{"id":"https://openalex.org/W2983554697","doi":"https://doi.org/10.1016/j.microc.2019.104384","title":"Hydrophobic deep eutectic solvents in microextraction techniques\u2013A review","display_name":"Hydrophobic deep eutectic solvents in microextraction techniques\u2013A review","publication_year":2019,"publication_date":"2019-11-01","ids":{"openalex":"https://openalex.org/W2983554697","doi":"https://doi.org/10.1016/j.microc.2019.104384","mag":"2983554697"},"language":"en","primary_location":{"id":"doi:10.1016/j.microc.2019.104384","doi":"https://doi.org/10.1016/j.microc.2019.104384","is_oa":true,"landing_page_url":"https://doi.org/10.1016/j.microc.2019.104384","pdf_url":"https://www.sciencedirect.com/science/article/pii/S0026265X19329352/pdf","source":{"id":"https://openalex.org/S151030190","display_name":"Microchemical Journal","issn_l":"0026-265X","issn":["0026-265X","1095-9149"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","jufo-1","ki-jl-1","norway-1","poland-70","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320990","host_organization_name":"Elsevier BV","host_organization_lineage":["https://openalex.org/P4310320990"],"host_organization_lineage_names":["Elsevier BV"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Microchemical Journal","raw_type":"journal-article"},"volume":null,"type":"review","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"hybrid","oa_url":"https://www.sciencedirect.com/science/article/pii/S0026265X19329352/pdf","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5056063889","display_name":"Patrycja Mako\u015b\u2010Che\u0142stowska","orcid":"https://orcid.org/0000-0002-1160-2790","observed_orcids":["https://orcid.org/0000-0002-1160-2790"]},"institutions":[{"id":"https://openalex.org/I169333911","display_name":"Gda\u0144sk University of Technology","ror":"https://ror.org/006x4sc24","country_code":"PL","type":"education","lineage":["https://openalex.org/I169333911"]}],"countries":["PL"],"is_corresponding":true,"raw_author_name":"Patrycja Mako\u015b","raw_affiliation_strings":["Faculty of Chemistry, Department of Process Engineering and Chemical Technology, Gdansk University of Technology, 80 \u2013 233 Gdansk, G. Narutowicza St. 11/12, Poland"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Faculty of Chemistry, Department of Process Engineering and Chemical Technology, Gdansk University of Technology, 80 \u2013 233 Gdansk, G. Narutowicza St. 11/12, Poland","institution_ids":["https://openalex.org/I169333911"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5080126772","display_name":"Edyta S\u0142upek","orcid":"https://orcid.org/0000-0002-4076-1176","observed_orcids":["https://orcid.org/0000-0002-4076-1176"]},"institutions":[{"id":"https://openalex.org/I169333911","display_name":"Gda\u0144sk University of Technology","ror":"https://ror.org/006x4sc24","country_code":"PL","type":"education","lineage":["https://openalex.org/I169333911"]}],"countries":["PL"],"is_corresponding":false,"raw_author_name":"Edyta S\u0142upek","raw_affiliation_strings":["Faculty of Chemistry, Department of Process Engineering and Chemical Technology, Gdansk University of Technology, 80 \u2013 233 Gdansk, G. Narutowicza St. 11/12, Poland"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Faculty of Chemistry, Department of Process Engineering and Chemical Technology, Gdansk University of Technology, 80 \u2013 233 Gdansk, G. Narutowicza St. 11/12, Poland","institution_ids":["https://openalex.org/I169333911"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5009359917","display_name":"Jacek G\u0119bicki","orcid":"https://orcid.org/0000-0002-4786-8363","observed_orcids":["https://orcid.org/0000-0002-4786-8363"]},"institutions":[{"id":"https://openalex.org/I169333911","display_name":"Gda\u0144sk University of Technology","ror":"https://ror.org/006x4sc24","country_code":"PL","type":"education","lineage":["https://openalex.org/I169333911"]}],"countries":["PL"],"is_corresponding":false,"raw_author_name":"Jacek G\u0119bicki","raw_affiliation_strings":["Faculty of Chemistry, Department of Process Engineering and Chemical Technology, Gdansk University of Technology, 80 \u2013 233 Gdansk, G. Narutowicza St. 11/12, Poland"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Faculty of Chemistry, Department of Process Engineering and Chemical Technology, Gdansk University of Technology, 80 \u2013 233 Gdansk, G. Narutowicza St. 