"https://openalex.org/keywords/catalyst-design","display_name":"catalyst design","score":0.9729999899864197},{"id":"https://openalex.org/keywords/ortho-substituent-effects","display_name":"ortho-substituent effects","score":0.7670000195503235},{"id":"https://openalex.org/keywords/para-substituent-effects","display_name":"para-substituent effects","score":0.9139999747276306},{"id":"https://openalex.org/keywords/transition-state","display_name":"transition state","score":0.4729999899864197}],"concepts":[{"id":"https://openalex.org/C2776920199","wikidata":"https://www.wikidata.org/wiki/Q408028","display_name":"Epoxide","level":3,"score":0.9257650375366211},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.7646567225456238},{"id":"https://openalex.org/C2776622989","wikidata":"https://www.wikidata.org/wiki/Q184782","display_name":"Phosphoric acid","level":2,"score":0.7383403182029724},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7137319445610046},{"id":"https://openalex.org/C2781076698","wikidata":"https://www.wikidata.org/wiki/Q718074","display_name":"Aryl","level":3,"score":0.6208474636077881},{"id":"https://openalex.org/C89031862","wikidata":"https://www.wikidata.org/wiki/Q906964","display_name":"Transition state","level":3,"score":0.5724361538887024},{"id":"https://openalex.org/C152365726","wikidata":"https://www.wikidata.org/wiki/Q1048589","display_name":"Density functional theory","level":2,"score":0.5052147507667542},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.4865507185459137},{"id":"https://openalex.org/C147597530","wikidata":"https://www.wikidata.org/wiki/Q369472","display_name":"Computational chemistry","level":1,"score":0.46456849575042725},{"id":"https://openalex.org/C89611455","wikidata":"https://www.wikidata.org/wiki/Q6804646","display_name":"Mechanism (biology)","level":2,"score":0.4512452781200409},{"id":"https://openalex.org/C65024703","wikidata":"https://www.wikidata.org/wiki/Q373406","display_name":"Reaction mechanism","level":3,"score":0.4140399694442749},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.3643845319747925},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.0},{"id":"https://openalex.org/C138885662","wikidata":"https://www.wikidata.org/wiki/Q5891","display_name":"Philosophy","level":0,"score":0.0},{"id":"https://openalex.org/C111472728","wikidata":"https://www.wikidata.org/wiki/Q9471","display_name":"Epistemology","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/ange.202113204","doi":"https://doi.org/10.1002/ange.202113204","is_oa":true,"landing_page_url":"https://doi.org/10.1002/ange.202113204","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/ange.202113204","source":{"id":"https://openalex.org/S4210200754","display_name":"Angewandte Chemie","issn_l":"0044-8249","issn":["0044-8249","0932-2140","1521-3757"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":"cc-by-nc","license_id":"https://openalex.org/licenses/cc-by-nc","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie","raw_type":"journal-article"}],"best_oa_location":{"id":"doi:10.1002/ange.202113204","doi":"https://doi.org/10.1002/ange.202113204","is_oa":true,"landing_page_url":"https://doi.org/10.1002/ange.202113204","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/ange.202113204","source":{"id":"https://openalex.org/S4210200754","display_name":"Angewandte Chemie","issn_l":"0044-8249","issn":["0044-8249","0932-2140","1521-3757"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":"cc-by-nc","license_id":"https://openalex.org/licenses/cc-by-nc","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G1273626434","display_name":null,"funder_award_id":"1764328","funder_id":"https://openalex.org/F4320337393","funder_display_name":"Division of Chemistry"},{"id":"https://openalex.org/G1715034380","display_name":null,"funder_award_id":"Grants 21822303","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"},{"id":"https://openalex.org/G2916181936","display_name":"Experimental and Theoretical Investigations of Organic Reaction Rates and Mechanisms","funder_award_id":"1764328","funder_id":"https://openalex.org/F4320306076","funder_display_name":"National Science Foundation"},{"id":"https://openalex.org/G4073382726","display_name":null,"funder_award_id":"21822303","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"},{"id":"https://openalex.org/G4497227990","display_name":null,"funder_award_id":"2020B121201002","funder_id":"https://openalex.org/F4320327605","funder_display_name":"Southern University of Science and Technology"},{"id":"https://openalex.org/G6594473193","display_name":"\u94dc\u50ac\u5316\u5076\u8054\u53cd\u5e94\u4e2dCu(III)\u4e2d\u95f4\u4f53\u751f\u6210\u673a\u5236\u7684\u7406\u8bba\u7814\u7a76","funder_award_id":"21772020","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"},{"id":"https://openalex.org/G6778350887","display_name":"XSEDE: eXtreme Science and Engineering Discovery Environment","funder_award_id":"1053575","funder_id":"https://openalex.org/F4320306076","funder_display_name":"National Science Foundation"},{"id":"https://openalex.org/G6856223732","display_name":null,"funder_award_id":"CHE-1764328","funder_id":"https://openalex.org/F4320335353","funder_display_name":"National Science Foundation of Sri Lanka"},{"id":"https://openalex.org/G7579982596","display_name":null,"funder_award_id":"1053575","funder_id":"https://openalex.org/F4320337393","funder_display_name":"Division of