{"id":"https://openalex.org/W2951691971","doi":"https://doi.org/10.1021/ja00432a006","title":"Kinetic applications of electron paramagnetic resonance spectroscopy. 25. Radicals formed by spin trapping with di-tert-butyl thioketone","display_name":"Kinetic applications of electron paramagnetic resonance spectroscopy. 25. Radicals formed by spin trapping with di-tert-butyl thioketone","publication_year":1976,"publication_date":"1976-08-01","ids":{"openalex":"https://openalex.org/W2951691971","doi":"https://doi.org/10.1021/ja00432a006","mag":"2951691971"},"language":"en","primary_location":{"id":"doi:10.1021/ja00432a006","doi":"https://doi.org/10.1021/ja00432a006","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja00432a006","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5016083791","display_name":"J. C. Scaiano","orcid":"https://orcid.org/0000-0002-4838-7123","observed_orcids":["https://orcid.org/0000-0002-4838-7123"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"J. C. Scaiano","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5112823944","display_name":"Keith Usherwood Ingold","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"K. U. Ingold","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":1.2766,"has_fulltext":false,"cited_by_count":81,"citation_normalized_percentile":{"value":0.76686195,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":97},"biblio":{"volume":"98","issue":"16","first_page":"4727","last_page":"4732"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12381","display_name":"Electron Spin Resonance Studies","score":0.8070999979972839,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12381","display_name":"Electron Spin Resonance Studies","score":0.8070999979972839,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13253","display_name":"Photolysis and Reactive Intermediates","score":0.06459999829530716,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12191","display_name":"Physical Organic Chemistry and Reaction Kinetics","score":0.029100000858306885,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/spin-trapping","display_name":"spin trapping","score":0.9860000014305115},{"id":"https://openalex.org/keywords/transient-radicals","display_name":"transient radicals","score":0.5230000019073486},{"id":"https://openalex.org/keywords/hyperfine-splitting","display_name":"hyperfine splitting","score":0.6349999904632568},{"id":"https://openalex.org/keywords/g-value","display_name":"g-value","score":0.7540000081062317},{"id":"https://openalex.org/keywords/radical-dimerization","display_name":"radical dimerization","score":0.7080000042915344},{"id":"https://openalex.org/keywords/radical-decay-kinetics","display_name":"radical decay kinetics","score":0.8989999890327454},{"id":"https://openalex.org/keywords/intramolecular-hydrogen-transfer","display_name":"intramolecular hydrogen transfer","score":0.902999997138977},{"id":"https://openalex.org/keywords/tert-butyl-radical","display_name":"tert-butyl radical","score":0.5860000252723694},{"id":"https://openalex.org/keywords/methyl-radical","display_name":"methyl radical","score":0.6740000247955322},{"id":"https://openalex.org/keywords/silicon-radicals","display_name":"silicon radicals","score":0.3880000114440918},{"id":"https://openalex.org/keywords/phosphorus-radicals","display_name":"phosphorus radicals","score":0.9810000061988831},{"id":"https://openalex.org/keywords/arrhenius-parameters","display_name":"Arrhenius parameters","score":0.6970000267028809}],"concepts":[{"id":"https://openalex.org/C187961010","wikidata":"https://www.wikidata.org/wiki/Q260463","display_name":"Electron paramagnetic resonance","level":2,"score":0.7213651537895203},{"id":"https://openalex.org/C2910908493","wikidata":"https://www.wikidata.org/wiki/Q260463","display_name":"Electron paramagnetic resonance spectroscopy","level":3,"score":0.6831977963447571},{"id":"https://openalex.org/C518677369","wikidata":"https://www.wikidata.org/wiki/Q202833","display_name":"Social media","level":2,"score":0.5190361738204956},{"id":"https://openalex.org/C32891209","wikidata":"https://www.wikidata.org/wiki/Q483666","display_name":"Spectroscopy","level":2,"score":0.5012702941894531},{"id":"https://openalex.org/C2778407487","wikidata":"https://www.wikidata.org/wiki/Q14565201","display_name":"Altmetrics","level":2,"score":0.475953072309494},{"id":"https://openalex.org/C2777924906","wikidata":"https://www.wikidata.org/wiki/Q34168","display_name":"Trapping","level":2,"score":0.4567098021507263},{"id":"https://openalex.org/C139066938","wikidata":"https://www.wikidata.org/wiki/Q185056","display_name":"Radical","level":2,"score":0.4538291096687317},{"id":"https://openalex.org/C2778805511","wikidata":"https://www.wikidata.org/wiki/Q1713","display_name":"Citation","level":2,"score":0.4495965242385864},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.3944280445575714},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.37324491143226624},{"id":"https://openalex.org/C23123220","wikidata":"https://www.wikidata.org/wiki/Q816826","display_name":"Information