11/12, Poland","institution_ids":["https://openalex.org/I169333911"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5056063889"],"corresponding_institution_ids":["https://openalex.org/I169333911"],"apc_list":{"value":2750,"currency":"USD","value_usd":2750},"apc_paid":{"value":2750,"currency":"USD","value_usd":2750},"fwci":4.5272,"has_fulltext":true,"cited_by_count":470,"citation_normalized_percentile":{"value":0.98148148,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":99,"max":100},"biblio":{"volume":"152","issue":null,"first_page":"104384","last_page":"104384"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10180","display_name":"Analytical chemistry methods development","score":0.6836000084877014,"subfield":{"id":"https://openalex.org/subfields/1602","display_name":"Analytical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10180","display_name":"Analytical chemistry methods development","score":0.6836000084877014,"subfield":{"id":"https://openalex.org/subfields/1602","display_name":"Analytical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10480","display_name":"Ionic liquids properties and applications","score":0.3093000054359436,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11936","display_name":"Chemical and Physical Properties in Aqueous Solutions","score":0.0005000000237487257,"subfield":{"id":"https://openalex.org/subfields/1506","display_name":"Filtration and Separation"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/hydrophobic-deep-eutectic-solvents","display_name":"hydrophobic deep eutectic solvents","score":0.9990000128746033},{"id":"https://openalex.org/keywords/deep-eutectic-solvents","display_name":"deep eutectic solvents","score":0.9440000057220459},{"id":"https://openalex.org/keywords/liquid-phase-microextraction","display_name":"liquid-phase microextraction","score":0.8109999895095825},{"id":"https://openalex.org/keywords/solid-phase-extraction","display_name":"solid-phase extraction","score":0.7879999876022339},{"id":"https://openalex.org/keywords/liquid-liquid-extraction","display_name":"liquid-liquid extraction","score":0.9259999990463257},{"id":"https://openalex.org/keywords/green-analytical-chemistry","display_name":"green analytical chemistry","score":0.847000002861023},{"id":"https://openalex.org/keywords/solvent-properties","display_name":"solvent properties","score":0.7630000114440918}],"concepts":[{"id":"https://openalex.org/C18168003","wikidata":"https://www.wikidata.org/wiki/Q628595","display_name":"Eutectic system","level":3,"score":0.8169702291488647},{"id":"https://openalex.org/C2778576202","wikidata":"https://www.wikidata.org/wiki/Q2540164","display_name":"Sample preparation","level":2,"score":0.5546400547027588},{"id":"https://openalex.org/C4725764","wikidata":"https://www.wikidata.org/wiki/Q844704","display_name":"Extraction (chemistry)","level":2,"score":0.4755170941352844},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.4668812155723572},{"id":"https://openalex.org/C2780371645","wikidata":"https://www.wikidata.org/wiki/Q168033","display_name":"Deep eutectic solvent","level":4,"score":0.4665367901325226},{"id":"https://openalex.org/C184651966","wikidata":"https://www.wikidata.org/wiki/Q906356","display_name":"Aqueous solution","level":2,"score":0.4419131278991699},{"id":"https://openalex.org/C91602232","wikidata":"https://www.wikidata.org/wiki/Q756115","display_name":"Volatility (finance)","level":2,"score":0.4411843717098236},{"id":"https://openalex.org/C43617362","wikidata":"https://www.wikidata.org/wiki/Q170050","display_name":"Chromatography","level":1,"score":0.36179953813552856},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.2516656517982483},{"id":"https://openalex.org/C2780026712","wikidata":"https://www.wikidata.org/wiki/Q37756","display_name":"Alloy","level":2,"score":0.0},{"id":"https://openalex.org/C162324750","wikidata":"https://www.wikidata.org/wiki/Q8134","display_name":"Economics","level":0,"score":0.0},{"id":"https://openalex.org/C106159729","wikidata":"https://www.wikidata.org/wiki/Q2294553","display_name":"Financial economics","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1016/j.microc.2019.104384","doi":"https://doi.org/10.1016/j.microc.2019.104384","is_oa":true,"landing_page_url":"https://doi.org/10.1016/j.microc.2019.104384","pdf_url":"https://www.sciencedirect.com/science/article/pii/S0026265X19329352/pdf","source":{"id":"https://openalex.org/S151030190","display_name":"Microchemical Journal","issn_l":"0026-265X","issn":["0026-265X","1095-9149"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","jufo-1","ki-jl-1","norway-1","poland-70","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320990","host_organization_name":"Elsevier