Chemistry"},{"id":"https://openalex.org/G826464495","display_name":null,"funder_award_id":"CHE 1764328","funder_id":"https://openalex.org/F4320337393","funder_display_name":"Division of Chemistry"}],"funders":[{"id":"https://openalex.org/F4320306076","display_name":"National Science Foundation","ror":"https://ror.org/021nxhr62"},{"id":"https://openalex.org/F4320321001","display_name":"National Natural Science Foundation of China","ror":"https://ror.org/01h0zpd94"},{"id":"https://openalex.org/F4320327605","display_name":"Southern University of Science and Technology","ror":null},{"id":"https://openalex.org/F4320335353","display_name":"National Science Foundation of Sri Lanka","ror":"https://ror.org/010xaa060"},{"id":"https://openalex.org/F4320337393","display_name":"Division of Chemistry","ror":"https://ror.org/01ar8dr59"}],"has_content":{"grobid_xml":true,"pdf":true},"content_urls":{"pdf":"https://content.openalex.org/works/W4200603566.pdf","grobid_xml":"https://content.openalex.org/works/W4200603566.grobid-xml"},"referenced_works_count":78,"referenced_works":["https://openalex.org/W1964137366","https://openalex.org/W1975199590","https://openalex.org/W1980896239","https://openalex.org/W1995293569","https://openalex.org/W2011215428","https://openalex.org/W2023271753","https://openalex.org/W2048577460","https://openalex.org/W2057615451","https://openalex.org/W2067244774","https://openalex.org/W2067463586","https://openalex.org/W2067718414","https://openalex.org/W2069702158","https://openalex.org/W2074699411","https://openalex.org/W2084848421","https://openalex.org/W2085336624","https://openalex.org/W2085351645","https://openalex.org/W2117799813","https://openalex.org/W2118422638","https://openalex.org/W2120780345","https://openalex.org/W2123532053","https://openalex.org/W2125600700","https://openalex.org/W2129462844","https://openalex.org/W2148284063","https://openalex.org/W2150552994","https://openalex.org/W2150697053","https://openalex.org/W2156965499","https://openalex.org/W2160382554","https://openalex.org/W2164621073","https://openalex.org/W2167619363","https://openalex.org/W2194770644","https://openalex.org/W2216566446","https://openalex.org/W2320534486","https://openalex.org/W2326194138","https://openalex.org/W2327985527","https://openalex.org/W2333272049","https://openalex.org/W2338912942","https://openalex.org/W2343699080","https://openalex.org/W2398350748","https://openalex.org/W2400862364","https://openalex.org/W2418973097","https://openalex.org/W2493553275","https://openalex.org/W2516528742","https://openalex.org/W2519805142","https://openalex.org/W2520095744","https://openalex.org/W2531307683","https://openalex.org/W2574005770","https://openalex.org/W2582020932","https://openalex.org/W2586868915","https://openalex.org/W2609987954","https://openalex.org/W2736178248","https://openalex.org/W2752175890","https://openalex.org/W2784837692","https://openalex.org/W2812104124","https://openalex.org/W2890446973","https://openalex.org/W2897973547","https://openalex.org/W2904643181","https://openalex.org/W2917894724","https://openalex.org/W2931198309","https://openalex.org/W2949035687","https://openalex.org/W2952361683","https://openalex.org/W2971896945","https://openalex.org/W3015233666","https://openalex.org/W3082818105","https://openalex.org/W3092594256","https://openalex.org/W3111520907","https://openalex.org/W3113120675","https://openalex.org/W3139322041","https://openalex.org/W3202670038","https://openalex.org/W4230148186","https://openalex.org/W4231297099","https://openalex.org/W4234122749","https://openalex.org/W4234448662","https://openalex.org/W4236289913","https://openalex.org/W4236587001","https://openalex.org/W4250244584","https://openalex.org/W4253880665","https://openalex.org/W4255712830","https://openalex.org/W4255905373"],"related_works":["https://openalex.org/W6904824122","https://openalex.org/W1806446040","https://openalex.org/W4401608958","https://openalex.org/W2300306635","https://openalex.org/W4409725102","https://openalex.org/W2952908571","https://openalex.org/W2770485590","https://openalex.org/W4296693149","https://openalex.org/W2519805142","https://openalex.org/W2784837692"],"abstract_inverted_index":{"Abstract":[0],"Computations":[1],"and":[2,23,48],"experiments":[3],"leading":[4],"to":[5,39,50,65],"new":[6,41],"chiral":[7],"phosphoric":[8],"acids":[9],"(CPAs)":[10],"for":[11,77],"epoxide":[12,31,71],"thionations":[13],"are":[14,63],"reported.":[15],"Density":[16],"functional":[17],"theory":[18],"calculations":[19],"reveal":[20],"the":[21,26,57,61,67,70,73,78,85,88],"mechanism":[22],"origin":[24],"of":[25,28,60,69,87],"enantioselectivity":[27,86],"such":[29],"CPA\u2010catalyzed":[30],"thionations.":[32],"The":[33],"calculated":[34],"mechanistic":[35],"information":[36],"was":[37],"used":[38],"design":[40],"efficient":[42],"CPAs":[43],"that":[44],"were":[45],"tested":[46],"experimentally":[47],"found":[49],"be":[51],"highly":[52],"effective.":[53],"Bulky":[54],"ortho\u2010substituents":[55],"on":[56],"3,3\u2032\u2010aryl":[58],"groups":[59],"CPA":[62],"important":[64],"restrict":[66],"position":[68],"in":[72],"key":[74],"transition":[75],"states":[76],"enantioselectivity\u2010determining":[79],"step.":[80],"Larger":[81],"para\u2010substituents":[82],"significantly":[83],"improve":[84],"reaction.":[89]},"counts_by_year":[{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":6}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2021-12-31T00:00:00"}