{"id":"https://openalex.org/W3207871969","doi":"https://doi.org/10.1002/anie.202111988","title":"Critical Assessment of the Reducing Ability of Breslow\u2010type Derivatives and Implications for Carbene\u2010Catalyzed Radical Reactions**","display_name":"Critical Assessment of the Reducing Ability of Breslow\u2010type Derivatives and Implications for Carbene\u2010Catalyzed Radical Reactions**","publication_year":2021,"publication_date":"2021-10-15","ids":{"openalex":"https://openalex.org/W3207871969","doi":"https://doi.org/10.1002/anie.202111988","mag":"3207871969","pmid":"https://pubmed.ncbi.nlm.nih.gov/34651408","pmcid":"https://www.ncbi.nlm.nih.gov/pmc/articles/9299025"},"language":"en","primary_location":{"id":"doi:10.1002/anie.202111988","doi":"https://doi.org/10.1002/anie.202111988","is_oa":true,"landing_page_url":"https://doi.org/10.1002/anie.202111988","pdf_url":null,"source":{"id":"https://openalex.org/S67393510","display_name":"Angewandte Chemie International Edition","issn_l":"1433-7851","issn":["1433-7851","1521-3773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie International Edition","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"hybrid","oa_url":"https://doi.org/10.1002/anie.202111988","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5039457179","display_name":"Ludivine Delfau","orcid":"https://orcid.org/0009-0002-3629-4218","observed_orcids":["https://orcid.org/0009-0002-3629-4218"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210099103","display_name":"D\u00e9partement de Chimie Mol\u00e9culaire","ror":"https://ror.org/010rs2a38","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I4210099103","https://openalex.org/I4210128300","https://openalex.org/I899635006"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Ludivine Delfau","raw_affiliation_strings":["Univ. Grenoble Alpes CNRS DCM  38000 Grenoble France"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Univ. Grenoble Alpes CNRS DCM  38000 Grenoble France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210099103"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5050738846","display_name":"Samantha Nichilo","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210099103","display_name":"D\u00e9partement de Chimie Mol\u00e9culaire","ror":"https://ror.org/010rs2a38","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I4210099103","https://openalex.org/I4210128300","https://openalex.org/I899635006"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Samantha Nichilo","raw_affiliation_strings":["Univ. Grenoble Alpes CNRS DCM  38000 Grenoble France"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Univ. Grenoble Alpes CNRS DCM  38000 Grenoble France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210099103"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5010427376","display_name":"Florian Molton","orcid":"https://orcid.org/0000-0001-6675-5551","observed_orcids":["https://orcid.org/0000-0001-6675-5551"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210099103","display_name":"D\u00e9partement de Chimie Mol\u00e9culaire","ror":"https://ror.org/010rs2a38","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I4210099103","https://openalex.org/I4210128300","https://openalex.org/I899635006"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Florian Molton","raw_affiliation_strings":["Univ. Grenoble Alpes CNRS DCM  38000 Grenoble France"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Univ. Grenoble Alpes CNRS DCM  38000 Grenoble France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210099103"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5010706054","display_name":"Julie Broggi","orcid":"https://orcid.org/0000-0003-4309-8004","observed_orcids":["https://orcid.org/0000-0003-4309-8004"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I21491767","display_name":"Aix-Marseille Universit\u00e9","ror":"https://ror.org/035xkbk20","country_code":"FR","type":"education","lineage":["https://openalex.org/I21491767"]},{"id":"https://openalex.org/I4210091534","display_name":"Institut de Chimie Radicalaire","ror":"https://ror.org/000d5zy28","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I21491767","https://openalex.org/I4210091534","https://openalex.org/I4210128300"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Julie Broggi","raw_affiliation_strings":["Aix Marseille Univ CNRS Institut de Chimie Radicalaire (ICR)  27 Bd