{"id":"https://openalex.org/W3127059707","doi":"https://doi.org/10.1021/acscatal.0c05481","title":"Copper-Catalyzed Meta-Selective Arylation of Phenol Derivatives: An Easy Access to m-Aryl Phenols","display_name":"Copper-Catalyzed Meta-Selective Arylation of Phenol Derivatives: An Easy Access to m-Aryl Phenols","publication_year":2021,"publication_date":"2021-02-05","ids":{"openalex":"https://openalex.org/W3127059707","doi":"https://doi.org/10.1021/acscatal.0c05481","mag":"3127059707"},"language":"en","primary_location":{"id":"doi:10.1021/acscatal.0c05481","doi":"https://doi.org/10.1021/acscatal.0c05481","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acscatal.0c05481","pdf_url":null,"source":{"id":"https://openalex.org/S37391459","display_name":"ACS Catalysis","issn_l":"2155-5435","issn":["2155-5435"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Catalysis","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5021695333","display_name":"Manikantha Maraswami","orcid":"https://orcid.org/0000-0003-4975-7365","observed_orcids":["https://orcid.org/0000-0003-4975-7365"]},"institutions":[{"id":"https://openalex.org/I172675005","display_name":"Nanyang Technological University","ror":"https://ror.org/02e7b5302","country_code":"SG","type":"education","lineage":["https://openalex.org/I172675005"]}],"countries":["SG"],"is_corresponding":false,"raw_author_name":"Manikantha Maraswami","raw_affiliation_strings":["Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 637371, Singapore"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 637371, Singapore","institution_ids":["https://openalex.org/I172675005"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5048588199","display_name":"Hajime Hirao","orcid":"https://orcid.org/0000-0002-8239-3471","observed_orcids":["https://orcid.org/0000-0002-8239-3471"]},"institutions":[{"id":"https://openalex.org/I177725633","display_name":"Chinese University of Hong Kong","ror":"https://ror.org/00t33hh48","country_code":"HK","type":"education","lineage":["https://openalex.org/I177725633"]},{"id":"https://openalex.org/I4210116924","display_name":"Chinese University of Hong Kong, Shenzhen","ror":"https://ror.org/02d5ks197","country_code":"CN","type":"education","lineage":["https://openalex.org/I177725633","https://openalex.org/I180726961","https://openalex.org/I4210116924"]}],"countries":["CN","HK"],"is_corresponding":true,"raw_author_name":"Hajime Hirao","raw_affiliation_strings":["School of Life and Health Sciences, The Chinese University of Hong Kong, Shenzhen, Longgang District, Shenzhen, Guangdong Province 518172, China","Warshel Institute for Computational Biology, The Chinese University of Hong Kong, Shenzhen, Longgang District, Shenzhen, Guangdong Province 518172, China"],"raw_orcid":"https://orcid.org/0000-0002-8239-3471","affiliations":[{"raw_affiliation_string":"School of Life and Health Sciences, The Chinese University of Hong Kong, Shenzhen, Longgang District, Shenzhen, Guangdong Province 518172, China","institution_ids":["https://openalex.org/I177725633","https://openalex.org/I4210116924"]},{"raw_affiliation_string":"Warshel Institute for Computational Biology, The Chinese University of Hong Kong, Shenzhen, Longgang District, Shenzhen, Guangdong Province 518172, China","institution_ids":["https://openalex.org/I4210116924"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5035805485","display_name":"Teck\u2010Peng Loh","orcid":"https://orcid.org/0000-0002-2936-337X","observed_orcids":["https://orcid.org/0000-0002-2936-337X"]},"institutions":[{"id":"https://openalex.org/I17145004","display_name":"Northwestern Polytechnical University","ror":"https://ror.org/01y0j0j86","country_code":"CN","type":"education","lineage":["https://openalex.org/I17145004"]},{"id":"https://openalex.org/I172675005","display_name":"Nanyang Technological University","ror":"https://ror.org/02e7b5302","country_code":"SG","type":"education","lineage":["https://openalex.org/I172675005"]}],"countries":["CN","SG"],"is_corresponding":true,"raw_author_name":"Teck-Peng Loh","raw_affiliation_strings":["Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 637371, Singapore","Institute of Advanced Synthesis (IAS), School of Chemistry and Chemical Engineering, Northwestern Polytechnical University (NPU), Xi\u2019an 710072, China","Yangtze River Delta Research Institute of NPU, Taicang, Jiangsu 215400, China"],"raw_orcid":"https://orcid.org/0000-0002-2936-337X","affiliations":[{"raw_affiliation_string":"Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 637371, Singapore","institution_ids":["https://openalex.org/I172675005"]},{"raw_affiliation_string":"Institute