{"id":"https://openalex.org/W3204465701","doi":"https://doi.org/10.1007/s41981-021-00199-6","title":"Slug flow as tool for selectivity control in the homogeneously catalysed solvent-free epoxidation of methyl oleate","display_name":"Slug flow as tool for selectivity control in the homogeneously catalysed solvent-free epoxidation of methyl oleate","publication_year":2021,"publication_date":"2021-09-01","ids":{"openalex":"https://openalex.org/W3204465701","doi":"https://doi.org/10.1007/s41981-021-00199-6","mag":"3204465701"},"language":"en","primary_location":{"id":"doi:10.1007/s41981-021-00199-6","doi":"https://doi.org/10.1007/s41981-021-00199-6","is_oa":true,"landing_page_url":"https://doi.org/10.1007/s41981-021-00199-6","pdf_url":"https://link.springer.com/content/pdf/10.1007/s41981-021-00199-6.pdf","source":{"id":"https://openalex.org/S2500698275","display_name":"Journal of Flow Chemistry","issn_l":"2062-249X","issn":["2062-249X","2063-0212"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","norway-1","poland-70","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310319900","host_organization_name":"Springer Science+Business Media","host_organization_lineage":["https://openalex.org/P4310319900","https://openalex.org/P4310319965"],"host_organization_lineage_names":["Springer Science+Business Media","Springer Nature"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Flow Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","datacite"],"open_access":{"is_oa":true,"oa_status":"hybrid","oa_url":"https://link.springer.com/content/pdf/10.1007/s41981-021-00199-6.pdf","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5081502670","display_name":"Anoj Winston Gladius","orcid":"https://orcid.org/0000-0003-2061-7684","observed_orcids":["https://orcid.org/0000-0003-2061-7684"]},"institutions":[{"id":"https://openalex.org/I200332995","display_name":"TU Dortmund University","ror":"https://ror.org/01k97gp34","country_code":"DE","type":"education","lineage":["https://openalex.org/I200332995"]}],"countries":["DE"],"is_corresponding":true,"raw_author_name":"Anoj Winston Gladius","raw_affiliation_strings":["Laboratory for Chemical Reaction Engineering, Department of Biochemical and Chemical Engineering, TU Dortmund University, Emil-Figge-Stra\u00dfe 66, 44227, Dortmund, Germany"],"raw_orcid":"https://orcid.org/0000-0003-2061-7684","affiliations":[{"raw_affiliation_string":"Laboratory for Chemical Reaction Engineering, Department of Biochemical and Chemical Engineering, TU Dortmund University, Emil-Figge-Stra\u00dfe 66, 44227, Dortmund, Germany","institution_ids":["https://openalex.org/I200332995"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5017845495","display_name":"Johanna Vondran","orcid":"https://orcid.org/0000-0003-1823-5636","observed_orcids":["https://orcid.org/0000-0003-1823-5636"]},"institutions":[{"id":"https://openalex.org/I200332995","display_name":"TU Dortmund University","ror":"https://ror.org/01k97gp34","country_code":"DE","type":"education","lineage":["https://openalex.org/I200332995"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Johanna Vondran","raw_affiliation_strings":["Laboratory for Industrial Chemistry, Department of Biochemical and Chemical Engineering, TU Dortmund University, Emil-Figge-Stra\u00dfe 66, 44227, Dortmund, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratory for Industrial Chemistry, Department of Biochemical and Chemical Engineering, TU Dortmund University, Emil-Figge-Stra\u00dfe 66, 44227, Dortmund, Germany","institution_ids":["https://openalex.org/I200332995"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5019257167","display_name":"Yashwanth Ramesh","orcid":"https://orcid.org/0000-0002-5763-5213","observed_orcids":["https://orcid.org/0000-0002-5763-5213"]},"institutions":[{"id":"https://openalex.org/I200332995","display_name":"TU Dortmund University","ror":"https://ror.org/01k97gp34","country_code":"DE","type":"education","lineage":["https://openalex.org/I200332995"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Yashwanth Ramesh","raw_affiliation_strings":["Laboratory for Chemical Reaction Engineering, Department of Biochemical and Chemical Engineering, TU Dortmund University, Emil-Figge-Stra\u00dfe 66, 44227, Dortmund, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratory for Chemical Reaction Engineering, Department of Biochemical and Chemical Engineering, TU Dortmund University, Emil-Figge-Stra\u00dfe 66, 44227, Dortmund, Germany","institution_ids":["https://openalex.org/I200332995"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5052604030","display_name":"Thomas Seidensticker","orcid":"https://orcid.org/0000-0003-0191-4421","observed_orcids":["https://orcid.org/0000-0003-0191-4421"]},"institutions":[{"id":"https://openalex.org/I200332995","display_name":"TU