{"id":"https://openalex.org/W2952258564","doi":"https://doi.org/10.1021/jo0708745","title":"The Effect of Iodine on the Peroxidation of Carbonyl Compounds","display_name":"The Effect of Iodine on the Peroxidation of Carbonyl Compounds","publication_year":2007,"publication_date":"2007-07-28","ids":{"openalex":"https://openalex.org/W2952258564","doi":"https://doi.org/10.1021/jo0708745","mag":"2952258564","pmid":"https://pubmed.ncbi.nlm.nih.gov/17661522"},"language":"en","primary_location":{"id":"doi:10.1021/jo0708745","doi":"https://doi.org/10.1021/jo0708745","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jo0708745","pdf_url":null,"source":{"id":"https://openalex.org/S205050996","display_name":"The Journal of Organic Chemistry","issn_l":"0022-3263","issn":["0022-3263","1520-6904"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Organic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5045958536","display_name":"Katja \u017dmitek","orcid":"https://orcid.org/0000-0002-0032-318X","observed_orcids":["https://orcid.org/0000-0002-0032-318X"]},"institutions":[{"id":"https://openalex.org/I153976015","display_name":"University of Ljubljana","ror":"https://ror.org/05njb9z20","country_code":"SI","type":"education","lineage":["https://openalex.org/I153976015"]},{"id":"https://openalex.org/I3006985408","display_name":"Jo\u017eef Stefan Institute","ror":"https://ror.org/05060sz93","country_code":"SI","type":"facility","lineage":["https://openalex.org/I3006985408"]}],"countries":["SI"],"is_corresponding":false,"raw_author_name":"Katja \u017dmitek","raw_affiliation_strings":["Laboratory of Organic and Bioorganic Chemistry, \u201cJo\u017eef Stefan\u201d Institute, Jamova 39, Ljubljana, Slovenia, and Faculty of Chemistry and Chemical Technology, University of Ljubljana, A\u0161ker\u010deva 5, Ljubljana, Slovenia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratory of Organic and Bioorganic Chemistry, \u201cJo\u017eef Stefan\u201d Institute, Jamova 39, Ljubljana, Slovenia, and Faculty of Chemistry and Chemical Technology, University of Ljubljana, A\u0161ker\u010deva 5, Ljubljana, Slovenia","institution_ids":["https://openalex.org/I153976015","https://openalex.org/I3006985408"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5109428393","display_name":"Marko Zupan","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I153976015","display_name":"University of Ljubljana","ror":"https://ror.org/05njb9z20","country_code":"SI","type":"education","lineage":["https://openalex.org/I153976015"]},{"id":"https://openalex.org/I3006985408","display_name":"Jo\u017eef Stefan Institute","ror":"https://ror.org/05060sz93","country_code":"SI","type":"facility","lineage":["https://openalex.org/I3006985408"]}],"countries":["SI"],"is_corresponding":false,"raw_author_name":"Marko Zupan","raw_affiliation_strings":["Laboratory of Organic and Bioorganic Chemistry, \u201cJo\u017eef Stefan\u201d Institute, Jamova 39, Ljubljana, Slovenia, and Faculty of Chemistry and Chemical Technology, University of Ljubljana, A\u0161ker\u010deva 5, Ljubljana, Slovenia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratory of Organic and Bioorganic Chemistry, \u201cJo\u017eef Stefan\u201d Institute, Jamova 39, Ljubljana, Slovenia, and Faculty of Chemistry and Chemical Technology, University of Ljubljana, A\u0161ker\u010deva 5, Ljubljana, Slovenia","institution_ids":["https://openalex.org/I153976015","https://openalex.org/I3006985408"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5028820087","display_name":"Stojan Stavber","orcid":"https://orcid.org/0000-0002-0850-6511","observed_orcids":["https://orcid.org/0000-0002-0850-6511"]},"institutions":[{"id":"https://openalex.org/I153976015","display_name":"University of Ljubljana","ror":"https://ror.org/05njb9z20","country_code":"SI","type":"education","lineage":["https://openalex.org/I153976015"]},{"id":"https://openalex.org/I3006985408","display_name":"Jo\u017eef Stefan Institute","ror":"https://ror.org/05060sz93","country_code":"SI","type":"facility","lineage":["https://openalex.org/I3006985408"]}],"countries":["SI"],"is_corresponding":false,"raw_author_name":"Stojan