Jean Moulin 13385 Marseille France","ICR - Institut de Chimie Radicalaire (Avenue Escadrille Normandie-Niemen \r\nService D42 \r\n13397 Marseille cedex 20 - France)"],"raw_orcid":"https://orcid.org/0000-0003-4309-8004","affiliations":[{"raw_affiliation_string":"Aix Marseille Univ CNRS Institut de Chimie Radicalaire (ICR)  27 Bd Jean Moulin 13385 Marseille France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I21491767","https://openalex.org/I4210091534"]},{"raw_affiliation_string":"ICR - Institut de Chimie Radicalaire (Avenue Escadrille Normandie-Niemen \r\nService D42 \r\n13397 Marseille cedex 20 - France)","institution_ids":["https://openalex.org/I4210091534"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5025100690","display_name":"Eder Tom\u00e1s\u2010Mendivil","orcid":"https://orcid.org/0000-0002-4247-6731","observed_orcids":["https://orcid.org/0000-0002-4247-6731"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210099103","display_name":"D\u00e9partement de Chimie Mol\u00e9culaire","ror":"https://ror.org/010rs2a38","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I4210099103","https://openalex.org/I4210128300","https://openalex.org/I899635006"]}],"countries":["FR"],"is_corresponding":true,"raw_author_name":"Eder Tom\u00e1s\u2010Mendivil","raw_affiliation_strings":["Univ. Grenoble Alpes CNRS DCM  38000 Grenoble France"],"raw_orcid":"https://orcid.org/0000-0002-4247-6731","affiliations":[{"raw_affiliation_string":"Univ. Grenoble Alpes CNRS DCM  38000 Grenoble France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210099103"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5009617769","display_name":"David Mart\u00edn","orcid":"https://orcid.org/0000-0002-3257-9876","observed_orcids":["https://orcid.org/0000-0002-3257-9876"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210099103","display_name":"D\u00e9partement de Chimie Mol\u00e9culaire","ror":"https://ror.org/010rs2a38","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I4210099103","https://openalex.org/I4210128300","https://openalex.org/I899635006"]}],"countries":["FR"],"is_corresponding":true,"raw_author_name":"David Martin","raw_affiliation_strings":["Univ. Grenoble Alpes CNRS DCM  38000 Grenoble France"],"raw_orcid":"https://orcid.org/0000-0002-3257-9876","affiliations":[{"raw_affiliation_string":"Univ. Grenoble Alpes CNRS DCM  38000 Grenoble France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210099103"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":4,"corresponding_author_ids":["https://openalex.org/A5009617769","https://openalex.org/A5025100690"],"corresponding_institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210099103"],"apc_list":{"value":5000,"currency":"USD","value_usd":5000},"apc_paid":{"value":5000,"currency":"USD","value_usd":5000},"fwci":8.2585,"has_fulltext":false,"cited_by_count":115,"citation_normalized_percentile":{"value":0.99250151,"is_in_top_1_percent":true,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":92,"max":100},"biblio":{"volume":"60","issue":"51","first_page":"26783","last_page":"26789"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11790","display_name":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","score":0.9984999895095825,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11790","display_name":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","score":0.9984999895095825,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10701","display_name":"Radical Photochemical Reactions","score":0.0003000000142492354,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12191","display_name":"Physical Organic Chemistry and Reaction Kinetics","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/reducing-ability","display_name":"reducing ability","score":0.6420000195503235},{"id":"https://openalex.org/keywords/n-heterocyclic-carbene-catalysis","display_name":"N-heterocyclic carbene catalysis","score":0.8220000267028809},{"id":"https://openalex.org/keywords/mesoionic-carbenes","display_name":"mesoionic carbenes","score":0.9929999709129333},{"id":"https://openalex.org/keywords/enolates","display_name":"enolates","score":0.843999981880188},{"id":"https://openalex.org/keywords/radicals","display_name":"radicals","score":0.6460000276565552},{"id":"https://openalex.org/keywords/electron-transfer","display_name":"electron transfer","score":0.6499999761581421},{"id":"https://openalex.org/keywords/aldehyde-derivatives","display_name":"aldehyde