{"id":"https://openalex.org/W2954548481","doi":"https://doi.org/10.1021/acs.organomet.9b00253","title":"Zirconocene-Catalyzed Polymerization of \u03b1-Olefins: When Intrinsic Higher Activity Is Flawed by Rapid Deactivation","display_name":"Zirconocene-Catalyzed Polymerization of \u03b1-Olefins: When Intrinsic Higher Activity Is Flawed by Rapid Deactivation","publication_year":2019,"publication_date":"2019-06-25","ids":{"openalex":"https://openalex.org/W2954548481","doi":"https://doi.org/10.1021/acs.organomet.9b00253","mag":"2954548481"},"language":"en","primary_location":{"id":"doi:10.1021/acs.organomet.9b00253","doi":"https://doi.org/10.1021/acs.organomet.9b00253","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.organomet.9b00253","pdf_url":null,"source":{"id":"https://openalex.org/S4924609","display_name":"Organometallics","issn_l":"0276-7333","issn":["0276-7333","1520-6041"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","norway-2","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organometallics","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://univ-rennes.hal.science/hal-02278426","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5079791727","display_name":"Xavier D\u00e9sert","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210090783","display_name":"Institut des Sciences Chimiques de Rennes","ror":"https://ror.org/00adwkx90","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I28221208","https://openalex.org/I4210090783","https://openalex.org/I4210115835","https://openalex.org/I4210128300","https://openalex.org/I56067802"]},{"id":"https://openalex.org/I56067802","display_name":"Universit\u00e9 de Rennes","ror":"https://ror.org/015m7wh34","country_code":"FR","type":"education","lineage":["https://openalex.org/I56067802"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Xavier Desert","raw_affiliation_strings":["Univ Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes), UMR 6226, F-35700 Rennes, France"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Univ Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes), UMR 6226, F-35700 Rennes, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210090783","https://openalex.org/I56067802"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5006206679","display_name":"Fabien Prouti\u00e8re","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210090783","display_name":"Institut des Sciences Chimiques de Rennes","ror":"https://ror.org/00adwkx90","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I28221208","https://openalex.org/I4210090783","https://openalex.org/I4210115835","https://openalex.org/I4210128300","https://openalex.org/I56067802"]},{"id":"https://openalex.org/I56067802","display_name":"Universit\u00e9 de Rennes","ror":"https://ror.org/015m7wh34","country_code":"FR","type":"education","lineage":["https://openalex.org/I56067802"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Fabien Proutiere","raw_affiliation_strings":["Univ Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes), UMR 6226, F-35700 Rennes, France"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Univ Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes), UMR 6226, F-35700 Rennes, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210090783","https://openalex.org/I56067802"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5046200204","display_name":"Alexandre Welle","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I103084370","display_name":"Total (France)","ror":"https://ror.org/04sk34n56","country_code":"FR","type":"company","lineage":["https://openalex.org/I103084370"]},{"id":"https://openalex.org/I4210122041","display_name":"Total (Belgium)","ror":"https://ror.org/032mp1e77","country_code":"BE","type":"company","lineage":["https://openalex.org/I103084370","https://openalex.org/I4210122041"]}],"countries":["BE","FR"],"is_corresponding":false,"raw_author_name":"Alexandre Welle","raw_affiliation_strings":["Total Research & Technology Feluy, Zone Industrielle Feluy C, B-7181 Seneffe, Belgium","TotalFinaElf (France)"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Total Research & Technology Feluy, Zone Industrielle Feluy C, B-7181 Seneffe, Belgium","institution_ids":["https://openalex.org/I4210122041"]},{"raw_affiliation_string":"TotalFinaElf (France)","institution_ids":["https://openalex.org/I103084370"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5033234454","display_name":"Katty Den