Stavber","raw_affiliation_strings":["Laboratory of Organic and Bioorganic Chemistry, \u201cJo\u017eef Stefan\u201d Institute, Jamova 39, Ljubljana, Slovenia, and Faculty of Chemistry and Chemical Technology, University of Ljubljana, A\u0161ker\u010deva 5, Ljubljana, Slovenia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratory of Organic and Bioorganic Chemistry, \u201cJo\u017eef Stefan\u201d Institute, Jamova 39, Ljubljana, Slovenia, and Faculty of Chemistry and Chemical Technology, University of Ljubljana, A\u0161ker\u010deva 5, Ljubljana, Slovenia","institution_ids":["https://openalex.org/I153976015","https://openalex.org/I3006985408"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5081685290","display_name":"Jernej Iskra","orcid":"https://orcid.org/0000-0001-6340-3577","observed_orcids":["https://orcid.org/0000-0001-6340-3577"]},"institutions":[{"id":"https://openalex.org/I153976015","display_name":"University of Ljubljana","ror":"https://ror.org/05njb9z20","country_code":"SI","type":"education","lineage":["https://openalex.org/I153976015"]},{"id":"https://openalex.org/I3006985408","display_name":"Jo\u017eef Stefan Institute","ror":"https://ror.org/05060sz93","country_code":"SI","type":"facility","lineage":["https://openalex.org/I3006985408"]}],"countries":["SI"],"is_corresponding":false,"raw_author_name":"Jernej Iskra","raw_affiliation_strings":["Laboratory of Organic and Bioorganic Chemistry, \u201cJo\u017eef Stefan\u201d Institute, Jamova 39, Ljubljana, Slovenia, and Faculty of Chemistry and Chemical Technology, University of Ljubljana, A\u0161ker\u010deva 5, Ljubljana, Slovenia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratory of Organic and Bioorganic Chemistry, \u201cJo\u017eef Stefan\u201d Institute, Jamova 39, Ljubljana, Slovenia, and Faculty of Chemistry and Chemical Technology, University of Ljubljana, A\u0161ker\u010deva 5, Ljubljana, Slovenia","institution_ids":["https://openalex.org/I153976015","https://openalex.org/I3006985408"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":5.4538,"has_fulltext":false,"cited_by_count":127,"citation_normalized_percentile":{"value":0.96910553,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":92,"max":99},"biblio":{"volume":"72","issue":"17","first_page":"6534","last_page":"6540"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11989","display_name":"Oxidative Organic Chemistry Reactions","score":0.9375,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11989","display_name":"Oxidative Organic Chemistry Reactions","score":0.9375,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11831","display_name":"Chemical Synthesis and Reactions","score":0.04019999876618385,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12136","display_name":"Vanadium and Halogenation Chemistry","score":0.00839999970048666,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/molecular-iodine-catalysis","display_name":"iodine catalysis","score":0.9779999852180481},{"id":"https://openalex.org/keywords/peroxidation","display_name":"peroxidation","score":0.6330000162124634},{"id":"https://openalex.org/keywords/ketones","display_name":"ketones","score":0.7559999823570251},{"id":"https://openalex.org/keywords/aldehydes","display_name":"aldehydes","score":0.996999979019165},{"id":"https://openalex.org/keywords/hydrogen-peroxide","display_name":"hydrogen peroxide","score":0.8320000171661377},{"id":"https://openalex.org/keywords/tert-butyl-hydroperoxide","display_name":"tert-butyl hydroperoxide","score":0.8519999980926514},{"id":"https://openalex.org/keywords/hammett-equation","display_name":"Hammett correlation","score":0.6430000066757202},{"id":"https://openalex.org/keywords/reaction-kinetics","display_name":"reaction kinetics","score":0.7910000085830688},{"id":"https://openalex.org/keywords/rehybridization","display_name":"rehybridization","score":0.8709999918937683},{"id":"https://openalex.org/keywords/transition-state","display_name":"transition