{"id":"https://openalex.org/W3018494381","doi":"https://doi.org/10.1039/d0nr01629b","title":"Finding the true pathway for reversible isomerization of a single azobenzene molecule tumbling on Au(111) surface","display_name":"Finding the true pathway for reversible isomerization of a single azobenzene molecule tumbling on Au(111) surface","publication_year":2020,"publication_date":"2020-01-01","ids":{"openalex":"https://openalex.org/W3018494381","doi":"https://doi.org/10.1039/d0nr01629b","mag":"3018494381","pmid":"https://pubmed.ncbi.nlm.nih.gov/32373867"},"language":"en","primary_location":{"id":"doi:10.1039/d0nr01629b","doi":"https://doi.org/10.1039/d0nr01629b","is_oa":false,"landing_page_url":"https://doi.org/10.1039/d0nr01629b","pdf_url":null,"source":{"id":"https://openalex.org/S23181512","display_name":"Nanoscale","issn_l":"2040-3364","issn":["2040-3364","2040-3372"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-3","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Nanoscale","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5022078199","display_name":"Zhen Xie","orcid":"https://orcid.org/0000-0003-3383-8080","observed_orcids":["https://orcid.org/0000-0003-3383-8080"]},"institutions":[{"id":"https://openalex.org/I28006308","display_name":"Shandong Normal University","ror":"https://ror.org/01wy3h363","country_code":"CN","type":"education","lineage":["https://openalex.org/I28006308"]},{"id":"https://openalex.org/I86987016","display_name":"KTH Royal Institute of Technology","ror":"https://ror.org/026vcq606","country_code":"SE","type":"education","lineage":["https://openalex.org/I86987016"]}],"countries":["CN","SE"],"is_corresponding":false,"raw_author_name":"Zhen Xie","raw_affiliation_strings":["Jinan 250014","People's Republic of China","School of Physics and Electronics","Shandong Normal University","Shandong Province Key Laboratory of Medical Physics and Image Processing Technology","Department of Theoretical Chemistry and Biology, School of Engineering Sciences in Chemistry, Biotechnology and Health, KTH Royal Institute of Technology, S-106 91 Stockholm, Sweden","Shandong Province Key Laboratory of Medical Physics and Image Processing Technology, School of Physics and Electronics, Shandong Normal University, Jinan 250014, People's Republic of China"],"raw_orcid":"https://orcid.org/0000-0003-3383-8080","affiliations":[{"raw_affiliation_string":"Jinan 250014","institution_ids":[]},{"raw_affiliation_string":"People's Republic of China","institution_ids":[]},{"raw_affiliation_string":"School of Physics and Electronics","institution_ids":[]},{"raw_affiliation_string":"Shandong Normal University","institution_ids":["https://openalex.org/I28006308"]},{"raw_affiliation_string":"Shandong Province Key Laboratory of Medical Physics and Image Processing Technology","institution_ids":[]},{"raw_affiliation_string":"Department of Theoretical Chemistry and Biology, School of Engineering Sciences in Chemistry, Biotechnology and Health, KTH Royal Institute of Technology, S-106 91 Stockholm, Sweden","institution_ids":["https://openalex.org/I86987016"]},{"raw_affiliation_string":"Shandong Province Key Laboratory of Medical Physics and Image Processing Technology, School of Physics and Electronics, Shandong Normal University, Jinan 250014, People's Republic of China","institution_ids":["https://openalex.org/I28006308"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5082788658","display_name":"Sai Duan","orcid":"https://orcid.org/0000-0002-3282-0711","observed_orcids":["https://orcid.org/0000-0002-3282-0711"]},"institutions":[{"id":"https://openalex.org/I24943067","display_name":"Fudan University","ror":"https://ror.org/013q1eq08","country_code":"CN","type":"education","lineage":["https://openalex.org/I24943067"]},{"id":"https://openalex.org/I4210156571","display_name":"Collaborative Innovation Center of Chemistry for Energy Materials","ror":"https://ror.org/05fdv7d34","country_code":"CN","type":"facility","lineage":["https://openalex.org/I4210156571"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Sai Duan","raw_affiliation_strings":["Collaborative Innovation Center of Chemistry for Energy Materials","Department of Chemistry","Key Laboratory of Molecular Catalysis and Innovative Materials","MOE Key Laboratory of Computational Physical Sciences","Shanghai","Collaborative Innovation Center of Chemistry for Energy Materials, Shanghai, Key Laboratory of Molecular Catalysis and Innovative Materials, MOE Key Laboratory of Computational Physical Sciences, Department of Chemistry, Fudan University, Shanghai 