{"id":"https://openalex.org/W2962040247","doi":"https://doi.org/10.1039/c9py00447e","title":"Rate-based approach for controlling the mechanical properties of \u2018thiol\u2013ene\u2019 hydrogels formed with visible light","display_name":"Rate-based approach for controlling the mechanical properties of \u2018thiol\u2013ene\u2019 hydrogels formed with visible light","publication_year":2019,"publication_date":"2019-01-01","ids":{"openalex":"https://openalex.org/W2962040247","doi":"https://doi.org/10.1039/c9py00447e","mag":"2962040247","pmid":"https://pubmed.ncbi.nlm.nih.gov/32405326","pmcid":"https://www.ncbi.nlm.nih.gov/pmc/articles/7218207"},"language":"en","primary_location":{"id":"doi:10.1039/c9py00447e","doi":"https://doi.org/10.1039/c9py00447e","is_oa":false,"landing_page_url":"https://doi.org/10.1039/c9py00447e","pdf_url":null,"source":{"id":"https://openalex.org/S187215728","display_name":"Polymer Chemistry","issn_l":"1759-9954","issn":["1759-9954","1759-9962"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-1","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Polymer Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/7218207","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5016677049","display_name":"Katherine L. Wiley","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I86501945","display_name":"University of Delaware","ror":"https://ror.org/01sbq1a82","country_code":"US","type":"education","lineage":["https://openalex.org/I86501945"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Katherine L. Wiley","raw_affiliation_strings":["Department of Chemical and Biomolecular Engineering","Newark","USA","University of Delaware","Department of Chemical and Biomolecular Engineering, University of Delaware, Newark, DE 19716, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemical and Biomolecular Engineering","institution_ids":[]},{"raw_affiliation_string":"Newark","institution_ids":[]},{"raw_affiliation_string":"USA","institution_ids":[]},{"raw_affiliation_string":"University of Delaware","institution_ids":["https://openalex.org/I86501945"]},{"raw_affiliation_string":"Department of Chemical and Biomolecular Engineering, University of Delaware, Newark, DE 19716, USA","institution_ids":["https://openalex.org/I86501945"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5006062614","display_name":"Elisa M. Ovadia","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I86501945","display_name":"University of Delaware","ror":"https://ror.org/01sbq1a82","country_code":"US","type":"education","lineage":["https://openalex.org/I86501945"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Elisa M. Ovadia","raw_affiliation_strings":["Department of Chemical and Biomolecular Engineering","Newark","USA","University of Delaware","Department of Chemical and Biomolecular Engineering, University of Delaware, Newark, DE 19716, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemical and Biomolecular Engineering","institution_ids":[]},{"raw_affiliation_string":"Newark","institution_ids":[]},{"raw_affiliation_string":"USA","institution_ids":[]},{"raw_affiliation_string":"University of Delaware","institution_ids":["https://openalex.org/I86501945"]},{"raw_affiliation_string":"Department of Chemical and Biomolecular Engineering, University of Delaware, Newark, DE 19716, USA","institution_ids":["https://openalex.org/I86501945"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5033012296","display_name":"Christopher J. Calo","orcid":"https://orcid.org/0009-0001-1262-107X","observed_orcids":["https://orcid.org/0009-0001-1262-107X"]},"institutions":[{"id":"https://openalex.org/I86501945","display_name":"University of Delaware","ror":"https://ror.org/01sbq1a82","country_code":"US","type":"education","lineage":["https://openalex.org/I86501945"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Christopher J. Calo","raw_affiliation_strings":["Department of Chemical and Biomolecular Engineering","Newark","USA","University of Delaware","Department of Chemical and Biomolecular Engineering, University of Delaware, Newark, DE 