{"id":"https://openalex.org/W3020196648","doi":"https://doi.org/10.1021/acscatal.0c01131","title":"Rhodium-Stabilized Diarylcarbenes Behaving as Donor/Acceptor Carbenes","display_name":"Rhodium-Stabilized Diarylcarbenes Behaving as Donor/Acceptor Carbenes","publication_year":2020,"publication_date":"2020-04-27","ids":{"openalex":"https://openalex.org/W3020196648","doi":"https://doi.org/10.1021/acscatal.0c01131","mag":"3020196648","pmid":"https://pubmed.ncbi.nlm.nih.gov/37275336","pmcid":"https://www.ncbi.nlm.nih.gov/pmc/articles/10237626"},"language":"en","primary_location":{"id":"doi:10.1021/acscatal.0c01131","doi":"https://doi.org/10.1021/acscatal.0c01131","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acscatal.0c01131","pdf_url":null,"source":{"id":"https://openalex.org/S37391459","display_name":"ACS Catalysis","issn_l":"2155-5435","issn":["2155-5435"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Catalysis","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://pmc.ncbi.nlm.nih.gov/articles/PMC10237626/pdf/nihms-1903752.pdf","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5091261511","display_name":"Maizie Lee","orcid":"https://orcid.org/0000-0003-0241-5130","observed_orcids":["https://orcid.org/0000-0003-0241-5130"]},"institutions":[{"id":"https://openalex.org/I150468666","display_name":"Emory University","ror":"https://ror.org/03czfpz43","country_code":"US","type":"education","lineage":["https://openalex.org/I150468666"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Maizie Lee","raw_affiliation_strings":["Department of Chemistry, Emory University, 1515 Dickey Drive, Atlanta, Georgia 30322, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Emory University, 1515 Dickey Drive, Atlanta, Georgia 30322, United States","institution_ids":["https://openalex.org/I150468666"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5056603372","display_name":"Zhi Min Ren","orcid":"https://orcid.org/0000-0001-9812-0251","observed_orcids":["https://orcid.org/0000-0001-9812-0251"]},"institutions":[{"id":"https://openalex.org/I150468666","display_name":"Emory University","ror":"https://ror.org/03czfpz43","country_code":"US","type":"education","lineage":["https://openalex.org/I150468666"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Zhi Ren","raw_affiliation_strings":["Department of Chemistry, Emory University, 1515 Dickey Drive, Atlanta, Georgia 30322, United States"],"raw_orcid":"https://orcid.org/0000-0001-9812-0251","affiliations":[{"raw_affiliation_string":"Department of Chemistry, Emory University, 1515 Dickey Drive, Atlanta, Georgia 30322, United States","institution_ids":["https://openalex.org/I150468666"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5012743614","display_name":"Djamaladdin G. Musaev","orcid":"https://orcid.org/0000-0003-1160-6131","observed_orcids":["https://orcid.org/0000-0003-1160-6131"]},"institutions":[{"id":"https://openalex.org/I150468666","display_name":"Emory University","ror":"https://ror.org/03czfpz43","country_code":"US","type":"education","lineage":["https://openalex.org/I150468666"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Djamaladdin G. Musaev","raw_affiliation_strings":["Cherry L. Emerson Center for Scientific Computation, Emory University, 1521 Dickey Drive, Atlanta, Georgia 30322, United States"],"raw_orcid":"https://orcid.org/0000-0003-1160-6131","affiliations":[{"raw_affiliation_string":"Cherry L. Emerson Center for Scientific Computation, Emory University, 1521 Dickey Drive, Atlanta, Georgia 30322, United States","institution_ids":["https://openalex.org/I150468666"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5083948798","display_name":"Huw M. L. Davies","orcid":"https://orcid.org/0000-0001-6254-9398","observed_orcids":["https://orcid.org/0000-0001-6254-9398"]},"institutions":[{"id":"https://openalex.org/I150468666","display_name":"Emory University","ror":"https://ror.org/03czfpz43","country_code":"US","type":"education","lineage":["https://openalex.org/I150468666"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Huw M. L. Davies","raw_affiliation_strings":["Department of Chemistry, Emory