200433, People's Republic of China"],"raw_orcid":"https://orcid.org/0000-0002-3282-0711","affiliations":[{"raw_affiliation_string":"Collaborative Innovation Center of Chemistry for Energy Materials","institution_ids":["https://openalex.org/I4210156571"]},{"raw_affiliation_string":"Department of Chemistry","institution_ids":[]},{"raw_affiliation_string":"Key Laboratory of Molecular Catalysis and Innovative Materials","institution_ids":[]},{"raw_affiliation_string":"MOE Key Laboratory of Computational Physical Sciences","institution_ids":[]},{"raw_affiliation_string":"Shanghai","institution_ids":[]},{"raw_affiliation_string":"Collaborative Innovation Center of Chemistry for Energy Materials, Shanghai, Key Laboratory of Molecular Catalysis and Innovative Materials, MOE Key Laboratory of Computational Physical Sciences, Department of Chemistry, Fudan University, Shanghai 200433, People's Republic of China","institution_ids":["https://openalex.org/I24943067","https://openalex.org/I4210156571"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5115591101","display_name":"Chuan\u2010Kui Wang","orcid":"https://orcid.org/0009-0004-6749-8365","observed_orcids":["https://orcid.org/0009-0004-6749-8365","https://orcid.org/0000-0002-6977-988X"]},"institutions":[{"id":"https://openalex.org/I28006308","display_name":"Shandong Normal University","ror":"https://ror.org/01wy3h363","country_code":"CN","type":"education","lineage":["https://openalex.org/I28006308"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Chuan-Kui Wang","raw_affiliation_strings":["Jinan 250014","People's Republic of China","School of Physics and Electronics","Shandong Normal University","Shandong Province Key Laboratory of Medical Physics and Image Processing Technology","Shandong Province Key Laboratory of Medical Physics and Image Processing Technology, School of Physics and Electronics, Shandong Normal University, Jinan 250014, People's Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Jinan 250014","institution_ids":[]},{"raw_affiliation_string":"People's Republic of China","institution_ids":[]},{"raw_affiliation_string":"School of Physics and Electronics","institution_ids":[]},{"raw_affiliation_string":"Shandong Normal University","institution_ids":["https://openalex.org/I28006308"]},{"raw_affiliation_string":"Shandong Province Key Laboratory of Medical Physics and Image Processing Technology","institution_ids":[]},{"raw_affiliation_string":"Shandong Province Key Laboratory of Medical Physics and Image Processing Technology, School of Physics and Electronics, Shandong Normal University, Jinan 250014, People's Republic of China","institution_ids":["https://openalex.org/I28006308"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5057282533","display_name":"Yi Luo","orcid":"https://orcid.org/0000-0003-0007-0394","observed_orcids":["https://orcid.org/0000-0003-0007-0394"]},"institutions":[{"id":"https://openalex.org/I126520041","display_name":"University of Science and Technology of China","ror":"https://ror.org/04c4dkn09","country_code":"CN","type":"education","lineage":["https://openalex.org/I126520041","https://openalex.org/I19820366"]},{"id":"https://openalex.org/I86987016","display_name":"KTH Royal Institute of Technology","ror":"https://ror.org/026vcq606","country_code":"SE","type":"education","lineage":["https://openalex.org/I86987016"]}],"countries":["CN","SE"],"is_corresponding":true,"raw_author_name":"Yi Luo","raw_affiliation_strings":["Biotechnology and Health","Department of Theoretical Chemistry and Biology","KTH Royal Institute of Technology","S-106 91 Stockholm","School of Engineering Sciences in Chemistry","Department of Theoretical Chemistry and Biology, School of Engineering Sciences in Chemistry, Biotechnology and Health, KTH Royal Institute of Technology, S-106 91 Stockholm, Sweden","Hefei National Laboratory for Physical Science at the Microscale and Synergetic Innovation Center of Quantum Information & Quantum Physics, University of Science and Technology of China, Hefei, 230026 Anhui, People's Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Biotechnology and Health","institution_ids":[]},{"raw_affiliation_string":"Department of Theoretical Chemistry and Biology","institution_ids":[]},{"raw_affiliation_string":"KTH Royal Institute of Technology","institution_ids":["https://openalex.org/I86987016"]},{"raw_affiliation_string":"S-106 91 Stockholm","institution_ids":[]},{"raw_affiliation_string":"School of Engineering Sciences in Chemistry","institution_ids":[]},{"raw_affiliation_string":"Department of Theoretical Chemistry and