Dauw","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I103084370","display_name":"Total (France)","ror":"https://ror.org/04sk34n56","country_code":"FR","type":"company","lineage":["https://openalex.org/I103084370"]},{"id":"https://openalex.org/I4210122041","display_name":"Total (Belgium)","ror":"https://ror.org/032mp1e77","country_code":"BE","type":"company","lineage":["https://openalex.org/I103084370","https://openalex.org/I4210122041"]}],"countries":["BE","FR"],"is_corresponding":false,"raw_author_name":"Katty Den Dauw","raw_affiliation_strings":["Total Research & Technology Feluy, Zone Industrielle Feluy C, B-7181 Seneffe, Belgium","TotalFinaElf (France)"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Total Research & Technology Feluy, Zone Industrielle Feluy C, B-7181 Seneffe, Belgium","institution_ids":["https://openalex.org/I4210122041"]},{"raw_affiliation_string":"TotalFinaElf (France)","institution_ids":["https://openalex.org/I103084370"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5088744175","display_name":"Aur\u00e9lien Vantomme","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I103084370","display_name":"Total (France)","ror":"https://ror.org/04sk34n56","country_code":"FR","type":"company","lineage":["https://openalex.org/I103084370"]},{"id":"https://openalex.org/I4210122041","display_name":"Total (Belgium)","ror":"https://ror.org/032mp1e77","country_code":"BE","type":"company","lineage":["https://openalex.org/I103084370","https://openalex.org/I4210122041"]}],"countries":["BE","FR"],"is_corresponding":false,"raw_author_name":"Aur\u00e9lien Vantomme","raw_affiliation_strings":["Total Research & Technology Feluy, Zone Industrielle Feluy C, B-7181 Seneffe, Belgium","TotalFinaElf (France)"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Total Research & Technology Feluy, Zone Industrielle Feluy C, B-7181 Seneffe, Belgium","institution_ids":["https://openalex.org/I4210122041"]},{"raw_affiliation_string":"TotalFinaElf (France)","institution_ids":["https://openalex.org/I103084370"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5075626059","display_name":"Olivier Miserque","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I103084370","display_name":"Total (France)","ror":"https://ror.org/04sk34n56","country_code":"FR","type":"company","lineage":["https://openalex.org/I103084370"]},{"id":"https://openalex.org/I4210122041","display_name":"Total (Belgium)","ror":"https://ror.org/032mp1e77","country_code":"BE","type":"company","lineage":["https://openalex.org/I103084370","https://openalex.org/I4210122041"]}],"countries":["BE","FR"],"is_corresponding":false,"raw_author_name":"Olivier Miserque","raw_affiliation_strings":["Total Research & Technology Feluy, Zone Industrielle Feluy C, B-7181 Seneffe, Belgium","TotalFinaElf (France)"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Total Research & Technology Feluy, Zone Industrielle Feluy C, B-7181 Seneffe, Belgium","institution_ids":["https://openalex.org/I4210122041"]},{"raw_affiliation_string":"TotalFinaElf (France)","institution_ids":["https://openalex.org/I103084370"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5068705381","display_name":"Jean\u2010Michel Brusson","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I103084370","display_name":"Total (France)","ror":"https://ror.org/04sk34n56","country_code":"FR","type":"company","lineage":["https://openalex.org/I103084370"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Jean-Michel Brusson","raw_affiliation_strings":["Total S.A., Direction R&D Groupe, Tour Michelet A, 24 Cours Michelet \u2212 La D\u00e9fense 10, F-92069 Paris La D\u00e9fense Cedex, France"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Total S.A., Direction R&D Groupe, Tour Michelet A, 24 Cours Michelet \u2212 La D\u00e9fense 10, F-92069 Paris La D\u00e9fense Cedex, France","institution_ids":["https://openalex.org/I103084370"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5064611725","display_name":"Jean\u2010Fran\u00e7ois Carpentier","orcid":"https://orcid.org/0000-0002-9160-7662","observed_orcids":["https://orcid.org/0000-0002-9160-7662","https://orcid.org/0000-0001-8961-900X"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210090783","display_name":"Institut des Sciences Chimiques de Rennes","ror":"https://ror.org/00adwkx90","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I28221208","https://openalex.org/I4210090783","https://openalex.org/I4210115835","https://openalex.org/I4210128300","https://openalex.org/I56067802"]},{"id":"https://openalex.org/I56067802","display_name":"Universit\u00e9 