{"id":"https://openalex.org/W3014290843","doi":"https://doi.org/10.1021/jacs.0c02860","title":"Gold-Catalyzed Chemoselective Couplings of Polyfluoroarenes with Aryl Germanes and Downstream Diversification","display_name":"Gold-Catalyzed Chemoselective Couplings of Polyfluoroarenes with Aryl Germanes and Downstream Diversification","publication_year":2020,"publication_date":"2020-04-05","ids":{"openalex":"https://openalex.org/W3014290843","doi":"https://doi.org/10.1021/jacs.0c02860","mag":"3014290843","pmid":"https://pubmed.ncbi.nlm.nih.gov/32249568"},"language":"en","primary_location":{"id":"doi:10.1021/jacs.0c02860","doi":"https://doi.org/10.1021/jacs.0c02860","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jacs.0c02860","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-3","ki-jl-3","medline","norway-2"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5016811639","display_name":"Amit Dahiya","orcid":"https://orcid.org/0009-0006-3844-1911","observed_orcids":["https://orcid.org/0009-0006-3844-1911"]},"institutions":[{"id":"https://openalex.org/I887968799","display_name":"RWTH Aachen University","ror":"https://ror.org/04xfq0f34","country_code":"DE","type":"education","lineage":["https://openalex.org/I887968799"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Amit Dahiya","raw_affiliation_strings":["Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany","institution_ids":["https://openalex.org/I887968799"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5085731021","display_name":"Christoph Fricke","orcid":"https://orcid.org/0000-0002-9653-1222","observed_orcids":["https://orcid.org/0000-0002-9653-1222"]},"institutions":[{"id":"https://openalex.org/I887968799","display_name":"RWTH Aachen University","ror":"https://ror.org/04xfq0f34","country_code":"DE","type":"education","lineage":["https://openalex.org/I887968799"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Christoph Fricke","raw_affiliation_strings":["Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany"],"raw_orcid":"https://orcid.org/0000-0002-9653-1222","affiliations":[{"raw_affiliation_string":"Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany","institution_ids":["https://openalex.org/I887968799"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5047300640","display_name":"Franziska Schoenebeck","orcid":"https://orcid.org/0000-0003-0047-0929","observed_orcids":["https://orcid.org/0000-0003-0047-0929"]},"institutions":[{"id":"https://openalex.org/I887968799","display_name":"RWTH Aachen University","ror":"https://ror.org/04xfq0f34","country_code":"DE","type":"education","lineage":["https://openalex.org/I887968799"]}],"countries":["DE"],"is_corresponding":true,"raw_author_name":"Franziska Schoenebeck","raw_affiliation_strings":["Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany"],"raw_orcid":"https://orcid.org/0000-0003-0047-0929","affiliations":[{"raw_affiliation_string":"Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany","institution_ids":["https://openalex.org/I887968799"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5047300640"],"corresponding_institution_ids":["https://openalex.org/I887968799"],"apc_list":{"value":5000,"currency":"USD","value_usd":5000},"apc_paid":null,"fwci":8.6509,"has_fulltext":false,"cited_by_count":145,"citation_normalized_percentile":{"value":0.99122825,"is_in_top_1_percent":true,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":99,"max":100},"biblio":{"volume":"142","issue":"17","first_page":"7754","last_page":"7759"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10871","display_name":"Catalytic Alkyne Reactions","score":0.4287000000476837,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10871","display_name":"Catalytic Alkyne Reactions","score":0.4287000000476837,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10548","display_name":"Catalytic Cross-Coupling Reactions","score":0.30300000309944153,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10354","display_name":"Catalytic C\u2013H Functionalization Methods","score":0.2207999974489212,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/gold-catalysis","display_name":"gold