BV","host_organization_lineage":["https://openalex.org/P4310320990"],"host_organization_lineage_names":["Elsevier BV"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Microchemical Journal","raw_type":"journal-article"}],"best_oa_location":{"id":"doi:10.1016/j.microc.2019.104384","doi":"https://doi.org/10.1016/j.microc.2019.104384","is_oa":true,"landing_page_url":"https://doi.org/10.1016/j.microc.2019.104384","pdf_url":"https://www.sciencedirect.com/science/article/pii/S0026265X19329352/pdf","source":{"id":"https://openalex.org/S151030190","display_name":"Microchemical Journal","issn_l":"0026-265X","issn":["0026-265X","1095-9149"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","jufo-1","ki-jl-1","norway-1","poland-70","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320990","host_organization_name":"Elsevier BV","host_organization_lineage":["https://openalex.org/P4310320990"],"host_organization_lineage_names":["Elsevier BV"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Microchemical Journal","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":true,"pdf":true},"content_urls":{"pdf":"https://content.openalex.org/works/W2983554697.pdf","grobid_xml":"https://content.openalex.org/works/W2983554697.grobid-xml"},"referenced_works_count":139,"referenced_works":["https://openalex.org/W107166638","https://openalex.org/W277559545","https://openalex.org/W1922564622","https://openalex.org/W1946580248","https://openalex.org/W1964697188","https://openalex.org/W1965397209","https://openalex.org/W1967303320","https://openalex.org/W1967363269","https://openalex.org/W1967410318","https://openalex.org/W1971966881","https://openalex.org/W1973197277","https://openalex.org/W1977426743","https://openalex.org/W1996580274","https://openalex.org/W2001473672","https://openalex.org/W2002715703","https://openalex.org/W2011212917","https://openalex.org/W2013379206","https://openalex.org/W2014761555","https://openalex.org/W2025071806","https://openalex.org/W2027467147","https://openalex.org/W2028890951","https://openalex.org/W2028921476","https://openalex.org/W2029467321","https://openalex.org/W2030462673","https://openalex.org/W2037900448","https://openalex.org/W2046289329","https://openalex.org/W2048705571","https://openalex.org/W2057032989","https://openalex.org/W2069637948","https://openalex.org/W2073557285","https://openalex.org/W2077891377","https://openalex.org/W2124985647","https://openalex.org/W2139213360","https://openalex.org/W2147993896","https://openalex.org/W2150884237","https://openalex.org/W2154733730","https://openalex.org/W2162173771","https://openalex.org/W2170257079","https://openalex.org/W2291754004","https://openalex.org/W2297103527","https://openalex.org/W2319365190","https://openalex.org/W2321005010","https://openalex.org/W2346199997","https://openalex.org/W2437552516","https://openalex.org/W2466885574","https://openalex.org/W2469809130","https://openalex.org/W2474070018","https://openalex.org/W2482212812","https://openalex.org/W2498904481","https://openalex.org/W2499815235","https://openalex.org/W2502248317","https://openalex.org/W2507344435","https://openalex.org/W2508726442","https://openalex.org/W2515138583","https://openalex.org/W2517001873","https://openalex.org/W2528272135","https://openalex.org/W2533555904","https://openalex.org/W2549685893","https://openalex.org/W2570259232","https://openalex.org/W2588563774","https://openalex.org/W2591910560","https://openalex.org/W2594593223","https://openalex.org/W2594839383","https://openalex.org/W2602717862","https://openalex.org/W2604611121","https://openalex.org/W2605998787","https://openalex.org/W2606096134","https://openalex.org/W2610973917","https://openalex.org/W2619621508","https://openalex.org/W2619908398","https://openalex.org/W2738375725","https://openalex.org/W2746204178","https://openalex.org/W2748289171","https://openalex.org/W2752330245","https://openalex.org/W2755244815","https://openalex.org/W2756902314","https://openalex.org/W2758653009","https://openalex.org/W2759292907","https://openalex.org/W2759308071","https://openalex.org/W2759450283","https://openalex.org/W2763354007","https://openalex.org/W2772910519","https://openalex.org/W2783256303","https://openalex.org/W2788980557","https://openalex.org/W2790246452","https://openalex.org/W2790551172","https://openalex.org/W2790810998","https://openalex.org/W2790876884","https://openalex.org/W2791226425","https://openalex.org/W2797789876","https://openalex.org/W2801255867","https://openalex.org/W2805202003","https://openalex.org/W2805781407","https://openalex.org/W2806097042","