Dortmund University","ror":"https://ror.org/01k97gp34","country_code":"DE","type":"education","lineage":["https://openalex.org/I200332995"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Thomas Seidensticker","raw_affiliation_strings":["Laboratory for Industrial Chemistry, Department of Biochemical and Chemical Engineering, TU Dortmund University, Emil-Figge-Stra\u00dfe 66, 44227, Dortmund, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratory for Industrial Chemistry, Department of Biochemical and Chemical Engineering, TU Dortmund University, Emil-Figge-Stra\u00dfe 66, 44227, Dortmund, Germany","institution_ids":["https://openalex.org/I200332995"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5080228563","display_name":"David W. Agar","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I200332995","display_name":"TU Dortmund University","ror":"https://ror.org/01k97gp34","country_code":"DE","type":"education","lineage":["https://openalex.org/I200332995"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"David William Agar","raw_affiliation_strings":["Laboratory for Chemical Reaction Engineering, Department of Biochemical and Chemical Engineering, TU Dortmund University, Emil-Figge-Stra\u00dfe 66, 44227, Dortmund, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratory for Chemical Reaction Engineering, Department of Biochemical and Chemical Engineering, TU Dortmund University, Emil-Figge-Stra\u00dfe 66, 44227, Dortmund, Germany","institution_ids":["https://openalex.org/I200332995"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5081502670"],"corresponding_institution_ids":["https://openalex.org/I200332995"],"apc_list":{"value":2780,"currency":"USD","value_usd":2780},"apc_paid":{"value":2780,"currency":"USD","value_usd":2780},"fwci":0.4572,"has_fulltext":true,"cited_by_count":8,"citation_normalized_percentile":{"value":0.47532697,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":87,"max":96},"biblio":{"volume":"11","issue":"3","first_page":"407","last_page":"427"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11407","display_name":"Innovative Microfluidic and Catalytic Techniques Innovation","score":0.826200008392334,"subfield":{"id":"https://openalex.org/subfields/1507","display_name":"Fluid Flow and Transfer Processes"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11407","display_name":"Innovative Microfluidic and Catalytic Techniques Innovation","score":0.826200008392334,"subfield":{"id":"https://openalex.org/subfields/1507","display_name":"Fluid Flow and Transfer Processes"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11831","display_name":"Chemical Synthesis and Reactions","score":0.07620000094175339,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11989","display_name":"Oxidative Organic Chemistry Reactions","score":0.02239999920129776,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/slug-flow","display_name":"slug flow","score":0.9480000138282776},{"id":"https://openalex.org/keywords/methyl-oleate","display_name":"methyl oleate","score":0.9950000047683716},{"id":"https://openalex.org/keywords/hydrogen-peroxide-oxidation","display_name":"hydrogen peroxide oxidation","score":0.7699999809265137},{"id":"https://openalex.org/keywords/tungsten-catalysts","display_name":"tungsten catalysts","score":0.8759999871253967},{"id":"https://openalex.org/keywords/aliquat-336","display_name":"Aliquat 336","score":0.9900000095367432},{"id":"https://openalex.org/keywords/phase-transfer-catalysis","display_name":"phase-transfer catalysis","score":0.8100000023841858},{"id":"https://openalex.org/keywords/continuous-flow-reactor","display_name":"continuous flow reactor","score":0.7289999723434448},{"id":"https://openalex.org/keywords/selectivity-control","display_name":"selectivity control","score":0.7670000195503235},{"id":"https://openalex.org/keywords/space-time-yield","display_name":"space-time yield","score":0.7689999938011169},{"id":"https://openalex.org/keywords/unsaturated-fatty-acid-esters","display_name":"unsaturated fatty acid esters","score":0.7260000109672546},{"id":"https://openalex.org/keywords/bioproducts","display_name":"bioproducts","score":0.5950000286102295},{"id":"https://openalex.org/keywords/flow-chemistry","display_name":"flow chemistry","score":0.47200000286102295}],"concepts":[{"id":"https://openalex.org/C139514615","wikidata":"https://www.wikidata.org/wiki/Q16935556","display_name":"Slug flow","level":4,"score":0.807636559009552},{"id":"https://openalex.org/C118792377","wikidata":"https://www.wikidata.org/wiki/Q108584245","display_name":"Selectivity","level":3,"score":0.7444468140602112},{"id":"https://openalex.org/C134121241","wikidata":"https://www.wikidata.org/wiki/Q899301","display_name":"Yield (engineering)","level":2,"score":0.7090803384780884},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5814523100852966},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.5676367878913879},{"id":"https://openalex.org/C2780471494","wikidata":"https://www.wikidata.org/wiki/Q146505","display_name":"Solvent","level":2,"score":0.4710808992385864},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.46086108684539795},{"id":"https://openalex.org/C172120300","wikidata":"https://www.wikidata.org/wiki/Q1134348","display_name":"Volumetric flow rate","level":2,"score":0.4391372799873352},{"id":"https://openalex.org/C132482357","wikidata":"https://www.wikidata.org/wiki/Q5462089","display_name":"Flow chemistry","level":3,"score":0.436546266078949},{"id":"https://openalex.org/C533411734","wikidata":"https://www.wikidata.org/wiki/Q171877","display_name":"Hydrogen peroxide","level":2,"score":0.4141019880771637},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.37112662196159363},{"id":"https://openalex.org/C38349280","wikidata":"https://www.wikidata.org/wiki/Q1434290","display_name":"Flow (mathematics)","level":2,"score":0.3083706200122833},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.2684805989265442},{"id":"https://openalex.org/C144308804","wikidata":"https://www.wikidata.org/wiki/Q232997","display_name":"Two-phase flow","level":3,"score":0.18381786346435547},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.10081768035888672},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.09466671943664551},{"id":"https://openalex.org/C2524010","wikidata":"https://www.wikidata.org/wiki/Q8087","display_name":"Geometry","level":1,"score":0.0},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0},{"id":"https://openalex.org/C33923547","wikidata":"https://www.wikidata.org/wiki/Q395","display_name":"Mathematics","level":0,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1007/s41981-021-00199-6","doi":"https://doi.org/10.1007/s41981-021-00199-6","is_oa":true,"landing_page_url":"https://doi.org/10.1007/s41981-021-00199-6","pdf_url":"https://link.springer.com/content/pdf/10.1007/s41981-021-00199-6.pdf","source":{"id":"https://openalex.org/S2500698275","display_name":"Journal of Flow Chemistry","issn_l":"2062-249X","issn":["2062-249X","2063-0212"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","norway-1","poland-70","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310319900","host_organization_name":"Springer Science+Business Media","host_organization_lineage":["https://openalex.org/P4310319900","https://openalex.org/P4310319965"],"host_organization_lineage_names":["Springer Science+Business Media","Springer Nature"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Flow Chemistry","raw_type":"journal-article"},{"id":"pmh:oai:eldorado.tu-dortmund.de:2003/40954","doi":null,"is_oa":true,"landing_page_url":"http://hdl.handle.net/2003/40954","pdf_url":"http://eldorado.tu-dortmund.de/bitstreams/e68c19d4-8deb-4f6b-9f79-43975882d542/download","source":{"id":"https://openalex.org/S4306400811","display_name":"Technische Universit\u00e4t Dortmund Eldorado (Technische Universit\u00e4t Dortmund)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I4210148506","host_organization_name":"Erich-Brost-Institut","host_organization_lineage":["https://openalex.org/I4210148506"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"Text"},{"id":"doi:10.17877/de290r-22804","doi":"https://doi.org/10.17877/de290r-22804","is_oa":true,"landing_page_url":"https://doi.org/10.17877/de290r-22804","pdf_url":null,"source":{"id":"https://openalex.org/S4306400811","display_name":"Technische Universit\u00e4t Dortmund Eldorado (Technische Universit\u00e4t Dortmund)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I4210148506","host_organization_name":"Erich-Brost-Institut","host_organization_lineage":["https://openalex.org/I4210148506"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"article-journal"}],"best_oa_location":{"id":"doi:10.1007/s41981-021-00199-6","doi":"https://doi.org/10.1007/s41981-021-00199-6","is_oa":true,"landing_page_url":"https://doi.org/10.1007/s41981-021-00199-6","pdf_url":"https://link.springer.com/content/pdf/10.1007/s41981-021-00199-6.pdf","source":{"id":"https://openalex.org/S2500698275","display_name":"Journal of Flow Chemistry","issn_l":"2062-249X","issn":["2062-249X","2063-0212"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","norway-1","poland-70","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310319900","host_organization_name":"Springer Science+Business Media","host_organization_lineage":["https://openalex.org/P4310319900","https://openalex.org/P4310319965"],"host_organization_lineage_names":["Springer Science+Business Media","Springer