derivatives","score":0.6269999742507935},{"id":"https://openalex.org/keywords/redox-properties","display_name":"redox properties","score":0.7379999756813049},{"id":"https://openalex.org/keywords/additives","display_name":"additives","score":0.40700000524520874},{"id":"https://openalex.org/keywords/iodobenzene","display_name":"iodobenzene","score":0.7860000133514404}],"concepts":[{"id":"https://openalex.org/C2777164566","wikidata":"https://www.wikidata.org/wiki/Q419257","display_name":"Carbene","level":3,"score":0.9383779764175415},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.7162453532218933},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5100075006484985},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.4395866394042969},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.37357673048973083},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.3316539525985718}],"mesh":[],"locations_count":7,"locations":[{"id":"doi:10.1002/anie.202111988","doi":"https://doi.org/10.1002/anie.202111988","is_oa":true,"landing_page_url":"https://doi.org/10.1002/anie.202111988","pdf_url":null,"source":{"id":"https://openalex.org/S67393510","display_name":"Angewandte Chemie International Edition","issn_l":"1433-7851","issn":["1433-7851","1521-3773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie International Edition","raw_type":"journal-article"},{"id":"doi:10.26434/chemrxiv-2021-hzttd","doi":"https://doi.org/10.26434/chemrxiv-2021-hzttd","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv-2021-hzttd","pdf_url":null,"source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},{"id":"doi:10.33774/chemrxiv-2021-hzttd","doi":"https://doi.org/10.33774/chemrxiv-2021-hzttd","is_oa":true,"landing_page_url":"https://doi.org/10.33774/chemrxiv-2021-hzttd","pdf_url":"https://chemrxiv.org/engage/api-gateway/chemrxiv/assets/orp/resource/item/6131d5bbac3219458f70113c/original/overhaul-of-the-reducing-ability-of-breslow-type-derivatives-and-implications-for-carbene-catalyzed-radical-reactions.pdf","source":null,"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},{"id":"pmid:34651408","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/34651408","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie (International ed. in English)","raw_type":"Journal Article"},{"id":"pmh:oai:pubmedcentral.nih.gov:9299025","doi":null,"is_oa":true,"landing_page_url":"https://pmc.ncbi.nlm.nih.gov/articles/PMC9299025/","pdf_url":null,"source":{"id":"https://openalex.org/S2764455111","display_name":"PubMed Central","issn_l":null,"issn":null,"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angew Chem Int Ed Engl","raw_type":"Text"},{"id":"pmh:oai:HAL:hal-03357777v1","doi":null,"is_oa":true,"landing_page_url":"https://hal.science/hal-03357777","pdf_url":null,"source":{"id":"https://openalex.org/S4306402512","display_name":"HAL","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I4405252976","host_organization_name":"Centre pour la Communication Scientifique Directe","host_organization_lineage":["https://openalex.org/I4405252976"],"host_organization_lineage_names":[],"type":"repository"},"license":"other-oa","license_id":"https://openalex.org/licenses/other-oa","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"2021","raw_type":"info:eu-repo/semantics/preprint"},{"id":"pmh:oai:HAL:hal-03411268v1","doi":null,"is_oa":true,"landing_page_url":"https://hal.science/hal-03411268","pdf_url":null,"source":{"id":"https://openalex.org/S4306402512","display_name":"HAL","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I4405252976","host_organization_name":"Centre pour la Communication Scientifique Directe","host_organization_lineage":["https://openalex.org/I4405252976"],"host_organization_lineage_names":[],"type":"repository"},"license":"other-oa","license_id":"https://openalex.org/licenses/other-oa","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Angewandte Chemie International Edition, 2021, 60 (51), pp.26783-26789. ⟨10.1002/anie.202111988⟩","raw_type":"info:eu-repo/semantics/article"}],"best_oa_location":{"id":"doi:10.1002/anie.202111988","doi":"https://doi.org/10.1002/anie.202111988","is_oa":true,"landing_page_url":"https://doi.org/10.1002/anie.202111988","pdf_url":null,"source":{"id":"https://openalex.org/S67393510","display_name":"Angewandte Chemie International