{"id":"https://openalex.org/W4200399996","doi":"https://doi.org/10.1021/acsami.1c20128","title":"Unsaturated NiII Centers Mediated the Coordination Activation of Benzylamine for Enhancing Photocatalytic Activity over Ultrathin Ni MOF-74 Nanosheets","display_name":"Unsaturated NiII Centers Mediated the Coordination Activation of Benzylamine for Enhancing Photocatalytic Activity over Ultrathin Ni MOF-74 Nanosheets","publication_year":2021,"publication_date":"2021-12-14","ids":{"openalex":"https://openalex.org/W4200399996","doi":"https://doi.org/10.1021/acsami.1c20128","pmid":"https://pubmed.ncbi.nlm.nih.gov/34904825"},"language":"en","primary_location":{"id":"doi:10.1021/acsami.1c20128","doi":"https://doi.org/10.1021/acsami.1c20128","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acsami.1c20128","pdf_url":null,"source":{"id":"https://openalex.org/S164001016","display_name":"ACS Applied Materials & Interfaces","issn_l":"1944-8244","issn":["1944-8244","1944-8252"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-1","medline","norway-1","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Applied Materials &amp; Interfaces","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5072446837","display_name":"Taikang Wu","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I80947539","display_name":"Fuzhou University","ror":"https://ror.org/011xvna82","country_code":"CN","type":"education","lineage":["https://openalex.org/I80947539"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Taikang Wu","raw_affiliation_strings":["Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350116, P. R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350116, P. R. China","institution_ids":["https://openalex.org/I80947539"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5085201486","display_name":"Yingzhang Shi","orcid":"https://orcid.org/0009-0007-3235-8460","observed_orcids":["https://orcid.org/0009-0007-3235-8460"]},"institutions":[{"id":"https://openalex.org/I80947539","display_name":"Fuzhou University","ror":"https://ror.org/011xvna82","country_code":"CN","type":"education","lineage":["https://openalex.org/I80947539"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yingzhang Shi","raw_affiliation_strings":["Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350116, P. R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350116, P. R. China","institution_ids":["https://openalex.org/I80947539"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100362837","display_name":"Zhiwen Wang","orcid":"https://orcid.org/0000-0001-8938-3631","observed_orcids":["https://orcid.org/0000-0001-8938-3631","https://orcid.org/0009-0009-0127-7849"]},"institutions":[{"id":"https://openalex.org/I80947539","display_name":"Fuzhou University","ror":"https://ror.org/011xvna82","country_code":"CN","type":"education","lineage":["https://openalex.org/I80947539"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Zhiwen Wang","raw_affiliation_strings":["Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350116, P. R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350116, P. R. China","institution_ids":["https://openalex.org/I80947539"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5055930042","display_name":"Cheng Liu","orcid":"https://orcid.org/0000-0003-0288-4172","observed_orcids":["https://orcid.org/0000-0003-0288-4172"]},"institutions":[{"id":"https://openalex.org/I80947539","display_name":"Fuzhou University","ror":"https://ror.org/011xvna82","country_code":"CN","type":"education","lineage":["https://openalex.org/I80947539"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Cheng Liu","raw_affiliation_strings":["Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350116, P. R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350116, P. R. China","institution_ids":["https://openalex.org/I80947539"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5005665234","display_name":"Jinhong Bi","orcid":"https://orcid.org/0000-0002-8141-7742","observed_orcids":["https://orcid.org/0000-0002-8141-7742"]},"institutions":[{"id":"https://openalex.org/I80947539","display_name":"Fuzhou