de Rennes","ror":"https://ror.org/015m7wh34","country_code":"FR","type":"education","lineage":["https://openalex.org/I56067802"]}],"countries":["FR"],"is_corresponding":true,"raw_author_name":"Jean-Fran\u00e7ois Carpentier","raw_affiliation_strings":["Univ Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes), UMR 6226, F-35700 Rennes, France"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Univ Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes), UMR 6226, F-35700 Rennes, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210090783","https://openalex.org/I56067802"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5010301750","display_name":"Evgueni Kirillov","orcid":"https://orcid.org/0000-0002-5067-480X","observed_orcids":["https://orcid.org/0000-0002-5067-480X"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210090783","display_name":"Institut des Sciences Chimiques de Rennes","ror":"https://ror.org/00adwkx90","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I28221208","https://openalex.org/I4210090783","https://openalex.org/I4210115835","https://openalex.org/I4210128300","https://openalex.org/I56067802"]},{"id":"https://openalex.org/I56067802","display_name":"Universit\u00e9 de Rennes","ror":"https://ror.org/015m7wh34","country_code":"FR","type":"education","lineage":["https://openalex.org/I56067802"]}],"countries":["FR"],"is_corresponding":true,"raw_author_name":"Evgueni Kirillov","raw_affiliation_strings":["Univ Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes), UMR 6226, F-35700 Rennes, France"],"raw_orcid":"https://orcid.org/0000-0002-5067-480X","affiliations":[{"raw_affiliation_string":"Univ Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes), UMR 6226, F-35700 Rennes, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210090783","https://openalex.org/I56067802"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":5,"corresponding_author_ids":["https://openalex.org/A5010301750","https://openalex.org/A5064611725"],"corresponding_institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210090783","https://openalex.org/I56067802"],"apc_list":{"value":5000,"currency":"USD","value_usd":5000},"apc_paid":null,"fwci":1.3086,"has_fulltext":false,"cited_by_count":21,"citation_normalized_percentile":{"value":0.75962377,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":98},"biblio":{"volume":"38","issue":"13","first_page":"2664","last_page":"2673"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.9990000128746033,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.9990000128746033,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.00019999999494757503,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11549","display_name":"Synthetic Organic Chemistry Methods","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/zirconocene-catalysts","display_name":"zirconocene catalysts","score":0.9539999961853027},{"id":"https://openalex.org/keywords/1-hexene-polymerization","display_name":"1-hexene polymerization","score":0.906000018119812},{"id":"https://openalex.org/keywords/alpha-olefin-polymerization","display_name":"\u03b1-olefin polymerization","score":0.8799999952316284},{"id":"https://openalex.org/keywords/catalyst-deactivation","display_name":"catalyst deactivation","score":0.8420000076293945},{"id":"https://openalex.org/keywords/catalyst-aging","display_name":"catalyst aging","score":0.382999986410141},{"id":"https://openalex.org/keywords/activation-efficiency","display_name":"activation efficiency","score":0.5910000205039978},{"id":"https://openalex.org/keywords/propagation-rate","display_name":"propagation rate","score":0.335999995470047},{"id":"https://openalex.org/keywords/active-site-concentration","display_name":"active site concentration","score":0.7459999918937683},{"id":"https://openalex.org/keywords/1-2-insertion","display_name":"1,2-insertion","score":0.718999981880188},{"id":"https://openalex.org/keywords/beta-hydride-elimination","display_name":"\u03b2-hydride