Biology, School of Engineering Sciences in Chemistry, Biotechnology and Health, KTH Royal Institute of Technology, S-106 91 Stockholm, Sweden","institution_ids":["https://openalex.org/I86987016"]},{"raw_affiliation_string":"Hefei National Laboratory for Physical Science at the Microscale and Synergetic Innovation Center of Quantum Information & Quantum Physics, University of Science and Technology of China, Hefei, 230026 Anhui, People's Republic of China","institution_ids":["https://openalex.org/I126520041"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":5,"corresponding_author_ids":["https://openalex.org/A5057282533","https://openalex.org/A5082788658"],"corresponding_institution_ids":["https://openalex.org/I126520041","https://openalex.org/I24943067","https://openalex.org/I4210156571","https://openalex.org/I86987016"],"apc_list":null,"apc_paid":null,"fwci":0.8606,"has_fulltext":false,"cited_by_count":11,"citation_normalized_percentile":{"value":0.63261837,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":87,"max":97},"biblio":{"volume":"12","issue":"19","first_page":"10474","last_page":"10479"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12285","display_name":"Surface Chemistry and Catalysis","score":0.6615999937057495,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12285","display_name":"Surface Chemistry and Catalysis","score":0.6615999937057495,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10913","display_name":"Molecular Junctions and Nanostructures","score":0.2709999978542328,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11708","display_name":"Photochromic and Fluorescence Chemistry","score":0.060600001364946365,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/azobenzene","display_name":"azobenzene","score":0.9980000257492065},{"id":"https://openalex.org/keywords/trans-cis-isomerization","display_name":"trans-cis isomerization","score":0.9490000009536743},{"id":"https://openalex.org/keywords/au-111","display_name":"Au(111)","score":0.949999988079071},{"id":"https://openalex.org/keywords/bistability","display_name":"bistability","score":0.6019999980926514},{"id":"https://openalex.org/keywords/molecular-switching","display_name":"molecular switching","score":0.45899999141693115},{"id":"https://openalex.org/keywords/molecular-motion","display_name":"molecular motion","score":0.4050000011920929},{"id":"https://openalex.org/keywords/kinetic-stability","display_name":"kinetic stability","score":0.5450000166893005},{"id":"https://openalex.org/keywords/molecular-devices","display_name":"molecular devices","score":0.5099999904632568}],"concepts":[{"id":"https://openalex.org/C2778150588","wikidata":"https://www.wikidata.org/wiki/Q8884513","display_name":"Azobenzene","level":3,"score":0.957304060459137},{"id":"https://openalex.org/C126661725","wikidata":"https://www.wikidata.org/wiki/Q903420","display_name":"Isomerization","level":3,"score":0.8901801109313965},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.5276466608047485},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.41622069478034973},{"id":"https://openalex.org/C125277925","wikidata":"https://www.wikidata.org/wiki/Q2572687","display_name":"Potential energy surface","level":3,"score":0.4152640104293823},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.37925422191619873},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.3750123977661133},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.11792489886283875},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.05106496810913086}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1039/d0nr01629b","doi":"https://doi.org/10.1039/d0nr01629b","is_oa":false,"landing_page_url":"https://doi.org/10.1039/d0nr01629b","pdf_url":null,"source":{"id":"https://openalex.org/S23181512","display_name":"Nanoscale","issn_l":"2040-3364","issn":["2040-3364","2040-3372"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-3","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Nanoscale","raw_type":"journal-article"},{"id":"pmid:32373867","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/32373867","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Nanoscale","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G2548614040","display_name":null,"funder_award_id":"21790350","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"},{"id":"https://openalex.org/G54932743","display_name":null,"funder_award_id":"21633007","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"},{"id":"https://openalex.org/G5595687939","display_name":"\u77f3\u58a8\u70ef\u57fa\u5206\u5b50\u903b\u8f91\u95e8\u5668\u4ef6\u7406\u8bba\u8bbe\u8ba1\u53ca\u673a\u7406\u548c\u53ef\u9760\u6027\u7814\u7a76","funder_award_id":"11874242","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"},{"id":"https://openalex.org/G8673316271","display_name":null,"funder_award_id":"2017YFA0303500","funder_id":"https://openalex.org/F4320321540","funder_display_name":"Ministry