of Advanced Synthesis (IAS), School of Chemistry and Chemical Engineering, Northwestern Polytechnical University (NPU), Xi\u2019an 710072, China","institution_ids":["https://openalex.org/I17145004"]},{"raw_affiliation_string":"Yangtze River Delta Research Institute of NPU, Taicang, Jiangsu 215400, China","institution_ids":[]}]}],"institutions":[],"countries_distinct_count":3,"institutions_distinct_count":4,"corresponding_author_ids":["https://openalex.org/A5035805485","https://openalex.org/A5048588199"],"corresponding_institution_ids":["https://openalex.org/I17145004","https://openalex.org/I172675005","https://openalex.org/I177725633","https://openalex.org/I4210116924"],"apc_list":{"value":5000,"currency":"USD","value_usd":5000},"apc_paid":null,"fwci":1.6325,"has_fulltext":false,"cited_by_count":28,"citation_normalized_percentile":{"value":0.81209132,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":95,"max":99},"biblio":{"volume":"11","issue":"4","first_page":"2302","last_page":"2309"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10548","display_name":"Catalytic Cross-Coupling Reactions","score":0.8651999831199646,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10548","display_name":"Catalytic Cross-Coupling Reactions","score":0.8651999831199646,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10354","display_name":"Catalytic C\u2013H Functionalization Methods","score":0.13169999420642853,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12189","display_name":"Sulfur-Based Synthesis Techniques","score":0.001500000013038516,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/copper-catalysis","display_name":"copper catalysis","score":0.9649999737739563},{"id":"https://openalex.org/keywords/phenols","display_name":"phenols","score":0.722000002861023},{"id":"https://openalex.org/keywords/directing-groups","display_name":"directing groups","score":0.6010000109672546},{"id":"https://openalex.org/keywords/functional-group-tolerance","display_name":"functional group tolerance","score":0.7200000286102295},{"id":"https://openalex.org/keywords/c-h-functionalization","display_name":"C\u2013H functionalization","score":0.5920000076293945}],"concepts":[{"id":"https://openalex.org/C2777728882","wikidata":"https://www.wikidata.org/wiki/Q407142","display_name":"Phenols","level":2,"score":0.801241934299469},{"id":"https://openalex.org/C2781076698","wikidata":"https://www.wikidata.org/wiki/Q718074","display_name":"Aryl","level":3,"score":0.7377302050590515},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.729157030582428},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7107998728752136},{"id":"https://openalex.org/C2777702071","wikidata":"https://www.wikidata.org/wiki/Q130336","display_name":"Phenol","level":2,"score":0.687687337398529},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.6179074048995972},{"id":"https://openalex.org/C544778455","wikidata":"https://www.wikidata.org/wiki/Q753","display_name":"Copper","level":2,"score":0.5714123249053955},{"id":"https://openalex.org/C115537861","wikidata":"https://www.wikidata.org/wiki/Q7645993","display_name":"Surface modification","level":2,"score":0.526395320892334},{"id":"https://openalex.org/C118792377","wikidata":"https://www.wikidata.org/wiki/Q108584245","display_name":"Selectivity","level":3,"score":0.4940681755542755},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.46926042437553406},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.0},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1021/acscatal.0c05481","doi":"https://doi.org/10.1021/acscatal.0c05481","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acscatal.0c05481","pdf_url":null,"source":{"id":"https://openalex.org/S37391459","display_name":"ACS Catalysis","issn_l":"2155-5435","issn":["2155-5435"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Catalysis","raw_type":"journal-article"},{"id":"pmh:oai:dr.ntu.edu.sg:10356/159979","doi":null,"is_oa":false,"landing_page_url":"https://hdl.handle.net/10356/159979","pdf_url":null,"source":{"id":"https://openalex.org/S4306402609","display_name":"DR-NTU (Nanyang Technological University)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I172675005","host_organization_name":"Nanyang Technological