Edition","issn_l":"1433-7851","issn":["1433-7851","1521-3773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie International Edition","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G1183670895","display_name":null,"funder_award_id":"ANR-17-EURE-0003","funder_id":"https://openalex.org/F4320320300","funder_display_name":"European Commission"},{"id":"https://openalex.org/G1513157868","display_name":"CBH-EUR-GS","funder_award_id":"ANR-17-EURE-0003","funder_id":"https://openalex.org/F4320320883","funder_display_name":"Agence Nationale de la Recherche"},{"id":"https://openalex.org/G2389725886","display_name":null,"funder_award_id":"ANR\u201017\u2010EURE\u20100003","funder_id":"https://openalex.org/F4320314200","funder_display_name":"LABoratoires d\u2019EXcellence ARCANE"},{"id":"https://openalex.org/G2659019386","display_name":null,"funder_award_id":"ANR-17-EURE-","funder_id":"https://openalex.org/F4320320883","funder_display_name":"Agence Nationale de la Recherche"},{"id":"https://openalex.org/G3829790186","display_name":"Upgrading Cyanines dyes: Non-Kekul\u00e9 ketocyanines and related patterns","funder_award_id":"892162","funder_id":"https://openalex.org/F4320320300","funder_display_name":"European Commission"},{"id":"https://openalex.org/G434337789","display_name":null,"funder_award_id":"HORIZON2020","funder_id":"https://openalex.org/F4320320300","funder_display_name":"European Commission"},{"id":"https://openalex.org/G4458006414","display_name":"Aldehydes as metal surrogates for reductions","funder_award_id":"ANR-20-CE07-0010","funder_id":"https://openalex.org/F4320320883","funder_display_name":"Agence Nationale de la Recherche"},{"id":"https://openalex.org/G6803667113","display_name":null,"funder_award_id":"ANR-17","funder_id":"https://openalex.org/F4320320883","funder_display_name":"Agence Nationale de la Recherche"},{"id":"https://openalex.org/G687766781","display_name":"Upgrading Cyanines dyes: Non-Kekul\u00e9 ketocyanines and related patterns","funder_award_id":"892162","funder_id":"https://openalex.org/F4320338337","funder_display_name":"H2020 Marie Sk\u0142odowska-Curie Actions"}],"funders":[{"id":"https://openalex.org/F4320314200","display_name":"LABoratoires d\u2019EXcellence ARCANE","ror":null},{"id":"https://openalex.org/F4320320300","display_name":"European Commission","ror":"https://ror.org/00k4n6c32"},{"id":"https://openalex.org/F4320320883","display_name":"Agence Nationale de la Recherche","ror":"https://ror.org/00rbzpz17"},{"id":"https://openalex.org/F4320322892","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73"},{"id":"https://openalex.org/F4320338337","display_name":"H2020 Marie Sk\u0142odowska-Curie Actions","ror":null},{"id":"https://openalex.org/F4320338463","display_name":"CHIST-ERA","ror":"https://ror.org/00rbzpz17"}],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W3207871969.pdf","grobid_xml":"https://content.openalex.org/works/W3207871969.grobid-xml"},"referenced_works_count":103,"referenced_works":["https://openalex.org/W1163011906","https://openalex.org/W1809069753","https://openalex.org/W1837410261","https://openalex.org/W1948359908","https://openalex.org/W1964697269","https://openalex.org/W1966983316","https://openalex.org/W1970752875","https://openalex.org/W1971927136","https://openalex.org/W1974954045","https://openalex.org/W1981312580","https://openalex.org/W1992769125","https://openalex.org/W1995945917","https://openalex.org/W2003555872","https://openalex.org/W2024339500","https://openalex.org/W2038092103","https://openalex.org/W2043304555","https://openalex.org/W2048122722","https://openalex.org/W2048512713","https://openalex.org/W2052837926","https://openalex.org/W2053370250","https://openalex.org/W2055557514","https://openalex.org/W2061977671","https://openalex.org/W2063677648","https://openalex.org/W2063701427","https://openalex.org/W2075557593","https://openalex.org/W2083357654","https://openalex.org/W2090253967","https://openalex.org/W2109193721","https://openalex.org/W2131937366","https://openalex.org/W2134879756","https://openalex.org/W2146051607","https://openalex.org/W2152871190","https://openalex.org/W2162846787","https://openalex.org/W2163114649","https://openalex.org/W2236745200","https://openalex.org/W2299637886","https://openalex.org/W2305454445","https://openalex.org/W2312952953","https://openalex.org/W2320163706","https://openalex.org/W2320679824","https://openalex.org/W2334373491","https://openalex.org/W2403918774","https