{"id":"https://openalex.org/W3162913648","doi":"https://doi.org/10.1080/00397911.2021.1924787","title":"High yielding electrophilic amination with lower order and higher order organocuprates: Application of acetone O-(4-Chlorophenylsulfonyl)oxime in the construction of the C\u2212N bond at room temperature","display_name":"High yielding electrophilic amination with lower order and higher order organocuprates: Application of acetone O-(4-Chlorophenylsulfonyl)oxime in the construction of the C\u2212N bond at room temperature","publication_year":2021,"publication_date":"2021-05-13","ids":{"openalex":"https://openalex.org/W3162913648","doi":"https://doi.org/10.1080/00397911.2021.1924787","mag":"3162913648"},"language":"en","primary_location":{"id":"doi:10.1080/00397911.2021.1924787","doi":"https://doi.org/10.1080/00397911.2021.1924787","is_oa":false,"landing_page_url":"https://doi.org/10.1080/00397911.2021.1924787","pdf_url":null,"source":{"id":"https://openalex.org/S114976158","display_name":"Synthetic Communications","issn_l":"0039-7911","issn":["0039-7911","1532-2432"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","poland-40","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320547","host_organization_name":"Taylor & Francis","host_organization_lineage":["https://openalex.org/P4310320547","https://openalex.org/P4310320449"],"host_organization_lineage_names":["Taylor & Francis","Informa"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Synthetic Communications","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://hdl.handle.net/20.500.12639/2774","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5077324569","display_name":"Adem Korkmaz","orcid":"https://orcid.org/0000-0002-0345-5794","observed_orcids":["https://orcid.org/0000-0002-0345-5794"]},"institutions":[{"id":"https://openalex.org/I140912994","display_name":"Mu\u015f Alparslan University","ror":"https://ror.org/009axq942","country_code":"TR","type":"education","lineage":["https://openalex.org/I140912994"]}],"countries":["TR"],"is_corresponding":true,"raw_author_name":"Adem Korkmaz","raw_affiliation_strings":["Department of Occupational Health and Safety, Faculty of Health Sciences, Mu\u015f Alparslan University, Mu\u015f, Turkey"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Occupational Health and Safety, Faculty of Health Sciences, Mu\u015f Alparslan University, Mu\u015f, Turkey","institution_ids":["https://openalex.org/I140912994"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5020440102","display_name":"Serdar Duran","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I140912994","display_name":"Mu\u015f Alparslan University","ror":"https://ror.org/009axq942","country_code":"TR","type":"education","lineage":["https://openalex.org/I140912994"]}],"countries":["TR"],"is_corresponding":false,"raw_author_name":"Serdar Duran","raw_affiliation_strings":["Department of Chemistry, Mu\u015f Alparslan University, Mu\u015f, Turkey"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Mu\u015f Alparslan University, Mu\u015f, Turkey","institution_ids":["https://openalex.org/I140912994"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5077324569"],"corresponding_institution_ids":["https://openalex.org/I140912994"],"apc_list":null,"apc_paid":null,"fwci":0.5748,"has_fulltext":false,"cited_by_count":6,"citation_normalized_percentile":{"value":0.51053043,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":87,"max":97},"biblio":{"volume":"51","issue":"14","first_page":"2077","last_page":"2087"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12228","display_name":"Coordination Chemistry and Organometallics","score":0.8476999998092651,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12228","display_name":"Coordination Chemistry and Organometallics","score":0.8476999998092651,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10548","display_name":"Catalytic Cross-Coupling Reactions","score":0.0608999989926815,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13649","display_name":"Advanced Synthetic Organic Chemistry","score":0.021700000390410423,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/electrophilic-amination","display_name":"electrophilic amination","score":1.0},{"id":"https://openalex.org/keywords/organocuprates","display_name":"organocuprates","score":0.9589999914169312},{"id":"https://openalex.org/keywords/c-n-bond-formation","display_name":"C\u2013N bond formation","score":0.7699999809265137},{"id":"https://openalex.org/keywords/primary-amines","display_name":"primary amines","score":0.828000009059906},{"id":"https://openalex.org/keywords/aromatic-amines","display_name":"aromatic amines","score":0.8949999809265137},{"id":"https://openalex.org/keywords/room-temperature-reaction","display_name":"room temperature reaction","score":0.6779999732971191}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9601556658744812},{"id":"https://openalex.org/C198503264","wikidata":"https://www.wikidata.org/wiki/Q471635","display_name":"Amination","level":3,"score":0.8834503889083862},{"id":"https://openalex.org/C2779426747","wikidata":"https://www.wikidata.org/wiki/Q5358516","display_name":"Electrophilic amination","level":4,"score":0.8738871812820435},{"id":"https://openalex.org/C50027330","wikidata":"https://www.wikidata.org/wiki/Q908086","display_name":"Electrophile","level":3,"score":0.8256223201751709},{"id":"https://openalex.org/C2779648554","wikidata":"https://www.wikidata.org/wiki/Q182738","display_name":"Oxime","level":2,"score":0.6341958045959473},{"id":"https://openalex.org/C131779359","wikidata":"https://www.wikidata.org/wiki/Q471875","display_name":"Amine