catalysis","score":0.9399999976158142},{"id":"https://openalex.org/keywords/chemoselective-coupling","display_name":"chemoselective coupling","score":0.8759999871253967},{"id":"https://openalex.org/keywords/polyfluoroarenes","display_name":"polyfluoroarenes","score":0.9929999709129333},{"id":"https://openalex.org/keywords/umpolung","display_name":"umpolung","score":0.9359999895095825},{"id":"https://openalex.org/keywords/biaryls","display_name":"biaryls","score":0.5379999876022339},{"id":"https://openalex.org/keywords/aryl-iodides","display_name":"aryl iodides","score":0.5429999828338623},{"id":"https://openalex.org/keywords/aryl-bromides","display_name":"aryl bromides","score":0.7149999737739563},{"id":"https://openalex.org/keywords/aryl-chlorides","display_name":"aryl chlorides","score":0.7580000162124634},{"id":"https://openalex.org/keywords/aryl-tosylates","display_name":"aryl tosylates","score":0.6779999732971191}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8976470232009888},{"id":"https://openalex.org/C2781076698","wikidata":"https://www.wikidata.org/wiki/Q718074","display_name":"Aryl","level":3,"score":0.7917388677597046},{"id":"https://openalex.org/C76164948","wikidata":"https://www.wikidata.org/wiki/Q904718","display_name":"Umpolung","level":4,"score":0.772089958190918},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.6967368721961975},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.37308967113494873},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.3537710905075073},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.339569628238678},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.325705885887146},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.12210807204246521},{"id":"https://openalex.org/C178907741","wikidata":"https://www.wikidata.org/wiki/Q745930","display_name":"Nucleophile","level":3,"score":0.09143120050430298}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1021/jacs.0c02860","doi":"https://doi.org/10.1021/jacs.0c02860","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jacs.0c02860","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-3","ki-jl-3","medline","norway-2"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},{"id":"pmid:32249568","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/32249568","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"Journal Article"},{"id":"pmh:oai:publications.rwth-aachen.de:793200","doi":null,"is_oa":false,"landing_page_url":"https://publications.rwth-aachen.de/record/793200","pdf_url":null,"source":{"id":"https://openalex.org/S4306401362","display_name":"RWTH Publications (RWTH Aachen)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I887968799","host_organization_name":"RWTH Aachen University","host_organization_lineage":["https://openalex.org/I887968799"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Journal of the American Chemical Society 142(17), 7754-7759 (2020). doi:10.1021/jacs.0c02860","raw_type":"info:eu-repo/semantics/article"}],"best_oa_location":null,"sustainable_development_goals":[],"sustainable_development_goals_aurora":[{"score":0.7599999904632568,"id":"https://metadata.un.org/sdg/1","display_name":"No poverty"}],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320324232","display_name":"RWTH Aachen University","ror":"https://ror.org/04xfq0f34"},{"id":"https://openalex.org/F4320338335","display_name":"H2020 European Research Council","ror":"https://ror.org/0472cxd90"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":79,"referenced_works":["https://openalex.org/W348623969","https://openalex.org/W1615391074","https://openalex.org/W1967062269","https://openalex.org/W1968810912","https://openalex.org/W1971115773","https://openalex.org/W1984851912","https://openalex.org/W1985498609","https://openalex.org/W1994725207","https://openalex.org/W2001152439","https://openalex.org/W2004171344","https://openalex.org/W2006695659","https://openalex.org/W2016755677","https://openalex.org/W2019339624","https://openalex.org/W2020224115","https://openalex.org/W2027392184