https://openalex.org/W2806258079","https://openalex.org/W2808383010","https://openalex.org/W2810252364","https://openalex.org/W2884685490","https://openalex.org/W2885850263","https://openalex.org/W2886705163","https://openalex.org/W2886801923","https://openalex.org/W2887567060","https://openalex.org/W2890474158","https://openalex.org/W2891061162","https://openalex.org/W2892001428","https://openalex.org/W2892994550","https://openalex.org/W2893313802","https://openalex.org/W2894903676","https://openalex.org/W2895254013","https://openalex.org/W2896437801","https://openalex.org/W2897714644","https://openalex.org/W2898309131","https://openalex.org/W2898451044","https://openalex.org/W2898785475","https://openalex.org/W2899272226","https://openalex.org/W2900041995","https://openalex.org/W2901493562","https://openalex.org/W2901692499","https://openalex.org/W2903289898","https://openalex.org/W2907468665","https://openalex.org/W2907803387","https://openalex.org/W2910507411","https://openalex.org/W2910770857","https://openalex.org/W2911203602","https://openalex.org/W2911374655","https://openalex.org/W2914124582","https://openalex.org/W2914896700","https://openalex.org/W2923837377","https://openalex.org/W2936005058","https://openalex.org/W2944635930","https://openalex.org/W2944716832","https://openalex.org/W2944809562","https://openalex.org/W2954948811","https://openalex.org/W2960654958","https://openalex.org/W2963507592","https://openalex.org/W2963596489","https://openalex.org/W2964637119","https://openalex.org/W2966027097","https://openalex.org/W2971565693"],"related_works":["https://openalex.org/W2964160685","https://openalex.org/W3120949875","https://openalex.org/W2913206390","https://openalex.org/W4390154910","https://openalex.org/W3212760611","https://openalex.org/W2980118033","https://openalex.org/W4407955008","https://openalex.org/W7118021939","https://openalex.org/W4387369303","https://openalex.org/W4220931235"],"abstract_inverted_index":{"Over":[0],"the":[1,22,32,42,84,100,109,120,161],"past":[2],"decade,":[3],"deep":[4,48],"eutectic":[5,49],"solvents":[6,50,103],"(DES)":[7],"have":[8],"been":[9],"widely":[10],"studied":[11],"and":[12,44,68,89,137,186],"applied":[13],"in":[14,31,105,130,172,183],"sample":[15,106,131,174],"preparation":[16,132,175],"techniques.":[17],"Until":[18],"recently,":[19],"most":[20,162],"of":[21,34,46,59,83,113,122,128,140,156,166,189],"synthesized":[23],"DES":[24],"were":[25],"hydrophilic,":[26],"which":[27,76],"prevented":[28],"their":[29,177,190],"use":[30],"extraction":[33],"aqueous":[35,173],"samples.":[36],"However,":[37],"after":[38],"2015":[39],"studies":[40],"on":[41,160],"synthesis":[43,112],"application":[45],"hydrophobic":[47],"(HDES)":[51],"has":[52],"rapidly":[53],"expanded.":[54],"Due":[55],"to":[56,99],"unique":[57],"properties":[58,165],"HDES":[60,95,111,117,129,167],"i.e.":[61],"density,":[62],"viscosity,":[63],"acidity":[64],"or":[65],"basicity,":[66],"polarity":[67],"volatility,":[69],"good":[70],"extractabilities":[71],"for":[72],"various":[73],"target":[74],"analytes,":[75],"could":[77],"be":[78],"altered":[79],"by":[80],"careful":[81],"selection":[82],"hydrogen":[85,90],"bond":[86,91],"donor":[87],"(HBD)":[88],"acceptor":[92],"(HBA)":[93],"components,":[94],"are":[96,192],"promising":[97],"alternatives":[98],"traditional":[101],"organic":[102],"employed":[104],"preparation.":[107],"Moreover,":[108],"possibility":[110],"non-toxic":[114],"ingredients,":[115],"makes":[116],"meet":[118],"all":[119],"standards":[121],"green":[123],"analytical":[124],"chemistry.":[125],"Practical":[126],"applications":[127],"include":[133],"conventional":[134],"liquid-liquid":[135],"extraction,":[136],"several":[138],"types":[139],"liquid-phase":[141],"microextraction,":[142],"as":[143,145,179,181],"well":[144,180],"solid":[146],"phase":[147],"extraction.":[148],"The":[149],"present":[150],"review":[151],"covers":[152],"a":[153,169,187],"comprehensive":[154],"summarizing":[155],"available":[157],"literature":[158],"data":[159],"important":[163],"physicochemical":[164],"playing":[168],"key":[170],"role":[171],"methods,":[176],"limitations":[178],"challenges":[182],"this":[184],"area,":[185],"perspective":[188],"future":[191],"described.":[193]},"counts_by_year":[{"year":2026,"cited_by_count":57},{"year":2025,"cited_by_count":87},{"year":2024,"cited_by_count":74},{"year":2023,"cited_by_count":63},{"year":2022,"cited_by_count":73},{"year":2021,"cited_by_count":74},{"year":2020,"cited_by_count":41}],"updated_date":"2026-11-06T12:05:46.655746","created_date":"2019-11-22T00:00:00"}