state","score":0.6100000143051147},{"id":"https://openalex.org/keywords/cyclic-ketones","display_name":"cyclic ketones","score":0.6729999780654907},{"id":"https://openalex.org/keywords/aromatic-aldehydes","display_name":"aromatic aldehydes","score":0.871999979019165}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9636573195457458},{"id":"https://openalex.org/C2777463227","wikidata":"https://www.wikidata.org/wiki/Q408047","display_name":"Acetonitrile","level":2,"score":0.8316542506217957},{"id":"https://openalex.org/C2779607525","wikidata":"https://www.wikidata.org/wiki/Q14982","display_name":"Methanol","level":2,"score":0.7881636023521423},{"id":"https://openalex.org/C539932907","wikidata":"https://www.wikidata.org/wiki/Q1103","display_name":"Iodine","level":2,"score":0.7380629777908325},{"id":"https://openalex.org/C533411734","wikidata":"https://www.wikidata.org/wiki/Q171877","display_name":"Hydrogen peroxide","level":2,"score":0.7116875052452087},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.6655052304267883},{"id":"https://openalex.org/C2776910235","wikidata":"https://www.wikidata.org/wiki/Q18574","display_name":"Reactivity (psychology)","level":3,"score":0.6471198797225952},{"id":"https://openalex.org/C134121241","wikidata":"https://www.wikidata.org/wiki/Q899301","display_name":"Yield (engineering)","level":2,"score":0.6410478353500366},{"id":"https://openalex.org/C2779825165","wikidata":"https://www.wikidata.org/wiki/Q101497","display_name":"Aldehyde","level":3,"score":0.5935970544815063},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.5201583504676819},{"id":"https://openalex.org/C2777738585","wikidata":"https://www.wikidata.org/wiki/Q170744","display_name":"Ketone","level":2,"score":0.43532052636146545},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.41572117805480957},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.3731670677661896},{"id":"https://openalex.org/C191897082","wikidata":"https://www.wikidata.org/wiki/Q11467","display_name":"Metallurgy","level":1,"score":0.0},{"id":"https://openalex.org/C142724271","wikidata":"https://www.wikidata.org/wiki/Q7208","display_name":"Pathology","level":1,"score":0.0},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.0},{"id":"https://openalex.org/C204787440","wikidata":"https://www.wikidata.org/wiki/Q188504","display_name":"Alternative medicine","level":2,"score":0.0},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.0}],"mesh":[{"descriptor_ui":"D000447","descriptor_name":"Aldehydes","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D007455","descriptor_name":"Iodine","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D007659","descriptor_name":"Ketones","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D010545","descriptor_name":"Peroxides","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true}],"locations_count":2,"locations":[{"id":"doi:10.1021/jo0708745","doi":"https://doi.org/10.1021/jo0708745","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jo0708745","pdf_url":null,"source":{"id":"https://openalex.org/S205050996","display_name":"The Journal of Organic Chemistry","issn_l":"0022-3263","issn":["0022-3263","1520-6904"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Organic Chemistry","raw_type":"journal-article"},{"id":"pmid:17661522","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/17661522","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of organic chemistry","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":47,"referenced_works":["https://openalex.org/W1964433945","https://openalex.org/W1965101991","https://openalex.org/W1969480032","https://openalex.org/W1970662863","https://openalex.org/W1970836616","https://openalex.org/W1972693841","https://openalex.org/W1977880362","https://openalex.org/W1991767095","https://openalex.org/W1994957329","https://openalex.org/W1995685979","https://openalex.org/W2007440506","https://openalex.org/W2008708004","https://openalex.org/W2008874819","https://openalex.org/W2017560118","https://openalex.org/W2018830295","https