{"id":"https://openalex.org/W2949627735","doi":"https://doi.org/10.1021/acs.organomet.9b00126","title":"Importance of Singlet Oxygen in Photocatalytic Reactions of 2-Aryl-1,2,3,4-tetrahydroisoquinolines Using Chalcogenorosamine Photocatalysts","display_name":"Importance of Singlet Oxygen in Photocatalytic Reactions of 2-Aryl-1,2,3,4-tetrahydroisoquinolines Using Chalcogenorosamine Photocatalysts","publication_year":2019,"publication_date":"2019-06-11","ids":{"openalex":"https://openalex.org/W2949627735","doi":"https://doi.org/10.1021/acs.organomet.9b00126","mag":"2949627735"},"language":"en","primary_location":{"id":"doi:10.1021/acs.organomet.9b00126","doi":"https://doi.org/10.1021/acs.organomet.9b00126","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.organomet.9b00126","pdf_url":null,"source":{"id":"https://openalex.org/S4924609","display_name":"Organometallics","issn_l":"0276-7333","issn":["0276-7333","1520-6041"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","norway-2","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organometallics","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":null,"display_name":"Jennifer L. Clark","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I63190737","display_name":"University at Buffalo, State University of New York","ror":"https://ror.org/01y64my43","country_code":"US","type":"education","lineage":["https://openalex.org/I63190737"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Jennifer L. Clark","raw_affiliation_strings":["Department of Chemistry, University at Buffalo, The State University of New York, Buffalo, New York 14260-3000, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University at Buffalo, The State University of New York, Buffalo, New York 14260-3000, United States","institution_ids":["https://openalex.org/I63190737"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5031447403","display_name":"Jackie E. Hill","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I63190737","display_name":"University at Buffalo, State University of New York","ror":"https://ror.org/01y64my43","country_code":"US","type":"education","lineage":["https://openalex.org/I63190737"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Jackie E. Hill","raw_affiliation_strings":["Department of Chemistry, University at Buffalo, The State University of New York, Buffalo, New York 14260-3000, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University at Buffalo, The State University of New York, Buffalo, New York 14260-3000, United States","institution_ids":["https://openalex.org/I63190737"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5024068778","display_name":"Irving D. Rettig","orcid":"https://orcid.org/0000-0002-8080-1806","observed_orcids":["https://orcid.org/0000-0002-8080-1806"]},"institutions":[{"id":"https://openalex.org/I126345244","display_name":"Portland State University","ror":"https://ror.org/00yn2fy02","country_code":"US","type":"education","lineage":["https://openalex.org/I126345244"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Irving D. Rettig","raw_affiliation_strings":["Department of Chemistry, Portland State University, Portland, Oregon 97207, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Portland State University, Portland, Oregon 97207, United States","institution_ids":["https://openalex.org/I126345244"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5109190021","display_name":"Joshua J. Beres","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I63190737","display_name":"University at Buffalo, State University of New York","ror":"https://ror.org/01y64my43","country_code":"US","type":"education","lineage":["https://openalex.org/I63190737"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Joshua J. Beres","raw_affiliation_strings":["Department of Chemistry, University at Buffalo, The State University of New York, Buffalo, New York 14260-3000, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University at Buffalo, The State University of New York, Buffalo, New York 14260-3000, United States","institution_ids":["https://openalex.org/I63190737"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5055592871","display_name":"Roman Ziniuk","orcid":"https://orcid.org/0000-0003-2580-5115","observed_orcids":["https://orcid.org/0000-0003-2580-5115"]},"institutions":[{"id":"https://openalex.org/I180726961","display_name":"Shenzhen University","ror":"https://ror.org/01vy4gh70","country_code":"CN","type":"education","lineage":["https://openalex.org/I180726961"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Roman Ziniuk","raw_affiliation_strings":["Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province, College