{"id":"https://openalex.org/W36630183","doi":null,"title":"The high-pressure structures and properties of \u03c4-Zr(HPO4)2","display_name":"The high-pressure structures and properties of \u03c4-Zr(HPO4)2","publication_year":2004,"publication_date":"2004-01-01","ids":{"openalex":"https://openalex.org/W36630183","mag":"36630183"},"language":"en","primary_location":{"id":"mag:36630183","doi":null,"is_oa":false,"landing_page_url":"http://www.diva-portal.org/smash/record.jsf?pid=diva2:191232","pdf_url":null,"source":null,"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null},"volume":null,"type":"article","indexed_in":[],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5111765689","display_name":"A.M. Krogh Andersen","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"A.M. Krogh Andersen","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5109344838","display_name":"Stefan Carlson","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Stefan Carlson","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.00258492,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11878","display_name":"Solid-state spectroscopy and crystallography","score":0.42820000648498535,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11878","display_name":"Solid-state spectroscopy and crystallography","score":0.42820000648498535,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10413","display_name":"High-pressure geophysics and materials","score":0.266400009393692,"subfield":{"id":"https://openalex.org/subfields/1908","display_name":"Geophysics"},"field":{"id":"https://openalex.org/fields/19","display_name":"Earth and Planetary Sciences"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10939","display_name":"Crystal Structures and Properties","score":0.06809999793767929,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/zirconium-hydrogen-phosphate","display_name":"zirconium hydrogen phosphate","score":0.7549999952316284},{"id":"https://openalex.org/keywords/pressure-induced-phase-transition","display_name":"pressure-induced phase transition","score":0.6079999804496765},{"id":"https://openalex.org/keywords/two-dimensional-layered-structure","display_name":"two-dimensional layered structure","score":0.5820000171661377},{"id":"https://openalex.org/keywords/three-dimensional-framework","display_name":"three-dimensional framework","score":0.7599999904632568},{"id":"https://openalex.org/keywords/phase-stability","display_name":"phase stability","score":0.5720000267028809},{"id":"https://openalex.org/keywords/reaction-kinetics","display_name":"reaction kinetics","score":0.7850000262260437},{"id":"https://openalex.org/keywords/hydrothermal-synthesis","display_name":"hydrothermal synthesis","score":0.8140000104904175},{"id":"https://openalex.org/keywords/pyrophosphate","display_name":"pyrophosphate","score":0.8479999899864197},{"id":"https://openalex.org/keywords/pyrovanadate","display_name":"pyrovanadate","score":0.9869999885559082},{"id":"https://openalex.org/keywords/molybdate","display_name":"molybdate","score":0.8629999756813049},{"id":"https://openalex.org/keywords/thermal-expansion","display_name":"thermal expansion","score":0.7620000243186951},{"id":"https://openalex.org/keywords/compressibility","display_name":"compressibility","score":0.9810000061988831}],"concepts":[{"id":"https://openalex.org/C37243968","wikidata":"https://www.wikidata.org/wiki/Q648961","display_name":"Orthorhombic crystal system","level":3,"score":0.8093205690383911},{"id":"https://openalex.org/C170751736","wikidata":"https://www.wikidata.org/wiki/Q503601","display_name":"Tetragonal crystal system","level":3,"score":0.7329147458076477},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.5804630517959595},{"id":"https://openalex.org/C115645028","wikidata":"https://www.wikidata.org/wiki/Q902629","display_name":"Rietveld refinement","level":3,"score":0.5502108931541443},{"id":"https://openalex.org/C44280652","wikidata":"https://www.wikidata.org/wiki/Q104837","display_name":"Phase (matter)","level":2,"score":0.547691822052002},{"id":"https://openalex.org/C185039092","wikidata":"https://www.wikidata.org/wiki/Q376044","display_name":"Powder diffraction","level":2,"score":0.5189311504364014},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.4727792739868164},{"id":"https://openalex.org/C156622251","wikidata":"https://www.wikidata.org/wiki/Q1036221","display_name":"Hydrothermal circulation","level":2,"score":0.442371129989624},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.43849965929985046},{"id":"https://openalex.org/C59061564","wikidata":"https://www.wikidata.org/wiki/Q7783071","display_name":"Thermal