19716, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemical and Biomolecular Engineering","institution_ids":[]},{"raw_affiliation_string":"Newark","institution_ids":[]},{"raw_affiliation_string":"USA","institution_ids":[]},{"raw_affiliation_string":"University of Delaware","institution_ids":["https://openalex.org/I86501945"]},{"raw_affiliation_string":"Department of Chemical and Biomolecular Engineering, University of Delaware, Newark, DE 19716, USA","institution_ids":["https://openalex.org/I86501945"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5030414562","display_name":"Rebecca E. Huber","orcid":"https://orcid.org/0009-0005-7622-7230","observed_orcids":["https://orcid.org/0009-0005-7622-7230"]},"institutions":[{"id":"https://openalex.org/I86501945","display_name":"University of Delaware","ror":"https://ror.org/01sbq1a82","country_code":"US","type":"education","lineage":["https://openalex.org/I86501945"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Rebecca E. Huber","raw_affiliation_strings":["Department of Chemical and Biomolecular Engineering","Newark","USA","University of Delaware","Department of Chemical and Biomolecular Engineering, University of Delaware, Newark, DE 19716, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemical and Biomolecular Engineering","institution_ids":[]},{"raw_affiliation_string":"Newark","institution_ids":[]},{"raw_affiliation_string":"USA","institution_ids":[]},{"raw_affiliation_string":"University of Delaware","institution_ids":["https://openalex.org/I86501945"]},{"raw_affiliation_string":"Department of Chemical and Biomolecular Engineering, University of Delaware, Newark, DE 19716, USA","institution_ids":["https://openalex.org/I86501945"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5030683908","display_name":"April M. Kloxin","orcid":"https://orcid.org/0000-0002-4594-2953","observed_orcids":["https://orcid.org/0000-0002-4594-2953"]},"institutions":[{"id":"https://openalex.org/I86501945","display_name":"University of Delaware","ror":"https://ror.org/01sbq1a82","country_code":"US","type":"education","lineage":["https://openalex.org/I86501945"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"April M. Kloxin","raw_affiliation_strings":["Department of Chemical and Biomolecular Engineering","Department of Material Science and Engineering","Newark","USA","University of Delaware","Department of Chemical and Biomolecular Engineering, University of Delaware, Newark, DE 19716, USA","Department of Material Science and Engineering, University of Delaware, Newark, DE 19716, USA"],"raw_orcid":"https://orcid.org/0000-0002-4594-2953","affiliations":[{"raw_affiliation_string":"Department of Chemical and Biomolecular Engineering","institution_ids":[]},{"raw_affiliation_string":"Department of Material Science and Engineering","institution_ids":[]},{"raw_affiliation_string":"Newark","institution_ids":[]},{"raw_affiliation_string":"USA","institution_ids":[]},{"raw_affiliation_string":"University of Delaware","institution_ids":["https://openalex.org/I86501945"]},{"raw_affiliation_string":"Department of Chemical and Biomolecular Engineering, University of Delaware, Newark, DE 19716, USA","institution_ids":["https://openalex.org/I86501945"]},{"raw_affiliation_string":"Department of Material Science and Engineering, University of Delaware, Newark, DE 19716, USA","institution_ids":["https://openalex.org/I86501945"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5030683908"],"corresponding_institution_ids":["https://openalex.org/I86501945"],"apc_list":null,"apc_paid":null,"fwci":1.3831,"has_fulltext":false,"cited_by_count":30,"citation_normalized_percentile":{"value":0.76969924,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":95,"max":99},"biblio":{"volume":"10","issue":"32","first_page":"4428","last_page":"4440"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10343","display_name":"Hydrogels: synthesis, properties, applications","score":0.6937999725341797,"subfield":{"id":"https://openalex.org/subfields/1313","display_name":"Molecular Medicine"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}},"topics":[{"id":"https://openalex.org/T10343","display_name":"Hydrogels: synthesis, properties, applications","score":0.6937999725341797,"subfield":{"id":"https://openalex.org/subfields/1313","display_name":"Molecular Medicine"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}},{"id":"https://openalex.org/T12570","display_name":"Photopolymerization techniques and applications","score":0.2712000012397766,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.026100000366568565,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/photopolymerization-rate","display_name":"photopolymerization rate","score":0.824999988079071},{"id":"https://openalex.org/keywords/mechanical-properties","display_name":"mechanical properties","score":0.7039999961853027},{"id":"https://openalex.org/keywords/young-s-modulus","display_name":"Young's modulus","score":0.7630000114440918},{"id":"https://openalex.org/keywords/visible-light-curing","display_name":"visible light curing","score":0.5690000057220459},{"id":"https://openalex.org/keywords/uv-photopolymerization","display_name":"UV photopolymerization","score":0.7599999904632568},{"id":"https://openalex.org/keywords/irradiation-wavelength","display_name":"irradiation wavelength","score":0.6909999847412109},{"id":"https://openalex.org/keywords/irradiance","display_name":"irradiance","score":0.7860000133514404},{"id":"https://openalex.org/keywords/nmr-relaxation","display_name":"NMR relaxation","score":0.32600000500679016}],"concepts":[{"id":"https://openalex.org/C108586683","wikidata":"https://www.wikidata.org/wiki/Q17164826","display_name":"Self-healing hydrogels","level":2,"score":0.7518715262413025},{"id":"https://openalex.org/C27777614","wikidata":"https://www.wikidata.org/wiki/Q26469","display_name":"Ene reaction","level":2,"score":0.7162023186683655},{"id":"https://openalex.org/C2781324293","wikidata":"https://www.wikidata.org/wiki/Q220410","display_name":"Thiol","level":2,"score":0.6773179173469543},{"id":"https://openalex.org/C104663316","wikidata":"https://www.wikidata.org/wiki/Q76299","display_name":"Visible spectrum","level":2,"score":0.44905734062194824},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.4055878520011902},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.3766464293003082},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.35232213139533997},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.3330293893814087},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.33066388964653015},{"id":"https://openalex.org/C49040817","wikidata":"https://www.wikidata.org/wiki/Q193091","display_name":"Optoelectronics","level":1,"score":0.16002553701400757},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.0969160795211792},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.05161741375923157}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1039/c9py00447e","doi":"https://doi.org/10.1039/c9py00447e","is_oa":false,"landing_page_url":"https://doi.org/10.1039/c9py00447e","pdf_url":null,"source":{"id":"https://openalex.org/S187215728","display_name":"Polymer Chemistry","issn_l":"1759-9954","issn":["1759-9954","1759-9962"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-1","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Polymer Chemistry","raw_type":"journal-article"},{"id":"pmid:32405326","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/32405326","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Polymer chemistry","raw_type":"Journal Article"},{"id":"pmh:oai:pubmedcentral.nih.gov:7218207","doi":null,"is_oa":true,"landing_page_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/7218207","pdf_url":null,"source":{"id":"https://openalex.org/S2764455111","display_name":"PubMed Central","issn_l":null,"issn":null,"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":"Polym Chem","raw_type":"Text"}],"best_oa_location":{"id":"pmh:oai:pubmedcentral.nih.gov:7218207","doi":null,"is_oa":true,"landing_page_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/7218207","pdf_url":null,"source":{"id":"https://openalex.org/S2764455111","display_name":"PubMed Central","issn_l":null,"issn":null,"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":"Polym