{"id":"https://openalex.org/W3148501347","doi":"https://doi.org/10.1021/acsmacrolett.1c00057","title":"Chain-Length-Dependent Photolysis of ortho-Nitrobenzyl-Centered Polymers","display_name":"Chain-Length-Dependent Photolysis of ortho-Nitrobenzyl-Centered Polymers","publication_year":2021,"publication_date":"2021-03-25","ids":{"openalex":"https://openalex.org/W3148501347","doi":"https://doi.org/10.1021/acsmacrolett.1c00057","mag":"3148501347","pmid":"https://pubmed.ncbi.nlm.nih.gov/35549234"},"language":"en","primary_location":{"id":"doi:10.1021/acsmacrolett.1c00057","doi":"https://doi.org/10.1021/acsmacrolett.1c00057","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acsmacrolett.1c00057","pdf_url":null,"source":{"id":"https://openalex.org/S75495113","display_name":"ACS Macro Letters","issn_l":"2161-1653","issn":["2161-1653"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","medline","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Macro Letters","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"http://purl.org/au-research/grants/arc/LP170100979","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5102779522","display_name":"Julian Bachmann","orcid":"https://orcid.org/0000-0003-0491-6123","observed_orcids":["https://orcid.org/0000-0003-0491-6123"]},"institutions":[{"id":"https://openalex.org/I102335020","display_name":"Karlsruhe Institute of Technology","ror":"https://ror.org/04t3en479","country_code":"DE","type":"education","lineage":["https://openalex.org/I102335020","https://openalex.org/I1305996414"]},{"id":"https://openalex.org/I160993911","display_name":"Queensland University of Technology","ror":"https://ror.org/03pnv4752","country_code":"AU","type":"education","lineage":["https://openalex.org/I160993911"]}],"countries":["AU","DE"],"is_corresponding":false,"raw_author_name":"Julian Bachmann","raw_affiliation_strings":["Centre for Materials Science, School of Chemistry and Physics, Queensland University of Technology (QUT), 2 George Street, Brisbane, Queensland 4000, Australia","Institute of Physical Chemistry, Karlsruhe Institute of Technology (KIT), Fritz-Haber-Weg 2, 76131 Karlsruhe, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Centre for Materials Science, School of Chemistry and Physics, Queensland University of Technology (QUT), 2 George Street, Brisbane, Queensland 4000, Australia","institution_ids":["https://openalex.org/I160993911"]},{"raw_affiliation_string":"Institute of Physical Chemistry, Karlsruhe Institute of Technology (KIT), Fritz-Haber-Weg 2, 76131 Karlsruhe, Germany","institution_ids":["https://openalex.org/I102335020"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5000565754","display_name":"Charlotte Petit","orcid":"https://orcid.org/0000-0002-8077-6735","observed_orcids":["https://orcid.org/0000-0002-8077-6735"]},"institutions":[{"id":"https://openalex.org/I160993911","display_name":"Queensland University of Technology","ror":"https://ror.org/03pnv4752","country_code":"AU","type":"education","lineage":["https://openalex.org/I160993911"]}],"countries":["AU"],"is_corresponding":false,"raw_author_name":"Charlotte Petit","raw_affiliation_strings":["Centre for Materials Science, School of Chemistry and Physics, Queensland University of Technology (QUT), 2 George Street, Brisbane, Queensland 4000, Australia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Centre for Materials Science, School of Chemistry and Physics, Queensland University of Technology (QUT), 2 George Street, Brisbane, Queensland 4000, Australia","institution_ids":["https://openalex.org/I160993911"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5001106556","display_name":"Lukas Felix Michalek","orcid":"https://orcid.org/0000-0002-2257-5038","observed_orcids":["https://orcid.org/0000-0002-2257-5038"]},"institutions":[{"id":"https://openalex.org/I160993911","display_name":"Queensland University of Technology","ror":"https://ror.org/03pnv4752","country_code":"AU","type":"education","lineage":["https://openalex.org/I160993911"]}],"countries":["AU"],"is_corresponding":false,"raw_author_name":"Lukas Michalek","raw_affiliation_strings":["Centre for Materials Science, School of Chemistry