University","ror":"https://ror.org/011xvna82","country_code":"CN","type":"education","lineage":["https://openalex.org/I80947539"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Jinhong Bi","raw_affiliation_strings":["Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350116, P. R. China"],"raw_orcid":"https://orcid.org/0000-0002-8141-7742","affiliations":[{"raw_affiliation_string":"Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350116, P. R. China","institution_ids":["https://openalex.org/I80947539"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5078751587","display_name":"Yan Yu","orcid":"https://orcid.org/0000-0001-6748-2620","observed_orcids":["https://orcid.org/0000-0001-6748-2620","https://orcid.org/0009-0003-7707-3830"]},"institutions":[{"id":"https://openalex.org/I80947539","display_name":"Fuzhou University","ror":"https://ror.org/011xvna82","country_code":"CN","type":"education","lineage":["https://openalex.org/I80947539"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yan Yu","raw_affiliation_strings":["Key Laboratory of Eco-materials Advanced Technology, College of Materials Science and Engineering, Fuzhou University, Fuzhou 350108, P. R. China"],"raw_orcid":"https://orcid.org/0000-0001-6748-2620","affiliations":[{"raw_affiliation_string":"Key Laboratory of Eco-materials Advanced Technology, College of Materials Science and Engineering, Fuzhou University, Fuzhou 350108, P. R. China","institution_ids":["https://openalex.org/I80947539"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5075843083","display_name":"Ling Wu","orcid":"https://orcid.org/0000-0003-2652-8105","observed_orcids":["https://orcid.org/0000-0003-2652-8105","https://orcid.org/0000-0002-3341-3915"]},"institutions":[{"id":"https://openalex.org/I80947539","display_name":"Fuzhou University","ror":"https://ror.org/011xvna82","country_code":"CN","type":"education","lineage":["https://openalex.org/I80947539"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Ling Wu","raw_affiliation_strings":["Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350116, P. R. China"],"raw_orcid":"https://orcid.org/0000-0003-2652-8105","affiliations":[{"raw_affiliation_string":"Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350116, P. R. China","institution_ids":["https://openalex.org/I80947539"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5075843083"],"corresponding_institution_ids":["https://openalex.org/I80947539"],"apc_list":{"value":5000,"currency":"USD","value_usd":5000},"apc_paid":null,"fwci":2.199,"has_fulltext":false,"cited_by_count":48,"citation_normalized_percentile":{"value":0.88742952,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":98,"max":99},"biblio":{"volume":"13","issue":"51","first_page":"61286","last_page":"61295"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10096","display_name":"Metal-Organic Frameworks: Synthesis and Applications","score":0.9789999723434448,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10096","display_name":"Metal-Organic Frameworks: Synthesis and Applications","score":0.9789999723434448,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10078","display_name":"Advanced Photocatalysis Techniques","score":0.01850000023841858,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10024","display_name":"TiO2 Photocatalysis and Solar Cells","score":0.00039999998989515007,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/ni-mof-74","display_name":"Ni-MOF-74","score":0.9649999737739563},{"id":"https://openalex.org/keywords/ultrathin-nanosheets","display_name":"ultrathin nanosheets","score":0.9079999923706055},{"id":"https://openalex.org/keywords/visible-light-photocatalysis","display_name":"visible light photocatalysis","score":0.7799999713897705},{"id":"https://openalex.org/keywords/n-h-bond-cleavage","display_name":"N-H bond cleavage","score":0.8159999847412109},{"id":"https://openalex.org/keywords/photogenerated-charge-separation","display_name":"photogenerated charge separation","score":0.6050000190734863},{"id":"https://openalex.org/keywords/superoxide-radicals","display_name":"superoxide","score":0.7139999866485596},{"id":"https://openalex.org/keywords/heterogeneous-photocatalysis","display_name":"heterogeneous