of Science and Technology of the People's Republic of China"}],"funders":[{"id":"https://openalex.org/F4320321001","display_name":"National Natural Science Foundation of China","ror":"https://ror.org/01h0zpd94"},{"id":"https://openalex.org/F4320321540","display_name":"Ministry of Science and Technology of the People's Republic of China","ror":"https://ror.org/027s68j25"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":39,"referenced_works":["https://openalex.org/W1970329522","https://openalex.org/W1973357302","https://openalex.org/W1981593938","https://openalex.org/W1987347836","https://openalex.org/W1998913648","https://openalex.org/W2001211706","https://openalex.org/W2022536042","https://openalex.org/W2023429023","https://openalex.org/W2026116093","https://openalex.org/W2033515074","https://openalex.org/W2034772262","https://openalex.org/W2038243482","https://openalex.org/W2040306273","https://openalex.org/W2052497963","https://openalex.org/W2056026177","https://openalex.org/W2061536973","https://openalex.org/W2076509548","https://openalex.org/W2079671816","https://openalex.org/W2082273679","https://openalex.org/W2082664117","https://openalex.org/W2084206465","https://openalex.org/W2085781418","https://openalex.org/W2088107985","https://openalex.org/W2110125850","https://openalex.org/W2120731666","https://openalex.org/W2128593076","https://openalex.org/W2155566808","https://openalex.org/W2295532072","https://openalex.org/W2323800223","https://openalex.org/W2325827185","https://openalex.org/W2435646143","https://openalex.org/W2475043505","https://openalex.org/W2802987400","https://openalex.org/W2804699840","https://openalex.org/W2885143418","https://openalex.org/W2914504560","https://openalex.org/W2914545592","https://openalex.org/W3102427348","https://openalex.org/W4244794499"],"related_works":["https://openalex.org/W3033357496","https://openalex.org/W2260326082","https://openalex.org/W2052497963","https://openalex.org/W2056026177","https://openalex.org/W4392342646","https://openalex.org/W2074249036","https://openalex.org/W2028154865","https://openalex.org/W2017180092","https://openalex.org/W2082273679","https://openalex.org/W7062082609"],"abstract_inverted_index":{"Switchable":[0],"trans-cis":[1,136],"isomerization":[2,29,138],"of":[3,23,27,40,48,101,115,148],"azobenzene":[4],"(AB)":[5],"and":[6],"its":[7],"derivatives":[8],"on":[9,52,81,103,139,152],"metallic":[10],"surfaces":[11],"have":[12],"offered":[13],"rich":[14],"possibilities":[15],"to":[16,109],"functionalize":[17],"molecular":[18,149],"devices.":[19],"However,":[20],"the":[21,28,41,45,49,53,58,64,87,91,99,104,110,116,135,153],"lack":[22],"a":[24,73,145],"good":[25],"understanding":[26],"pathway":[30,124],"has":[31,141],"severely":[32],"limited":[33],"our":[34],"ability":[35],"for":[36,56,79,134],"rational":[37],"design.":[38],"One":[39],"long-debated":[42],"issues":[43],"is":[44,107],"cis":[46],"configuration":[47,78],"parental":[50],"AB":[51,102,137,154],"Au(111)":[54,82,105,140],"surface,":[55],"which":[57],"experimentally":[59],"inferred":[60],"structure":[61],"differs":[62],"from":[63],"theoretically":[65,71],"predicted":[66],"global":[67],"minimum.":[68],"Here,":[69],"we":[70],"identify":[72],"new":[74,146],"in":[75,90],"situ":[76],"metastable":[77],"cis-AB":[80,119],"that":[83,98,125],"can":[84],"reproduce":[85],"all":[86],"observations":[88],"reported":[89],"scanning":[92],"tunneling":[93,132],"microscopy":[94],"experiments.":[95],"It":[96],"reveals":[97],"bistability":[100],"surface":[106],"attributed":[108],"significantly":[111],"increased":[112],"kinetic":[113],"stability":[114],"newly":[117],"discovered":[118],"isomer.":[120],"A":[121],"fascinating":[122],"tumbling":[123],"overcomes":[126],"two":[127],"energy":[128],"barriers":[129],"stimulated":[130],"by":[131],"electrons":[133],"been":[142],"verified,":[143],"suggesting":[144],"type":[147],"motion":[150],"based":[151],"systems.":[155]},"counts_by_year":[{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":2},{"year":2023,"cited_by_count":4},{"year":2022,"cited_by_count":2},{"year":2021,"cited_by_count":1},{"year":2020,"cited_by_count":1}],"updated_date":"2026-10-16T09:59:22.235173","created_date":"2020-05-01T00:00:00"}