and Physics, Queensland University of Technology (QUT), 2 George Street, Brisbane, Queensland 4000, Australia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Centre for Materials Science, School of Chemistry and Physics, Queensland University of Technology (QUT), 2 George Street, Brisbane, Queensland 4000, Australia","institution_ids":["https://openalex.org/I160993911"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5090607403","display_name":"Yohann Catel","orcid":"https://orcid.org/0000-0003-4928-3374","observed_orcids":["https://orcid.org/0000-0003-4928-3374","https://orcid.org/0009-0006-7690-4446"]},"institutions":[{"id":"https://openalex.org/I4210086727","display_name":"Ivoclar Vivadent (Liechtenstein)","ror":"https://ror.org/001tmkc70","country_code":"LI","type":"company","lineage":["https://openalex.org/I4210086727"]}],"countries":["LI"],"is_corresponding":false,"raw_author_name":"Yohann Catel","raw_affiliation_strings":["Ivoclar Vivadent AG, Bendererstrasse 2, 9494 Schaan, Liechtenstein"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Ivoclar Vivadent AG, Bendererstrasse 2, 9494 Schaan, Liechtenstein","institution_ids":["https://openalex.org/I4210086727"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5029954997","display_name":"Eva Blasco","orcid":"https://orcid.org/0000-0002-0849-4223","observed_orcids":["https://orcid.org/0000-0002-0849-4223"]},"institutions":[{"id":"https://openalex.org/I102335020","display_name":"Karlsruhe Institute of Technology","ror":"https://ror.org/04t3en479","country_code":"DE","type":"education","lineage":["https://openalex.org/I102335020","https://openalex.org/I1305996414"]},{"id":"https://openalex.org/I223822909","display_name":"Heidelberg University","ror":"https://ror.org/038t36y30","country_code":"DE","type":"education","lineage":["https://openalex.org/I223822909"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Eva Blasco","raw_affiliation_strings":["Centre for Advanced Materials, Heidelberg University, im Neuenheimer Feld 225, 69120 Heidelberg, Germany","Institute of Nanotechnology, Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany","Institute of Organic Chemistry, Heidelberg University, im Neuenheimer Feld 225, 69120 Heidelberg, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Centre for Advanced Materials, Heidelberg University, im Neuenheimer Feld 225, 69120 Heidelberg, Germany","institution_ids":["https://openalex.org/I223822909"]},{"raw_affiliation_string":"Institute of Nanotechnology, Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany","institution_ids":["https://openalex.org/I102335020"]},{"raw_affiliation_string":"Institute of Organic Chemistry, Heidelberg University, im Neuenheimer Feld 225, 69120 Heidelberg, Germany","institution_ids":["https://openalex.org/I223822909"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5080205224","display_name":"James P. Blinco","orcid":"https://orcid.org/0000-0003-0092-2040","observed_orcids":["https://orcid.org/0000-0003-0092-2040"]},"institutions":[{"id":"https://openalex.org/I160993911","display_name":"Queensland University of Technology","ror":"https://ror.org/03pnv4752","country_code":"AU","type":"education","lineage":["https://openalex.org/I160993911"]}],"countries":["AU"],"is_corresponding":true,"raw_author_name":"James P. Blinco","raw_affiliation_strings":["Centre for Materials Science, School of Chemistry and Physics, Queensland University of Technology (QUT), 2 George Street, Brisbane, Queensland 4000, Australia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Centre for Materials Science, School of Chemistry and Physics, Queensland University of Technology (QUT), 2 George Street, Brisbane, Queensland 4000, Australia","institution_ids":["https://openalex.org/I160993911"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5017048139","display_name":"Andreas\u2010Neil Unterreiner","orcid":"https://orcid.org/0000-0002-1225-5460","observed_orcids":["https://orcid.org/0000-0002-1225-5460"]},"institutions":[{"id":"https://openalex.org/I102335020","display_name":"Karlsruhe Institute of