","https://openalex.org/W2027743433","https://openalex.org/W2031556326","https://openalex.org/W2034880948","https://openalex.org/W2037872925","https://openalex.org/W2067290495","https://openalex.org/W2077445395","https://openalex.org/W2080723695","https://openalex.org/W2080883051","https://openalex.org/W2091372901","https://openalex.org/W2096021030","https://openalex.org/W2105260974","https://openalex.org/W2105699949","https://openalex.org/W2125154097","https://openalex.org/W2127432745","https://openalex.org/W2140220962","https://openalex.org/W2147020084","https://openalex.org/W2149487039","https://openalex.org/W2149992143","https://openalex.org/W2159356452","https://openalex.org/W2160388306","https://openalex.org/W2172084141","https://openalex.org/W2191692478","https://openalex.org/W2201590124","https://openalex.org/W2214705350","https://openalex.org/W2231580600","https://openalex.org/W2270441675","https://openalex.org/W2289035101","https://openalex.org/W2312916256","https://openalex.org/W2318692662","https://openalex.org/W2323959218","https://openalex.org/W2329263808","https://openalex.org/W2334424914","https://openalex.org/W2335210868","https://openalex.org/W2344278015","https://openalex.org/W2436889725","https://openalex.org/W2470383994","https://openalex.org/W2470646646","https://openalex.org/W2474125139","https://openalex.org/W2524479485","https://openalex.org/W2544011392","https://openalex.org/W2562110564","https://openalex.org/W2563384685","https://openalex.org/W2567027439","https://openalex.org/W2603852585","https://openalex.org/W2615259598","https://openalex.org/W2752231181","https://openalex.org/W2753269481","https://openalex.org/W2758945147","https://openalex.org/W2770026568","https://openalex.org/W2790853432","https://openalex.org/W2792746130","https://openalex.org/W2799778684","https://openalex.org/W2800107638","https://openalex.org/W2807597119","https://openalex.org/W2883461251","https://openalex.org/W2896408295","https://openalex.org/W2905263512","https://openalex.org/W2914980961","https://openalex.org/W2925158074","https://openalex.org/W2949382223","https://openalex.org/W2963288745","https://openalex.org/W2970266253","https://openalex.org/W2972405169","https://openalex.org/W2975677283"],"related_works":["https://openalex.org/W4391375266","https://openalex.org/W2635361226","https://openalex.org/W2551488466","https://openalex.org/W2761265498","https://openalex.org/W2589555175","https://openalex.org/W2904994735","https://openalex.org/W4309352837","https://openalex.org/W2404641279","https://openalex.org/W3111005695","https://openalex.org/W2541848794"],"abstract_inverted_index":{"This":[0],"report":[1],"describes":[2],"the":[3,12,28,49,70,78],"chemoselective":[4],"coupling":[5,61,81],"of":[6,14,48,72],"polyfluoroarenes":[7],"with":[8,62],"aryl":[9,66],"germanes":[10],"in":[11,45,69,83],"presence":[13,71],"aromatic":[15],"C\u2013I,":[16],"C\u2013Br,":[17],"C\u2013Cl,":[18],"C\u2013OTf,":[19],"and":[20,36,76],"C\u2013SiMe":[21],"3":[22],"groups,":[23],"as":[24,26],"well":[25],"demonstrates":[27],"further":[29],"downstream":[30],"diversification":[31],"to":[32,87],"give":[33],"richly":[34],"functionalized":[35],"highly":[37],"fluorinated":[38],"polyarenes.":[39],"The":[40],"strategy":[41],"relies":[42],"on":[43],"an":[44],"situ":[46],"Umpolung":[47],"F":[50],"n":[51],"ArH,":[52],"followed":[53],"by":[54],"selective":[55],"Au":[56],"(I)":[57],"/Au":[58],"(III)":[59],"-catalyzed":[60],"electron-poor":[63],"or":[64],"-rich":[65],"germanes,":[67],"even":[68],"challenging":[73],"ortho":[74],"-substituents,":[75],"widens":[77],"currently":[79],"available":[80],"space":[82],"oxidative":[84],"gold":[85],"catalysis":[86],"previously":[88],"inaccessible":[89],"electron-poor/electron-poor":[90],"biaryls.":[91]},"counts_by_year":[{"year":2026,"cited_by_count":14},{"year":2025,"cited_by_count":15},{"year":2024,"cited_by_count":20},{"year":2023,"cited_by_count":26},{"year":2022,"cited_by_count":26},{"year":2021,"cited_by_count":20},{"year":2020,"cited_by_count":23}],"updated_date":"2026-10-07T09:51:55.459714","created_date":"2025-10-10T00:00:00"}
