{"id":"https://openalex.org/W33977593","doi":null,"title":"\u4e0d\u540c\u524d\u9a71\u4f53\u5236\u5907\u7684Mn-H4SiW12O40/SiO2\u50ac\u5316\u5242\u5bf9\u4e8c\u7532\u919a\u50ac\u5316\u6c27\u5316\u5236\u53d6\u7532\u7f29\u919b\u53cd\u5e94\u6027\u80fd\u7684\u5f71\u54cd","display_name":"\u4e0d\u540c\u524d\u9a71\u4f53\u5236\u5907\u7684Mn-H4SiW12O40/SiO2\u50ac\u5316\u5242\u5bf9\u4e8c\u7532\u919a\u50ac\u5316\u6c27\u5316\u5236\u53d6\u7532\u7f29\u919b\u53cd\u5e94\u6027\u80fd\u7684\u5f71\u54cd","publication_year":2007,"publication_date":"2007-01-01","ids":{"openalex":"https://openalex.org/W33977593","mag":"33977593"},"language":"zh-cn","primary_location":{"id":"mag:33977593","doi":null,"is_oa":false,"landing_page_url":"http://www.irgrid.ac.cn/handle/1471x/123548","pdf_url":null,"source":{"id":"https://openalex.org/S4306554486","display_name":"\u71c3\u6599\u5316\u5b66\u5b66\u62a5","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"journal"},"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":"\u71c3\u6599\u5316\u5b66\u5b66\u62a5","raw_type":null},"volume":null,"type":"article","is_traditional":true,"indexed_in":[],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":null,"display_name":"\u5f20\u6e05\u5fb7","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"\u5f20\u6e05\u5fb7","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5036684904","display_name":"\u8c2d\u7317\u751f","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"\u8c2d\u7317\u751f","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5005360580","display_name":"\u6768\u5f69\u8679","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"\u6768\u5f69\u8679","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5055723938","display_name":"\u97e9\u6021\u5353","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"\u97e9\u6021\u5353","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.00293403,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":"35","issue":"2","first_page":"207","last_page":"210"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11286","display_name":"Polyoxometalates: Synthesis and Applications","score":0.7314000129699707,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11286","display_name":"Polyoxometalates: Synthesis and Applications","score":0.7314000129699707,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11825","display_name":"Catalysis and Oxidation Reactions","score":0.23280000686645508,"subfield":{"id":"https://openalex.org/subfields/1503","display_name":"Catalysis"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10353","display_name":"Zeolite Catalysis and Synthesis","score":0.01080000028014183,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/dimethyl-ether-oxidation","display_name":"dimethyl ether oxidation","score":0.7360000014305115},{"id":"https://openalex.org/keywords/heteropolyacid-catalysts","display_name":"heteropolyacid catalysts","score":0.8209999799728394},{"id":"https://openalex.org/keywords/manganese-chloride","display_name":"manganese chloride","score":0.3930000066757202},{"id":"https://openalex.org/keywords/manganese-sulfate","display_name":"manganese sulfate","score":0.5950000286102295},{"id":"https://openalex.org/keywords/manganese-acetate","display_name":"manganese acetate","score":0.6600000262260437},{"id":"https://openalex.org/keywords/manganese-nitrate","display_name":"manganese nitrate","score":0.9890000224113464},{"id":"https://openalex.org/keywords/catalyst-preparation","display_name":"catalyst preparation","score":0.3869999945163727},{"id":"https://openalex.org/keywords/reaction-temperature-effects","display_name":"reaction temperature effects","score":0.5450000166893005},{"id":"https://openalex.org/keywords/selectivity","display_name":"selectivity","score":0.47200000286102295}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.32798415422439575}],"mesh":[],"locations_count":1,"locations":[{"id":"mag:33977593","doi":null,"is_oa":false,"landing_page_url":"http://www.irgrid.ac.cn/handle/1471x/123548","pdf_url":null,"source":{"id":"https://openalex.org/S4306554486","display_name":"\u71c3\u6599\u5316\u5b66\u5b66\u62a5","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"journal"},"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":"\u71c3\u6599\u5316\u5b66\u5b66\u62a5","raw_type":null}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320334705","display_name":"National Health and Medical Research