Technology","ror":"https://ror.org/04t3en479","country_code":"DE","type":"education","lineage":["https://openalex.org/I102335020","https://openalex.org/I1305996414"]}],"countries":["DE"],"is_corresponding":true,"raw_author_name":"Andreas-Neil Unterreiner","raw_affiliation_strings":["Institute of Physical Chemistry, Karlsruhe Institute of Technology (KIT), Fritz-Haber-Weg 2, 76131 Karlsruhe, Germany"],"raw_orcid":"https://orcid.org/0000-0002-1225-5460","affiliations":[{"raw_affiliation_string":"Institute of Physical Chemistry, Karlsruhe Institute of Technology (KIT), Fritz-Haber-Weg 2, 76131 Karlsruhe, Germany","institution_ids":["https://openalex.org/I102335020"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5004482996","display_name":"Christopher Barner\u2010Kowollik","orcid":"https://orcid.org/0000-0002-6745-0570","observed_orcids":["https://orcid.org/0000-0002-6745-0570"]},"institutions":[{"id":"https://openalex.org/I160993911","display_name":"Queensland University of Technology","ror":"https://ror.org/03pnv4752","country_code":"AU","type":"education","lineage":["https://openalex.org/I160993911"]}],"countries":["AU"],"is_corresponding":true,"raw_author_name":"Christopher Barner-Kowollik","raw_affiliation_strings":["Centre for Materials Science, School of Chemistry and Physics, Queensland University of Technology (QUT), 2 George Street, Brisbane, Queensland 4000, Australia"],"raw_orcid":"https://orcid.org/0000-0002-6745-0570","affiliations":[{"raw_affiliation_string":"Centre for Materials Science, School of Chemistry and Physics, Queensland University of Technology (QUT), 2 George Street, Brisbane, Queensland 4000, Australia","institution_ids":["https://openalex.org/I160993911"]}]}],"institutions":[],"countries_distinct_count":3,"institutions_distinct_count":4,"corresponding_author_ids":["https://openalex.org/A5004482996","https://openalex.org/A5017048139","https://openalex.org/A5080205224"],"corresponding_institution_ids":["https://openalex.org/I102335020","https://openalex.org/I160993911"],"apc_list":{"value":5000,"currency":"USD","value_usd":5000},"apc_paid":null,"fwci":1.2484,"has_fulltext":false,"cited_by_count":20,"citation_normalized_percentile":{"value":0.74587694,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":92,"max":98},"biblio":{"volume":"10","issue":"4","first_page":"447","last_page":"452"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.8047000169754028,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.8047000169754028,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12570","display_name":"Photopolymerization techniques and applications","score":0.10459999740123749,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10810","display_name":"Polymer composites and self-healing","score":0.0746999979019165,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/photolysis","display_name":"photolysis","score":0.6480000019073486},{"id":"https://openalex.org/keywords/chain-length-dependence","display_name":"chain length dependence","score":0.9509999752044678},{"id":"https://openalex.org/keywords/poly-methyl-acrylate","display_name":"poly(methyl acrylate)","score":0.8999999761581421},{"id":"https://openalex.org/keywords/raft-polymerization","display_name":"RAFT polymerization","score":0.7559999823570251},{"id":"https://openalex.org/keywords/entropic-effects","display_name":"entropic effects","score":0.7509999871253967}],"concepts":[{"id":"https://openalex.org/C2776568683","wikidata":"https://www.wikidata.org/wiki/Q23005640","display_name":"Moiety","level":2,"score":0.8933701515197754},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.7777230143547058},{"id":"https://openalex.org/C54582936","wikidata":"https://www.wikidata.org/wiki/Q16814","display_name":"Photodissociation","level":2,"score":0.7368654012680054},{"id":"https://openalex.org/C121120078","wikidata":"https://www.wikidata.org/wiki/Q3737603","display_name":"Chain transfer","level":5,"score":0.5946562886238098},{"id":"https://openalex.org/C2778004933","wikidata":"https://www.wikidata.org/wiki/Q343028","display_name":"Methyl