{"id":"https://openalex.org/W2953346207","doi":"https://doi.org/10.1021/jo981047u","title":"Novel Heterocycloaddition Reaction of Glycals","display_name":"Novel Heterocycloaddition Reaction of Glycals","publication_year":1998,"publication_date":"1998-08-26","ids":{"openalex":"https://openalex.org/W2953346207","doi":"https://doi.org/10.1021/jo981047u","mag":"2953346207"},"language":"en","primary_location":{"id":"doi:10.1021/jo981047u","doi":"https://doi.org/10.1021/jo981047u","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jo981047u","pdf_url":null,"source":{"id":"https://openalex.org/S205050996","display_name":"The Journal of Organic Chemistry","issn_l":"0022-3263","issn":["0022-3263","1520-6904"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Organic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5053100570","display_name":"Angeles Dios","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I39694355","display_name":"Hunter College","ror":"https://ror.org/00g2xk477","country_code":"US","type":"education","lineage":["https://openalex.org/I39694355"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Angeles Dios","raw_affiliation_strings":["Department of Chemistry, Hunter College, 695 Park Avenue, New York, New York 10021"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Hunter College, 695 Park Avenue, New York, New York 10021","institution_ids":["https://openalex.org/I39694355"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5085376915","display_name":"Aloma Geer","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I39694355","display_name":"Hunter College","ror":"https://ror.org/00g2xk477","country_code":"US","type":"education","lineage":["https://openalex.org/I39694355"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Aloma Geer","raw_affiliation_strings":["Department of Chemistry, Hunter College, 695 Park Avenue, New York, New York 10021"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Hunter College, 695 Park Avenue, New York, New York 10021","institution_ids":["https://openalex.org/I39694355"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5004240874","display_name":"Cecilia H. Marzabadi","orcid":"https://orcid.org/0000-0002-8459-2060","observed_orcids":["https://orcid.org/0000-0002-8459-2060"]},"institutions":[{"id":"https://openalex.org/I39694355","display_name":"Hunter College","ror":"https://ror.org/00g2xk477","country_code":"US","type":"education","lineage":["https://openalex.org/I39694355"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Cecilia H. Marzabadi","raw_affiliation_strings":["Department of Chemistry, Hunter College, 695 Park Avenue, New York, New York 10021"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Hunter College, 695 Park Avenue, New York, New York 10021","institution_ids":["https://openalex.org/I39694355"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5110471080","display_name":"Richard W. Franck","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I39694355","display_name":"Hunter College","ror":"https://ror.org/00g2xk477","country_code":"US","type":"education","lineage":["https://openalex.org/I39694355"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Richard W. Franck","raw_affiliation_strings":["Department of Chemistry, Hunter College, 695 Park Avenue, New York, New York 10021"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Hunter College, 695 Park Avenue, New York, New York 10021","institution_ids":["https://openalex.org/I39694355"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I39694355"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":1.2133,"has_fulltext":false,"cited_by_count":19,"citation_normalized_percentile":{"value":0.76733725,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":96},"biblio":{"volume":"63","issue":"19","first_page":"6673","last_page":"6679"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10835","display_name":"Carbohydrate Chemistry and Synthesis","score":0.6304000020027161,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10835","display_name":"Carbohydrate Chemistry and Synthesis","score":0.6304000020027161,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12893","display_name":"Organic Chemistry Cycloaddition Reactions","score":0.2442999929189682,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13859","display_name":"Organic Chemistry Synthesis Methods","score":0.03009999915957451,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/glycals","display_name":"glycals","score":0.8799999952316284},{"id":"https://openalex.org/keywords/diels-alder-reaction","display_name":"Diels-Alder