{"id":"https://openalex.org/W2967295752","doi":"https://doi.org/10.1021/acs.joc.9b01816","title":"Regioselective Cp*Ir(III)-Catalyzed Allylic C\u2013H Sulfamidation of Allylbenzene Derivatives","display_name":"Regioselective Cp*Ir(III)-Catalyzed Allylic C\u2013H Sulfamidation of Allylbenzene Derivatives","publication_year":2019,"publication_date":"2019-08-16","ids":{"openalex":"https://openalex.org/W2967295752","doi":"https://doi.org/10.1021/acs.joc.9b01816","mag":"2967295752","pmid":"https://pubmed.ncbi.nlm.nih.gov/31418569"},"language":"en","primary_location":{"id":"doi:10.1021/acs.joc.9b01816","doi":"https://doi.org/10.1021/acs.joc.9b01816","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.joc.9b01816","pdf_url":null,"source":{"id":"https://openalex.org/S205050996","display_name":"The Journal of Organic Chemistry","issn_l":"0022-3263","issn":["0022-3263","1520-6904"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Organic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5060872436","display_name":"Amaan M. Kazerouni","orcid":"https://orcid.org/0000-0002-4121-2603","observed_orcids":["https://orcid.org/0000-0002-4121-2603"]},"institutions":[{"id":"https://openalex.org/I150468666","display_name":"Emory University","ror":"https://ror.org/03czfpz43","country_code":"US","type":"education","lineage":["https://openalex.org/I150468666"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Amaan M. Kazerouni","raw_affiliation_strings":["Department of Chemistry, Emory University, Atlanta, Georgia 30322, United States"],"raw_orcid":"https://orcid.org/0000-0002-4121-2603","affiliations":[{"raw_affiliation_string":"Department of Chemistry, Emory University, Atlanta, Georgia 30322, United States","institution_ids":["https://openalex.org/I150468666"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5038812537","display_name":"Taylor A. F. Nelson","orcid":"https://orcid.org/0000-0002-4685-1455","observed_orcids":["https://orcid.org/0000-0002-4685-1455"]},"institutions":[{"id":"https://openalex.org/I150468666","display_name":"Emory University","ror":"https://ror.org/03czfpz43","country_code":"US","type":"education","lineage":["https://openalex.org/I150468666"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Taylor A. F. Nelson","raw_affiliation_strings":["Department of Chemistry, Emory University, Atlanta, Georgia 30322, United States"],"raw_orcid":"https://orcid.org/0000-0002-4685-1455","affiliations":[{"raw_affiliation_string":"Department of Chemistry, Emory University, Atlanta, Georgia 30322, United States","institution_ids":["https://openalex.org/I150468666"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5071583176","display_name":"Steven W. Chen","orcid":"https://orcid.org/0000-0002-5926-7557","observed_orcids":["https://orcid.org/0000-0002-5926-7557"]},"institutions":[{"id":"https://openalex.org/I150468666","display_name":"Emory University","ror":"https://ror.org/03czfpz43","country_code":"US","type":"education","lineage":["https://openalex.org/I150468666"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Steven W. Chen","raw_affiliation_strings":["Department of Chemistry, Emory University, Atlanta, Georgia 30322, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Emory University, Atlanta, Georgia 30322, United States","institution_ids":["https://openalex.org/I150468666"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5076910572","display_name":"Kimberly R. Sharp","orcid":"https://orcid.org/0000-0002-5718-3552","observed_orcids":["https://orcid.org/0000-0002-5718-3552"]},"institutions":[{"id":"https://openalex.org/I150468666","display_name":"Emory University","ror":"https://ror.org/03czfpz43","country_code":"US","type":"education","lineage":["https://openalex.org/I150468666"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Kimberly R. Sharp","raw_affiliation_strings":["Department of Chemistry, Emory University, Atlanta, Georgia 30322, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Emory University, Atlanta, Georgia 30322, United States","institution_ids":["https://openalex.org/I150468666"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5031746021","display_name":"Simon B. Blakey","orcid":"https://orcid.org/0000-0002-4100-8610","observed_orcids":["https://orcid.org/0000-0002-4100-8610"]},"institutions":[{"id":"https://openalex.org/I150468666","display_name":"Emory University","ror":"https://ror.org/03czfpz43","country_code":"US","type":"education","lineage":["https://openalex.org/I150468666"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Simon B. Blakey","raw_affiliation_strings":["Department of Chemistry, Emory University, Atlanta, Georgia 30322, United States"],"raw_orcid":"https://orcid.org/0000-0002-4100-8610","affiliations":[{"raw_affiliation_string":"Department of Chemistry, Emory University, Atlanta, Georgia 30322, United States","institution_ids":["https://openalex.org/I150468666"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5031746021"],"corresponding_institution_ids":["https://openalex.org/I150468666"],"apc_list":{"value":5000,"currency":"USD","value_usd":5000},"apc_paid":null,"fwci":2.0591,"has_fulltext":false,"cited_by_count":28,"citation_normalized_percentile":{"value":0.86400321,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":99},"biblio":{"volume":"84","issue":"20","first_page":"13179","last_page":"13185"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10354","display_name":"Catalytic C\u2013H Functionalization Methods","score":0.6958000063896179,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10354","display_name":"Catalytic C\u2013H Functionalization