University","host_organization_lineage":["https://openalex.org/I172675005"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":89,"referenced_works":["https://openalex.org/W571255174","https://openalex.org/W958199577","https://openalex.org/W1905467186","https://openalex.org/W1972224750","https://openalex.org/W1975240837","https://openalex.org/W1977851260","https://openalex.org/W1980862751","https://openalex.org/W1985484434","https://openalex.org/W1988091937","https://openalex.org/W1989688131","https://openalex.org/W1990872426","https://openalex.org/W1991012385","https://openalex.org/W2003640875","https://openalex.org/W2016461749","https://openalex.org/W2017005288","https://openalex.org/W2024983608","https://openalex.org/W2026915412","https://openalex.org/W2041386409","https://openalex.org/W2042405660","https://openalex.org/W2048756564","https://openalex.org/W2050791488","https://openalex.org/W2053433812","https://openalex.org/W2057572037","https://openalex.org/W2058401870","https://openalex.org/W2058792806","https://openalex.org/W2059153246","https://openalex.org/W2060296131","https://openalex.org/W2061142370","https://openalex.org/W2062841450","https://openalex.org/W2063160857","https://openalex.org/W2064262385","https://openalex.org/W2066309940","https://openalex.org/W2067433167","https://openalex.org/W2068195780","https://openalex.org/W2068589900","https://openalex.org/W2068617439","https://openalex.org/W2073885568","https://openalex.org/W2078442327","https://openalex.org/W2085537246","https://openalex.org/W2091678516","https://openalex.org/W2096856823","https://openalex.org/W2097184152","https://openalex.org/W2097186155","https://openalex.org/W2108181912","https://openalex.org/W2110563740","https://openalex.org/W2110930514","https://openalex.org/W2117084768","https://openalex.org/W2119515142","https://openalex.org/W2120153400","https://openalex.org/W2122188849","https://openalex.org/W2125014016","https://openalex.org/W2132810014","https://openalex.org/W2139783896","https://openalex.org/W2143768437","https://openalex.org/W2150697053","https://openalex.org/W2152909116","https://openalex.org/W2163655706","https://openalex.org/W2225285985","https://openalex.org/W2286162655","https://openalex.org/W2315014362","https://openalex.org/W2316321048","https://openalex.org/W2316916804","https://openalex.org/W2319843356","https://openalex.org/W2321928492","https://openalex.org/W2322629797","https://openalex.org/W2323752112","https://openalex.org/W2323979563","https://openalex.org/W2327602306","https://openalex.org/W2327749385","https://openalex.org/W2329119240","https://openalex.org/W2331452414","https://openalex.org/W2337626246","https://openalex.org/W2349506784","https://openalex.org/W2413721036","https://openalex.org/W2462202077","https://openalex.org/W2466331446","https://openalex.org/W2519849782","https://openalex.org/W2576120716","https://openalex.org/W2592549031","https://openalex.org/W2594860913","https://openalex.org/W2612724267","https://openalex.org/W2766799918","https://openalex.org/W2884091089","https://openalex.org/W2911727533","https://openalex.org/W2949772843","https://openalex.org/W2952837374","https://openalex.org/W2953055474","https://openalex.org/W2971135930","https://openalex.org/W3014704490"],"related_works":["https://openalex.org/W2057572037","https://openalex.org/W2867635324","https://openalex.org/W1991012385","https://openalex.org/W2890763670","https://openalex.org/W2952253757","https://openalex.org/W2123049131","https://openalex.org/W2343808724","https://openalex.org/W2466122920","https://openalex.org/W2110563740","https://openalex.org/W7203976356"],"abstract_inverted_index":{"Achieving":[0],"selective":[1],"meta-functionalization":[2],"of":[3,18,49],"phenols":[4,30],"is":[5],"a":[6,24,32,47,65],"significant":[7],"challenge.":[8],"Accessing":[9],"such":[10],"compounds":[11],"generally":[12],"needs":[13],"elevated":[14],"temperature":[15],"or":[16],"incorporation":[17],"complex":[19],"templates.":[20],"Here,":[21],"we":[22],"report":[23],"general":[25],"approach":[26],"to":[27],"achieve":[28],"meta-arylated":[29],"with":[31,42],"simple":[33],"and":[34,45],"common":[35],"directing":[36],"group.":[37],"This":[38],"copper-catalyzed":[39],"protocol":[40],"proceeds":[41],"complete":[43],"meta-selectivity":[44],"tolerates":[46],"variety":[48],"functional":[50],"groups":[51],"in":[52],"both":[53],"coupling":[54],"partners.":[55],"Computational":[56],"studies":[57],"have":[58],"revealed":[59],"that":[60],"the":[61],"reaction":[62],"proceeded":[63],"via":[64],"Heck-like":[66],"pathway.":[67]},"counts_by_year":[{"year":2026,"cited_by_count":4},{"year":2025,"cited_by_count":7},{"year":2024,"cited_by_count":4},{"year":2023,"cited_by_count":5},{"year":2022,"cited_by_count":5},{"year":2021,"cited_by_count":3}],"updated_date":"2026-11-05T12:25:35.769452","created_date":"2021-02-15T00:00:00"}