Chem","raw_type":"Text"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G3037964080","display_name":"Discovery of Chemical Probes and Therapeutic Leads, Phase II","funder_award_id":"P20GM104316","funder_id":"https://openalex.org/F4320337354","funder_display_name":"National Institute of General Medical Sciences"},{"id":"https://openalex.org/G8612150275","display_name":"Molecular Design of Advanced Biomaterials","funder_award_id":"P30GM110758","funder_id":"https://openalex.org/F4320337354","funder_display_name":"National Institute of General Medical Sciences"}],"funders":[{"id":"https://openalex.org/F4320337354","display_name":"National Institute of General Medical Sciences","ror":"https://ror.org/04q48ey07"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":39,"referenced_works":["https://openalex.org/W1843091404","https://openalex.org/W1862989971","https://openalex.org/W1983302798","https://openalex.org/W1995475776","https://openalex.org/W1999848701","https://openalex.org/W2023952099","https://openalex.org/W2034942332","https://openalex.org/W2036827000","https://openalex.org/W2069977719","https://openalex.org/W2070170630","https://openalex.org/W2082182581","https://openalex.org/W2086999700","https://openalex.org/W2087816485","https://openalex.org/W2092934158","https://openalex.org/W2094761102","https://openalex.org/W2095108228","https://openalex.org/W2096543831","https://openalex.org/W2105895997","https://openalex.org/W2134208433","https://openalex.org/W2166027129","https://openalex.org/W2213595904","https://openalex.org/W2229444275","https://openalex.org/W2280422486","https://openalex.org/W2329616710","https://openalex.org/W2330373241","https://openalex.org/W2520809832","https://openalex.org/W2531386852","https://openalex.org/W2547875537","https://openalex.org/W2551328341","https://openalex.org/W2594594706","https://openalex.org/W2596643820","https://openalex.org/W2734616537","https://openalex.org/W2763034768","https://openalex.org/W2767569544","https://openalex.org/W2770693508","https://openalex.org/W2796682556","https://openalex.org/W2891230587","https://openalex.org/W2908369651","https://openalex.org/W2912204648"],"related_works":["https://openalex.org/W2531386852","https://openalex.org/W2888487222","https://openalex.org/W4322743978","https://openalex.org/W2607679481","https://openalex.org/W4412717809","https://openalex.org/W2809634452","https://openalex.org/W6963801746","https://openalex.org/W2952295989","https://openalex.org/W4380786914","https://openalex.org/W2039579180"],"abstract_inverted_index":{"H":[0],"NMR)":[1],"correlated":[2],"with":[3,33,64],"these":[4],"mechanical":[5,20],"properties":[6,73],"measurements,":[7],"suggesting":[8],"that":[9],"both":[10],"dangling":[11],"end":[12,23],"groups":[13,24],"and":[14,68,94],"looping":[15],"contribute":[16],"to":[17,70,88],"the":[18,57,72],"observed":[19],"properties.":[21],"Dangling":[22],"provide":[25],"reactive":[26],"handles":[27],"for":[28,90],"temporal":[29],"stiffening":[30],"of":[31,48,59,74,84],"hydrogels":[32],"a":[34,46,82],"secondary":[35],"UV-initiated":[36],"thiol-ene":[37],"polymerization,":[38],"where":[39],"an":[40],"increase":[41],"in":[42,81],"Young's":[43],"modulus":[44],"by":[45],"factor":[47],"~":[49],"2.5x":[50],"was":[51],"observed.":[52],"These":[53],"studies":[54],"demonstrate":[55],"how":[56],"rate":[58],"photopolymerization":[60],"can":[61],"be":[62],"tuned":[63],"irradiation":[65],"wavelength,":[66],"intensity,":[67],"time":[69],"control":[71],"synthetic":[75],"hydrogels,":[76],"which":[77],"may":[78],"prove":[79],"useful":[80],"variety":[83],"applications":[85],"from":[86],"coatings":[87],"biomaterials":[89],"controlled":[91],"cell":[92],"culture":[93],"regenerative":[95],"medicine.":[96]},"counts_by_year":[{"year":2025,"cited_by_count":6},{"year":2024,"cited_by_count":3},{"year":2023,"cited_by_count":5},{"year":2022,"cited_by_count":3},{"year":2021,"cited_by_count":4},{"year":2020,"cited_by_count":6},{"year":2019,"cited_by_count":3}],"updated_date":"2026-10-28T10:33:24.094632","created_date":"2019-07-23T00:00:00"}