elimination","score":0.7329999804496765}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8579292297363281},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.7194809913635254},{"id":"https://openalex.org/C44228677","wikidata":"https://www.wikidata.org/wiki/Q181898","display_name":"Polymerization","level":3,"score":0.6736822128295898},{"id":"https://openalex.org/C66882249","wikidata":"https://www.wikidata.org/wiki/Q169336","display_name":"Homogeneous","level":2,"score":0.6616216897964478},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.5930671095848083},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.5636925101280212},{"id":"https://openalex.org/C166940927","wikidata":"https://www.wikidata.org/wiki/Q178827","display_name":"Monomer","level":3,"score":0.5078652501106262},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.4251285493373871},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.3368905186653137},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.17740491032600403},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.0788809061050415},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1021/acs.organomet.9b00253","doi":"https://doi.org/10.1021/acs.organomet.9b00253","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.organomet.9b00253","pdf_url":null,"source":{"id":"https://openalex.org/S4924609","display_name":"Organometallics","issn_l":"0276-7333","issn":["0276-7333","1520-6041"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","norway-2","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organometallics","raw_type":"journal-article"},{"id":"pmh:oai:HAL:hal-02278426v1","doi":null,"is_oa":true,"landing_page_url":"https://univ-rennes.hal.science/hal-02278426","pdf_url":null,"source":{"id":"https://openalex.org/S4306402512","display_name":"HAL","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I4405252976","host_organization_name":"Centre pour la Communication Scientifique Directe","host_organization_lineage":["https://openalex.org/I4405252976"],"host_organization_lineage_names":[],"type":"repository"},"license":"other-oa","license_id":"https://openalex.org/licenses/other-oa","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Organometallics, 2019, 38 (13), pp.2664-2673. &#x27E8;10.1021/acs.organomet.9b00253&#x27E9;","raw_type":"info:eu-repo/semantics/article"}],"best_oa_location":{"id":"pmh:oai:HAL:hal-02278426v1","doi":null,"is_oa":true,"landing_page_url":"https://univ-rennes.hal.science/hal-02278426","pdf_url":null,"source":{"id":"https://openalex.org/S4306402512","display_name":"HAL","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I4405252976","host_organization_name":"Centre pour la Communication Scientifique Directe","host_organization_lineage":["https://openalex.org/I4405252976"],"host_organization_lineage_names":[],"type":"repository"},"license":"other-oa","license_id":"https://openalex.org/licenses/other-oa","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Organometallics, 2019, 38 (13), pp.2664-2673. &#x27E8;10.1021/acs.organomet.9b00253&#x27E9;","raw_type":"info:eu-repo/semantics/article"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320324219","display_name":"Total","ror":"https://ror.org/04sk34n56"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":69,"referenced_works":["https://openalex.org/W167207629","https://openalex.org/W408371293","https://openalex.org/W1524652066","https://openalex.org/W1525662183","https://openalex.org/W1540608370","https://openalex.org/W1588532305","https://openalex.org/W1594376184","https://openalex.org/W1761661010","https://openalex.org/W1771894287","https://openalex.org/W1939948905","https://openalex.org/W1965363517","https://openalex.org/W1967967126","https://openalex.org/W1969364668","https://openalex.org/W1970121803","https://openalex.org/W1971037885","https://openalex.org/W1974329067","https://openalex.org/W1978253368","https://openalex.org/W1985927607","https://openalex.org/W1990335611","https://openalex.org/W1990640004","https://openalex.org/W1991436567","https://openalex.org/W1991933231","https://openalex.org/W1996508350","https://openalex.org/W1998951657","https://openalex.org/W2001827177","https://openalex.org/W2013755834","https://openalex.org/W2033340431","https://openalex.org/W2034585266","https://openalex.org/W2036279732","https://openalex.org/W2039410044","https://openalex.org/W2040643557","https://openalex.org/W2057442814","https://openalex.org/W2062424252","https://openalex.org/W2062719632","https://openalex.org/W2067722023","https://openalex.org/W2069156443","https://openalex.org/W2070821101","https://openalex.org/W2077575043","https://openalex.org/W2079544812","https://openalex.org/W2081677885","https://openalex.org/W2082294282","https://openalex.org/W2083924613","https://openalex.org/W2085834540","https://openalex.org/W2093