retrieval","level":1,"score":0.3516371250152588},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.3454124927520752},{"id":"https://openalex.org/C161191863","wikidata":"https://www.wikidata.org/wiki/Q199655","display_name":"Library science","level":1,"score":0.27808696031570435},{"id":"https://openalex.org/C46141821","wikidata":"https://www.wikidata.org/wiki/Q209402","display_name":"Nuclear magnetic resonance","level":1,"score":0.27709996700286865},{"id":"https://openalex.org/C136764020","wikidata":"https://www.wikidata.org/wiki/Q466","display_name":"World Wide Web","level":1,"score":0.24416831135749817},{"id":"https://openalex.org/C205649164","wikidata":"https://www.wikidata.org/wiki/Q1071","display_name":"Geography","level":0,"score":0.15048983693122864},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.12990862131118774},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.0},{"id":"https://openalex.org/C97137747","wikidata":"https://www.wikidata.org/wiki/Q38112","display_name":"Forestry","level":1,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1021/ja00432a006","doi":"https://doi.org/10.1021/ja00432a006","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja00432a006","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},{"id":"pmh:oai:cisti-icist.nrc-cnrc.ca:cistinparc:21276617","doi":null,"is_oa":false,"landing_page_url":"https://nrc-publications.canada.ca/fra/voir/objet/?id=f9dec1a1-d384-4833-977e-f454237b0728","pdf_url":null,"source":{"id":"https://openalex.org/S7407055245","display_name":"NPARC","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2993708883","https://openalex.org/W1985656868","https://openalex.org/W4239523168","https://openalex.org/W3004706178","https://openalex.org/W3004821413","https://openalex.org/W2012008987","https://openalex.org/W3005038759","https://openalex.org/W2951470965","https://openalex.org/W2950500544","https://openalex.org/W4232257368"],"abstract_inverted_index":{"A":[0],"variety":[1],"of":[2,38,56,80,91,110,169,192],"transient":[3],"RnM\u00b7":[4],"radicals":[5],"(M":[6],"=":[7,136,142],"C,":[8],"Si,":[9],"Sn,":[10],"and":[11,22,46,49,52,88,162],"P,":[12],"but":[13],"not":[14],"O)":[15],"have":[16,29],"been":[17,30],"trapped":[18],"with":[19,82,93,124,153,185],"di-tert-butyl":[20],"thioketone":[21],"the":[23,39,57,67,71,78,89,104,130,149,154,193],"persistent":[24],"adduct":[25],"radicals,":[26,51],"RnMS\u010a(CMe3)2":[27],"(1).":[28],"examined":[31],"by":[32,42,165],"EPR":[33],"spectroscopy.":[34],"From":[35],"a":[36,54,107,125],"comparison":[37],"hyperfine":[40],"splittings":[41],"M":[43,172],"in":[44,47,122,129],"1":[45,61],"RnMCH2\u010a(CMe3)2":[48],"analogous":[50],"from":[53,171],"consideration":[55],"g":[58],"values":[59],"for":[60,190],"(2.0024-2.0033),":[62],"it":[63],"is":[64,158,178],"concluded":[65,159],"that":[66,100,160],"RnM":[68],"group":[69],"eclipses":[70],"C\u03b1":[72],"2pz":[73],"orbital.":[74],"Competitive":[75],"experiments":[76],"involving":[77],"reaction":[79,90],"tert-butyl":[81],"thione":[83,94,105],"or":[84,95],"oxygen":[85],"at":[86,97,115,127],"-80\u00b0C":[87],"methyl":[92],"Me3CNO":[96],"-40\u00b0C":[98],"indicate":[99],"alkyl":[101],"addition":[102],"to":[103,133,173],"has":[106],"rate":[108],"constant":[109],"ca.":[111],"106":[112],"M-1":[113],"s-1":[114],"these":[116],"temperatures.":[117],"The":[118,175,181],"CH3S\u010a(CMe3)2":[119,150,161],"radial":[120],"exists":[121],"equilibrium":[123],"dimer":[126],"temperatures":[128],"range":[131],"-70":[132],"-110\u00b0C:":[134],"\u0394H":[135],"9.6":[137],"\u00b1":[138,144],"1.5":[139],"kcal/mol;":[140],"\u0394S":[141],"32":[143],"3":[145],"gibbs/mol.":[146],"Above":[147],"-50\u00b0C":[148],"radical":[151,177,183],"decays":[152,184],"first-order":[155],"kinetics.":[156,187],"It":[157],"SiH3S\u010a(CMe3)2":[163],"decay":[164,194],"an":[166],"intramolecular":[167],"transfer":[168],"H":[170],"C\u03b1.":[174],"CF3S\u010a(CMe3)2":[176],"extremely":[179],"persistent.":[180],"(n-Bu)3SnS\u010a(CMe3)2":[182],"second-order":[186],"Arrhenius":[188],"parameters":[189],"some":[191],"reactions":[195],"are":[196],"reported.":[197]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2024,"cited_by_count":1},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":1},{"year":2021,"cited_by_count":3},{"year":2020,"cited_by_count":2},{"year":2019,"cited_by_count":2},{"year":2018,"cited_by_count":2},{"year":2013,"cited_by_count":1},{"year":2012,"cited_by_count":3}],"updated_date":"2026-09-22T06:50:58.402377","created_date":"2019-06-27T00:00:00"}