University, 1515 Dickey Drive, Atlanta, Georgia 30322, United States"],"raw_orcid":"https://orcid.org/0000-0001-6254-9398","affiliations":[{"raw_affiliation_string":"Department of Chemistry, Emory University, 1515 Dickey Drive, Atlanta, Georgia 30322, United States","institution_ids":["https://openalex.org/I150468666"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5012743614","https://openalex.org/A5083948798"],"corresponding_institution_ids":["https://openalex.org/I150468666"],"apc_list":{"value":5000,"currency":"USD","value_usd":5000},"apc_paid":null,"fwci":3.7256,"has_fulltext":true,"cited_by_count":62,"citation_normalized_percentile":{"value":0.95131231,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":95,"max":100},"biblio":{"volume":"10","issue":"11","first_page":"6240","last_page":"6247"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11611","display_name":"Cyclopropane Reaction Mechanisms","score":0.9955999851226807,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11611","display_name":"Cyclopropane Reaction Mechanisms","score":0.9955999851226807,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11790","display_name":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","score":0.002300000051036477,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.0005000000237487257,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/dirhodium-catalysts","display_name":"dirhodium catalysts","score":0.7699999809265137},{"id":"https://openalex.org/keywords/cyclopropanation","display_name":"cyclopropanation","score":0.8450000286102295},{"id":"https://openalex.org/keywords/enantioselectivity","display_name":"enantioselectivity","score":0.8370000123977661},{"id":"https://openalex.org/keywords/diastereoselectivity","display_name":"diastereoselectivity","score":0.996999979019165},{"id":"https://openalex.org/keywords/chiral-ligands","display_name":"chiral ligands","score":0.5770000219345093},{"id":"https://openalex.org/keywords/carbene-reactivity","display_name":"carbene reactivity","score":0.5009999871253967}],"concepts":[{"id":"https://openalex.org/C521398313","wikidata":"https://www.wikidata.org/wiki/Q1087","display_name":"Rhodium","level":3,"score":0.9612528085708618},{"id":"https://openalex.org/C2777164566","wikidata":"https://www.wikidata.org/wiki/Q419257","display_name":"Carbene","level":3,"score":0.8962074518203735},{"id":"https://openalex.org/C146686406","wikidata":"https://www.wikidata.org/wiki/Q898628","display_name":"Enantioselective synthesis","level":3,"score":0.7337947487831116},{"id":"https://openalex.org/C2781076698","wikidata":"https://www.wikidata.org/wiki/Q718074","display_name":"Aryl","level":3,"score":0.7278855443000793},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6661233901977539},{"id":"https://openalex.org/C2779892579","wikidata":"https://www.wikidata.org/wiki/Q912138","display_name":"Acceptor","level":2,"score":0.6480562090873718},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.5651628375053406},{"id":"https://openalex.org/C2776910235","wikidata":"https://www.wikidata.org/wiki/Q18574","display_name":"Reactivity (psychology)","level":3,"score":0.538569450378418},{"id":"https://openalex.org/C2777052750","wikidata":"https://www.wikidata.org/wiki/Q17156600","display_name":"Cyclopropanation","level":3,"score":0.5173584818840027},{"id":"https://openalex.org/C2780378348","wikidata":"https://www.wikidata.org/wiki/Q25351438","display_name":"Ring (chemistry)","level":2,"score":0.48581910133361816},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.3620891869068146},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.361810564994812},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.1764335334300995},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.06823605298995972},{"id":"https://openalex.org/C26873012","wikidata":"https://www.wikidata.org/wiki/Q214781","display_name":"Condensed matter physics","level":1,"score":0.0},{"id":"https://openalex.org/C142724271","wikidata":"https://www.wikidata.org/wiki/Q7208","display_name":"Pathology","level":1,"score":0.0},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.0},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.0},{"id":"https://openalex.org/C204787440","wikidata":"https://www.wikidata.org/wiki/Q188504","display_name":"Alternative