{"id":"https://openalex.org/W2953210541","doi":"https://doi.org/10.1002/chin.198935306","title":"ChemInform Abstract: Synthetic Analogue Approach to Cobalt(III)\u2010Bleomycin: Synthesis, Crystal and Solution Structures and Redox Properties of Bis(N\u2010(2\u2010(4\u2010imidazolyl)ethyl)pyrimidine\u20104\u2010carboxamido)cobalt(III) Perchlorate\u00b72.25 H2O.","display_name":"ChemInform Abstract: Synthetic Analogue Approach to Cobalt(III)\u2010Bleomycin: Synthesis, Crystal and Solution Structures and Redox Properties of Bis(N\u2010(2\u2010(4\u2010imidazolyl)ethyl)pyrimidine\u20104\u2010carboxamido)cobalt(III) Perchlorate\u00b72.25 H2O.","publication_year":1989,"publication_date":"1989-08-29","ids":{"openalex":"https://openalex.org/W2953210541","doi":"https://doi.org/10.1002/chin.198935306","mag":"2953210541"},"language":"en","primary_location":{"id":"doi:10.1002/chin.198935306","doi":"https://doi.org/10.1002/chin.198935306","is_oa":false,"landing_page_url":"https://doi.org/10.1002/chin.198935306","pdf_url":null,"source":{"id":"https://openalex.org/S41354064","display_name":"ChemInform","issn_l":"0009-2975","issn":["0009-2975","0931-7597","1431-5890","1522-2667","2199-2924"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ChemInform","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5043218984","display_name":"Mark C. Muetterties","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I185103710","display_name":"University of California, Santa Cruz","ror":"https://ror.org/03s65by71","country_code":"US","type":"education","lineage":["https://openalex.org/I185103710"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"M. MUETTERTIES","raw_affiliation_strings":["Dep. Chem., Univ. Calif., Santa Cruz, CA 95064, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Dep. Chem., Univ. Calif., Santa Cruz, CA 95064, USA","institution_ids":["https://openalex.org/I185103710"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5060131715","display_name":"Pradip K. Mascharak","orcid":"https://orcid.org/0000-0002-7044-944X","observed_orcids":["https://orcid.org/0000-0002-7044-944X"]},"institutions":[{"id":"https://openalex.org/I185103710","display_name":"University of California, Santa Cruz","ror":"https://ror.org/03s65by71","country_code":"US","type":"education","lineage":["https://openalex.org/I185103710"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"P. K. MASCHARAK","raw_affiliation_strings":["Dep. Chem., Univ. Calif., Santa Cruz, CA 95064, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Dep. Chem., Univ. Calif., Santa Cruz, CA 95064, USA","institution_ids":["https://openalex.org/I185103710"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5055868553","display_name":"M. B. Cox","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I185103710","display_name":"University of California, Santa Cruz","ror":"https://ror.org/03s65by71","country_code":"US","type":"education","lineage":["https://openalex.org/I185103710"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"M. B. COX","raw_affiliation_strings":["Dep. Chem., Univ. Calif., Santa Cruz, CA 95064, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Dep. Chem., Univ. Calif., Santa Cruz, CA 95064, USA","institution_ids":["https://openalex.org/I185103710"]}]},{"author_position":"last","author":{"id":null,"display_name":"S. K. ARORA","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I185103710","display_name":"University of California, Santa Cruz","ror":"https://ror.org/03s65by71","country_code":"US","type":"education","lineage":["https://openalex.org/I185103710"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"S. K. ARORA","raw_affiliation_strings":["Dep. Chem., Univ. Calif., Santa Cruz, CA 95064, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Dep. Chem., Univ. Calif., Santa Cruz, CA 95064, USA","institution_ids":["https://openalex.org/I185103710"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I185103710"],"apc_list":null,"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.3869547,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":"20","issue":"35","first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10163","display_name":"Metal complexes synthesis and properties","score":0.989300012588501,"subfield":{"id":"https://openalex.org/subfields/2730","display_name":"Oncology"},"field":{"id":"https://openalex.org/fields/27","display_name":"Medicine"},"domain":{"id":"https://openalex.org/domains/4","display_name":"Health Sciences"}},"topics":[{"id":"https://openalex.org/T10163","display_name":"Metal complexes synthesis and properties","score":0.989300012588501,"subfield":{"id":"https://openalex.org/subfields/2730","display_name":"Oncology"},"field":{"id":"https://openalex.org/fields/27","display_name":"Medicine"},"domain":{"id":"https://openalex.org/domains/4","display_name":"Health Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.0044999998062849045,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11747","display_name":"Metal-Catalyzed Oxygenation Mechanisms","score":0.0027000000700354576,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/bleomycin","display_name":"bleomycin","score":0.843999981880188},{"id":"https://openalex.org/keywords/peptide-ligands","display_name":"peptide