reaction","score":0.9290000200271606},{"id":"https://openalex.org/keywords/face-selectivity","display_name":"face selectivity","score":0.9860000014305115},{"id":"https://openalex.org/keywords/homo-lumo-gap","display_name":"HOMO-LUMO gap","score":0.9639999866485596},{"id":"https://openalex.org/keywords/protecting-groups","display_name":"protecting groups","score":0.7979999780654907},{"id":"https://openalex.org/keywords/in-medium-effects","display_name":"medium effects","score":0.7139999866485596}],"concepts":[{"id":"https://openalex.org/C2779664164","wikidata":"https://www.wikidata.org/wiki/Q898648","display_name":"Cycloaddition","level":3,"score":0.8221323490142822},{"id":"https://openalex.org/C2776910235","wikidata":"https://www.wikidata.org/wiki/Q18574","display_name":"Reactivity (psychology)","level":3,"score":0.821403980255127},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6723995208740234},{"id":"https://openalex.org/C118792377","wikidata":"https://www.wikidata.org/wiki/Q108584245","display_name":"Selectivity","level":3,"score":0.6515917181968689},{"id":"https://openalex.org/C14158195","wikidata":"https://www.wikidata.org/wiki/Q899637","display_name":"HOMO/LUMO","level":3,"score":0.49066030979156494},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.3485611081123352},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.3403233289718628},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.3359282314777374},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.11354866623878479},{"id":"https://openalex.org/C142724271","wikidata":"https://www.wikidata.org/wiki/Q7208","display_name":"Pathology","level":1,"score":0.0},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.0},{"id":"https://openalex.org/C204787440","wikidata":"https://www.wikidata.org/wiki/Q188504","display_name":"Alternative medicine","level":2,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/jo981047u","doi":"https://doi.org/10.1021/jo981047u","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jo981047u","pdf_url":null,"source":{"id":"https://openalex.org/S205050996","display_name":"The Journal of Organic Chemistry","issn_l":"0022-3263","issn":["0022-3263","1520-6904"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Organic Chemistry","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":15,"referenced_works":["https://openalex.org/W1973932359","https://openalex.org/W2032235400","https://openalex.org/W2034562061","https://openalex.org/W2037428084","https://openalex.org/W2041428698","https://openalex.org/W2043562797","https://openalex.org/W2050249790","https://openalex.org/W2067721207","https://openalex.org/W2095100168","https://openalex.org/W2128634587","https://openalex.org/W2165685850","https://openalex.org/W2331249020","https://openalex.org/W2950627517","https://openalex.org/W3024337882","https://openalex.org/W4251131007"],"related_works":["https://openalex.org/W1984635402","https://openalex.org/W2058985919","https://openalex.org/W2074364803","https://openalex.org/W4297375579","https://openalex.org/W1984193952","https://openalex.org/W2949636686","https://openalex.org/W2951926281","https://openalex.org/W4401267059","https://openalex.org/W4283070935","https://openalex.org/W1992453523"],"abstract_inverted_index":{"Diacyl":[0],"thione":[1],"species":[2,66],"1":[3],"has":[4],"been":[5],"generated":[6],"and":[7,14,29,48,63],"reacted":[8],"in":[9,33,82],"situ":[10],"with":[11,37,55],"both":[12],"pyranoid":[13],"furanoid":[15],"glycals":[16,35],"to":[17,42],"form":[18],"novel":[19],"[4":[20],"+":[21],"2]":[22],"cycloadducts.":[23],"Factors":[24],"such":[25],"as":[26],"protecting":[27],"groups":[28],"configuration":[30],"of":[31,53,75],"substituents":[32],"the":[34,56,60,64,73,79],"along":[36],"medium":[38],"effects":[39],"were":[40],"varied":[41],"discover":[43],"influences":[44],"on":[45],"face":[46],"selectivity":[47],"reactivity.":[49],"A":[50],"qualitative":[51],"correlation":[52],"reactivity":[54],"HOMO\u2212LUMO":[57],"gap":[58],"between":[59],"glycal":[61],"(HOMO)":[62],"heterodienic":[65],"(LUMO)":[67],"is":[68],"observed.":[69],"In":[70],"one":[71],"example,":[72],"isolation":[74],"byproducts":[76],"suggests":[77],"that":[78],"cycloaddition":[80],"may":[81],"fact":[83],"be":[84],"stepwise.":[85]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2022,"cited_by_count":2},{"year":2017,"cited_by_count":1},{"year":2016,"cited_by_count":1},{"year":2015,"cited_by_count":1},{"year":2013,"cited_by_count":1}],"updated_date":"2026-10-01T08:54:57.152042","created_date":"2019-06-27T00:00:00"}