://openalex.org/W2525167161","https://openalex.org/W2535450494","https://openalex.org/W2536121445","https://openalex.org/W2536148570","https://openalex.org/W2552408838","https://openalex.org/W2553736986","https://openalex.org/W2579066596","https://openalex.org/W2582748086","https://openalex.org/W2585995678","https://openalex.org/W2592126099","https://openalex.org/W2592957136","https://openalex.org/W2762926781","https://openalex.org/W2796895606","https://openalex.org/W2805560125","https://openalex.org/W2885371647","https://openalex.org/W2903777026","https://openalex.org/W2912316590","https://openalex.org/W2915743380","https://openalex.org/W2945887359","https://openalex.org/W2945968496","https://openalex.org/W2947141118","https://openalex.org/W2952348548","https://openalex.org/W2952858831","https://openalex.org/W2953378669","https://openalex.org/W2970991365","https://openalex.org/W2988908382","https://openalex.org/W2997873262","https://openalex.org/W3007749984","https://openalex.org/W3009123515","https://openalex.org/W3015879606","https://openalex.org/W3017712261","https://openalex.org/W3020976311","https://openalex.org/W3044817820","https://openalex.org/W3045095995","https://openalex.org/W3048647494","https://openalex.org/W3081752729","https://openalex.org/W3083604264","https://openalex.org/W3093785208","https://openalex.org/W3113776240","https://openalex.org/W3116346001","https://openalex.org/W3119253335","https://openalex.org/W3129124368","https://openalex.org/W3129485416","https://openalex.org/W3152410730","https://openalex.org/W3162211292","https://openalex.org/W3162642407","https://openalex.org/W3175760115","https://openalex.org/W3185629812","https://openalex.org/W3194485460","https://openalex.org/W3197633608","https://openalex.org/W4211182939","https://openalex.org/W4235163690","https://openalex.org/W4237555848","https://openalex.org/W4238255686","https://openalex.org/W4240416671","https://openalex.org/W4248082382","https://openalex.org/W4249226240","https://openalex.org/W6600175564","https://openalex.org/W6600529467","https://openalex.org/W6603139312","https://openalex.org/W6685750046"],"related_works":["https://openalex.org/W3198105276","https://openalex.org/W4416043432","https://openalex.org/W2951597644","https://openalex.org/W4410787809","https://openalex.org/W3197421867","https://openalex.org/W4389784394","https://openalex.org/W4247089990","https://openalex.org/W3122933496","https://openalex.org/W2014763621","https://openalex.org/W7163476957"],"abstract_inverted_index":{"Abstract":[0],"We":[1],"report":[2],"the":[3,24,40,45,68,78,114],"synthesis":[4],"of":[5,26,42,48,59,71,80,123],"acyl":[6],"azolium":[7],"salts":[8],"stemming":[9],"from":[10,109],"thiazolylidenes":[11],"C":[12,16,21,82,110,124,127],"NS":[13,83,125],",":[14,18],"triazolylidenes":[15],"TN":[17],"mesoionic":[19],"carbenes":[20],"MIC":[22,111,128],"and":[23,30,51,126],"generation":[25],"their":[27],"corresponding":[28],"radicals":[29],"enolates,":[31],"covering":[32],"about":[33,56],"60":[34],"Breslow\u2010type":[35],"derivatives.":[36],"This":[37],"study":[38],"highlights":[39],"role":[41],"additives":[43],"in":[44,77],"redox":[46],"behavior":[47],"these":[49,94],"compounds":[50],"unveils":[52],"several":[53],"critical":[54],"misconceptions":[55],"radical":[57],"transformations":[58],"aldehyde":[60],"derivatives":[61,122],"under":[62],"N\u2010heterocyclic":[63],"carbene":[64],"catalysis.":[65],"In":[66,85],"particular,":[67],"reducing":[69,131],"ability":[70],"enolates":[72],"has":[73],"been":[74],"dramatically":[75],"underestimated":[76],"case":[79],"biomimetic":[81],".":[84],"contrast":[86],"with":[87],"previous":[88],"electrochemical":[89],"studies,":[90],"we":[91],"show":[92],"that":[93],"catalytic":[95],"intermediates":[96],"can":[97],"transfer":[98],"electrons":[99],"to":[100],"iodobenzene":[101],"within":[102],"minutes":[103],"at":[104],"room":[105],"temperature.":[106],"Enols":[107],"derived":[108],"are":[112,129],"not":[113],"previously":[115],"claimed":[116],"super":[117],"electron":[118],"donors,":[119],"although":[120],"enolate":[121],"powerful":[130],"agents.":[132]},"counts_by_year":[{"year":2026,"cited_by_count":9},{"year":2025,"cited_by_count":20},{"year":2024,"cited_by_count":31},{"year":2023,"cited_by_count":30},{"year":2022,"cited_by_count":23},{"year":2021,"cited_by_count":2}],"updated_date":"2026-11-10T11:39:43.021295","created_date":"2021-10-25T00:00:00"}