of Optoelectronic Engineering, Shenzhen University, Shenzhen 518060, P.R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province, College of Optoelectronic Engineering, Shenzhen University, Shenzhen 518060, P.R. China","institution_ids":["https://openalex.org/I180726961"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5012020083","display_name":"Tymish Y. Ohulchanskyy","orcid":"https://orcid.org/0000-0002-7051-6534","observed_orcids":["https://orcid.org/0000-0002-7051-6534"]},"institutions":[{"id":"https://openalex.org/I180726961","display_name":"Shenzhen University","ror":"https://ror.org/01vy4gh70","country_code":"CN","type":"education","lineage":["https://openalex.org/I180726961"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Tymish Y. Ohulchanskyy","raw_affiliation_strings":["Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province, College of Optoelectronic Engineering, Shenzhen University, Shenzhen 518060, P.R. China"],"raw_orcid":"https://orcid.org/0000-0002-7051-6534","affiliations":[{"raw_affiliation_string":"Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province, College of Optoelectronic Engineering, Shenzhen University, Shenzhen 518060, P.R. China","institution_ids":["https://openalex.org/I180726961"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5003158752","display_name":"Theresa M. McCormick","orcid":"https://orcid.org/0000-0003-1745-2911","observed_orcids":["https://orcid.org/0000-0003-1745-2911"]},"institutions":[{"id":"https://openalex.org/I126345244","display_name":"Portland State University","ror":"https://ror.org/00yn2fy02","country_code":"US","type":"education","lineage":["https://openalex.org/I126345244"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Theresa M. McCormick","raw_affiliation_strings":["Department of Chemistry, Portland State University, Portland, Oregon 97207, United States"],"raw_orcid":"https://orcid.org/0000-0003-1745-2911","affiliations":[{"raw_affiliation_string":"Department of Chemistry, Portland State University, Portland, Oregon 97207, United States","institution_ids":["https://openalex.org/I126345244"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5039149956","display_name":"Michael R. Detty","orcid":"https://orcid.org/0000-0002-8815-1481","observed_orcids":["https://orcid.org/0000-0002-8815-1481"]},"institutions":[{"id":"https://openalex.org/I63190737","display_name":"University at Buffalo, State University of New York","ror":"https://ror.org/01y64my43","country_code":"US","type":"education","lineage":["https://openalex.org/I63190737"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Michael R. Detty","raw_affiliation_strings":["Department of Chemistry, University at Buffalo, The State University of New York, Buffalo, New York 14260-3000, United States"],"raw_orcid":"https://orcid.org/0000-0002-8815-1481","affiliations":[{"raw_affiliation_string":"Department of Chemistry, University at Buffalo, The State University of New York, Buffalo, New York 14260-3000, United States","institution_ids":["https://openalex.org/I63190737"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":3,"corresponding_author_ids":["https://openalex.org/A5003158752","https://openalex.org/A5039149956"],"corresponding_institution_ids":["https://openalex.org/I126345244","https://openalex.org/I63190737"],"apc_list":{"value":5000,"currency":"USD","value_usd":5000},"apc_paid":null,"fwci":2.004,"has_fulltext":false,"cited_by_count":34,"citation_normalized_percentile":{"value":0.8586812,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":99},"biblio":{"volume":"38","issue":"12","first_page":"2431","last_page":"2442"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10701","display_name":"Radical Photochemical Reactions","score":0.8583999872207642,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10701","display_name":"Radical Photochemical Reactions","score":0.8583999872207642,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10078","display_name":"Advanced Photocatalysis Techniques","score":0.04910000041127205,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11989","display_name":"Oxidative Organic Chemistry Reactions","score":0.027300000190734863,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/singlet-oxygen","display_name":"singlet oxygen","score":0.9919999837875366},{"id":"https://openalex.org/keywords/aerobic-oxidation","display_name":"aerobic oxidation","score":0.7799999713897705},{"id":"https://openalex.org/keywords/aza-henry-reaction","display_name":"aza-Henry