://openalex.org/W2041082642","https://openalex.org/W2045615815","https://openalex.org/W2056351009","https://openalex.org/W2060160842","https://openalex.org/W2085607344","https://openalex.org/W2088743397","https://openalex.org/W2100708232","https://openalex.org/W2111882434","https://openalex.org/W2112676846","https://openalex.org/W2115861729","https://openalex.org/W2127173748","https://openalex.org/W2135568117","https://openalex.org/W2141041081","https://openalex.org/W2141164125","https://openalex.org/W2144927680","https://openalex.org/W2150667627","https://openalex.org/W2175015632","https://openalex.org/W2180688430","https://openalex.org/W2320981135","https://openalex.org/W2334762585","https://openalex.org/W2477606128","https://openalex.org/W2951434562","https://openalex.org/W2951798123","https://openalex.org/W2952014321","https://openalex.org/W2952040962","https://openalex.org/W2952113566","https://openalex.org/W2952122690","https://openalex.org/W2952545872","https://openalex.org/W2952547877","https://openalex.org/W2952652513","https://openalex.org/W4239045735","https://openalex.org/W4251476598"],"related_works":["https://openalex.org/W2127173748","https://openalex.org/W2007726117","https://openalex.org/W2001202673","https://openalex.org/W2951667960","https://openalex.org/W2141945914","https://openalex.org/W2951438952","https://openalex.org/W2003941250","https://openalex.org/W1513163877","https://openalex.org/W1991764852","https://openalex.org/W1964789191"],"abstract_inverted_index":{"Peroxidation":[0],"of":[1,22,26,39,41,82,108,112,124,140,145,162,171],"ketones":[2,44,51],"and":[3,33,68,74,136,166,169,174],"aldehydes":[4,59],"with":[5,14,54,65],"iodine":[6,27,69,152],"as":[7,70,88],"a":[8,55,95,120,163,177],"catalyst":[9,71,153],"was":[10,45,105],"studied.":[11],"Ketones":[12],"reacted":[13,93],"30%":[15],"aq":[16],"hydrogen":[17,66],"peroxide":[18,67],"in":[19,31,35,72,77,89,94,132,142],"the":[20,80,86,99,109,116,127,133,137,143,151,160],"presence":[21],"10":[23],"mol":[24],"%":[25],"to":[28,63,75,147,157,176],"yield":[29,38],"gem-dihydroperoxides":[30,64],"acetonitrile":[32,73],"hydroperoxyketals":[34],"methanol.":[36],"The":[37],"hydroperoxidation":[40],"various":[42],"cyclic":[43],"60-98%,":[46],"including":[47],"androstane-3,17-dione,":[48],"while":[49,79],"acyclic":[50],"were":[52,60],"converted":[53,62],"similar":[56,96],"efficiency.":[57],"Aromatic":[58],"also":[61,106],"hydroperoxyacetal":[76],"methanol,":[78,173],"reactivity":[81],"aliphatic":[83],"ones":[84],"remained":[85],"same":[87],"noncatalyzed":[90],"reactions.":[91],"tert-Butylhydroperoxide":[92],"manner,":[97],"giving":[98],"corresponding":[100],"perether":[101],"derivatives.":[102],"A":[103],"study":[104],"made":[107],"relative":[110],"kinetics":[111],"dihydroperoxidation":[113],"from":[114],"which":[115],"Hammet":[117],"equation":[118],"gave":[119],"reaction":[121],"constant":[122],"(rho)":[123],"-2.76,":[125],"indicating":[126],"strong":[128],"positive":[129],"charge":[130],"development":[131],"transition":[134],"state":[135],"important":[138],"role":[139],"rehybridization":[141],"conversion":[144],"hydroperoxyhemiketal":[146],"gem-dihydroperoxide.":[148],"In":[149],"acetonitrile,":[150],"is":[154],"apparently":[155],"able":[156],"discriminate":[158],"between":[159],"elimination":[161],"hydroxy,":[164],"methoxy,":[165],"hydroperoxy":[167],"group":[168],"addition":[170],"water,":[172],"H2O2":[175],"carbonyl":[178],"group.":[179]},"counts_by_year":[{"year":2026,"cited_by_count":5},{"year":2025,"cited_by_count":3},{"year":2024,"cited_by_count":4},{"year":2023,"cited_by_count":3},{"year":2022,"cited_by_count":5},{"year":2021,"cited_by_count":2},{"year":2020,"cited_by_count":4},{"year":2019,"cited_by_count":7},{"year":2018,"cited_by_count":4},{"year":2017,"cited_by_count":9},{"year":2016,"cited_by_count":9},{"year":2015,"cited_by_count":8},{"year":2014,"cited_by_count":8},{"year":2013,"cited_by_count":5},{"year":2012,"cited_by_count":12}],"updated_date":"2026-11-10T11:39:43.021295","created_date":"2019-06-27T00:00:00"}
