{"id":"https://openalex.org/W333397242","doi":"https://doi.org/10.21236/ad0643933","title":"SYNTHESIS OF SILICON COMPOUNDS","display_name":"SYNTHESIS OF SILICON COMPOUNDS","publication_year":1966,"publication_date":"1966-06-01","ids":{"openalex":"https://openalex.org/W333397242","doi":"https://doi.org/10.21236/ad0643933","mag":"333397242"},"language":"en","primary_location":{"id":"doi:10.21236/ad0643933","doi":"https://doi.org/10.21236/ad0643933","is_oa":false,"landing_page_url":"https://doi.org/10.21236/ad0643933","pdf_url":null,"source":{"id":"https://openalex.org/S4406923043","display_name":"Defense Technical Information Center (DTIC)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"OSD or Non-Service DoD Agency","raw_type":"report"},"volume":null,"type":"report","is_traditional":false,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5056394084","display_name":"Eduard W. Krah\u00e9","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":true,"raw_author_name":"Eduard Krahe","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":["https://openalex.org/A5056394084"],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":null,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":null,"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11441","display_name":"Organoboron and organosilicon chemistry","score":0.7318999767303467,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11441","display_name":"Organoboron and organosilicon chemistry","score":0.7318999767303467,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12420","display_name":"Silicone and Siloxane Chemistry","score":0.1875,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.06909999996423721,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/organosilicon-compounds","display_name":"organosilicon compounds","score":0.7400000095367432},{"id":"https://openalex.org/keywords/gold-silicon-alloys","display_name":"gold-silicon alloys","score":0.8270000219345093},{"id":"https://openalex.org/keywords/methylchlorosilanes","display_name":"methylchlorosilanes","score":0.9200000166893005},{"id":"https://openalex.org/keywords/chloromethane","display_name":"methyl chloride","score":0.7639999985694885},{"id":"https://openalex.org/keywords/gold-contamination","display_name":"gold contamination","score":0.5799999833106995},{"id":"https://openalex.org/keywords/gold-dust","display_name":"gold dust","score":0.5049999952316284},{"id":"https://openalex.org/keywords/methanol","display_name":"methanol","score":0.7239999771118164},{"id":"https://openalex.org/keywords/ethers","display_name":"ethers","score":0.9660000205039978},{"id":"https://openalex.org/keywords/direct-synthesis","display_name":"direct synthesis","score":0.45100000500679016}],"concepts":[{"id":"https://openalex.org/C2778736354","wikidata":"https://www.wikidata.org/wiki/Q422789","display_name":"Organosilicon","level":2,"score":0.9439154863357544},{"id":"https://openalex.org/C18168003","wikidata":"https://www.wikidata.org/wiki/Q628595","display_name":"Eutectic system","level":3,"score":0.8076106309890747},{"id":"https://openalex.org/C544956773","wikidata":"https://www.wikidata.org/wiki/Q670","display_name":"Silicon","level":2,"score":0.7345678806304932},{"id":"https://openalex.org/C40875361","wikidata":"https://www.wikidata.org/wiki/Q2356542","display_name":"Reagent","level":2,"score":0.6545472145080566},{"id":"https://openalex.org/C2779607525","wikidata":"https://www.wikidata.org/wiki/Q14982","display_name":"Methanol","level":2,"score":0.5617381930351257},{"id":"https://openalex.org/C2778695967","wikidata":"https://www.wikidata.org/wiki/Q44791900","display_name":"Chloride","level":2,"score":0.5540748834609985},{"id":"https://openalex.org/C2780407432","wikidata":"https://www.wikidata.org/wiki/Q103230","display_name":"Ether","level":2,"score":0.4817514419555664},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.4459567070007324},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.4376462996006012},{"id":"https://openalex.org/C2780026712","wikidata":"https://www.wikidata.org/wiki/Q37756","display_name":"Alloy","level":2,"score":0.4207671880722046},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.40941494703292847},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.38697564601898193},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.21236/ad0643933","doi":"https://doi.org/10.21236/ad0643933","is_oa":false,"landing_page_url":"https://doi.org/10.21236/ad0643933","pdf_url":null,"source":{"id":"https://openalex.org/S4406923043","display_name":"Defense Technical Information Center (DTIC)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"OSD or Non-Service DoD Agency","raw_type":"report"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2060251255","https://openalex.org/W2043011443","https://openalex.org/W2005931126","https://openalex.org/W7009208852","https://openalex.org/W2042509634","https://openalex.org/W1971229925","https://openalex.org/W1971432803","https://openalex.org/W2001580435","https://openalex.org/W2738430584","https://openalex.org/W4252712823"],"abstract_inverted_index":{"Abstract":[0],":":[1],"There":[2],"is":[3,12],"only":[4,90],"one":[5],"binary":[6],"alloy":[7],"system":[8],"of":[9,17,19,30,36,45,52,56,62,85,95,152],"silicon":[10,37],"which":[11,96],"liquid":[13,33],"below":[14],"the":[15,25,42,53,60,82,86,93,126,130],"temperature":[16],"decomposition":[18],"methyl":[20,119],"chloride,":[21],"alcohol,":[22],"and":[23,80,121,154],"ether:":[24],"gold-silicon":[26,122],"system.":[27],"The":[28,103,143,156],"possibility":[29],"using":[31],"a":[32,134],"eutectic":[34],"form":[35],"as":[38,136,140],"starting":[39],"material":[40],"for":[41,111],"direct":[43],"synthesis":[44],"organosilicon":[46],"compounds":[47],"was":[48,70,146],"so":[49,81],"inviting,":[50],"because":[51],"constant":[54],"exposure":[55],"fresh":[57],"surface":[58],"to":[59,137],"stream":[61],"organic":[63],"reagent,":[64],"that":[65,72,108,125],"experiments":[66,104],"were":[67],"undertaken.":[68],"It":[69],"expected":[71],"no":[73],"gold":[74,87,127],"would":[75,88],"be":[76,98,138],"consumed":[77],"or":[78],"transported,":[79],"high":[83],"price":[84],"represent":[89],"capital":[91],"investment,":[92],"cost":[94],"might":[97],"overbalanced":[99],"by":[100],"operational":[101],"advantages.":[102],"reported":[105],"here":[106],"show":[107],"methylchlorosilanes":[109],"(intermediates":[110],"making":[112],"silicone":[113],"polymers)":[114],"are":[115],"indeed":[116],"produced":[117],"from":[118],"chloride":[120],"alloy,":[123],"but":[124],"enters":[128],"into":[129],"reaction":[131],"in":[132],"such":[133],"way":[135],"transported":[139],"fine":[141],"dust.":[142],"chemical":[144],"change":[145],"studied":[147],"intensively,":[148],"along":[149],"with":[150,159],"reactions":[151],"methanol":[153],"ethers.":[155],"report":[157],"concludes":[158],"some":[160],"work":[161],"on":[162],"organoboran":[163],"chlorides.":[164]},"counts_by_year":[],"updated_date":"2026-11-06T12:05:46.655746","created_date":"2016-06-24T00:00:00"}