reaction","score":0.9810000061988831},{"id":"https://openalex.org/keywords/nitromethane","display_name":"nitromethane","score":0.8679999709129333},{"id":"https://openalex.org/keywords/exciplex","display_name":"exciplex","score":0.7400000095367432}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.945692777633667},{"id":"https://openalex.org/C65165184","wikidata":"https://www.wikidata.org/wiki/Q218831","display_name":"Photocatalysis","level":3,"score":0.839009165763855},{"id":"https://openalex.org/C2777516457","wikidata":"https://www.wikidata.org/wiki/Q2413613","display_name":"Singlet oxygen","level":3,"score":0.7942252159118652},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.780258059501648},{"id":"https://openalex.org/C2781076698","wikidata":"https://www.wikidata.org/wiki/Q718074","display_name":"Aryl","level":3,"score":0.6912788152694702},{"id":"https://openalex.org/C2777463227","wikidata":"https://www.wikidata.org/wiki/Q408047","display_name":"Acetonitrile","level":2,"score":0.6055086255073547},{"id":"https://openalex.org/C2777327210","wikidata":"https://www.wikidata.org/wiki/Q407733","display_name":"Nitromethane","level":2,"score":0.5643953084945679},{"id":"https://openalex.org/C2776910235","wikidata":"https://www.wikidata.org/wiki/Q18574","display_name":"Reactivity (psychology)","level":3,"score":0.47963079810142517},{"id":"https://openalex.org/C184651966","wikidata":"https://www.wikidata.org/wiki/Q906356","display_name":"Aqueous solution","level":2,"score":0.4632832407951355},{"id":"https://openalex.org/C540031477","wikidata":"https://www.wikidata.org/wiki/Q629","display_name":"Oxygen","level":2,"score":0.37157344818115234},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.2532498836517334},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.2030142843723297},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.0},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.0},{"id":"https://openalex.org/C204787440","wikidata":"https://www.wikidata.org/wiki/Q188504","display_name":"Alternative medicine","level":2,"score":0.0},{"id":"https://openalex.org/C142724271","wikidata":"https://www.wikidata.org/wiki/Q7208","display_name":"Pathology","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/acs.organomet.9b00126","doi":"https://doi.org/10.1021/acs.organomet.9b00126","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.organomet.9b00126","pdf_url":null,"source":{"id":"https://openalex.org/S4924609","display_name":"Organometallics","issn_l":"0276-7333","issn":["0276-7333","1520-6041"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","norway-2","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organometallics","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G3781913676","display_name":null,"funder_award_id":"CHE-1800288","funder_id":"https://openalex.org/F4320337393","funder_display_name":"Division of Chemistry"},{"id":"https://openalex.org/G4669121527","display_name":null,"funder_award_id":"CHE-1800599","funder_id":"https://openalex.org/F4320337393","funder_display_name":"Division of Chemistry"}],"funders":[{"id":"https://openalex.org/F4320309493","display_name":"Portland State University","ror":"https://ror.org/00yn2fy02"},{"id":"https://openalex.org/F4320337393","display_name":"Division of Chemistry","ror":"https://ror.org/01ar8dr59"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":61,"referenced_works":["https://openalex.org/W638557855","https://openalex.org/W1966182479","https://openalex.org/W1970874708","https://openalex.org/W1979103178","https://openalex.org/W1980603394","https://openalex.org/W1984549305","https://openalex.org/W1984614201","https://openalex.org/W1986724293","https://openalex.org/W1991192698","https://openalex.org/W1994702118","https://openalex.org/W1996941025","https://openalex.org/W1998875076","https://openalex.org/W1999031172","https://openalex.org/W2011215428","https://openalex.org/W2012615651","https://openalex.org/W2012748063","https://openalex.org/W2014234337","https://openalex.org/W2023271753","https://openalex.org/W2025258560","https://openalex.org/W2036234414","https://openalex.org/W2044490585","https://openalex.org/W2047056736","https://openalex.org/W2050379798","https://openalex.org/W2054496327","https://openalex.org/W2058363175","https://openalex.org/W2063589866","https://openalex.org/W2065497177","https://openalex.org/W2066153691","https://openalex.org/W2068617439","https://openalex.org/W2074105832","https://openalex.org/W2077090609","https://openalex.org/W2080628813","https://openalex.org/W2090251756","https://openalex.org/W2094642658","https://openalex.org/W2100717503","https://openalex.org/W2136803810","https://openalex.org/W2143981217","https://openalex.org/W2154956446","https://openalex.org/W2253