{"id":"https://openalex.org/W2952270976","doi":"https://doi.org/10.1002/chin.201404187","title":"ChemInform Abstract: Iridium\u2010Catalyzed Diastereoselective Dehydrogenative Silylation of Terminal Alkenes with (TMSO)2MeSiH.","display_name":"ChemInform Abstract: Iridium\u2010Catalyzed Diastereoselective Dehydrogenative Silylation of Terminal Alkenes with (TMSO)2MeSiH.","publication_year":2014,"publication_date":"2014-01-03","ids":{"openalex":"https://openalex.org/W2952270976","doi":"https://doi.org/10.1002/chin.201404187","mag":"2952270976"},"language":"en","primary_location":{"id":"doi:10.1002/chin.201404187","doi":"https://doi.org/10.1002/chin.201404187","is_oa":false,"landing_page_url":"https://doi.org/10.1002/chin.201404187","pdf_url":null,"source":{"id":"https://openalex.org/S41354064","display_name":"ChemInform","issn_l":"0009-2975","issn":["0009-2975","0931-7597","1431-5890","1522-2667","2199-2924"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ChemInform","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5038019595","display_name":"Cheng Chen","orcid":"https://orcid.org/0000-0001-5439-5421","observed_orcids":["https://orcid.org/0000-0001-5439-5421"]},"institutions":[{"id":"https://openalex.org/I95457486","display_name":"University of California, Berkeley","ror":"https://ror.org/01an7q238","country_code":"US","type":"education","lineage":["https://openalex.org/I95457486"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Chen Cheng","raw_affiliation_strings":["Dep. Chem., Univ. Calif., Berkeley, CA 94720, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Dep. Chem., Univ. Calif., Berkeley, CA 94720, USA","institution_ids":["https://openalex.org/I95457486"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5028469979","display_name":"Eric M. Simmons","orcid":"https://orcid.org/0000-0002-3854-1561","observed_orcids":["https://orcid.org/0000-0002-3854-1561"]},"institutions":[{"id":"https://openalex.org/I95457486","display_name":"University of California, Berkeley","ror":"https://ror.org/01an7q238","country_code":"US","type":"education","lineage":["https://openalex.org/I95457486"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Eric M. Simmons","raw_affiliation_strings":["Dep. Chem., Univ. Calif., Berkeley, CA 94720, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Dep. Chem., Univ. Calif., Berkeley, CA 94720, USA","institution_ids":["https://openalex.org/I95457486"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5088865204","display_name":"John F. Hartwig","orcid":"https://orcid.org/0000-0002-4157-468X","observed_orcids":["https://orcid.org/0000-0002-4157-468X"]},"institutions":[{"id":"https://openalex.org/I95457486","display_name":"University of California, Berkeley","ror":"https://ror.org/01an7q238","country_code":"US","type":"education","lineage":["https://openalex.org/I95457486"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"John F. Hartwig","raw_affiliation_strings":["Dep. Chem., Univ. Calif., Berkeley, CA 94720, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Dep. Chem., Univ. Calif., Berkeley, CA 94720, USA","institution_ids":["https://openalex.org/I95457486"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I95457486"],"apc_list":null,"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.32581724,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":"45","issue":"4","first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11441","display_name":"Organoboron and organosilicon chemistry","score":0.5371000170707703,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11441","display_name":"Organoboron and organosilicon chemistry","score":0.5371000170707703,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.14970000088214874,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10013","display_name":"Asymmetric Synthesis and Catalysis","score":0.11500000208616257,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/iridium-catalysis","display_name":"iridium catalysis","score":0.9940000176429749},{"id":"https://openalex.org/keywords/dehydrogenative-silylation","display_name":"dehydrogenative silylation","score":0.9169999957084656},{"id":"https://openalex.org/keywords/diastereoselectivity","display_name":"diastereoselectivity","score":0.8679999709129333},{"id":"https://openalex.org/keywords/terminal-alkenes","display_name":"terminal alkenes","score":0.9919999837875366},{"id":"https://openalex.org/keywords/cis-trans-isomers","display_name":"cis-trans isomers","score":0.6840000152587891},{"id":"https://openalex.org/keywords/organosilicon-compounds","display_name":"organosilicon compounds","score":0.6610000133514404}],"concepts":[{"id":"https://openalex.org/C5304478","wikidata":"https://www.wikidata.org/wiki/Q502457","display_name":"Silylation","level":3,"score":0.9694679975509644},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9550065398216248},{"id":"https://openalex.org/C528581852","wikidata":"https://www.wikidata.org/wiki/Q877","display_name":"Iridium","level":3,"score":0.9264763593673706},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.7186346650123596},{"id":"https://openalex.org/C2779664074","wikidata":"https://www.wikidata.org/wiki/Q3518405","display_name":"Terminal (telecommunication)","level":2,"score":0.6261695027351379},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.4394538998603821},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.33974313735961914},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.3207774758338928},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.0},{"id":"https://openalex.org/C76155785","wikidata":"https://www.wikidata.org/wiki/Q418","display_name":"Telecommunications","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/chin.201404187","doi":"https://doi.org/10.1002/chin.201404187","is_oa":false,"landing_page_url":"https://doi.org/10.1002/chin.201404187","pdf_url":null,"source":{"id":"https://openalex.org/S41354064","display_name":"ChemInform","issn_l":"0009-2975","issn":["0009-2975","0931-7597","1431-5890","1522-2667","2199-2924"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ChemInform","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":1,"referenced_works":["https://openalex.org/W2120355630"],"related_works":["https://openalex.org/W2120355630","https://openalex.org/W2080497603","https://openalex.org/W2950792518","https://openalex.org/W2031335587","https://openalex.org/W4253438217","https://openalex.org/W2952594478","https://openalex.org/W2728747393","https://openalex.org/W7131256693","https://openalex.org/W2952764482","https://openalex.org/W1964455379"],"abstract_inverted_index":{"Abstract":[0],"Depending":[1],"on":[2],"the":[3],"reaction":[4],"conditions,":[5],"this":[6],"silylation":[7],"method":[8],"yields":[9],"either":[10],"Z\u2010":[11],"or":[12,15],"E\u2010silyl\u2010alkenes":[13],"(III)":[14],"(IX).":[16]},"counts_by_year":[],"updated_date":"2026-08-21T09:56:20.448147","created_date":"2019-06-27T00:00:00"}