photocatalysis","score":0.6290000081062317}],"concepts":[{"id":"https://openalex.org/C65165184","wikidata":"https://www.wikidata.org/wiki/Q218831","display_name":"Photocatalysis","level":3,"score":0.8814952373504639},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.6772063970565796},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.6370867490768433},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.6331761479377747},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.619013249874115},{"id":"https://openalex.org/C139066938","wikidata":"https://www.wikidata.org/wiki/Q185056","display_name":"Radical","level":2,"score":0.5035557150840759},{"id":"https://openalex.org/C150394285","wikidata":"https://www.wikidata.org/wiki/Q180254","display_name":"Adsorption","level":2,"score":0.467481791973114},{"id":"https://openalex.org/C175708663","wikidata":"https://www.wikidata.org/wiki/Q899559","display_name":"X-ray photoelectron spectroscopy","level":2,"score":0.45099779963493347},{"id":"https://openalex.org/C2776276205","wikidata":"https://www.wikidata.org/wiki/Q424000","display_name":"Benzylamine","level":2,"score":0.43169182538986206},{"id":"https://openalex.org/C123669783","wikidata":"https://www.wikidata.org/wiki/Q902898","display_name":"Electron transfer","level":2,"score":0.4182650148868561},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.33441197872161865},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.20357483625411987},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.16805583238601685},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.15193194150924683},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.1200772225856781},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1021/acsami.1c20128","doi":"https://doi.org/10.1021/acsami.1c20128","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acsami.1c20128","pdf_url":null,"source":{"id":"https://openalex.org/S164001016","display_name":"ACS Applied Materials & Interfaces","issn_l":"1944-8244","issn":["1944-8244","1944-8252"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-1","medline","norway-1","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Applied Materials &amp; Interfaces","raw_type":"journal-article"},{"id":"pmid:34904825","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/34904825","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS applied materials & interfaces","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G6942272728","display_name":null,"funder_award_id":"21872032","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"}],"funders":[{"id":"https://openalex.org/F4320321001","display_name":"National Natural Science Foundation of China","ror":"https://ror.org/01h0zpd94"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":56,"referenced_works":["https://openalex.org/W2059829662","https://openalex.org/W2087373107","https://openalex.org/W2099581170","https://openalex.org/W2113737247","https://openalex.org/W2132512431","https://openalex.org/W2215709144","https://openalex.org/W2415259703","https://openalex.org/W2466841153","https://openalex.org/W2654495469","https://openalex.org/W2762436865","https://openalex.org/W2767692926","https://openalex.org/W2791958841","https://openalex.org/W2793492942","https://openalex.org/W2794088502","https://openalex.org/W2883042906","https://openalex.org/W2890136209","https://openalex.org/W2898365681","https://openalex.org/W2906581948","https://openalex.org/W2908025813","https://openalex.org/W2913379862","https://openalex.org/W2916591823","https://openalex.org/W2921131885","https://openalex.org/W2924619279","https://openalex.org/W2932568896","https://openalex.org/W2942998504","https://openalex.org/W2953401462","https://openalex.org/W2954092915","https://openalex.org/W2954591269","https://openalex.org/W2957431360","https://openalex.org/W2969531510","https://openalex.org/W2983953780","https://openalex.org/W2995827724","https://openalex.org/W3014911130","https://openalex.org/W3022080631","https