245228","https://openalex.org/W2265362920","https://openalex.org/W2313239886","https://openalex.org/W2315022637","https://openalex.org/W2317194706","https://openalex.org/W2318174119","https://openalex.org/W2318227018","https://openalex.org/W2320327705","https://openalex.org/W2322300302","https://openalex.org/W2323735535","https://openalex.org/W2325759087","https://openalex.org/W2327452598","https://openalex.org/W2331363712","https://openalex.org/W2333067175","https://openalex.org/W2334964705","https://openalex.org/W2335491400","https://openalex.org/W2403949481","https://openalex.org/W2418394635","https://openalex.org/W2467970661","https://openalex.org/W2507897858","https://openalex.org/W2578046998","https://openalex.org/W2612347156","https://openalex.org/W2613526393"],"related_works":["https://openalex.org/W2060545905","https://openalex.org/W2511409636","https://openalex.org/W7151496827","https://openalex.org/W2016388163","https://openalex.org/W2613526393","https://openalex.org/W2034460543","https://openalex.org/W3120128128","https://openalex.org/W3185854863","https://openalex.org/W3213553336","https://openalex.org/W4220682478"],"abstract_inverted_index":{"Aerobic":[0],"oxidation":[1,193],"of":[2,40,132,158,175,196,203,211,223,226,235,248,256],"2-aryl-1,2,3,4-tetrahydroisoquinolines":[3,72],"was":[4,22],"achieved":[5],"photocatalytically":[6],"using":[7],"chalcogenorosamine":[8],"photocatalysts":[9,29,42,86],"and":[10,20,27,33,84,94,128,178,194,199,205,215,228,237],"LED":[11],"irradiation.":[12],"The":[13,71],"photocatalytic":[14,56,173],"aza-Henry":[15,57],"reaction":[16,58],"between":[17,124],"these":[18],"substrates":[19],"nitromethane":[21],"more":[23],"efficient":[24],"with":[25,31,82],"selenorosamine":[26,83],"tellurorosamine":[28,85],"than":[30],"thiorosamine":[32,184],"rosamine":[34],"photocatalysts,":[35,105],"corresponding":[36,77,136],"to":[37,43,75,98,167,182],"the":[38,41,55,63,76,122,129,133,142,156,171,176,183,192,212,224,254],"propensity":[39],"generate":[44,108],"singlet":[45],"oxygen":[46],"(":[47],"1":[48,109,125],"O":[49,110,126],"2":[50,111,127],").":[51],"Appropriately,":[52],"yields":[53],"for":[54,170,191,201,253],"were":[59,65,73,96,165,189],"greatly":[60],"reduced":[61],"when":[62],"reactions":[64],"conducted":[66],"under":[67],"a":[68,242],"nitrogen":[69],"atmosphere.":[70],"oxidized":[74],"2-aryl-3,4-dihydroisoquinolones":[78],"13a":[79,159],"\u2013":[80,160],"13c":[81,161],"in":[87,101,155],"2%":[88],"aqueous":[89],"acetonitrile.":[90],"Di-2-aryl-1,2,3,4-tetrahydroisoquinolin-1-yl":[91],"peroxides":[92],"14a":[93],"14b":[95],"shown":[97],"be":[99,151],"intermediates":[100,218],"this":[102,261],"reaction.":[103],"Thiorosamine":[104],"which":[106,258],"do":[107],"upon":[112],"irradiation,":[113],"did":[114],"not":[115,265],"give":[116],"2-aryl-3,4-dihydroisoquinolones.":[117],"These":[118],"results":[119],"suggested":[120],"that":[121,260],"exciplex":[123,217],"chalcogen":[130],"atom":[131],"chalcogenorosamines":[134],"(the":[135],"pertelluoxide,":[137],"perselenoxide,":[138,214],"or":[139,148],"persulfoxide)":[140],"and/or":[141],"hydrated":[143],"perchalcogenoxide":[144],"[hydroxy":[145],"(perhydroxy)tellurane,":[146],"-selenane,":[147],"-thiane]":[149],"might":[150],"an":[152],"active":[153],"oxidant":[154],"formation":[157,202,210],".":[162],"Computational":[163],"methods":[164],"employed":[166],"provide":[168],"support":[169],"observed":[172,252],"reactivity":[174],"tellurorhodamine":[177],"selenorhodamine":[179],"chromophores":[180],"compared":[181],"chromophores.":[185],"\u0394":[186,233,245],"G":[187,234,246],"values":[188],"determined":[190],"hydration":[195,255],"10-Te,":[197],"10-Se,":[198],"10-S":[200],"perchalcogenoxides":[204],"hydroxyl(perhydroxy)chalcogenanes,":[206],"respectively.":[207,240],"Calculations":[208],"indicate":[209],"pertelluroxide":[213],"persulfoxide":[216],"are":[219],"energetically":[220],"favorable.":[221],"Hydration":[222],"exciplexes":[225],"10-Te":[227],"10-Se":[229],"have":[230],"similarly":[231],"small":[232],"\u22123.49":[236],"4.51":[238],"kcal/mol,":[239],"However,":[241],"significantly":[243],"higher":[244],"value":[247],"+22.4":[249],"kcal/mol":[250],"is":[251,264],"10-S,":[257],"suggests":[259],"reactive":[262],"intermediate":[263],"readily":[266],"formed.":[267]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2025,"cited_by_count":6},{"year":2024,"cited_by_count":3},{"year":2023,"cited_by_count":3},{"year":2022,"cited_by_count":9},{"year":2021,"cited_by_count":6},{"year":2020,"cited_by_count":5},{"year":2019,"cited_by_count":1}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2019-06-27T00:00:00"}