Nature"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Flow Chemistry","raw_type":"journal-article"},"sustainable_development_goals":[{"id":"https://metadata.un.org/sdg/12","display_name":"Responsible consumption and production","score":0.7811999917030334}],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320320879","display_name":"Deutsche Forschungsgemeinschaft","ror":"https://ror.org/018mejw64"},{"id":"https://openalex.org/F4320329559","display_name":"Technische Universit\u00e4t Dortmund","ror":"https://ror.org/01k97gp34"}],"has_content":{"grobid_xml":true,"pdf":true},"content_urls":{"pdf":"https://content.openalex.org/works/W3204465701.pdf","grobid_xml":"https://content.openalex.org/works/W3204465701.grobid-xml"},"referenced_works_count":37,"referenced_works":["https://openalex.org/W323877688","https://openalex.org/W1963746959","https://openalex.org/W1967894209","https://openalex.org/W1992380700","https://openalex.org/W1998584340","https://openalex.org/W2005297976","https://openalex.org/W2008715297","https://openalex.org/W2021093366","https://openalex.org/W2022652902","https://openalex.org/W2022870315","https://openalex.org/W2026509206","https://openalex.org/W2030542729","https://openalex.org/W2047304268","https://openalex.org/W2056332581","https://openalex.org/W2060079099","https://openalex.org/W2062836628","https://openalex.org/W2066180840","https://openalex.org/W2078793035","https://openalex.org/W2085510751","https://openalex.org/W2088460214","https://openalex.org/W2110534188","https://openalex.org/W2159799800","https://openalex.org/W2163011281","https://openalex.org/W2203937047","https://openalex.org/W2235931321","https://openalex.org/W2237440835","https://openalex.org/W2479954787","https://openalex.org/W2527330915","https://openalex.org/W2560009365","https://openalex.org/W2756833285","https://openalex.org/W2797848805","https://openalex.org/W2958666457","https://openalex.org/W2991266602","https://openalex.org/W3005427996","https://openalex.org/W3073844271","https://openalex.org/W3109941128","https://openalex.org/W4241653882"],"related_works":["https://openalex.org/W2076227832","https://openalex.org/W2524385951","https://openalex.org/W4225164040","https://openalex.org/W4406856198","https://openalex.org/W6996940207","https://openalex.org/W2037042303","https://openalex.org/W4408284048","https://openalex.org/W4379986116","https://openalex.org/W4292823912","https://openalex.org/W6941175709"],"abstract_inverted_index":{"Abstract":[0],"Catalytic":[1],"oxidation":[2,178],"of":[3,68,100,114,139,161,168,180],"sustainable":[4],"raw":[5],"materials":[6],"like":[7],"unsaturated":[8],"fats":[9],"and":[10,15,96,124],"oils,":[11],"or":[12],"fatty":[13],"acids":[14],"their":[16],"esters,":[17],"lead":[18],"to":[19,86],"biobased,":[20],"high-value":[21],"products.":[22],"Starting":[23],"from":[24,81],"technical":[25],"grade":[26],"methyl":[27,131,181],"oleate,":[28],"hydrogen":[29],"peroxide":[30],"as":[31,38,52,172],"a":[32,53,136,158],"green":[33],"oxidant":[34],"produces":[35],"only":[36,140],"water":[37],"by-product.":[39],"A":[40],"commercially":[41],"available,":[42],"cheap":[43],"water-soluble":[44],"tungsten":[45],"catalyst":[46],"is":[47,79,133],"combined":[48,149],"with":[49,150],"Aliquat\u00ae":[50],"336":[51],"phase-transfer":[54],"agent":[55],"in":[56,84,89,142,154],"solvent-free":[57],"reaction":[58],"conditions.":[59],"In":[60],"this":[61,69],"study,":[62],"we":[63],"first":[64],"report":[65],"the":[66,101,129,166],"transfer":[67,95],"well-known":[70],"batch":[71,85],"system":[72],"into":[73],"continuous":[74],"mode.":[75,91],"The":[76,92],"space\u2013time":[77],"yield":[78,148],"improved":[80,93],"0.08":[82],"kg/L.h":[83,88],"1.29":[87],"flow":[90,105,116,122,143,155,170],"mass":[94],"reduced":[97],"back":[98],"mixing":[99],"biphasic":[102],"liquid\u2013liquid":[103],"slug":[104,115,125,169],"allows":[106],"for":[107,174],"selectivity":[108,138,176],"control":[109],"depending":[110],"on":[111],"physical":[112],"parameters":[113,171],"namely":[117],"volumetric":[118,121],"phase":[119],"ratio,":[120],"rate,":[123],"length.":[126],"Even":[127],"though":[128],"product,":[130],"9,10-epoxystearate":[132],"obtained":[134],"at":[135],"maximum":[137],"58%":[141],"mode,":[144],"higher":[145],"space":[146],"time":[147],"possible":[151],"reactant":[152],"recycling":[153],"mode":[156],"offers":[157],"promising":[159],"avenue":[160],"research.":[162],"This":[163],"work":[164],"analyses":[165],"use":[167],"tools":[173],"controlling":[175],"towards":[177],"products":[179],"oleate.":[182]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":2},{"year":2023,"cited_by_count":3},{"year":2021,"cited_by_count":1}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2021-10-11T00:00:00"}