://openalex.org/W3034585612","https://openalex.org/W3047078929","https://openalex.org/W3083180347","https://openalex.org/W3083910900","https://openalex.org/W3096835314","https://openalex.org/W3097342269","https://openalex.org/W3110276664","https://openalex.org/W3111113304","https://openalex.org/W3112530094","https://openalex.org/W3114620468","https://openalex.org/W3119772086","https://openalex.org/W3120803954","https://openalex.org/W3123655876","https://openalex.org/W3125202386","https://openalex.org/W3132590780","https://openalex.org/W3134018606","https://openalex.org/W3134219571","https://openalex.org/W3141509879","https://openalex.org/W3152873560","https://openalex.org/W3158839207","https://openalex.org/W3183351922","https://openalex.org/W3196218432"],"related_works":["https://openalex.org/W4407996261","https://openalex.org/W4401490893","https://openalex.org/W4400687890","https://openalex.org/W4396854548","https://openalex.org/W4327901991","https://openalex.org/W4321370758","https://openalex.org/W3085512487","https://openalex.org/W4411021272","https://openalex.org/W3185707065","https://openalex.org/W4388623759"],"abstract_inverted_index":{"Creating":[0],"accessible":[1],"unsaturated":[2,26],"active":[3,56],"sites":[4,57],"in":[5,38,159],"metal\u2013organic":[6],"frameworks":[7],"(MOFs)":[8],"holds":[9],"great":[10],"promise":[11],"for":[12,58,84,116,153,179,228,236],"developing":[13],"highly":[14],"efficient":[15],"catalysts.":[16],"Herein,":[17],"ultrathin":[18,238],"Ni":[19,27,49,163],"MOF-74":[20,164],"nanosheets":[21],"(NMNs)":[22],"with":[23,161,207],"high-density":[24],"coordinatively":[25],"II":[28,50],"centers":[29,51],"are":[30],"prepared":[31],"as":[32,54],"a":[33,132,150,167,171,202,215],"photocatalyst.":[34],"The":[35,70,103,120],"results":[36],"of":[37,72,78,94,100,127,143,156,175,184,195,225],"situ":[39],"ATR\u2013IR,":[40],"Raman,":[41],"UV\u2013vis":[42],"DRS,":[43],"and":[44,97,141,210],"XPS":[45],"suggest":[46],"that":[47,123,194],"abundant":[48],"can":[52],"act":[53],"the":[55,76,92,98,118,124,139,154,180,223],"boosting":[59],"benzylamine":[60],"(BA)":[61],"activation":[62,126,142,209,227],"via":[63],"forming":[64],"\u2212Ni\u2013NH":[65],"2":[66,109,113,145],"\u2013":[67],"coordination":[68,73,125,208,226],"intermediates.":[69],"generation":[71],"intermediates":[74],"assists":[75],"transfer":[77],"photo-generated":[79,104,157],"holes":[80],"to":[81,111],"BA":[82,86,101,128,185],"molecules":[83,110,129],"producing":[85],"cation":[87],"free":[88],"radicals,":[89],"better":[90,151],"impelling":[91],"breaking":[93],"N\u2013H":[95],"bonds":[96],"photooxidation":[99],"molecules.":[102,146],"electrons":[105],"further":[106],"activate":[107],"O":[108,112,144],"\u2022\u2013":[114],"radicals":[115],"triggering":[117],"reaction.":[119],"experiments":[121],"reveal":[122],"may":[130],"be":[131],"rate-determining":[133],"step":[134],"on":[135,214],"NMNs":[136,148,169],"rather":[137],"than":[138,193],"adsorption":[140],"Moreover,":[147],"possess":[149],"ability":[152],"separation":[155],"carriers":[158],"comparison":[160],"bulk":[162],"(NMBs).":[165],"As":[166],"result,":[168],"achieve":[170],"kinetic":[172],"rate":[173],"constant":[174],"0.538":[176],"h":[177,198],"\u20131":[178,199],"photocatalytic":[181],"oxidative":[182],"coupling":[183],"under":[186],"visible":[187],"light,":[188],"about":[189],"50":[190],"times":[191],"higher":[192],"NMBs":[196],"(0.0011":[197],").":[200],"Finally,":[201],"probable":[203],"synergetic":[204],"catalytic":[205],"mechanism":[206],"photocatalysis":[211,230],"is":[212],"discussed":[213],"molecular":[216],"level.":[217],"This":[218],"study":[219],"not":[220],"only":[221],"highlights":[222],"importance":[224],"heterogeneous":[229],"but":[231],"also":[232],"affords":[233],"an":[234],"inspiration":[235],"building":[237],"MOF":[239],"nanosheets.":[240]},"counts_by_year":[{"year":2026,"cited_by_count":9},{"year":2025,"cited_by_count":11},{"year":2024,"cited_by_count":7},{"year":2023,"cited_by_count":15},{"year":2022,"cited_by_count":6}],"updated_date":"2026-11-10T11:39:43.021295","created_date":"2021-12-31T00:00:00"}