ligands","score":0.7329999804496765},{"id":"https://openalex.org/keywords/aerobic-oxidation","display_name":"aerobic oxidation","score":0.8669999837875366},{"id":"https://openalex.org/keywords/cobalt-iii-complexes","display_name":"cobalt(III) complexes","score":0.7850000262260437},{"id":"https://openalex.org/keywords/perchlorate-complexes","display_name":"perchlorate complexes","score":0.8019999861717224},{"id":"https://openalex.org/keywords/tetrafluoroborate-complexes","display_name":"tetrafluoroborate complexes","score":0.9470000267028809},{"id":"https://openalex.org/keywords/crystal-structure","display_name":"crystal structure","score":0.9269999861717224},{"id":"https://openalex.org/keywords/solution-structure","display_name":"solution structure","score":0.9950000047683716},{"id":"https://openalex.org/keywords/redox-properties","display_name":"redox properties","score":0.996999979019165},{"id":"https://openalex.org/keywords/anticancer-agents","display_name":"anticancer agents","score":0.7459999918937683}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9703570604324341},{"id":"https://openalex.org/C2780709120","wikidata":"https://www.wikidata.org/wiki/Q407189","display_name":"Perchlorate","level":3,"score":0.8589444160461426},{"id":"https://openalex.org/C515602321","wikidata":"https://www.wikidata.org/wiki/Q740","display_name":"Cobalt","level":2,"score":0.7989219427108765},{"id":"https://openalex.org/C2779321679","wikidata":"https://www.wikidata.org/wiki/Q207722","display_name":"Pyrimidine","level":2,"score":0.7629393339157104},{"id":"https://openalex.org/C2780872544","wikidata":"https://www.wikidata.org/wiki/Q7706343","display_name":"Tetrafluoroborate","level":4,"score":0.743459165096283},{"id":"https://openalex.org/C2779607525","wikidata":"https://www.wikidata.org/wiki/Q14982","display_name":"Methanol","level":2,"score":0.5379069447517395},{"id":"https://openalex.org/C55904794","wikidata":"https://www.wikidata.org/wiki/Q82682","display_name":"Redox","level":2,"score":0.5269138216972351},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.5116720199584961},{"id":"https://openalex.org/C197404232","wikidata":"https://www.wikidata.org/wiki/Q319827","display_name":"Chelation","level":2,"score":0.5057203769683838},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.5023431777954102},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.4296228587627411},{"id":"https://openalex.org/C2776232574","wikidata":"https://www.wikidata.org/wiki/Q415571","display_name":"Bleomycin","level":3,"score":0.42211028933525085},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.34517228603363037},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.32804763317108154},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.32766053080558777},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.31681329011917114},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.25769031047821045},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.16518396139144897},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.14987066388130188},{"id":"https://openalex.org/C154881586","wikidata":"https://www.wikidata.org/wiki/Q898579","display_name":"Ionic liquid","level":3,"score":0.09898722171783447},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.06728225946426392},{"id":"https://openalex.org/C141071460","wikidata":"https://www.wikidata.org/wiki/Q40821","display_name":"Surgery","level":1,"score":0.0},{"id":"https://openalex.org/C2776694085","wikidata":"https://www.wikidata.org/wiki/Q974135","display_name":"Chemotherapy","level":2,"score":0.0},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/chin.198935306","doi":"https://doi.org/10.1002/chin.198935306","is_oa":false,"landing_page_url":"https://doi.org/10.1002/chin.198935306","pdf_url":null,"source":{"id":"https://openalex.org/S41354064","display_name":"ChemInform","issn_l":"0009-2975","issn":["0009-2975","0931-7597","1431-5890","1522-2667","2199-2924"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ChemInform","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":1,"referenced_works":["https://openalex.org/W2086230238"],"related_works":["https://openalex.org/W2949160551","https://openalex.org/W2086230238","https://openalex.org/W2026726261","https://openalex.org/W1999862280","https://openalex.org/W2949823797","https://openalex.org/W1991197110","https://openalex.org/W2050504194","https://openalex.org/W2952931297","https://openalex.org/W2952568060","https://openalex.org/W1984049509"],"abstract_inverted_index":{"Abstract":[0],"Aerobic":[1],"oxidation":[2],"of":[3,5,13,19,23],"mixtures":[4],"N\u2010(2\u2010(4\u2010imidazolyl)ethyl)pyrimidine\u20104\u2010carboxamide,":[6],"a":[7],"peptide":[8],"ligand":[9],"that":[10],"contains":[11],"three":[12],"the":[14,20,24,38,44,48],"five":[15],"proposed":[16],"donor":[17],"centers":[18],"metal\u2010chelating":[21],"portion":[22],"antitumor":[25],"drug":[26],"bleomycin,":[27],"and":[28],"Co(II)":[29],"salts":[30],"(ratio":[31],"2:1)":[32],"in":[33],"water":[34],"or":[35,47],"methanol":[36],"affords":[37],"corresponding":[39],"Co(III)":[40],"complex":[41],"isolated":[42],"as":[43],"perchlorate":[45],"(I)":[46],"tetrafluoroborate.":[49]},"counts_by_year":[],"updated_date":"2026-09-29T14:09:16.559479","created_date":"2019-06-27T00:00:00"}