{"id":"https://openalex.org/W2952444533","doi":"https://doi.org/10.1002/chin.201516099","title":"ChemInform Abstract: N\u2010Heterocyclic Carbene Organocatalytic Reductive \u03b2,\u03b2\u2010Coupling Reactions of Nitroalkenes via Radical Intermediates.","display_name":"ChemInform Abstract: N\u2010Heterocyclic Carbene Organocatalytic Reductive \u03b2,\u03b2\u2010Coupling Reactions of Nitroalkenes via Radical Intermediates.","publication_year":2015,"publication_date":"2015-04-01","ids":{"openalex":"https://openalex.org/W2952444533","doi":"https://doi.org/10.1002/chin.201516099","mag":"2952444533"},"language":"en","primary_location":{"id":"doi:10.1002/chin.201516099","doi":"https://doi.org/10.1002/chin.201516099","is_oa":false,"landing_page_url":"https://doi.org/10.1002/chin.201516099","pdf_url":null,"source":{"id":"https://openalex.org/S41354064","display_name":"ChemInform","issn_l":"0009-2975","issn":["0009-2975","0931-7597","1431-5890","1522-2667","2199-2924"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ChemInform","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5042138153","display_name":"Yu Du","orcid":"https://orcid.org/0000-0003-2287-5265","observed_orcids":["https://orcid.org/0000-0003-2287-5265"]},"institutions":[{"id":"https://openalex.org/I172675005","display_name":"Nanyang Technological University","ror":"https://ror.org/02e7b5302","country_code":"SG","type":"education","lineage":["https://openalex.org/I172675005"]}],"countries":["SG"],"is_corresponding":false,"raw_author_name":"Yu Du","raw_affiliation_strings":["Div. Chem. Biol. Chem., Sch. Phys. Math. Sci., Nanyang Technol. Univ., Singapore 637371, Singapore"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Div. Chem. Biol. Chem., Sch. Phys. Math. Sci., Nanyang Technol. Univ., Singapore 637371, Singapore","institution_ids":["https://openalex.org/I172675005"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5008767601","display_name":"YuHuang Wang","orcid":"https://orcid.org/0000-0002-5664-1849","observed_orcids":["https://orcid.org/0000-0002-5664-1849"]},"institutions":[{"id":"https://openalex.org/I172675005","display_name":"Nanyang Technological University","ror":"https://ror.org/02e7b5302","country_code":"SG","type":"education","lineage":["https://openalex.org/I172675005"]}],"countries":["SG"],"is_corresponding":false,"raw_author_name":"Yuhuang Wang","raw_affiliation_strings":["Div. Chem. Biol. Chem., Sch. Phys. Math. Sci., Nanyang Technol. Univ., Singapore 637371, Singapore"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Div. Chem. Biol. Chem., Sch. Phys. Math. Sci., Nanyang Technol. Univ., Singapore 637371, Singapore","institution_ids":["https://openalex.org/I172675005"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5116225866","display_name":"Xin Li","orcid":"https://orcid.org/0000-0001-6020-9170","observed_orcids":["https://orcid.org/0000-0001-6020-9170"]},"institutions":[{"id":"https://openalex.org/I172675005","display_name":"Nanyang Technological University","ror":"https://ror.org/02e7b5302","country_code":"SG","type":"education","lineage":["https://openalex.org/I172675005"]}],"countries":["SG"],"is_corresponding":false,"raw_author_name":"Xin Li","raw_affiliation_strings":["Div. Chem. Biol. Chem., Sch. Phys. Math. Sci., Nanyang Technol. Univ., Singapore 637371, Singapore"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Div. Chem. Biol. Chem., Sch. Phys. Math. Sci., Nanyang Technol. Univ., Singapore 637371, Singapore","institution_ids":["https://openalex.org/I172675005"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5069636178","display_name":"Yaling Shao","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I172675005","display_name":"Nanyang Technological University","ror":"https://ror.org/02e7b5302","country_code":"SG","type":"education","lineage":["https://openalex.org/I172675005"]}],"countries":["SG"],"is_corresponding":false,"raw_author_name":"Yaling Shao","raw_affiliation_strings":["Div. Chem. Biol. Chem., Sch. Phys. Math. Sci., Nanyang Technol. Univ., Singapore 637371, Singapore"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Div. Chem. Biol. Chem., Sch. Phys. Math. Sci., Nanyang Technol. Univ., Singapore 637371, Singapore","institution_ids":["https://openalex.org/I172675005"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100337869","display_name":"Guohui Li","orcid":"https://orcid.org/0000-0001-8223-705X","observed_orcids":["https://orcid.org/0000-0001-8223-705X","https://orcid.org/0000-0003-4585-5152"]},"institutions":[{"id":"https://openalex.org/I172675005","display_name":"Nanyang Technological University","ror":"https://ror.org/02e7b5302","country_code":"SG","type":"education","lineage":["https://openalex.org/I172675005"]}],"countries":["SG"],"is_corresponding":false,"raw_author_name":"Guohui Li","raw_affiliation_strings":["Div. Chem. Biol. Chem., Sch. Phys. Math. Sci., Nanyang Technol. Univ., Singapore 637371, Singapore"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Div. Chem. Biol. Chem., Sch. Phys. Math. Sci., Nanyang Technol. Univ., Singapore 637371, Singapore","institution_ids":["https://openalex.org/I172675005"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5020466328","display_name":"Richard David Webster","orcid":"https://orcid.org/0000-0002-0896-1960","observed_orcids":["https://orcid.org/0000-0002-0896-1960"]},"institutions":[{"id":"https://openalex.org/I172675005","display_name":"Nanyang Technological University","ror":"https://ror.org/02e7b5302","country_code":"SG","type":"education","lineage":["https://openalex.org/I172675005"]}],"countries":["SG"],"is_corresponding":false,"raw_author_name":"Richard D. Webster","raw_affiliation_strings":["Div. Chem. Biol. Chem., Sch. Phys. Math. Sci., Nanyang Technol. Univ., Singapore 