acrylate","level":4,"score":0.5305272340774536},{"id":"https://openalex.org/C148898269","wikidata":"https://www.wikidata.org/wiki/Q1108792","display_name":"Kinetics","level":2,"score":0.4982645511627197},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.45315101742744446},{"id":"https://openalex.org/C199185054","wikidata":"https://www.wikidata.org/wiki/Q552299","display_name":"Chain (unit)","level":2,"score":0.4317163825035095},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.4264664351940155},{"id":"https://openalex.org/C191015642","wikidata":"https://www.wikidata.org/wiki/Q1132459","display_name":"Fragmentation (computing)","level":2,"score":0.41874775290489197},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.4066668450832367},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.4008544981479645},{"id":"https://openalex.org/C15920480","wikidata":"https://www.wikidata.org/wiki/Q421281","display_name":"Copolymer","level":3,"score":0.22040799260139465},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.18580317497253418},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.15102830529212952},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.06551998853683472},{"id":"https://openalex.org/C111998727","wikidata":"https://www.wikidata.org/wiki/Q2620998","display_name":"Radical polymerization","level":4,"score":0.06141957640647888},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.051159679889678955},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C111919701","wikidata":"https://www.wikidata.org/wiki/Q9135","display_name":"Operating system","level":1,"score":0.0},{"id":"https://openalex.org/C1276947","wikidata":"https://www.wikidata.org/wiki/Q333","display_name":"Astronomy","level":1,"score":0.0}],"mesh":[{"descriptor_ui":"D008970","descriptor_name":"Molecular Weight","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D010782","descriptor_name":"Photolysis","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D011108","descriptor_name":"Polymers","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true}],"locations_count":3,"locations":[{"id":"doi:10.1021/acsmacrolett.1c00057","doi":"https://doi.org/10.1021/acsmacrolett.1c00057","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acsmacrolett.1c00057","pdf_url":null,"source":{"id":"https://openalex.org/S75495113","display_name":"ACS Macro Letters","issn_l":"2161-1653","issn":["2161-1653"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","medline","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Macro Letters","raw_type":"journal-article"},{"id":"pmid:35549234","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/35549234","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS macro letters","raw_type":"Journal Article"},{"id":"pmh:oai:eprints.qut.edu.au:212434","doi":null,"is_oa":true,"landing_page_url":"http://purl.org/au-research/grants/arc/LP170100979","pdf_url":null,"source":{"id":"https://openalex.org/S4306402607","display_name":"QUT ePrints (Queensland University of Technology)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I160993911","host_organization_name":"Queensland University of Technology","host_organization_lineage":["https://openalex.org/I160993911"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc","license_id":"https://openalex.org/licenses/cc-by-nc","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"ACS Macro Letters","raw_type":"Contribution to Journal"}],"best_oa_location":{"id":"pmh:oai:eprints.qut.edu.au:212434","doi":null,"is_oa":true,"landing_page_url":"http://purl.org/au-research/grants/arc/LP170100979","pdf_url":null,"source":{"id":"https://openalex.org/S4306402607","display_name":"QUT ePrints (Queensland University of Technology)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I160993911","host_organization_name":"Queensland University of Technology","host_organization_lineage":["https://openalex.org/I160993911"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc","license_id":"https://openalex.org/licenses/cc-by-nc","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"ACS Macro Letters","raw_type":"Contribution to Journal"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G1960092938","display_name":"On-demand visible light degradable dental materials","funder_award_id":"LP170100979","funder_id":"https://openalex.org/F4320334704","funder_display_name":"Australian