medicine","level":2,"score":0.0}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1021/acscatal.0c01131","doi":"https://doi.org/10.1021/acscatal.0c01131","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acscatal.0c01131","pdf_url":null,"source":{"id":"https://openalex.org/S37391459","display_name":"ACS Catalysis","issn_l":"2155-5435","issn":["2155-5435"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Catalysis","raw_type":"journal-article"},{"id":"pmid:37275336","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/37275336","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS catalysis","raw_type":"Journal Article"},{"id":"pmh:oai:pubmedcentral.nih.gov:10237626","doi":null,"is_oa":true,"landing_page_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/10237626","pdf_url":"https://pmc.ncbi.nlm.nih.gov/articles/PMC10237626/pdf/nihms-1903752.pdf","source":{"id":"https://openalex.org/S2764455111","display_name":"PubMed Central","issn_l":null,"issn":null,"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":"ACS Catal","raw_type":"Text"}],"best_oa_location":{"id":"pmh:oai:pubmedcentral.nih.gov:10237626","doi":null,"is_oa":true,"landing_page_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/10237626","pdf_url":"https://pmc.ncbi.nlm.nih.gov/articles/PMC10237626/pdf/nihms-1903752.pdf","source":{"id":"https://openalex.org/S2764455111","display_name":"PubMed Central","issn_l":null,"issn":null,"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":"ACS Catal","raw_type":"Text"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G2027168600","display_name":null,"funder_award_id":"1700982","funder_id":"https://openalex.org/F4320337393","funder_display_name":"Division of Chemistry"},{"id":"https://openalex.org/G2071680558","display_name":"New Directions in Enantioselective C-H Functionalization","funder_award_id":"R01GM099142","funder_id":"https://openalex.org/F4320337354","funder_display_name":"National Institute of General Medical Sciences"},{"id":"https://openalex.org/G236029928","display_name":null,"funder_award_id":"CHE-1626172","funder_id":"https://openalex.org/F4320337393","funder_display_name":"Division of Chemistry"},{"id":"https://openalex.org/G2519521358","display_name":"MRI: Acquisition of a 600 MHz NMR Spectrometer for Chemistry","funder_award_id":"1531620","funder_id":"https://openalex.org/F4320306076","funder_display_name":"National Science Foundation"},{"id":"https://openalex.org/G3085896116","display_name":null,"funder_award_id":"1531620","funder_id":"https://openalex.org/F4320337393","funder_display_name":"Division of Chemistry"},{"id":"https://openalex.org/G3274925470","display_name":"MRI: Acquisition of a High Intensity Single Crystal X-ray Diffractometer","funder_award_id":"1626172","funder_id":"https://openalex.org/F4320306076","funder_display_name":"National Science Foundation"},{"id":"https://openalex.org/G4421890870","display_name":null,"funder_award_id":"CHE-1700982","funder_id":"https://openalex.org/F4320337393","funder_display_name":"Division of Chemistry"},{"id":"https://openalex.org/G454325550","display_name":null,"funder_award_id":"CHE 1531620","funder_id":"https://openalex.org/F4320337393","funder_display_name":"Division of Chemistry"},{"id":"https://openalex.org/G803071204","display_name":"NSF Center for Selective CH Functionalization","funder_award_id":"1700982","funder_id":"https://openalex.org/F4320306076","funder_display_name":"National Science Foundation"}],"funders":[{"id":"https://openalex.org/F4320306076","display_name":"National Science Foundation","ror":"https://ror.org/021nxhr62"},{"id":"https://openalex.org/F4320309381","display_name":"Emory University","ror":"https://ror.org/03czfpz43"},{"id":"https://openalex.org/F4320337354","display_name":"National Institute of General Medical Sciences","ror":"https://ror.org/04q48ey07"},{"id":"https://openalex.org/F4320337393","display_name":"Division of