637371, Singapore"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Div. Chem. Biol. Chem., Sch. Phys. Math. Sci., Nanyang Technol. Univ., Singapore 637371, Singapore","institution_ids":["https://openalex.org/I172675005"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5056403313","display_name":"Yonggui Robin Chi","orcid":"https://orcid.org/0000-0003-0573-257X","observed_orcids":["https://orcid.org/0000-0003-0573-257X"]},"institutions":[{"id":"https://openalex.org/I172675005","display_name":"Nanyang Technological University","ror":"https://ror.org/02e7b5302","country_code":"SG","type":"education","lineage":["https://openalex.org/I172675005"]}],"countries":["SG"],"is_corresponding":false,"raw_author_name":"Yonggui Robin Chi","raw_affiliation_strings":["Div. Chem. Biol. Chem., Sch. Phys. Math. Sci., Nanyang Technol. Univ., Singapore 637371, Singapore"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Div. Chem. Biol. Chem., Sch. Phys. Math. Sci., Nanyang Technol. Univ., Singapore 637371, Singapore","institution_ids":["https://openalex.org/I172675005"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I172675005"],"apc_list":null,"apc_paid":null,"fwci":0.1526,"has_fulltext":false,"cited_by_count":1,"citation_normalized_percentile":{"value":0.53702052,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":94},"biblio":{"volume":"46","issue":"16","first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11790","display_name":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","score":0.9746000170707703,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11790","display_name":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","score":0.9746000170707703,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11281","display_name":"Asymmetric Hydrogenation and Catalysis","score":0.00800000037997961,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10013","display_name":"Asymmetric Synthesis and Catalysis","score":0.007499999832361937,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/n-heterocyclic-carbenes","display_name":"N-heterocyclic carbenes","score":0.878000020980835},{"id":"https://openalex.org/keywords/organocatalysis","display_name":"organocatalysis","score":0.9769999980926514},{"id":"https://openalex.org/keywords/reductive-coupling","display_name":"reductive coupling","score":0.7429999709129333},{"id":"https://openalex.org/keywords/nitroalkenes","display_name":"nitroalkenes","score":1.0},{"id":"https://openalex.org/keywords/radical-intermediates","display_name":"radical intermediates","score":0.9660000205039978},{"id":"https://openalex.org/keywords/aldehydes","display_name":"aldehydes","score":0.7960000038146973},{"id":"https://openalex.org/keywords/diastereoselectivity","display_name":"diastereoselectivity","score":0.6420000195503235},{"id":"https://openalex.org/keywords/carbon-carbon-bond-formation","display_name":"C\u2013C bond formation","score":0.5580000281333923}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9771252274513245},{"id":"https://openalex.org/C2777164566","wikidata":"https://www.wikidata.org/wiki/Q419257","display_name":"Carbene","level":3,"score":0.8646805286407471},{"id":"https://openalex.org/C138716334","wikidata":"https://www.wikidata.org/wiki/Q268477","display_name":"Diastereomer","level":2,"score":0.7779093980789185},{"id":"https://openalex.org/C66972969","wikidata":"https://www.wikidata.org/wiki/Q898995","display_name":"Organocatalysis","level":4,"score":0.6653765439987183},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.5639990568161011},{"id":"https://openalex.org/C48424934","wikidata":"https://www.wikidata.org/wiki/Q898912","display_name":"Coupling reaction","level":3,"score":0.4996209144592285},{"id":"https://openalex.org/C131584629","wikidata":"https://www.wikidata.org/wiki/Q4308705","display_name":"Coupling (piping)","level":2,"score":0.46683064103126526},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.45882534980773926},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.3615192770957947},{"id":"https://openalex.org/C146686406","wikidata":"https://www.wikidata.org/wiki/Q898628","display_name":"Enantioselective synthesis","level":3,"score":0.13954517245292664},{"id":"https://openalex.org/C78519656","wikidata":"https://www.wikidata.org/wiki/Q101333","display_name":"Mechanical engineering","level":1,"score":0.0},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/chin.201516099","doi":"https://doi.org/10.1002/chin.201516099","is_oa":false,"landing_page_url":"https://doi.org/10.1002/chin.201516099","pdf_url":null,"source":{"id":"https://openalex.org/S41354064","display_name":"ChemInform","issn_l":"0009-2975","issn":["0009-2975","0931-7597","1431-5890","1522-2667","2199-2924"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ChemInform","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":1,"referenced_works":["https://openalex.org/W2048122722"],"related_works":["https://openalex.org/W3150022011","https://openalex.org/W2048122722","https://openalex.org/W2950930471","https://openalex.org/W2767921629","https://openalex.org/W2092046086","https://openalex.org/W2951833994","https://openalex.org/W2949403675","https://openalex.org/W2945968496","https://openalex.org/W2800190044","https://openalex.org/W2950554179"],"abstract_inverted_index":{"Abstract":[0],"The":[1],"coupling":[2],"of":[3,8],"nitroalkenes":[4],"in":[5],"the":[6],"presence":[7],"a":[9],"NHC\u2010catalyst":[10],"and":[11,19],"aldehydes":[12],"as":[13,21],"reducing":[14],"agents":[15],"provides":[16],"dl\u2010diastereomers":[17],"(II)":[18],"(VII)":[20],"major":[22],"products.":[23]},"counts_by_year":[{"year":2018,"cited_by_count":1}],"updated_date":"2026-10-06T10:28:23.643775","created_date":"2019-06-27T00:00:00"}