Council","ror":"https://ror.org/011kf5r70"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":50,"referenced_works":["https://openalex.org/W1985117435","https://openalex.org/W1989188472","https://openalex.org/W1997226402","https://openalex.org/W2006749039","https://openalex.org/W2007215297","https://openalex.org/W2009777674","https://openalex.org/W2014612827","https://openalex.org/W2020260928","https://openalex.org/W2021627286","https://openalex.org/W2027197889","https://openalex.org/W2040066248","https://openalex.org/W2046703988","https://openalex.org/W2048056998","https://openalex.org/W2058179492","https://openalex.org/W2065504943","https://openalex.org/W2070457596","https://openalex.org/W2083850806","https://openalex.org/W2090433349","https://openalex.org/W2097295599","https://openalex.org/W2098886423","https://openalex.org/W2103920106","https://openalex.org/W2109671400","https://openalex.org/W2121053402","https://openalex.org/W2126396720","https://openalex.org/W2141642891","https://openalex.org/W2142745453","https://openalex.org/W2147267208","https://openalex.org/W2151746400","https://openalex.org/W2166461214","https://openalex.org/W2167357721","https://openalex.org/W2200420822","https://openalex.org/W2209585205","https://openalex.org/W2253902140","https://openalex.org/W2329987517","https://openalex.org/W2337789354","https://openalex.org/W2343450311","https://openalex.org/W2523369352","https://openalex.org/W2526691204","https://openalex.org/W2607059365","https://openalex.org/W2622476014","https://openalex.org/W2764314901","https://openalex.org/W2889634295","https://openalex.org/W2936218101","https://openalex.org/W2995482720","https://openalex.org/W3005549563","https://openalex.org/W3093191237","https://openalex.org/W6761181208","https://openalex.org/W6967318991","https://openalex.org/W7073846576","https://openalex.org/W7075717053"],"related_works":["https://openalex.org/W1164740397","https://openalex.org/W1991427205","https://openalex.org/W1981800839","https://openalex.org/W2024796080","https://openalex.org/W1012743338","https://openalex.org/W1141217615","https://openalex.org/W953806468","https://openalex.org/W6988777213","https://openalex.org/W2409787453","https://openalex.org/W1011433343"],"abstract_inverted_index":{"\u91c7\u7528\u6d78\u6e0d\u6cd5\u5206\u522b\u7528\u786b\u9178\u9530\u3001\u918b\u9178\u9530\u3001\u6c2f\u5316\u9530\u548c\u785d\u9178\u9530\u4e3a\u539f\u6599\u5236\u5907\u4e86Mn-H4SiW12O40\uff0fSiO2\u6742\u591a\u9178\u50ac\u5316\u5242\u3002\u5728\u5e38\u538b\u8fde\u7eed\u6d41\u52a8\u56fa\u5b9a\u5e8a\u53cd\u5e94\u5668\u4e2d\uff0c\u8003\u5bdf\u4e86\u4e8c\u7532\u919a\u9009\u62e9\u6c27\u5316\u5236\u53d6\u7532\u7f29\u919b\u7684\u53cd\u5e94\u6d3b\u6027\u3002\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\uff0c\u50ac\u5316\u5242\u7684\u50ac\u5316\u6d3b\u6027\u987a\u5e8f\u4e3aMnCl2-H4SiW12O40\uff0fSiO2\u3009Mn\uff08NO3\uff092-H4SiW12O40\uff0fSiO2\u3009MnSO4-H4SiW12O40\uff0fSiO2\u3009Mn\uff08AC\uff092-H4SiW12O40\uff0fSiO2\u3002\u5e76\u8fdb\u4e00\u6b65\u8003\u5bdf\u4e86\u53cd\u5e94\u6e29\u5ea6\u5bf9\u4e0d\u540c\u9530\u76d0\u524d\u9a71\u4f53\u50ac\u5316\u5242\u6027\u80fd\u7684\u5f71\u54cd\u3002\u7ed3\u679c\u8868\u660e\uff0c\u968f\u6e29\u5ea6\u7684\u5347\u9ad8\uff0c\u786b\u9178\u9530\u4fee\u9970\u7684H4SiW12O40\uff0fSiO2\u50ac\u5316\u5242\u50ac\u5316\u6c27\u5316\u6bd4\u8f83\u5267\u70c8\uff0c\u5728613K\u65f6\u4e8c\u7532\u919a\u8f6c\u5316\u7387\u9ad8\u8fbe42\uff0e4\uff05\uff0c\u4f46\u6b64\u65f6\u7532\u7f29\u919b\u9009\u62e9\u6027\u4ec5\u4e3a0\uff0e9\uff05\u3002\u91c7\u7528\u6c2f\u5316\u9530\u4fee\u9970\u7684H4SiW12O40\uff0fSiO2\u50ac\u5316\u5242\uff0c\u4e8c\u7532\u919a\u50ac\u5316\u6c27\u5316\u53cd\u5e94\u8f83\u7f13\u548c\uff0c\u5e76\u4e14\u7532\u7f29\u919b\u7684\u9009\u62e9\u6027\u660e\u663e\u9ad8\u4e8e\u5206\u522b\u91c7\u7528\u786b\u9178\u9530\u3001\u918b\u9178\u9530\u548c\u785d\u9178\u9530\u6539\u6027\u7684\u50ac\u5316\u5242\uff0c\u5728593K\u53cd\u5e941h\u65f6\uff0c\u4e8c\u7532\u919a\u8f6c\u5316\u7387\u4e3a8\uff0e6\uff05\uff0c\u7532\u7f29\u919b\u9009\u62e9\u6027\u8fbe\u523037\uff0e5\uff05\u3002H2-TPR\u7ed3\u679c\u663e\u793a\uff0c\u786b\u9178\u9530\u6539\u6027\u7684\u50ac\u5316\u5242\u9ad8\u6e29\u6c27\u5316\u6027\u80fd\u660e\u663e\u5f3a\u4e8e\u53e6\u5916\u4e09\u79cd\u50ac\u5316\u5242\uff0c\u6c2f\u5316\u9530\u7684\u4fee\u9970\u4f7f\u5f97\u50ac\u5316\u5242\u7684\u4f4e\u6e29\u6c27\u5316\u6027\u80fd\u53d8\u5f3a\u3002XRD\u7ed3\u679c\u8868\u660e\uff0cMnCl2-H4SiW12O40\uff0fSiO2\u50ac\u5316\u5242\u7684\u884d\u5c04\u7279\u5f81\u5cf0\u660e\u663e\u5f3a\u4e8e\u5176\u4ed6\u4e09\u79cd\u50ac\u5316\u5242\uff0c\u5e76\u4e14\u53d1\u73b0\u4e86MnO2\u884d\u5c04\u7279\u5f81\u5cf0\u3002":[0]},"counts_by_year":[],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2016-06-24T00:00:00"}