{"id":"https://openalex.org/W2951521145","doi":"https://doi.org/10.1021/jo00067a051","title":"Phosphorus compounds. Part 68. Tetraphosphacubane chemistry: probing phosphorus reactivity by protonation, alkylation, and alkynylation. Formation of novel phosphonium di- and monocations in superacid media and monocations with super electrophiles","display_name":"Phosphorus compounds. Part 68. Tetraphosphacubane chemistry: probing phosphorus reactivity by protonation, alkylation, and alkynylation. Formation of novel phosphonium di- and monocations in superacid media and monocations with super electrophiles","publication_year":1993,"publication_date":"1993-07-01","ids":{"openalex":"https://openalex.org/W2951521145","doi":"https://doi.org/10.1021/jo00067a051","mag":"2951521145"},"language":"en","primary_location":{"id":"doi:10.1021/jo00067a051","doi":"https://doi.org/10.1021/jo00067a051","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jo00067a051","pdf_url":null,"source":{"id":"https://openalex.org/S205050996","display_name":"The Journal of Organic Chemistry","issn_l":"0022-3263","issn":["0022-3263","1520-6904"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Organic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5040503085","display_name":"Kenneth Khosrow Laali","orcid":"https://orcid.org/0000-0002-0294-844X","observed_orcids":["https://orcid.org/0000-0002-0294-844X"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Kenneth K. Laali","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5047848437","display_name":"Manfred Regitz","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Manfred Regitz","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5087927398","display_name":"Manfred Birkel","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Manfred Birkel","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5076778537","display_name":"Peter J. Stang","orcid":"https://orcid.org/0000-0002-2307-0576","observed_orcids":["https://orcid.org/0000-0002-2307-0576"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Peter J. Stang","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5035635949","display_name":"Charles M. Crittell","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Charles M. Crittell","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":5.051,"has_fulltext":false,"cited_by_count":41,"citation_normalized_percentile":{"value":0.96904599,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":89,"max":98},"biblio":{"volume":"58","issue":"15","first_page":"4105","last_page":"4109"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T14068","display_name":"Organic and Inorganic Chemical Reactions","score":0.4465000033378601,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T14068","display_name":"Organic and Inorganic Chemical Reactions","score":0.4465000033378601,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.3361999988555908,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11748","display_name":"Organophosphorus compounds synthesis","score":0.11050000041723251,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/phosphorus-reactivity","display_name":"phosphorus reactivity","score":0.7990000247955322},{"id":"https://openalex.org/keywords/phosphonium-cations","display_name":"phosphonium cations","score":0.8019999861717224},{"id":"https://openalex.org/keywords/superacid-media","display_name":"superacid media","score":0.8429999947547913},{"id":"https://openalex.org/keywords/protonation","display_name":"protonation","score":0.8519999980926514},{"id":"https://openalex.org/keywords/alkylation","display_name":"alkylation","score":0.9940000176429749},{"id":"https://openalex.org/keywords/alkynylation","display_name":"alkynylation","score":0.9950000047683716}],"concepts":[{"id":"https://openalex.org/C2780707935","wikidata":"https://www.wikidata.org/wiki/Q907718","display_name":"Phosphonium","level":2,"score":0.8839262127876282},{"id":"https://openalex.org/C50027330","wikidata":"https://www.wikidata.org/wiki/Q908086","display_name":"Electrophile","level":3,"score":0.6322734951972961},{"id":"https://openalex.org/C30095370","wikidata":"https://www.wikidata.org/wiki/Q899488","display_name":"Protonation","level":3,"score":0.608953595161438},{"id":"https://openalex.org/C2778805511","wikidata":"https://www.wikidata.org/wiki/Q1713","display_name":"Citation","level":2,"score":0.5190070867538452},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.46477511525154114},{"id":"https://openalex.org/C518677369","wikidata":"https://www.wikidata.org/wiki/Q202833","display_name":"Social media","level":2,"score":0.4476567208766937},{"id":"https://openalex.org/C2776910235","wikidata":"https://www.wikidata.org/wiki/Q18574","display_name":"Reactivity (psychology)","level":3,"score":0.4456164836883545},{"id":"https://openalex.org/C164361826","wikidata":"https://www.wikidata.org/wiki/Q177604","display_name":"Alkylation","level":3,"score":0.43690332770347595},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.4142570197582245},{"id":"https://openalex.org/C161191863","wikidata":"https://www.wikidata.org/wiki/Q199655","display_name":"Library