Research Council"}],"funders":[{"id":"https://openalex.org/F4320334704","display_name":"Australian Research Council","ror":"https://ror.org/05mmh0f86"},{"id":"https://openalex.org/F4320335837","display_name":"Institute for Future Environments, Queensland University of Technology","ror":null}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":41,"referenced_works":["https://openalex.org/W1836441987","https://openalex.org/W1961347528","https://openalex.org/W1965396569","https://openalex.org/W1967440921","https://openalex.org/W1976733851","https://openalex.org/W1996873145","https://openalex.org/W2007395447","https://openalex.org/W2022270174","https://openalex.org/W2026108012","https://openalex.org/W2029227600","https://openalex.org/W2032082925","https://openalex.org/W2034467076","https://openalex.org/W2058128681","https://openalex.org/W2067897176","https://openalex.org/W2069022257","https://openalex.org/W2072147451","https://openalex.org/W2080306433","https://openalex.org/W2089645827","https://openalex.org/W2099198411","https://openalex.org/W2136698583","https://openalex.org/W2169151120","https://openalex.org/W2189835188","https://openalex.org/W2215208662","https://openalex.org/W2279836435","https://openalex.org/W2287970811","https://openalex.org/W2308581119","https://openalex.org/W2325439480","https://openalex.org/W2489001055","https://openalex.org/W2592634495","https://openalex.org/W2749950284","https://openalex.org/W2770370523","https://openalex.org/W2789551058","https://openalex.org/W2801556762","https://openalex.org/W2801948185","https://openalex.org/W2802450038","https://openalex.org/W2907821191","https://openalex.org/W2942735406","https://openalex.org/W2980513544","https://openalex.org/W3087969336","https://openalex.org/W3092193339","https://openalex.org/W3116223999"],"related_works":["https://openalex.org/W2215938508","https://openalex.org/W2343664856","https://openalex.org/W3010211965","https://openalex.org/W1968685749","https://openalex.org/W2019244529","https://openalex.org/W2109400022","https://openalex.org/W1941839265","https://openalex.org/W2066541269","https://openalex.org/W4401975967","https://openalex.org/W2024708768"],"abstract_inverted_index":{"Herein,":[0],"we":[1],"demonstrate":[2],"that":[3,118],"the":[4,18,62,68,109,124],"photochemical":[5],"cleavage":[6],"of":[7,61,70,77],"linear":[8],"polymers":[9],"containing":[10],"a":[11,51,97],"midchain":[12],"photocleavable":[13,132],"moiety":[14,65],"strongly":[15,90],"depends":[16],"on":[17,22,123],"chain":[19,111,126],"length.":[20],"Based":[21],"an":[23],"ortho":[24,63],"-nitrobenzyl":[25,64],"(":[26,37],"o":[27,78],"NB)":[28],"difunctional":[29],"reversible":[30],"addition\u2013fragmentation":[31],"chain-transfer":[32],"agent,":[33],"well-defined":[34],"poly(methyl":[35],"acrylate)s":[36],"M":[38],"n":[39],"=":[40,46,58],"1.59\u201367.6":[41],"kg":[42],"mol":[43],"\u20131,":[44],"\u0110":[45],"1.3\u20131.4)":[47],"were":[48],"synthesized":[49],"following":[50],"core-first":[52],"approach.":[53],"Photolysis":[54],"at":[55],"\u03bb":[56],"max":[57],"350":[59],"nm":[60],"led":[66],"to":[67,108],"generation":[69],"equally":[71],"sized":[72],"polymer":[73,80,119,125],"segments.":[74],"The":[75,113],"rate":[76],"NB-driven":[79],"fragmentation,":[81],"which":[82],"can":[83],"be":[84],"well":[85],"described":[86],"by":[87,102],"first-order":[88],"kinetics,":[89],"increases":[91],"with":[92,128],"increasing":[93],"molecular":[94],"weight":[95],"in":[96],"nonlinear":[98],"fashion,":[99],"potentially":[100],"caused":[101],"entropic":[103],"considerations":[104],"and":[105],"is":[106,121],"compared":[107],"ideal":[110],"model.":[112],"current":[114],"study":[115],"thus":[116],"demonstrates":[117],"photolysis":[120],"dependent":[122],"length,":[127],"critical":[129],"implications":[130],"for":[131],"network":[133],"design.":[134]},"counts_by_year":[{"year":2026,"cited_by_count":4},{"year":2025,"cited_by_count":3},{"year":2024,"cited_by_count":5},{"year":2023,"cited_by_count":2},{"year":2022,"cited_by_count":4},{"year":2021,"cited_by_count":2}],"updated_date":"2026-11-06T12:05:46.655746","created_date":"2021-04-13T00:00:00"}