stability","level":2,"score":0.4255949854850769},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.3844636082649231},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.21870523691177368},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.0},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"mag:36630183","doi":null,"is_oa":false,"landing_page_url":"http://www.diva-portal.org/smash/record.jsf?pid=diva2:191232","pdf_url":null,"source":null,"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":33,"referenced_works":["https://openalex.org/W654883890","https://openalex.org/W1969186778","https://openalex.org/W1998203489","https://openalex.org/W2023081218","https://openalex.org/W2046217022","https://openalex.org/W2048175288","https://openalex.org/W2084315798","https://openalex.org/W2091194550","https://openalex.org/W2109334244","https://openalex.org/W2119274021","https://openalex.org/W2164591389","https://openalex.org/W2168891894","https://openalex.org/W2178527379","https://openalex.org/W2291443053","https://openalex.org/W2595110790","https://openalex.org/W2624469506","https://openalex.org/W2757437757","https://openalex.org/W2794102241","https://openalex.org/W2803674881","https://openalex.org/W2912654919","https://openalex.org/W2913614159","https://openalex.org/W2921561928","https://openalex.org/W2946661342","https://openalex.org/W2947722878","https://openalex.org/W2961020354","https://openalex.org/W2991582092","https://openalex.org/W3022227971","https://openalex.org/W3082490768","https://openalex.org/W3129649658","https://openalex.org/W3156926718","https://openalex.org/W3194585947","https://openalex.org/W4282570432","https://openalex.org/W4293776637"],"related_works":["https://openalex.org/W7062285753","https://openalex.org/W60099229","https://openalex.org/W2159362988","https://openalex.org/W2952658830","https://openalex.org/W1828416028","https://openalex.org/W1966324319","https://openalex.org/W1988158563","https://openalex.org/W2470939662","https://openalex.org/W2001280945","https://openalex.org/W2946436009"],"abstract_inverted_index":{"This":[0],"thesis":[1],"is":[2],"concerned":[3],"with":[4,21,48,59,73],"in-situ":[5],"time-,":[6],"temperature-":[7],"and":[8,25,37,57,66,84,94,119,128,142,148,179,195,212,219,228,240,242,276,299,306,319],"pressure-resolved":[9],"synchrotron":[10],"X-ray":[11,278],"powder":[12],"diffraction":[13],"investigations":[14],"of":[15,18,92,96,110,204,224,236,287,293,312],"a":[16,265],"variety":[17],"inorganic":[19],"compounds":[20],"twodimensional":[22],"layer":[23],"structures":[24,189],"three-dimensional":[26,135],"framework":[27],"structures.":[28],"In":[29,106,154],"particular,":[30],"phase":[31,137,266],"stability,":[32],"reaction":[33],"kinetics,":[34],"thermal":[35],"expansion":[36],"compressibility":[38],"at":[39,125,176,184,217,268,280,304],"non-ambient":[40],"conditions":[41],"has":[42,264],"been":[43],"studied":[44,102,247],"for":[45,88],"1)":[46],"Phosphates":[47],"composition":[49,60,74],"MIV(HPO4)2\u00b7nH2O":[50],"(MIV":[51,62],"=":[52,63,68],"Ti,":[53,64],"Zr);":[54],"2)":[55],"Pyrophosphates":[56],"pyrovanadates":[58],"MIVX2O7":[61],"Zr":[65],"X":[67],"P,":[69],"V);":[70],"3)":[71],"Molybdates":[72],"ZrMo2O8.":[75],"The":[76,170,222,310],"results":[77],"are":[78],"compiled":[79],"in":[80,99],"seven":[81],"published":[82],"papers":[83],"two":[85,163,207,294],"manuscripts.Reaction":[86],"kinetics":[87],"the":[89,107,151,155,180,198,231,237,243,259,291,322],"hydrothermal":[90],"synthesis":[91],"\u03b1-Ti(HPO4)2\u00b7H2O":[93],"intercalation":[95],"alkane":[97],"diamines":[98],"\u03b1-Zr(HPO4)2\u00b7H2O":[100],"was":[101,140,146,226,314],"using":[103,150,192,197,230,321],"time-resolved":[104],"experiments.":[105],"high-temperature":[108,156],"transformation":[109,157,267],"\u03b3-Ti(PO4)(H2PO4)\u00b72H2O":[111],"to":[112,123,160,249,258,273],"TiP2O7":[113],"three":[114],"intermediate":[115,166,172],"phases,":[116,209,296],"\u03b3'-Ti(PO4)(H2PO4)\u00b7(2-x)H2O,":[117],"\u03b2-Ti(PO4)(H2PO4)":[118],"Ti(PO4)(H2P2O7)0.5":[120],"were":[121,168,190,246],"found":[122],"crystallise":[124,216],"323,":[126],"373":[127],"748":[129],"K,":[130,178],"respectively.":[131,309],"A":[132],"new":[133,164,208,295],"tetragonal":[134,210],"phosphate":[136],"called":[138],"\u03c4-Zr(HPO4)2":[139,159,205],"prepared,":[141],"subsequently":[143],"its":[144],"structure":[145,223,311],"determined":[147],"refined":[149,196,229,320],"Rietveld":[152,199,232,323],"method.":[153,200,324],"from":[158,271],"cubic":[161,272],"\u03b1-ZrP2O7":[162],"orthorhombic":[165,213],"phases":[167],"found.":[169],"first":[171],"phase,":[173,182],"\u03c1-Zr(HPO4)2,":[174],"forms":[175],"598":[177],"second":[181],"\u03b2-ZrP2O7,":[183],"688":[185],"K.":[186],"Their":[187],"respective":[188],"solved":[191,227,315],"direct":[193,317],"methods":[194,318],"In-situ":[201],"high-pressure":[202,234,285],"studies":[203,286],"revealed":[206,290],"\u03bd-Zr(HPO4)2":[211,225],"\u03c9-Zr(HPO4)2":[214],"that":[215,302],"1.1":[218,305],"8.2":[220],"GPa.":[221,251],"method.The":[233],"properties":[235],"pyrophosphates":[238,253],"ZrP2O7":[239],"TiP2O7,":[241],"pyrovanadate":[244],"ZrV2O7":[245,263],"up":[248,257],"40":[250],"Both":[252],"display":[254],"smooth":[255],"compression":[256],"highest":[260],"pressures,":[261],"while":[262],"1.38":[269],"GPa":[270],"pseudo-tetragonal":[274],"\u03b2-ZrV2O7":[275],"becomes":[277],"amorphous":[279],"pressures":[281],"above":[282],"4":[283],"GPa.In-situ":[284],"trigonal":[288],"\u03b1-ZrMo2O8":[289],"existence":[292],"monoclinic":[297],"\u03b4-ZrMo2O8":[298,313],"triclinic":[300],"e-ZrMo2O8":[301],"crystallises":[303],"2.5":[307],"GPa,":[308],"by":[316]},"counts_by_year":[],"updated_date":"2026-09-29T14:09:16.559479","created_date":"2016-06-24T00:00:00"}