science","level":1,"score":0.3473623991012573},{"id":"https://openalex.org/C136764020","wikidata":"https://www.wikidata.org/wiki/Q466","display_name":"World Wide Web","level":1,"score":0.29661667346954346},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.2567739486694336},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.10438203811645508},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.08941072225570679},{"id":"https://openalex.org/C142724271","wikidata":"https://www.wikidata.org/wiki/Q7208","display_name":"Pathology","level":1,"score":0.0},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.0},{"id":"https://openalex.org/C204787440","wikidata":"https://www.wikidata.org/wiki/Q188504","display_name":"Alternative medicine","level":2,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/jo00067a051","doi":"https://doi.org/10.1021/jo00067a051","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jo00067a051","pdf_url":null,"source":{"id":"https://openalex.org/S205050996","display_name":"The Journal of Organic Chemistry","issn_l":"0022-3263","issn":["0022-3263","1520-6904"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Organic Chemistry","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2142909241","https://openalex.org/W2049992321","https://openalex.org/W2949251573","https://openalex.org/W2096457581","https://openalex.org/W4238204443","https://openalex.org/W2953115145","https://openalex.org/W2100425779","https://openalex.org/W2064948699","https://openalex.org/W4393023973","https://openalex.org/W4285806990"],"abstract_inverted_index":{"ADVERTISEMENT":[0],"RETURN":[1],"TO":[2],"ISSUEPREVArticleNEXTPhosphorus":[3],"compounds.":[4],"Part":[5],"68.":[6],"Tetraphosphacubane":[7],"chemistry:":[8],"probing":[9],"phosphorus":[10],"reactivity":[11],"by":[12,120],"protonation,":[13],"alkylation,":[14],"and":[15,22,27,41,88,93,122,166,183,199,201],"alkynylation.":[16],"Formation":[17],"of":[18,78,113,139],"novel":[19],"phosphonium":[20],"di-":[21],"monocations":[23,28],"in":[24],"superacid":[25],"media":[26,169],"with":[29,160,195],"super":[30],"electrophilesKenneth":[31],"K.":[32],"Laali,":[33],"Manfred":[34,36],"Regitz,":[35],"Birkel,":[37],"Peter":[38],"J.":[39,46],"Stang,":[40],"Charles":[42],"M.":[43],"CrittellCite":[44],"this:":[45],"Org.":[47],"Chem.":[48],"1993,":[49],"58,":[50],"15,":[51],"4105\u20134109Publication":[52],"Date":[53],"(Print):July":[54],"1,":[55],"1993Publication":[56],"History":[57],"Published":[58],"online1":[59],"May":[60],"2002Published":[61],"inissue":[62],"1":[63],"July":[64],"1993https://pubs.acs.org/doi/10.1021/jo00067a051https://doi.org/10.1021/jo00067a051research-articleACS":[65],"PublicationsRequest":[66],"reuse":[67],"permissionsArticle":[68],"Views152Altmetric-Citations38LEARN":[69],"ABOUT":[70],"THESE":[71],"METRICSArticle":[72],"Views":[73],"are":[74,97,110],"the":[75,106,111,140,151,164,167,172,179,185],"COUNTER-compliant":[76],"sum":[77],"full":[79],"text":[80],"article":[81,145],"downloads":[82],"since":[83],"November":[84],"2008":[85],"(both":[86],"PDF":[87],"HTML)":[89],"across":[90],"all":[91],"institutions":[92],"individuals.":[94],"These":[95],"metrics":[96],"regularly":[98],"updated":[99,123],"to":[100,105],"reflect":[101],"usage":[102],"leading":[103],"up":[104],"last":[107],"few":[108],"days.Citations":[109],"number":[112],"other":[114],"articles":[115],"citing":[116],"this":[117],"article,":[118],"calculated":[119],"Crossref":[121,129],"daily.":[124],"Find":[125,175],"more":[126,176],"information":[127,177],"about":[128,163],"citation":[130],"counts.The":[131],"Altmetric":[132,180],"Attention":[133,181],"Score":[134,182],"is":[135,187],"a":[136,143,156],"quantitative":[137],"measure":[138],"attention":[141],"that":[142],"research":[144],"has":[146],"received":[147],"online.":[148],"Clicking":[149],"on":[150,178],"donut":[152],"icon":[153],"will":[154],"load":[155],"page":[157],"at":[158],"altmetric.com":[159],"additional":[161],"details":[162],"score":[165,186],"social":[168],"presence":[170],"for":[171],"given":[173],"article.":[174],"how":[184],"calculated.":[188],"Share":[189,204],"Add":[190],"toView":[191],"InAdd":[192],"Full":[193],"Text":[194],"ReferenceAdd":[196],"Description":[197],"ExportRISCitationCitation":[198],"abstractCitation":[200],"referencesMore":[202],"Options":[203],"onFacebookTwitterWechatLinked":[205],"InRedditEmail":[206],"Other":[207],"access":[208],"optionsGet":[209],"e-Alertsclose":[210],"Get":[211],"e-Alerts":[212]},"counts_by_year":[{"year":2024,"cited_by_count":1},{"year":2019,"cited_by_count":1},{"year":2018,"cited_by_count":4},{"year":2017,"cited_by_count":2},{"year":2015,"cited_by_count":1}],"updated_date":"2026-09-23T05:00:35.095934","created_date":"2019-06-27T00:00:00"}