Chemistry","ror":"https://ror.org/01ar8dr59"}],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W3020196648.pdf","grobid_xml":"https://content.openalex.org/works/W3020196648.grobid-xml"},"referenced_works_count":54,"referenced_works":["https://openalex.org/W617891233","https://openalex.org/W640030404","https://openalex.org/W1148208603","https://openalex.org/W1964284609","https://openalex.org/W1966182479","https://openalex.org/W1982356449","https://openalex.org/W1984232099","https://openalex.org/W1984605747","https://openalex.org/W1989156004","https://openalex.org/W1994882314","https://openalex.org/W1997833502","https://openalex.org/W2009904876","https://openalex.org/W2013665598","https://openalex.org/W2016847480","https://openalex.org/W2023271753","https://openalex.org/W2024874069","https://openalex.org/W2027137290","https://openalex.org/W2034554844","https://openalex.org/W2039559098","https://openalex.org/W2044490585","https://openalex.org/W2050359473","https://openalex.org/W2051778076","https://openalex.org/W2055468380","https://openalex.org/W2056594639","https://openalex.org/W2058848030","https://openalex.org/W2068617439","https://openalex.org/W2086957099","https://openalex.org/W2092157292","https://openalex.org/W2098919928","https://openalex.org/W2099955759","https://openalex.org/W2100312378","https://openalex.org/W2105436702","https://openalex.org/W2131074179","https://openalex.org/W2162010830","https://openalex.org/W2173005426","https://openalex.org/W2283724313","https://openalex.org/W2311990895","https://openalex.org/W2318029555","https://openalex.org/W2319112640","https://openalex.org/W2322568743","https://openalex.org/W2410085868","https://openalex.org/W2589152395","https://openalex.org/W2590975633","https://openalex.org/W2620554660","https://openalex.org/W2772590431","https://openalex.org/W2887606625","https://openalex.org/W2889806851","https://openalex.org/W2891441538","https://openalex.org/W2891928443","https://openalex.org/W2944679719","https://openalex.org/W2950797181","https://openalex.org/W2951745804","https://openalex.org/W2973858315","https://openalex.org/W2984935654"],"related_works":["https://openalex.org/W2283724313","https://openalex.org/W2950444793","https://openalex.org/W2009904876","https://openalex.org/W4231340221","https://openalex.org/W4306913805","https://openalex.org/W2950931125","https://openalex.org/W2088829679","https://openalex.org/W4306822733","https://openalex.org/W2046912512","https://openalex.org/W2950138013"],"abstract_inverted_index":{"Rhodium-stabilized":[0],"diarylcarbenes":[1,21],"typically":[2],"generated":[3],"from":[4],"diaryldiazomethanes":[5],"have":[6],"been":[7],"generally":[8],"classified":[9],"as":[10,102,113],"donor/donor":[11],"carbenes.":[12,31],"This":[13],"combined":[14],"computational":[15],"and":[16,49,58],"experimental":[17],"study":[18],"demonstrates":[19],"that":[20,25],"display":[22],"reactivity":[23],"characteristics":[24],"are":[26,35,76],"more":[27],"reminiscent":[28],"of":[29,83,98],"donor/acceptor":[30],"When":[32],"the":[33,39,73,81,84,88,96,99,107],"reactions":[34],"carried":[36],"out":[37],"with":[38],"chiral":[40],"dirhodium":[41],"catalysts":[42],"Rh":[43,50],"2":[44,51],"(":[45,52],"S":[46,53],"-PTAD)":[47],"4":[48],"-NTTL)":[54],"4,":[55],"highly":[56],"enantioselective":[57],"diastereoselective":[59],"cyclopropanations":[60],"can":[61],"be":[62],"achieved,":[63],"forming":[64],"1,1,2-triarylcyclopropanes.":[65],"The":[66,91],"reason":[67],"for":[68],"this":[69],"behavior":[70],"is":[71],"because":[72],"two":[74],"rings":[75],"unable":[77],"to":[78],"align":[79],"in":[80,95],"plane":[82,97],"rhodium":[85],"carbene":[86,100],"at":[87],"same":[89],"time.":[90],"aryl":[92,108],"ring":[93,109],"aligned":[94,110],"behaves":[101,112],"a":[103],"donor":[104],"group,":[105],"whereas":[106],"orthogonally":[111],"an":[114],"acceptor":[115],"group.":[116]},"counts_by_year":[{"year":2026,"cited_by_count":6},{"year":2025,"cited_by_count":3},{"year":2024,"cited_by_count":13},{"year":2023,"cited_by_count":7},{"year":2022,"cited_by_count":8},{"year":2021,"cited_by_count":20},{"year":2020,"cited_by_count":5}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2020-05-01T00:00:00"}