054849","https://openalex.org/W2134026850","https://openalex.org/W2137097813","https://openalex.org/W2153624834","https://openalex.org/W2158856628","https://openalex.org/W2163568720","https://openalex.org/W2164733797","https://openalex.org/W2222550034","https://openalex.org/W2235848855","https://openalex.org/W2274822436","https://openalex.org/W2298590441","https://openalex.org/W2315915695","https://openalex.org/W2317006802","https://openalex.org/W2322790578","https://openalex.org/W2326015281","https://openalex.org/W2331929369","https://openalex.org/W2332389559","https://openalex.org/W2333995973","https://openalex.org/W2337983725","https://openalex.org/W2409389613","https://openalex.org/W2412221568","https://openalex.org/W2509508976","https://openalex.org/W2522810396","https://openalex.org/W2741338833","https://openalex.org/W2904904937","https://openalex.org/W2914818856"],"related_works":["https://openalex.org/W4394589294","https://openalex.org/W7148704553","https://openalex.org/W1990640004","https://openalex.org/W2946910387","https://openalex.org/W2062879890","https://openalex.org/W2075120473","https://openalex.org/W3033917199","https://openalex.org/W71921153","https://openalex.org/W2137097813","https://openalex.org/W2011839451"],"abstract_inverted_index":{"Kinetic":[0],"studies":[1],"of":[2,18,103,113,128,141,186,200,210,237,257],"homogeneous":[3],"1-hexene":[4,201],"polymerization":[5],"have":[6],"been":[7,119],"used":[8],"for":[9,150,183,231],"determining":[10],"the":[11,125,142,147,151,162,190,203,217,232,238,248],"propagation":[12,148],"rates":[13,149],"and":[14,26,111,171],"active":[15,212],"sites":[16],"concentrations":[17],"industrially":[19],"relevant":[20],"zirconocene":[21],"catalytic":[22,187],"systems":[23,153,192],"incorporating":[24],"{SBI}-":[25],"{Cp/Flu}-":[27],"ancillaries:":[28],"{":[29,42],"rac":[30,43],"-Me":[31,44],"2":[32,36,38,45,47,49,54,58,62,69,73,78,82,86,93,97,261],"Si(2-Me-Benz[":[33],"e":[34],"]Ind)":[35],"}ZrCl":[37,48],"(":[39,50,63,74,87,98],"{SBI}-1":[40],"),":[41,52,65,76,89],"Si(2-Me-4-Ph-Ind)":[46],"{SBI}-2":[51],"{Me":[53],"C(3,6-":[55],"t":[56,60,67,71,80,84,91,95],"Bu":[57,68,81,92],"-Flu)(2-Me-4-":[59,83,94],"Bu-Cp)}ZrCl":[61,72,85,96],"{Cp/Flu}-1":[64],"{Ph(H)C(3,6-":[66],"-Flu)(2-Et-4-":[70],"{Cp/Flu}-2":[75],"{Ph":[77],"C(2,7-":[79],"{Cp/Flu}-3":[88],"{Ph(H)C(2,7-":[90],"{Cp/Flu}-4":[99],").":[100],"The":[101],"influence":[102],"different":[104],"activation":[105,126],"parameters,":[106],"such":[107],"as":[108],"aging":[109],"time":[110],"nature":[112],"coactivator":[114],"(MAO":[115],"vs":[116],"boraluminoxane),":[117],"has":[118],"investigated.":[120],"It":[121],"was":[122],"found":[123],"that":[124,140],"efficiency":[127],"{Cp/Flu}-type":[129,218,240],"precatalysts":[130,144],"by":[131,255],"MAO":[132],"is":[133,227],"similar":[134],"(1\u201312%":[135],"at":[136],"30":[137],"\u00b0C)":[138],"to":[139,155,158,181,195,223,229],"{SBI}-type":[143,163,191],"(4\u201318%).":[145],"Moreover,":[146],"{Cp/Flu}-based":[152],"appeared":[154],"be":[156,252],"superior":[157],"those":[159],"obtained":[160],"with":[161,247],"congeners.":[164],"Deactivation":[165],"processes,":[166],"arising":[167],"from":[168],"monomer":[169],"2,1-misinsertions":[170],"resulting":[172],"in":[173],"dormant":[174],"M\u2013":[175,204,243],"sec":[176,205,244],"-alkyl":[177,206,245],"species,":[178],"were":[179],"demonstrated":[180],"occur":[182],"both":[184],"types":[185],"systems.":[188,241],"While":[189],"are":[193,220],"capable":[194],"undergo":[196,208],"further":[197,224],"regular":[198],"1,2-insertions":[199],"into":[202],"(or":[207],"regeneration":[209],"an":[211],"species":[213,246],"through":[214],"\u03b2-H":[215],"elimination),":[216],"congeners":[219],"apparently":[221],"reluctant":[222],"enchainement;":[225],"this":[226],"proposed":[228],"account":[230],"observed":[233],"overall":[234],"lower":[235],"productivity":[236],"latter":[239],"Dormant":[242],"{Cp/Flu}":[249],"ancillaries":[250],"can":[251],"efficiently":[253],"reactivated":[254],"introduction":[256],"small":[258],"molecules":[259],"(H":[260],"or":[262],"ethylene).":[263]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2025,"cited_by_count":2},{"year":2024,"cited_by_count":2},{"year":2023,"cited_by_count":2},{"year":2022,"cited_by_count":3},{"year":2021,"cited_by_count":5},{"year":2020,"cited_by_count":5},{"year":2019,"cited_by_count":1}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2019-07-12T00:00:00"}