gas treating","level":2,"score":0.5974264740943909},{"id":"https://openalex.org/C2781213060","wikidata":"https://www.wikidata.org/wiki/Q49546","display_name":"Acetone","level":2,"score":0.5875847339630127},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.5326694250106812},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.4046604633331299},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.3211376667022705},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.07439768314361572}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1080/00397911.2021.1924787","doi":"https://doi.org/10.1080/00397911.2021.1924787","is_oa":false,"landing_page_url":"https://doi.org/10.1080/00397911.2021.1924787","pdf_url":null,"source":{"id":"https://openalex.org/S114976158","display_name":"Synthetic Communications","issn_l":"0039-7911","issn":["0039-7911","1532-2432"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","poland-40","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320547","host_organization_name":"Taylor & Francis","host_organization_lineage":["https://openalex.org/P4310320547","https://openalex.org/P4310320449"],"host_organization_lineage_names":["Taylor & Francis","Informa"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Synthetic Communications","raw_type":"journal-article"},{"id":"pmh:oai:akademikarsiv.alparslan.edu.tr:20.500.12639/2774","doi":null,"is_oa":true,"landing_page_url":"https://hdl.handle.net/20.500.12639/2774","pdf_url":null,"source":{"id":"https://openalex.org/S7407055300","display_name":"DSpace@M\u015eU","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"Article"}],"best_oa_location":{"id":"pmh:oai:akademikarsiv.alparslan.edu.tr:20.500.12639/2774","doi":null,"is_oa":true,"landing_page_url":"https://hdl.handle.net/20.500.12639/2774","pdf_url":null,"source":{"id":"https://openalex.org/S7407055300","display_name":"DSpace@M\u015eU","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"Article"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320324167","display_name":"Mu\u015f Alparslan \u00dcniversitesi","ror":"https://ror.org/009axq942"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":48,"referenced_works":["https://openalex.org/W75367971","https://openalex.org/W634854578","https://openalex.org/W1970296509","https://openalex.org/W1979553189","https://openalex.org/W1984446488","https://openalex.org/W1988018518","https://openalex.org/W2019478224","https://openalex.org/W2022711498","https://openalex.org/W2023166403","https://openalex.org/W2041368477","https://openalex.org/W2058983479","https://openalex.org/W2065813156","https://openalex.org/W2069884360","https://openalex.org/W2087716089","https://openalex.org/W2113593243","https://openalex.org/W2119603701","https://openalex.org/W2157953135","https://openalex.org/W2164944877","https://openalex.org/W2320458843","https://openalex.org/W2334703837","https://openalex.org/W2341924749","https://openalex.org/W2461858346","https://openalex.org/W2546614251","https://openalex.org/W2588067446","https://openalex.org/W2764886111","https://openalex.org/W2944316653","https://openalex.org/W2949078136","https://openalex.org/W2949362222","https://openalex.org/W2949822239","https://openalex.org/W2950615965","https://openalex.org/W2950695687","https://openalex.org/W2950874686","https://openalex.org/W2951259356","https://openalex.org/W2951887753","https://openalex.org/W2952244769","https://openalex.org/W2952330629","https://openalex.org/W2954042167","https://openalex.org/W2964680771","https://openalex.org/W2990469548","https://openalex.org/W2997257931","https://openalex.org/W3035925194","https://openalex.org/W3088656270","https://openalex.org/W3095306805","https://openalex.org/W3126916172","https://openalex.org/W3159270940","https://openalex.org/W4245908558","https://openalex.org/W4247950783","https://openalex.org/W4250560170"],"related_works":["https://openalex.org/W7132391547","https://openalex.org/W2951012383","https://openalex.org/W2588067446","https://openalex.org/W450811419","https://openalex.org/W2112039881","https://openalex.org/W2951259356","https://openalex.org/W3193998976","https://openalex.org/W1966930861","https://openalex.org/W2949078136","https://openalex.org/W2106078813"],"abstract_inverted_index":{"Electrophilic":[0],"amination":[1,50],"reaction":[2],"was":[3,17],"performed":[4],"with":[5,37],"lower":[6,73],"order":[7,10,67,74],"and":[8,39,54,60],"higher":[9,66],"organocuprates":[11,27,68,75],"using":[12],"acetone":[13],"O-(4-Chlorophenylsulfonyl)oxime":[14],"(1).":[15],"It":[16],"proceeded":[18],"smoothly":[19],"at":[20],"room":[21],"temperature":[22],"in":[23,34,76],"the":[24,30,48,77],"presence":[25],"of":[26,47,51,79],"to":[28],"provide":[29],"corresponding":[31],"primary":[32,44],"amines":[33],"good":[35],"yields":[36,46],"10":[38],"60":[40],"min,":[41],"respectively.":[42,62],"The":[43],"amine":[45],"electrophilic":[49,83],"bromomagnesium":[52],"organocyanocuprates":[53],"dibromomagnesium":[55],"diorganocyanocuprates":[56],"were":[57,69],"obtained":[58],"52\u201372%":[59],"58\u201383%,":[61],"We":[63],"observed":[64],"that":[65],"more":[70],"successful":[71],"than":[72],"synthesis":[78],"functionalized":[80],"arylamines":[81],"by":[82],"amination.":[84]},"counts_by_year":[{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":4},{"year":2021,"cited_by_count":1}],"updated_date":"2026-10-08T09:06:37.294493","created_date":"2021-05-24T00:00:00"}