Methods","score":0.6958000063896179,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12251","display_name":"Synthesis and Catalytic Reactions","score":0.25780001282691956,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12189","display_name":"Sulfur-Based Synthesis Techniques","score":0.020099999383091927,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/regioselectivity","display_name":"regioselectivity","score":0.8370000123977661},{"id":"https://openalex.org/keywords/pi-allyl-intermediate","display_name":"\u03c0-allyl intermediate","score":0.8650000095367432}],"concepts":[{"id":"https://openalex.org/C59759590","wikidata":"https://www.wikidata.org/wiki/Q2275927","display_name":"Regioselectivity","level":3,"score":0.970988392829895},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9522649049758911},{"id":"https://openalex.org/C120095180","wikidata":"https://www.wikidata.org/wiki/Q2695010","display_name":"Allylic rearrangement","level":3,"score":0.9349347949028015},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.6515272259712219},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.45866692066192627},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.389819860458374},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.19648346304893494}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1021/acs.joc.9b01816","doi":"https://doi.org/10.1021/acs.joc.9b01816","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.joc.9b01816","pdf_url":null,"source":{"id":"https://openalex.org/S205050996","display_name":"The Journal of Organic Chemistry","issn_l":"0022-3263","issn":["0022-3263","1520-6904"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Organic Chemistry","raw_type":"journal-article"},{"id":"pmid:31418569","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/31418569","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of organic chemistry","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"sustainable_development_goals_aurora":[{"display_name":"Clean water and sanitation","score":0.6299999952316284,"id":"https://metadata.un.org/sdg/6"}],"study_designs":[],"awards":[{"id":"https://openalex.org/G4421890870","display_name":null,"funder_award_id":"CHE-1700982","funder_id":"https://openalex.org/F4320337393","funder_display_name":"Division of Chemistry"}],"funders":[{"id":"https://openalex.org/F4320337393","display_name":"Division of Chemistry","ror":"https://ror.org/01ar8dr59"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":38,"referenced_works":["https://openalex.org/W154538047","https://openalex.org/W1964658576","https://openalex.org/W1965641484","https://openalex.org/W1976734654","https://openalex.org/W2029501153","https://openalex.org/W2048705687","https://openalex.org/W2064951719","https://openalex.org/W2066015021","https://openalex.org/W2066786115","https://openalex.org/W2076952990","https://openalex.org/W2080040943","https://openalex.org/W2084452985","https://openalex.org/W2096886476","https://openalex.org/W2104837971","https://openalex.org/W2106557976","https://openalex.org/W2113278931","https://openalex.org/W2121016236","https://openalex.org/W2124002600","https://openalex.org/W2166466785","https://openalex.org/W2167829310","https://openalex.org/W2313664653","https://openalex.org/W2317771072","https://openalex.org/W2322034841","https://openalex.org/W2489824448","https://openalex.org/W2517093895","https://openalex.org/W2756202433","https://openalex.org/W2792067496","https://openalex.org/W2794432698","https://openalex.org/W2885211886","https://openalex.org/W2892995793","https://openalex.org/W2896178193","https://openalex.org/W2908459398","https://openalex.org/W2911325032","https://openalex.org/W2918975704","https://openalex.org/W2936828926","https://openalex.org/W2944678743","https://openalex.org/W2944912465","https://openalex.org/W2951156615"],"related_works":["https://openalex.org/W3118908972","https://openalex.org/W2969550306","https://openalex.org/W2936828926","https://openalex.org/W3127712031","https://openalex.org/W2923588187","https://openalex.org/W2413111098","https://openalex.org/W2081360871","https://openalex.org/W2515495840","https://openalex.org/W2522089613","https://openalex.org/W2944678743"],"abstract_inverted_index":{"In":[0],"this":[1,71],"study":[2],"we":[3],"report":[4],"the":[5,8,20,36,40,84,88],"development":[6],"of":[7,14,39,55,59,87],"regioselective":[9],"Cp*Ir(III)-catalyzed":[10],"allylic":[11],"C-H":[12],"sulfamidation":[13],"allylbenzene":[15,50],"derivatives,":[16],"using":[17],"azides":[18],"as":[19],"nitrogen":[21],"source.":[22],"The":[23,42,67],"reaction":[24,43,72],"putatively":[25],"proceeds":[26,73],"through":[27],"a":[28,56,79],"Cp*Ir(III)-\u03c0-allyl":[29],"intermediate":[30],"and":[31,48,52,65],"demonstrates":[32],"exclusive":[33],"regioselectivity":[34],"for":[35,70],"branched":[37,85],"position":[38,86],"\u03c0-allyl.":[41,89],"performs":[44],"well":[45],"on":[46],"electron-rich":[47],"electron-deficient":[49],"derivatives":[51],"is":[53],"tolerant":[54],"wide":[57],"range":[58],"functional":[60],"groups,":[61],"including":[62],"carbamates,":[63],"esters,":[64],"ketones.":[66],"proposed":[68],"mechanism":[69],"via":[74],"C-N":[75],"reductive":[76],"elimination":[77],"from":[78],"Cp*Ir(V)":[80],"nitrenoid":[81],"complex":[82],"at":[83]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2025,"cited_by_count":2},{"year":2024,"cited_by_count":2},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":5},{"year":2021,"cited_by_count":6},{"year":2020,"cited_by_count":9},{"year":2019,"cited_by_count":1}],"updated_date":"2026-08-28T12:50:07.497085","created_date":"2019-08-22T00:00:00"}
